共查询到20条相似文献,搜索用时 156 毫秒
1.
《精细与专用化学品》2015,(9)
采用两步模板法,通过制备二氧化硅胶体晶体模板,以钛酸异丙酯为钛源和三嵌段共聚物P123为介孔导向合成介孔钛硅氧化物光子晶体微球光催化剂。采用扫描电子显微镜(SEM)、透射电子显微镜(TEM)、高分辨透射电子显微镜(HRTEM)对制得的薄膜材料的结构进行表征。结果表明,介孔复合薄膜中锐钛矿型TiO2纳米粒子均匀排列。以罗丹明B为模型物,考察其在紫外光区的光催化活性。结果表明,钛硅氧化物光催化剂降解效果比普通TiO2薄膜有所提高。 相似文献
2.
采用溶胶-凝胶/旋转涂覆法在玻璃基板表面制备含钛介孔SiO2薄膜.利用XRD、UV-Vis以及接触角测量仪对薄膜的孔结构和超亲水性进行表征.结果表明,当Ti/Si物质的量比为0~0.05时,薄膜均具有良好的介孔结构;而随着Ti/Si物质的量比的增加,薄膜的介孔有序度下降.即使在无光照条件下,含钛介孔SiO2薄膜也表现出高效的超亲水性.涂有油酸的薄膜在紫外光照射后恢复其超亲水性,且薄膜对甲基橙具有良好的光催化降解效果,表明制备的含钛介孔SiO2薄膜具有良好的自洁净性能. 相似文献
3.
光催化制备结晶TiO_2介孔薄膜及其性能表征(英文) 总被引:1,自引:0,他引:1
提出了一种在室温条件下制备结晶TiO2介孔薄膜的简便方法。首先采用含有罗丹明B的TiO2纳米晶溶胶通过浸渍提拉制备结晶TiO2薄膜,然后将薄膜置于紫外灯下照射,通过TiO2薄膜自身的光催化作用将薄膜中的罗丹明B分解去除,从而形成介孔薄膜。分别采用X射线衍射仪、扫描电子显微镜和透射电子显微镜对样品进行了表征,并考察了薄膜对水的接触角及光催化活性。结果表明:所制备的TiO2介孔薄膜由30~50nm的纳米粒子组成,其晶型为锐钛矿-板钛矿-金红石混晶;适当的罗丹明B添加量有利于介孔形成;由于介孔的作用,TiO2介孔薄膜的亲水性及光催化活性相对于致密TiO2薄膜有显著提高。 相似文献
4.
5.
6.
7.
《化工进展》2017,(5)
以自制双亚胺硅烷偶联剂和正硅酸乙酯为硅源,十六烷基三甲基溴化铵(CTAB)/聚丙烯酸钠(PAANa)为混合模板剂,通过共缩聚法合成桥连双亚胺席夫碱功能化介孔材料。利用红外光谱(FTIR)、氮气吸附-脱附、X射线衍射(XRD)、扫描电子显微镜(SEM)和透射电子显微镜(TEM)对桥连双亚胺介孔材料进行了表征,着重探讨了不同PAANa用量对介孔材料的结构和形貌的影响,并将其应用于重金属离子的吸附。结果表明,PAANa用量对桥连双亚胺介孔材料的比表面积、孔容积和有序度都有一定的影响;当PAANa的加入量为0.01%时,功能化介孔材料(PMOS_(0.01))展现出较好的形貌、有序度和比表面积。此外,在酸性条件下,PMOS_(0.01)对Cr(Ⅵ)的吸附量为289.24mg/g;而在碱性条件下,PMOS_(0.01)对Cu(Ⅱ)的吸附量为276mg/g。 相似文献
8.
电子显微镜研究分子筛的新进展 总被引:1,自引:0,他引:1
电子显微镜在沸石分子筛的研究中起着重要的作用.阐述了透射电子显微镜(TEM)和扫描电子显微镜(SEM)技术研究沸石分子筛的原理,描述了使用不同种类的电子显微镜剖析沸石分子筛的形态、尺寸、粒径分布等,并介绍了近年来电镜技术对沸石分子筛,特别是对新型功能介孔材料及手性介孔材料的研究进展.电子显微镜的发展将推动分子筛及纳米材料在选择性催化/吸附过程中的应用. 相似文献
9.
以介孔材料SBA-15为模版,采用硬模版法制备了有序介孔氧化铁,并对其催化过氧化氢(H2O2)降解水中有机污染物效能与机理进行了研究。采用X射线衍射(XRD)、透射电子显微镜(TEM)、氮气吸附-脱附、X射线荧光(XRF)、X射线光电子能谱(XPS)等分析手段对介孔氧化铁进行表征。以诺氟沙星为目标物,利用介孔氧化铁催化H2O2降解水中有机污染物效能,研究了溶液初始p H、H2O2初始投加量和催化剂初始投加量对反应的影响。通过叔丁醇(TBA)、对苯醌(p-BQ)的抑制实验对反应机理进行了讨论。 相似文献
10.
11.
12.
将经去离子水处理陈化后的锌粉与沸石混合后在950℃下煅烧制备了四针状氧化锌晶须(T-ZnOw)。以SEM、TEM、SRD、UV-Vis等对T-ZnOw的形貌、可见-紫外光特性进行了表征;将其掺杂于锐钛矿型的TiO2中,负载于聚甲基丙烯酸甲酯(PMMA)薄膜上,测试其光催化性能。结果表明:T-ZnOw-TiO2/PMMA纳米复合材料较单一的ZnO/PMMA和TiO2/PMMA显示出更高的光催化降解亚甲基蓝的活性,紫外光照60min后降解率高达98%。 相似文献
13.
