Nutrient loss pathways from grazed grasslands and the effects of decreasing inputs: experimental results for three soil types

Agriculture is a main contributor of diffuse emissions of N and P to the environment. For N the main loss pathways are NH₃-volatilization, leaching to ground and surface water and N₂(O) emissions. Currently, imposing restraints on farm inputs are used as policy tool to decrease N and P leaching to ground water and to surface water, and the same measure is suggested to combat emissions of N₂O. The response, however, to these measures largely depends on the soil type. In this study nutrient flows of three dairy farms in The Netherlands with comparable intensity on sand, peat and clay soils were monitored for at least 2 years. The first aim was to provide quantitative data on current nutrient loss pathways. The second aim was to explore the responses in partitioning of the nutrient loss pathways when farm inputs were altered. Mean denitrification rates ranged from 103 kg N ha⁻¹ year⁻¹ for the sandy soil to 170 kg N ha⁻¹ year⁻¹ for the peat soil and leaching to surface water was about 73 kg N ha⁻¹ year⁻¹ for the sandy soil, 15 kg N ha⁻¹ year⁻¹ for the clay soil and 38 kg N ha⁻¹ year⁻¹ for the peat soil. For P, leaching to surface water ranged from 2 kg P ha⁻¹ year⁻¹ for the sandy site to 5 kg P ha⁻¹ year⁻¹ for the peat site. The sandy soil was most responsive to changes in N surpluses on leaching to surface water, followed by the peat soil and least responsive was the clay soil. For P, a similar sequence was found. This article demonstrates that similar reductions of N and P inputs result in different responses in N and P loss pathways for different soil types. These differences should be taken into account when evaluating measures to improve environmental performance of (dairy) farms.     

Long-term tillage,straw management and N fertilization effects on quantity and quality of organic C and N in a Black Chernozem soil

Soil, crop and fertilizer management practices may affect the amount and quality of organic C and N in soil. A long-term field experiment (growing barley, wheat, or canola) was conducted on a Black Chernozem (Albic Argicryoll) loam at Ellerslie, Alberta, Canada, to determine the influence of 19 (1980 to 1998) or 27 years (1980 to 2006) of tillage (zero tillage [ZT] and conventional tillage [CT]), straw management (straw removed [S_Rem]and straw retained [S_Ret]) and N fertilizer rate (0, 50 and 100 kg N ha⁻¹ in S_Ret and 0 kg N ha⁻¹ in S_Rem plots) on total organic C (TOC) and N (TON), and light fraction organic C (LFOC) and N (LFON) in the 0–7.5 and 7.5–15 cm or 0–5, 5–10 and 10–15 cm soil layers. The mass of TOC and TON in soil was usually higher in S_Ret than in S_Rem treatment (by 3.44 Mg C ha⁻¹ for TOC and 0.248 Mg N ha⁻¹ for TON after 27 years), but there was little effect of tillage and N fertilization on these parameters. The mass of LFOC and LFON in soil tended to increase with S_Ret (by 285 kg C ha⁻¹ for LFOC and 12.6 kg N ha⁻¹ for LFON with annual rate of 100 kg N ha⁻¹ for 27 years)_, increased with N fertilizer application (by 517 kg C ha⁻¹ for LFOC and 36.0 kg N ha⁻¹ for LFON after 27 years), but was usually higher under CT than ZT (by 451 kg C ha⁻¹ for LFOC and 25.3 kg N ha⁻¹ for LFON after 27 years). Correlations between soil organic C or N fractions were highly significant in most cases. Linear regressions between crop residue C input and soil organic C or N were significant in most cases. The effects of tillage, straw management and N fertilizer on soil were more pronounced for LFOC and LFON than TOC and TON, and also in the surface layers than in the deeper layers. Tillage and straw management had little or no effect on C:N ratios, but the C:N ratios in light organic fractions significantly decreased with increasing N rate (from 20.06 at zero-N to 18.91 at 100 kg N ha⁻¹). Compared to the 1979 results, in treatments that did not receive N fertilizer (CTS_Rem0, CTS_Ret0, ZTS_Rem0 and ZTS_Ret0), CTS_Rem0 resulted in a net decrease in TOC concentration (by 1.9 g C kg⁻¹) in the 0–15 cm soil layer in 2007 (after 27 years), with little or no change in the CTS_Ret0 and ZTS_Rem0 treatments, while there was a net increase in TOC concentration (by 1.2 g C kg⁻¹) in the ZTS_Ret0 treatment. Straw retention and N fertilizer application at 50 and 100 kg N ha⁻¹ rates showed a net positive effect on TOC concentration under both ZT (ZTS_Ret50 by 2.3 g C kg⁻¹ and ZTS_Ret100 by 3.1 g C kg⁻¹) and CT (CTS_Ret50 by 3.5 g C kg⁻¹ and CTS_Ret100 by 1.6 g C kg⁻¹) treatments in 2007 compared to 1979 data. In conclusion, the findings suggest that retention of straw, application of N fertilizer and elimination of tillage would improve soil quality, and this might increase the potential for N supplying power of the soil and sustainability of crop productivity.     

