共查询到19条相似文献,搜索用时 125 毫秒
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乙酰丙酸乙酯是一种潜在的生物质基平台化合物,在工业上具有很高的应用价值。乙酰丙酸乙酯传统的生产方法主要为间歇反应法,效率较低,产物分离困难且工艺流程较长。因此,本文提出了反应精馏工艺生产乙酰丙酸乙酯,在以中试实验结果为依据的基础上,使用Aspen Plus模拟软件建立了工艺流程,并考察了回流比、进料位置、进料摩尔比以及理论塔板数等关键参数,得到了常规单塔反应精馏工艺生产乙酰丙酸乙酯的最优配置。而后,为了得到纯度大于99.9%的乙酰丙酸乙酯,本文进一步提出了反应精馏双塔精制流程以及反应精馏隔壁塔流程,并通过对两种流程所得到的产品纯度以及能耗的对比,验证了反应精馏隔壁塔工艺生产乙酰丙酸乙酯的有效性以及在节能方面较大的优势。 相似文献
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《高校化学工程学报》2020,(2)
为了制备乙酰丙酸和乙酰丙酸酯两种新型平台化合物,今从工艺路线、原料、预处理和催化剂4个角度,对比阐述了乙酰丙酸和乙酰丙酸酯两类平台化合物在国内外的研究进展,综述了近年来生物质基制备乙酰丙酸和乙酰丙酸酯的研究趋势。首先分析了乙酰丙酸和乙酰丙酸酯的合成工艺路线的特点,列举了不同生物质原料在乙酰丙酸和乙酰丙酸酯中的应用,并对不同预处理方法对生物质制备乙酰丙酸和乙酰丙酸酯产率的影响进行了对比分析。进一步对不同种类催化剂在乙酰丙酸和乙酰丙酸酯的应用进行了总结。根据近年来生物质制备乙酰丙酸和乙酰丙酸酯的研究现状,展望了该研究领域的研究方向。 相似文献
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乙酰丙酸生产应用与开发前景 总被引:3,自引:0,他引:3
乙酰丙酸生产应用与开发前景棉子壳或玉米芯制糠醛后的残渣(糠醛渣)用稀酸加压水解可制得乙酰丙酸。另一种制法由糠醇经重排、水解而得。乙酰丙酸的应用范围很广,乙酰丙酸既可作为羧酸又可作为酮发生反应,通过酯化、卤化、加氢、氧化脱氢、缩合等,制取各种产品包括树脂、医药、香料、溶剂、涂料和油墨、橡胶和塑料助剂、润滑油添加剂、表面活性剂等,乙酰内酸也是农药、染料的中间体。乙酰内酸可制造水溶性树脂,应用于造纸工业生产过滤纸。乙酰丙酸的另一种重要衍生物是1,3-戊二烯,为合成橡胶的原料。以乙酰丙酸和糠醛为原料,可以制得癸二酸… 相似文献
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生物质原料淀粉在酸催化条件下,加热水解为葡萄糖,再脱水降解为5-羟甲基糠醛,最后降解成乙酰丙酸。综述了反应挤压法及螺杆挤压机工艺,碳水化合物物料连续水解工艺生产乙酰丙酸;采用树脂吸附法提纯乙酰丙酸。两种生产乙酰丙酸工艺适合商业化生产,生产成本低,易于产业化。据预测,以木薯淀粉为原料生产乙酰丙酸,建立年产50~500 t 的中试规模,技术上可能,经济上可行。 相似文献
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以木质纤维原料非均相催化转化制备高附加值平台化合物乙酰丙酸和乙酰丙酸酯为研究对象, 对以硫酸盐为催化体系的木质纤维定向转化生成乙酰丙酸和乙酰丙酸酯的国内外的研究进展和趋势进行了综述。文章概述了乙酰丙酸及乙酰丙酸酯在工业产业中的应用情况; 重点比较了不同硫酸盐催化木质纤维制备乙酰丙酸及乙酰丙酸酯的过程, 并对不同溶剂体系协同作用下的木质纤维转化为乙酰丙酸和乙酰丙酸酯过程的影响规律进行了深入分析, 总结了硫酸盐类催化剂催化木质纤维定向转化的过程机理。同时针对现有工艺存在的问题进行了分析, 展望了该研究领域的发展方向。 相似文献
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Smrati Sanghi Tejas Chirmade Snehal More Asmita Prabhune Vidya Gupta Narendra Kadoo 《Journal of the American Oil Chemists' Society》2019,96(8):945-954
Beauveria species are well-known insect pathogenic fungi, and Beauveria bassiana is used as a biopesticide against various pests in agriculture. However, the Beauveria species has not been reported as producers of microbial oils. In this study, Beauveria spp. MTCC 5184 was used to produce microbial oil with high linoleic acid (LA) content. Ten experiments were performed to evaluate the effects of several media parameters, such as carbon and nitrogen sources, pH, various concentrations of carbon and nitrogen, growth duration, and oleic acid (OLA) supplementation for maximum LA and dry biomass production by the fungus. Several of these parameters had a significant impact on the production of LA, as well as dry biomass. The glucose yeast extract (GYE) medium supplemented with 1.5% (w/v) peptone yielded maximum LA (0.32 ± 0.01 g L−1) and biomass (5.51 ± 0.26 g L−1). However, through the addition of 1.0% (w/v) OLA, the precursor of LA, LA production was enhanced 12-fold (1.24 ± 0.03 g L−1), and the biomass production increased by 5-fold (11.05 ± 0.46 g L−1) in comparison to those in the basal (GYE) medium. Using lactose as the sole carbon source produced the lowest LA (0.05 ± 0.00 g L−1) and biomass (1.04 ± 0.10 g L−1). The results of this study will be useful for the commercial exploitation of this fungus for the production of LA-rich microbial oil for use in the production of lubricants, greases, paints, cosmetics, etc. 相似文献
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《Fuel Processing Technology》2006,87(5):461-472