Soil nitrate-N levels required for high yield maize production in the North China Plain

High profile nitrate-nitrogen (N) accumulation has caused a series of problems, including low N use efficiency and environmental contamination in intensive agricultural systems. The key objective of this study was to evaluate summer maize (Zea mays L.) yield and N uptake response to soil nitrate-N accumulation, and determine soil nitrate-N levels to meet N demand of high yield maize production in the North China Plain (NCP). A total of 1,883 farmers’ fields were investigated and data from 458 no-N plots were analyzed in eight key maize production regions of the NCP from 2000 to 2005. High nitrate-N accumulation (≥172 kg N ha⁻¹) was observed in the top (0–90 cm) and deep (90–180 cm) soil layer with farmers’ N practice during maize growing season. Across all 458 no-N plots, maize grain yield and N uptake response to initial soil nitrate-N content could be simulated by a linear plus plateau model, and calculated minimal pre-planting soil nitrate-N content for maximum grain yield and N uptake was 180 and 186 kg N ha⁻¹, respectively, under no-N application conditions. Economically optimum N rate (EONR) decreased linearly with increasing pre-planting soil nitrate-N content (r ² = 0.894), and 1 kg soil nitrate-N ha⁻¹ was equivalent to 1.23 kg fertilizer-N ha⁻¹ for maize production. Residual soil nitrate-N content after maize harvest increased exponentially with increasing N fertilizer rate (P < 0.001), and average residual soil nitrate-N content at the EONR was 87 kg N ha⁻¹ with a range from 66 to 118 kg N ha⁻¹. We conclude that soil nitrate-N content in the top 90 cm of the soil profile should be maintained within the range of 87–180 kg N ha⁻¹ for high yield maize production. The upper limit of these levels would be reduce if N fertilizer was applied during maize growing season.     

Nitrogen balances of smallholder farms in major cropping systems in a peri-urban area of Beijing,China

An in-depth understanding of nutrient management variability on the regional scale is urgently required due to rapid changes in cropping patterns and farmers’ resource use in peri-urban areas of China. The soil surface nitrogen (N) balances of cereal, orchard and vegetable systems were studied over a 2-year period on smallholder fields in a representative peri-urban area of Beijing. Positive soil surface N balances were obtained across all three cropping systems. The mean annual N surplus of the vegetable system was 1,575 kg N ha⁻¹ year⁻¹, or approximately 3 times the corresponding values in the cereal (531 kg N ha⁻¹ year⁻¹) and orchard systems (519 kg N ha⁻¹ year⁻¹). In the vegetable system, animal manure (1,443 kg N ha⁻¹ year⁻¹ on average) was the major source of N input (65 % of the total N input) and the factor with strongest impact on the N surplus. In the cereal system, however, about 74 % of the total N input originated from mineral fertilizer application which was the major contributor to the N surplus, while in the orchard system, the N surplus was strongly and positively correlated with both mineral fertilizer and animal manure applications. Furthermore, within each cropping system, N fertilization, crop yields and N balances showed large variations among different smallholder fields, especially in orchard and vegetable systems. This study highlights that differences in farming practices within or among cropping systems should be taken into account when calculating nutrient balances and designing strategies of integrated nutrient management on a regional scale.     

Influence of organic amendments on growth, yield and quality of wheat and on soil properties during transition to organic production

A transition period of at least 2 years is required for annual crops before the produce may be certified as organically grown. The purpose of this study was to evaluate the effects of three organic amendments on the yield and quality of wheat (Triticum aestivum L.) and on soil properties during transition to organic production. The organic amendments were composted farmyard manure (FYMC), vermicompost and lantana (Lantana spp. L.) compost applied to soil at four application rates (60 kg N ha⁻¹, 90 kg N ha⁻¹, 120 kg N ha⁻¹ and 150 kg N ha⁻¹). The grain yield of wheat in all the treatments involving organic amendments was markedly lower (36–65% and 23–54% less in the first and second year of transition, respectively) than with the mineral fertilizer treatment. For the organic treatments applied at equivalent N rates, grain yield was higher for FYMC treatment, closely followed by vermicompost. In the first year of transition, protein content of wheat grain was higher (85.9 g kg⁻¹) for mineral fertilizer treatment, whereas, in the second year, there were no significant differences among the mineral fertilizer treatment and the highest application rate (150 kg N ha⁻¹) of three organic amendments. The grain P and K contents were, however, significantly higher for the treatments involving organic amendments than their mineral fertilizer counterpart in both years. Application of organic amendments, irrespective of source and rate, greatly lowered bulk density (1.14–1.25 Mg m⁻³) and enhanced pH (6.0–6.5) and oxidizable organic carbon (13–18.8 g kg⁻¹) of soil compared with mineral fertilizer treatment after a 2-year transition period. Mineral fertilized plots, however, had higher levels of available N and P than plots with organic amendments. All the treatments involving organic amendments, particularly at higher application rates, enhanced soil microbial activities of dehydrogenase, β-glucosidase, urease and phosphatase compared with the mineral fertilizer and unamended check treatments. We conclude that the application rate of 120 kg N ha⁻¹ and 150 kg N ha⁻¹ of all the three sources of organic amendments improved soil properties. There was, however, a 23–65% reduction in wheat yield during the 2 years of transition to organic production.     

Effects of fertilization on nutrient budget and nitrogen use efficiency of farmland soil under different precipitations in Northeastern China

Based on a consecutive 16-year field trial and meteorological data, the effects of fertilization on the nutrient budget and nitrogen use efficiency in farmland soil under different precipitation years were studied. With no fertilization treatment, the grain yield of maize was 3,520 kg ha⁻¹ (mean yield over 13 years). But the maximum yield increased to 7,470 kg ha⁻¹ when treated with mineral N, P and K fertilizers and recycled manure. The nutrient uptake also increased by twofold to threefold in NPKM treated field compared with that in the control treatment. The highest yields were obtained in years with normal precipitation, despite the different fertilization schemes. The lowest yields were obtained in drought or waterlogging years, which were 44.7–58.5% of the yields in years with normal precipitation. It also appeared that the deficits of N, P and K were greater in the years with proper precipitation than those in arid or flood years, because more production was removed from the field. Soil total N decreased significantly when treated with mineral fertilizer or recycled manure alone. The maximum deficit of soil total N was observed in control treatment (557 kg ha⁻¹) from 1990 to 2005. The N treatment resulted in a significant negative balance of P, due to the high yield of the crop in response to applied N. The application of NP or N to soils resulted in a greater negative K balance than that of the control. The greatest negative balance of total P and available P were obtained under the control and N treatment, and the highest deficit of soil total K and exchangeable K were obtained under NP treatment. We found that the rate of 150 kg N ha⁻¹ year⁻¹ was inadequate for maintaining soil N balance, and amendment of soil with organic source could not stop the loss of soil P and K. The applying rates of 150 kg N ha⁻¹ year⁻¹, 25 kg P ha⁻¹ year⁻¹, and 60 kg K ha⁻¹ year⁻¹ combined with 2–3 t ha⁻¹ organic manure were recommended to maintain soil fertility level. The nitrogen use efficiency (NUE) was greatly improved in the years with proper precipitation and balanced fertilization. Higher NUE and grain yields were achieved under NPK and NPKM treatments in years with normal precipitation. The results clearly demonstrated that both organic and mineral fertilizers were needed to increase crop production, improve NUE and maintain soil fertility level.     

Agro-ecological nitrogen management in soils vulnerable to nitrate leaching: a case study in the Lower Suwannee Watershed

Environmental benefits associated with reduced rates of nitrogen (N) application, while maintaining economically optimum yields have economic and social benefits. Although N is an indispensable plant nutrient, residual soil N could leach out to contaminate groundwater and surface water resources, particularly in sandy soils. A 2-year field study was conducted in an established bermudagrass (Cynodon dactylon) pasture in the Lower Suwannee Watershed, Florida, to evaluate N application rates on forage yield, forage quality, and nitrate (NO₃-N) leaching in rapidly permeable upland sandy soils. Four N application rates (30, 50, 70, and 90 kg N ha⁻¹ harvest⁻¹) corresponding to 0.33, 0.55, 0.77 and IX, respectively, of recommended N rate (90 kg N ha⁻¹ harvest⁻¹) for bermudagrass hay production in Florida were evaluated vis-à-vis an unfertilized (0 N) control. Suction cups were installed near the center of each plot at two depths (30 and 100 cm) to monitor NO₃-N leaching. The grass was harvested at 28 days intervals to determine dry matter yield, N uptake, and herbage nutritive value. Nitrogen application at the recommended rate produced the greatest total dry matter yield (~18.4 Mg ha⁻¹ year⁻¹), but a modeled economically optimum N rate of ~57 kg N ha⁻¹ harvest⁻¹ (~60% of the recommended N rate) projected an average dry matter yield of ~17.3 Mg ha⁻¹ year⁻¹, which represents >90% of the observed maximum yield. Nitrogen application increased nutritive quality of the grass, but increases in N application rate above 30 kg N ha⁻¹ did not result in significant increases in in vitro digestible organic matter concentration, and tissue crude protein was not significant above 50 kg N ha⁻¹. Across the sampling period, treatments with N rates ≤50 kg N ha⁻¹ harvest⁻¹ had leachate NO₃-N concentration below the maximum contaminant limit of <10 mg l⁻¹. Conversely, applying N at rates ≥70 kg N ha⁻¹ harvest⁻¹ resulted in leachate N concentration that exceeded the maximum contaminant limit, and suggest high risk of impacting groundwater quality, if such rates are applied to soils with coarse (sand) textures. The study demonstrates that recommendation of a single N application rate may not be appropriate under all agro-climatic conditions and, thus, a site-specific evaluation of best N management strategy is critical.     

Utilization of liquid hog manure to fertilize grasslands in southeast Manitoba: impact of application timing and forage harvest strategy on nutrient utilization and accumulation