Hydrogen production plays a very important role in the development of hydrogen economy. One of the promising hydrogen production approaches is conversion from biomass, which is abundant, clean and renewable. Alternative thermochemical (pyrolysis and gasification) and biological (biophotolysis, water–gas shift reaction and fermentation) processes can be practically applied to produce hydrogen. This paper gives an overview of these technologies for hydrogen production from biomass. The future development will also be addressed. 相似文献
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目前开发氢能技术已具备了推广应用的基本条件,而发展生物质为原料的绿色氢能将有助于解决氢气来源绿色化与氢气储运成本两大问题。本文首先从解决氢能源发展制约因素、实现碳中和目标、加速生物质资源化能源化利用的角度阐述了发展生物质绿色氢能的意义。接着,从氢能产业的政策环境和技术成熟度分析出发,对我国氢能源的制取和储运技术发展现状及存在的问题进行了分析,比较高压、液氢和含氢化合物作为氢载体储运的几种方式,提出以生物质作为氢载体储运具有的突出优势。最后,探讨了生物质氢载体未来的发展方向,对氢生产和储运的多条技术路径成本和产业化前景进行了初步技术经济分析,指出以生物质为原料生产的甲烷、甲醇和乙醇有望成为最先实现产业化的储氢载体,在未来将有可能成为实现氢燃料电池“绿色化”的一种经济可行的方式。 相似文献
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The demand, production, supply and use of biomass in a future world after the depletion of fossil fuels is described. In a world without fossils, the limited biomass harvest is the only carbon source. Supply of food and feed has first priority. Demand, supply and use of biomass as the only carbon raw material for the production of a number of indispensable carbon products are analyzed. Bioenergy via combustion plays a significant, but not a decisive role, because the future energy mix is dominated by other renewables. Despite considerable uncertainties of the long‐term assessment, some clear hints for a reasonable further development of biomass technologies can be extracted. 相似文献
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The future industrial development of biomass energy depends on the application of renewable energy technology in an efficient manner. Of all the competing technologies under biomass, gasifiers are considered to be one of most viable applications. The use of biomass fuel, especially biomass wastes, for distributed power production can be economically viable in many parts of the world through gasification of biomass. Since biomass, is a clean and renewable fuel, gasification gives the opportunity to convert biomass into clean fuel gas or synthesis gas for industrial uses. The preparation of feedstock for a gasifier requires time, energy and labour and this has been a setback for gasifier technology development. The present work is focused on gasification of long-stick wood as a feed material for gasifiers. This application makes reduction not only in the cost but also on the power consumption of feed material preparation. A 50 m3/h capacity gasifier was fabricated in the cross draft mode. The cross draft mode makes it possible to produce low tar content in producer gas. This cross draft mode operates with 180 W of blower supply for air to produce 10 kW of thermal output. The initial bed heights of the long-stick wood and charcoal are 58 cm and 48 cm respectively. Results were obtained for various flow conditions with air flow rates ranging from 20 to 30 m3/h. For modelling, the flaming pyrolysis time for long-stick wood in the gasifier is calculated to be 1.6 min. The length of the flaming pyrolysis zone and char gasification zone is found to be 34 cm and 30 cm respectively. The rate of feed was between 9 and 10 kg/h. Continuous operation for 5 h was used for three runs to study the performance. In this study we measured the temperature and pressure in the different zones as a function of airflow. We measured the gas flow and efficiency of the gasifier in order to determine its commercial potential for process and power industries. 相似文献