Liquid hog manure (LHM) is used to improve productivity of grasslands in western Canada. However, application of manure to meet crop N requirements can result in excessive accumulation of P, especially in grazing systems. A three-year study was carried out to assess the impact of timing of liquid hog manure application and harvest strategy on nutrient utilization and accumulation by grasslands in southeast Manitoba. Liquid hog manure was applied annually at a full rate of 142 ± 20 kg available N ha⁻¹ in spring (Single application) or as two half rate applications of 70 ± 6 kg available N ha⁻¹, one in fall and one in spring (Split application). Two harvest strategies, haying and grazing, were employed to export nutrients from grasslands. Spring-applied manure averaged 8.9% dry matter, 5.7 g total N L⁻¹, 1.5 g total P L⁻¹, and 2.1 g total K L⁻¹ and fall-applied manure from the same source averaged 3.9% dry matter, 4.4 g total N L⁻¹, 0.7 g total P L⁻¹, and 2.2 g total K L⁻¹. Manure application based on grass N requirements resulted in at least two times more P and K applied than recommended for Manitoba grasslands. Nutrient (N, P, and K) export from grasslands was five times higher when grass forage was harvested as hay than through grazing. Average nutrient utilization when forage was harvested as hay was 153 kg N ha⁻¹, 18 kg P ha⁻¹, and 123 kg K ha⁻¹ and was higher in the years with increased precipitation. Grazing was not effective in removing nutrients from grasslands as indicated by lower N, P, and K utilization efficiency (% applied nutrient) in grazed (30% for N, 7% for P, and 18% for K) relative to hayed (75% for N 32% for P, and 103% for K) paddocks. Nutrient accumulation was impacted by a combination of harvest strategy and timing of manure application. Both single and split applications increased soil extractable nutrients, but soil extractable nutrients were higher in grazed relative to hayed paddocks following single manure application. After 3 years of manure application, the amount of Olsen-P (62 kg ha⁻¹) exceeded that required for optimal forage growth. However, soil levels did not exceed the soil Olsen-P regulatory threshold (60 mg kg⁻¹) that restricts manure P applications in Manitoba. An analysis of P balance, for this particular soil, indicated that a surplus of 18.9 kg manure P ha⁻¹ (in excess of forage P exported as hay or weight gain) increased the soil Olsen-P concentration by 1 mg kg⁻¹. Nutrient utilization and accumulation will be impacted by timing of manure application and harvest strategy employed as well as amount of precipitation received during the growing season.     

Emissions of N<Subscript>2</Subscript>O from fertilized and grazed grassland on organic soil in relation to groundwater level

Intensively managed grasslands on organic soils are a major source of nitrous oxide (N₂O) emissions. The Intergovernmental Panel on Climate Change (IPCC) therefore has set the default emission factor at 8 kg N–N₂O ha⁻¹ year⁻¹ for cultivation and management of organic soils. Also, the Dutch national reporting methodology for greenhouse gases uses a relatively high calculated emission factor of 4.7 kg N–N₂O ha⁻¹ year⁻¹. In addition to cultivation, the IPCC methodology and the Dutch national methodology account for N₂O emissions from N inputs through fertilizer applications and animal urine and faeces deposition to estimate annual N₂O emissions from cultivated and managed organic soils. However, neither approach accounts for other soil parameters that might control N₂O emissions such as groundwater level. In this paper we report on the relations between N₂O emissions, N inputs and groundwater level dynamics for a fertilized and grazed grassland on drained peat soil. We measured N₂O emissions from fields with different target groundwater levels of 40 cm (‘wet’) and 55 cm (‘dry’) below soil surface in the years 1992, 1993, 2002, 2006 and 2007. Average emissions equalled 29.5 kg N₂O–N ha⁻¹ year⁻¹ and 11.6 kg N–N₂O ha⁻¹ year⁻¹ for the dry and wet conditions, respectively. Especially under dry conditions, measured N₂O emissions exceeded current official estimates using the IPCC methodology and the Dutch national reporting methodology. The N₂O–N emissions equalled 8.2 and 3.2% of the total N inputs through fertilizers, manure and cattle droppings for the dry and wet field, respectively and were strongly related to average groundwater level (R ² = 0.74). We argue that this relation should be explored for other sites and could be used to derive accurate emission data for fertilized and grazed grasslands on organic soils.     

Conservation tillage,local organic resources and nitrogen fertilizer combinations affect maize productivity,soil structure and nutrient balances in semi-arid Kenya

Smallholder land productivity in drylands can be increased by optimizing locally available resources, through nutrient enhancement and water conservation. In this study, we investigated the effect of tillage system, organic resource and chemical nitrogen fertilizer application on maize productivity in a sandy soil in eastern Kenya over four seasons. The objectives were to (1) determine effects of different tillage-organic resource combinations on soil structure and crop yield, (2) determine optimum organic–inorganic nutrient combinations for arid and semi-arid environments in Kenya and, (3) assess partial nutrient budgets of different soil, water and nutrient management practices using nutrient inflows and outflows. This experiment, initiated in the short rainy season of 2005, was a split plot design with 7 treatments involving combinations of tillage (tied-ridges, conventional tillage and no-till) and organic resource (1 t ha⁻¹ manure + 1 t ha⁻¹ crop residue and; 2 t ha⁻¹ of manure (no crop residue) in the main plots. Chemical nitrogen fertilizer at 0 and 60 kg N ha⁻¹ was used in sub-plots. Although average yield in no-till was by 30–65% lower than in conventional and tied-ridges during the initial two seasons, it achieved 7–40% higher yields than these tillage systems by season four. Combined application of 1 t ha⁻¹ of crop residue and 1 t ha⁻¹ of manure increased maize yield over sole application of manure at 2 t ha⁻¹ by between 17 and 51% depending on the tillage system, for treatments without inorganic N fertilizer. Cumulative nutrients in harvested maize in the four seasons ranged from 77 to 196 kg N ha⁻¹, 12 to 27 kg P ha⁻¹ and 102 to 191 kg K ha⁻¹, representing 23 and 62% of applied N in treatments with and without mineral fertilizer N respectively, 10% of applied P and 35% of applied K. Chemical nitrogen fertilizer application increased maize yields by 17–94%; the increases were significant in the first 3 seasons (P < 0.05). Tillage had significant effect on soil macro- (>2 mm) and micro-aggregates fractions (<250 μm >53 μm: P < 0.05), with aggregation indices following the order no-till > tied-ridges > conventional tillage. Also, combining crop residue and manure increased large macro-aggregates by 1.4–4.0 g 100 g⁻¹ soil above manure only treatments. We conclude that even with modest organic resource application, and depending on the number of seasons of use, conservation tillage systems such as tied-ridges and no-till can be effective in improving crop yield, nutrient uptake and soil structure and that farmers are better off applying 1 t ha⁻¹ each of crop residue and manure rather than sole manure.     

Quantification of seasonal soil nitrogen mineralization for corn production in eastern Canada

Precise estimation of soil nitrogen (N) supply to corn (Zea mays L.) through N mineralization plays a key role in implementing N best management practices for economic consideration and environmental sustainability. To quantify soil N availability to corn during growing seasons, a series of in situ incubation experiments using the method of polyvinyl chloride tube attached with resin bag at the bottom were conducted on two typical agricultural soils in a cool and humid region of eastern Canada. Soil filled tubes were retrieved at 10-d intervals within 2 months after planting, and at 3- to 4-week intervals thereafter until corn harvest. Ammonium and nitrate in the soil and resin part of the incubation tubes were analyzed. In general, there was minimal NH₄⁺-N with ranges from 1.5 to 7.3 kg N ha⁻¹, which was declined in the first 30 d and fluctuated thereafter. Nitrate, the main form of mineral N, ranged from 20 to 157 kg N ha⁻¹. In the first 20–50 d, main portion of the NO₃⁻-N was in the soil and thereafter in the resin, reflecting the movement of NO₃⁻ in the soil, which was affected by rainfall events and amount. Total mineralized N was affected by soil total N and weather conditions: There was more total mineralized N in the soil with higher total N, and rainy weather stimulated N mineralization. The relationship between the accumulated mineral N and accumulated growing degree-days (GDD) fitted well into first order kinetic models. The accumulated mineralized soil N during corn growing season ranged from 96 to 120 kg N ha⁻¹, which accounted for 2–3% of soil total N. Corn plants took up 110–137 kg N ha⁻¹. While the mineralized N and crop uptake were in the same magnitude, a quantitative relationship between them could not be established in this study.     

The O<Subscript>2</Subscript> + NH<Subscript>3</Subscript> Reaction Over Rh(110): Steady State Kinetics and Oscillatory Behavior

Abstract  

The kinetics of ammonia oxidation with oxygen over a Rh(110) surface were studied in the pressure range 10⁻⁵–10⁻⁴ mbar. Nitrogen was found to be the preferred product at low partial pressures ratios \textp_{\texto 2} :\textp_{\textNH 3} {\text{p}}_{{{\text{o}}_{ 2} }} :{\text{p}}_{{{\text{NH}}_{ 3} }} , while the NO pathway was favored with oxygen rich gas mixtures and at high temperature. The reactive sticking coefficient of O₂ reaches up to 0.05 under steady state conditions. Pronounced hysteresis effects in the reaction rates were found in T-cycling experiments. Sustained oscillations in the reaction rates occurred under isothermal conditions at T = 620 K at a total pressure of 4 × 10⁻⁵ mbar.     

Effects of mulch,N fertilizer,and plant density on wheat yield,wheat nitrogen uptake,and residual soil nitrate in a dryland area of China

Understanding mulching influences on nitrogen (N) activities in soil is important for developing N management strategies in dryland. A 3 year field experiment was conducted in the Loess Plateau of China to investigate the effects of mulching, N fertilizer application rate and plant density on winter wheat yield, N uptake by wheat and residual soil nitrate in a winter wheat-fallow system. The split plot design included four mulching methods (CK, no mulch; SM, straw mulch; FM, plastic film mulch; CM, combined mulch with plastic film and straw) as main plot treatments. Three N fertilizer rates (N0, 0 kg N ha⁻¹; N120, 120 kg N ha⁻¹; N240, 240 kg N ha⁻¹) were sub-plot treatments and two wheat sowing densities (LD, low density, seeding rate = 180 kg ha⁻¹; HD, high density, seeding rate = 225 kg ha⁻¹) were sub-subplot treatments. The results showed that wheat yield, N uptake, and N use efficiency (NUE) were higher for FM and CM compared to CK. However, soil nitrate-N contents in the 0–200 cm soil profile were also higher for FM and CM compared to CK after the 3 year experiment. Wheat grain yields were higher for SM compared to CK only when high levels of nitrogen or high planting density were applied. Mulching did not have a significant effect on wheat yield, nitrogen uptake and NUE when soil water content at planting was much high. Wheat yield, N uptake, and residual nitrate in 0–200 cm were significantly higher for N240 compared to N120 and N0. Wheat yield and N uptake were also significantly higher for HD compared to LD. When 0 or 120 kg N ha⁻¹ was applied, HD had more residual nitrate than LD while the reverse was true when 240 kg N ha⁻¹ was applied. After 3 years, residual nitrate-N in 0–200 cm soil averaged 170 kg ha⁻¹, which was equivalent to ~40% of the total N uptake by wheat in the three growing seasons.     

Looking beyond fertilizer: assessing the contribution of nitrogen from hydrologic inputs and organic matter to plant growth in the cranberry agroecosystem

Even though nitrogen (N) is a key nutrient for successful cranberry production, N cycling in cranberry agroecosystems is not completely understood. Prior research has focused mainly on timing and uptake of ammonium fertilizer, but the objective of our study was to evaluate the potential for additional N contributions from hydrologic inputs (flooding, irrigation, groundwater, and precipitation) and organic matter (OM). Plant biomass, soil, surface and groundwater samples were collected from five cranberry beds (cranberry production fields) on four different farms, representing both upland and lowland systems. Estimated average annual plant uptake (63.3 ± 22.5 kg N ha⁻¹ year⁻¹) exceeded total average annual fertilizer inputs (39.5 ± 11.6 kg N ha⁻¹ year⁻¹). Irrigation, precipitation, and floodwater N summed to an average 23 ± 0.7 kg N ha⁻¹ year⁻¹, which was about 60% of fertilizer N. Leaf and stem litterfall added 5.2 ± 1.2 and 24.1 ± 3.0 kg N ha⁻¹ year⁻¹ respectively. The estimated net N mineralization rate from the buried bag technique was 5 ± 0.2 kg N ha⁻¹ year⁻¹, which was nearly 15% of fertilizer N. Dissolved organic nitrogen represented a significant portion of the total N pool in both surface water and soil samples. Mixed-ion exchange resin core incubations indicated that 80% of total inorganic N from fertilizer, irrigation, precipitation, and mineralization was nitrate, and approximately 70% of recovered inorganic N from groundwater was nitrate. There was a weak but significant negative relationship between extractable soil ammonium concentrations and ericoid mycorrhizal colonization (ERM) rates (r = −0.22, P < 0.045). Growers may benefit from balancing the N inputs from hydrologic sources and OM relative to fertilizer N in order to maximize the benefits of ERM fungi in actively mediating N cycling in cranberry agroecosystems.     

Crop production,soil carbon and nutrient balances as affected by fertilisation in a Mollisol agroecosystem

A 19-year field experiment on a Mollisol agroecosystem was carried out to study the productivity of a wheat-maize-soybean rotation and the changes in soil carbon and nutrient status in response to different fertiliser applications in Northeast China. The experiment consisted of seven fertiliser treatments: (1) unfertilised control, (2) annual application of P and K fertilisers, (3) N and K fertilisers, (4) N and P fertilisers, (5) N, P and K fertilisers, (6) N, K and second level P fertilisers, and (7) N, P and second level K fertilisers. Without fertiliser, the Mollisols could support an average yield of 1.88 t ha⁻¹ for wheat, 3.89 t ha⁻¹ for maize and 2.12 t ha⁻¹ for soybean, compared to yields of 3.20, 9.30 and 2.45 t ha⁻¹ respectively for wheat, maize and soybean if the crop nutrient demands were met. At the potential yield level, the N, P and K removal by wheat are 79 kg N ha⁻¹, 15 kg P ha⁻¹, and 53 kg K ha⁻¹, by maize are 207 kg N ha⁻¹, 47 kg P ha⁻¹, and 180 kg K ha⁻¹, by soybean are 174 kg N ha⁻¹, 18 kg P ha⁻¹, and 55 kg K ha⁻¹. Crop yield, change in soil organic carbon (SOC), and the total and available nutrient status were used to evaluate the fertility of this soil over different time periods. This study showed that a fertiliser strategy that was able to maintain yields in the short term (19 years) would not maintain the long term fertility of these soils. Although organic carbon levels did not rise to the level of virgin soil in any treatment, a combination of N, P and K fertiliser that approximated crop export was required to stabilise SOC and prevent a decline in the total store of soil nutrients.     

Two New Organic–Inorganic Hybrids Based on [SiW12O40]4? Anion: Hydrothermal Syntheses, Crystal Structures, and Electrochemical Properties

Two new organic–inorganic hybrid compounds [\textCu^\textI ( \texten ) ₂ ( \textH ₂ \textO )] ₂ { ( \textSiW^\textVI _{1 1} \textW^\textV ₁\textO ₄₀ ) ₂ [ \textCu^\textII ( \texten ) ₂ ( \textH ₂ \textO )] ₂ [\textCu^\textII ( \texten ) ₂ ] ₂ }·6 \textH ₂ \textO [{\text{Cu}}^{\text{I}} \left( {\text{en}} \right)_{ 2} \left( {{\text{H}}_{ 2} {\text{O}}} \right)]_{ 2} \left\{ {\left( {{\text{SiW}}^{\text{VI}}_{ 1 1} {\text{W}}^{\text{V}}_{ 1}{\text{O}}_{ 40} } \right)_{ 2} \left[ {{\text{Cu}}^{\text{II}} \left( {\text{en}} \right)_{ 2} \left( {{\text{H}}_{ 2} {\text{O}}} \right)\left] {_{ 2} } \right[{\text{Cu}}^{\text{II}} \left( {\text{en}} \right)_{ 2} } \right]_{ 2} } \right\}{\cdot}6 {\text{H}}_{ 2} {\text{O}} (1) and (H₂ L)₂[SiW₁₂O₄₀]·H₂O (2) [en = ethylenediamine, L = 1,4-bis(3-pyridinecarboxamido)benzene], have been hydrothermally synthesized and characterized by IR, elemental analyses, TG analysis, and single-crystal X-ray diffraction. Structural analyses indicate that compound 1 exhibits an interesting three-dimensional(3D) cross-like supramolecular network through arrangement of a 1D organic–inorganic hybrid chain { ( \textSiW^\textVI _{1 1} \textW^\textV ₁ \textO ₄₀ ) ₂ [ \textCu^\textII ( \texten ) ₂ ( \textH ₂ \textO )] ₂ [\textCu^\textII ( \texten ) ₂ ] ₂ } ^2- . \left\{ {\left( {{\text{SiW}}^{\text{VI}}_{ 1 1} {\text{W}}^{\text{V}}_{ 1} {\text{O}}_{ 40} } \right)_{ 2} \left[ {{\text{Cu}}^{\text{II}} \left( {\text{en}} \right)_{ 2} \left( {{\text{H}}_{ 2} {\text{O}}} \right)\left] {_{ 2} } \right[{\text{Cu}}^{\text{II}} \left( {\text{en}} \right)_{ 2} } \right]_{ 2} } \right\}^{ 2- } . The compound 2 consists of protonated L ligand and [SiW₁₂O₄₀]⁴⁻ anion. The protonated L ligands have been extended into a 2D network via hydrogen-bonding interactions. The guest [SiW₁₂O₄₀]⁴⁻ clusters have been incorporated into the square voids of the 2D host network as templates. The electrochemical behavior and electrocatalysis of compound 2 bulk-modified carbon paste electrode (2-CPE) have been studied.     

Soil organic carbon fractions after 16-years of applications of fertilizers and organic manure in a Typic Rhodalfs in semi-arid tropics

Agricultural soils can act as a potential sink of the increased carbon dioxide in the atmosphere if managed properly by application of organic manures and balanced fertilizers. However, the rate of carbon (C) sequestration in soils is low in warm climates and thus the short term changes in soil organic carbon (SOC) contents are almost negligible. Therefore, the knowledge about other C fractions that are more sensitive or responsive and indicative of the early changes in SOC can help to determine the effect of the management practices on soil C sequestration. The objective of this study was to determine the soil C sequestration after 16-years of applications of chemical fertilizers and farmyard manure (FYM) to rice (Oryza sativa)—cowpea (Vigna unguiculata) rotation system in a sandy loam soil (Typic Rhodalfs). The treatments were—(1) one control (no fertilizer or FYM); (2) three chemical fertilizer treatments [100 kg N ha⁻¹ (N), 100 kg N ha⁻¹ + 50 kg P₂O₅ ha⁻¹ (NP), 100 kg N ha⁻¹ + 50 kg P₂O₅ ha⁻¹ + 50 kg K₂O ha⁻¹ (NPK)]; (3) one integrated treatment [(50 kg N ha⁻¹ + 25 kg P₂O₅ ha⁻¹ + 25 K₂O ha⁻¹) + (50 kg N ha⁻¹ from FYM)]; and (4) one organic treatment at10 Mg ha⁻¹ FYM. Compared to the control treatment, the increase in SOC was 36, 33, and 19% greater in organic, integrated, and NPK treatments. The 16-years application of fertilizers and/or FYM resulted in much greater changes in water soluble C (WSC), microbial biomass C (MBC), light fraction of C (LFC), and particulate organic matter (POM) than SOC. Of the SOC, the proportion of POM was highest (24–35%), which was followed by LFC (12–14%), MBC (4.6–6.6%), and WSC (0.6–0.8%). The application of fertilizers and/or FYM increased the mean weight diameter of soil aggregates; thus provided physical protection to SOC from decomposition. Our results suggests that the application of fertilizers and/or FYM helps to sequester C in the soil and that the labile fractions of C can be used as indicators to determine the amount of C sequestered as a result of different management practices.     

Recovery of mineral fertiliser N and slurry N in continuous silage maize using the <Superscript>15</Superscript>N and difference methods

The stable isotope technique and the difference method are common approaches for estimating fertiliser N uptake efficiency. Both methods, however, have limitations and their suitability may depend on N management and environmental conditions. A field experiment was conducted on a humus sandy soil in northern Germany to estimate fertiliser N uptake efficiency of silage maize in the year of application (Zea mays L.) by the stable isotope and the difference method as influenced by the type of N fertiliser (mineral vs. cattle slurry), the application mode (separate or combined application), and N rate. Seven N treatments were included (0, 50, 100 and 150 kg mineral N ha⁻¹; 20, 40 m3 cattle slurry ha⁻¹; 50 kg mineral N ha⁻¹ plus 40 m3 slurry ha⁻¹), where either mineral N or slurry N was labelled, and mineral N was split into two dressings. In addition, 4.1 kg ha⁻¹ labelled mineral N was incorporated into otherwise unlabelled treatments (0, 20, 40 m3 ha⁻¹, and 50 kg mineral N ha⁻¹ plus 40 m3 ha⁻¹) to estimate N uptake from the upper soil layer. Uptake of ¹⁵N was followed in leaves, stalk, ear, and the whole crop. Fertiliser N uptake efficiency (FNUE_15N) of mineral fertiliser N obtained by the isotope technique ranged between 51 and 61%. Recovered fertiliser N was mainly found in the ear, while less labelled N remained in leaves and the stalk. The nitrogen rate tended to increase the amount of recovered N, but the effect was not consistent among plant parts and the whole crop. Plant N uptake from non-fertiliser N was found to increase N input up to 100 kg N ha⁻¹. Nitrogen recoveries of the two mineral N dressings were similar for the different plant parts as well as for the whole crop. Fertiliser N uptake efficiency (FNUE_diff) of mineral N estimated by the difference method resulted in substantially higher values compared to FNUE_15N, varying between 56 and 98%. More N was taken up from the upper soil layer with increasing N supply, which is regarded as a major error source of the difference method. Slurry N was taken up less efficient in the year of application than mineral fertiliser N as indicated by recovery rates of 21–22% (FNUE_15N) and 39–62% (FNUE_diff), respectively. When mineral N and slurry were applied together, the difference method estimated significantly lower N uptake efficiencies for both mineral and slurry N compared to a single application, while values obtained by the isotope method were not affected.     

Green leaf manuring with prunings of Leucaena leucocephala for nitrogen economy and improved productivity of maize (Zea mays)–wheat (Triticum aestivum) cropping system

Green leaf manuring with prunings of Leucaena leucocephala is regarded as a useful source of N to plants but the actual substitution of N fertilizer, release and recovery of N as well as effects on soil fertility are not adequately studied. The present studies investigated the effect of sole and combined use of Leucaena prunings and urea N fertilizer in different proportions on productivity, profitability, N uptake and balance in maize (Zea mays)–wheat (Triticum aestivum) cropping system at New Delhi during 2002–2003 and 2003–2004. Varying quantities of Leucaena green leaf biomass containing 3.83–4.25% N (18.2–20.5 C:N ratio) were applied to provide 0, 25, 50, 75 and 100% of recommended N (120 kg ha⁻¹) to both maize and wheat before sowing. In general, direct application of urea N increased the productivity of both crops more than Leucaena green leaf manure, but the reverse was true for the residual effect of these sources. The productivity of maize increased progressively with increasing proportions of N through urea fertilizer and was 2.41–2.52 t ha⁻¹ with 60 kg N ha⁻¹ each applied through Leucaena and urea, which was at par with that obtained with 120 kg N ha⁻¹ through urea alone (2.56–2.74 t ha⁻¹). Similarly, wheat yield was also near maximum (4.46–5.11 t ha⁻¹) when equal amounts of N were substituted through Leucaena and urea. Residual effects were obtained on the following crops and were significant when greater quantity of N (>50%) was substituted through Leucaena. Nitrogen uptake and recovery were also maximum with urea N alone, and N recovery was higher in maize (33.4–42.1%) than in wheat (27.3–29.8%). However, recovery of residual N in the following crop was more from Leucaena N alone (8.5–10.3%) than from urea fertilizer (1.7–3.8%). Residual soil fertility in terms of organic C and KMnO₄ oxidizable N showed improvement with addition of Leucaena prunings, which led to a positive N balance at the end of second cropping cycle. Net returns were considerably higher with wheat than with maize, and were comparatively lower with greater proportion of Leucaena because of its higher cost. Nonetheless, it was beneficial to apply Leucaena and urea on equal N basis for higher productivity and sustainability of this cereal-based cropping system.     

Horizontal nutrient fluxes and food safety in urban and peri-urban vegetable and millet cultivation of Niamey,Niger

Urban and peri-urban agriculture (UPA) has often been accused of being nutrient inefficient and producing negative externalities. To investigate these problems for the West African capital Niamey (Niger), nutrient inputs through fertilizer and manure to 10 vegetable gardens and 9 millet fields and nutrient offtakes through harvests were quantified during 24 months, and contamination of irrigation water and selected vegetables with faecal pathogens and heavy metals was determined. Annual partial horizontal balances for carbon (C), nitrogen (N), phosphorus (P) and potassium (K) amounted to 9,936 kg C ha⁻¹, 1,133 kg N ha⁻¹, 223 kg P ha⁻¹ and 312 kg K ha⁻¹ in high input vegetable gardens as opposed to 9,580 kg C ha⁻¹, 290 kg N ha⁻¹, 125 kg P ha⁻¹ and 351 kg K ha⁻¹ in low input gardens. In high input millet fields, annual surpluses of 259 kg C ha⁻¹, 126 kg N ha⁻¹, 20 kg P ha⁻¹ and 0.4 kg K ha⁻¹ were recorded, whereas surpluses of 12 kg C ha⁻¹, 17 kg N ha⁻¹, and deficits of −3 kg P ha⁻¹ and −3 kg K ha⁻¹ were determined for low input fields. Counts of Salmonella spp. and Escherichia coli yielded above threshold contamination levels of 7.2 × 10⁴ CFU 25 g⁻¹ and 3.9 × 10⁴ CFU g⁻¹ in lettuce irrigated with river water and fertilized with animal manure. Salmonella counts averaged 9.8 × 10⁴ CFU 25 g⁻¹ and E. coli 0.6 × 10⁴ CFU g⁻¹ for lettuce irrigated with wastewater, while these pathogens were not detected on vegetables irrigated with pond water. These results underline the need for urban gardeners to better adjust the nutrients applied to crop requirements which might also reduce nutrient accumulations in the soil and further in the edibles parts of the vegetables. Appropriate pre-treatment of irrigation water would help improve the quality of the latter and enhance the food safety of vegetables determined for the urban markets.