《Journal of the European Ceramic Society》2003,23(10):1593-1598
ZnO films were prepared on unheated silicon substrate by RF magnetron sputtering technique. Postdeposition annealing of ZnO films in vacuum were found to improve film structure and electrical characteristics, such as dense structure, smooth surface, stress relief and increasing resistivity. Suitable annealing temperature also reduced loss factor. The correlation between annealing conditions and the physical structure of the films (crystalline structure and microstructure) was investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM) and atomic force microscopy (AFM). The preferred annealing condition has been found to improve ZnO film characteristics for piezoelectric applications. An over-mode acoustic resonator using the ZnO film after annealing at 400 °C in vacuum circumstance for 1 h showed a large return loss of 42 dB at the center frequency of 1.957 GHz. 相似文献
14.
Mohd Abdul Majeed Khan Sushil Kumar Maqusood Ahamed Salman A Alrokayan Mohammad Saleh AlSalhi 《Nanoscale research letters》2011,6(1):434
This work reports the preparation and characterization of silver nanoparticles synthesized through wet chemical solution method and of silver films deposited by dip-coating method. X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), field emission transmission electron microscopy (FETEM), high-resolution transmission electron microscopy (HRTEM), selected area electron diffraction (SAED), and energy dispersive spectroscopy (EDX) have been used to characterize the prepared silver nanoparticles and thin film. The morphology and crystal structure of silver nanoparticles have been determined by FESEM, HRTEM, and FETEM. The average grain size of silver nanoparticles is found to be 17.5 nm. The peaks in XRD pattern are in good agreement with that of face-centered-cubic form of metallic silver. TGA/DTA results confirmed the weight loss and the exothermic reaction due to desorption of chemisorbed water. The temperature dependence of resistivity of silver thin film, determined in the temperature range of 100-300 K, exhibit semiconducting behavior of the sample. The sample shows the activated variable range hopping in the localized states near the Fermi level. 相似文献
15.
Chitosan/poly(vinyl alcohol)/methylcellulose (CS/PVA/MC) ternary blend was prepared and chemically cross-linked with glutaraldehyde.
The prepared ternary blends were characterized by Fourier transform infrared spectroscopy (FTIR), Thermogravimetric analysis
(TGA), and X-ray diffraction (XRD). The FTIR results showed that the strong intermolecular hydrogen bonds took place between
CS and PVA. TGA showed the thermostability of the blend is enhanced by glutaraldehyde as crosslink agent. Results of XRD indicated
that the relative crystalline of pure CS film was reduced when the polymeric network was reticulated by glutaraldehyde. Finally,
the results of scanning electron microscopy (SEM) indicated that the morphology of the blend is rough and heterogenous, further
it confirms the interaction between the functional groups of the blend components. 相似文献
16.
《Diamond and Related Materials》2006,15(9):1434-1437
Ultrathin silicon films were deposited on nanocrystalline diamonds by means of atomic layer deposition (ALD) from gaseous monosilane. The silicon deposition was achieved through the sequential reaction of SiH4 saturated adsorption and in-site pyrogenation. X-ray diffraction (XRD), transmission electron microscopy (TEM), high-resolution electron microscopy (HREM) and Fourier transform infrared (FTIR) spectra were utilized to investigate the structure and the morphology of Si-coated nanocrystalline diamonds. The results confirmed that continuous silicon films were successfully deposited on both basal planes and edges of nanocrystalline diamond particles by this ALD method and the structure of the film was mainly determined by deposition temperature and deposition cycle. 相似文献
17.
《Journal of the European Ceramic Society》2005,25(5):759-765
Thin film samples of 0.15PMN–0.45PZ–0.40PT (PMN–PZ–PT) three-component system were prepared on Pt-coated Si substrates by a sol–gel process. X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), atomic force microscopy (AFM), and secondary ion mass spectrometry (SIMS) show that the above films can be formed in a single-phase perovskite structure at 800 °C. This was further confirmed by the dielectric and ferroelectric properties of the samples annealed at different temperatures. It was demonstrated that the morphology and microstructures of the PMN–PZ–PT films were quite sensitive to their annealing conditions, which strongly affects their electrical properties. 相似文献
18.
Metal copper films coated on microparticle substrates using an ultrasonic-assisted magnetron sputtering system 总被引:1,自引:0,他引:1
Xiaozheng Yu 《Powder Technology》2008,187(3):239-243
Metal copper films were coated on micrometer silicon carbide (SiC) and polymer particles with different sizes using the ultrasonic-assisted magnetron sputtering system. The surface morphology, the chemical composition and the crystallization of the SiC and the polymer particles were characterized by the field emission scanning electron microscopy (FE-SEM), energy dispersive analysis of X-rays (EDAX) and X-ray diffraction (XRD) analysis before and after film deposition. The experiment results indicate that the copper films were successfully coated on SiC and polymer particles. The XRD results show that the copper films have a face centred cubic structure. It was found from the FE-SEM results that film growth of copper films is a three-dimensional island growth mode. 相似文献
19.
Shadpour Mallakpour Amir Abdolmaleki Maryam Rostami 《Polymer-Plastics Technology and Engineering》2013,52(15):1615-1624
A new nanostructure poly(amide-imide) (PAI) was prepared from the polymerization of 4,4′-methylenebis(3-chloro-2,6-diethyl trimellitimidobenzene) as a diacid with 3,5-diamino-N-(4-hydroxyphenyl)benzamide using triphenyl phosphite as a condensing agent and tetra-n-butylammonium bromide as a green media. The synthesized polymer was used to prepare PAI/ZnO nanocomposites (PZNC)s using nano-ZnO surface-coupled by N-trimellitylimido-L-alanine diacid as a coupling agent through ultrasonic process. The resulting PZNCs were also characterized by FT-IR, powder X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM) and thermogravimetric analysis (TGA). The TEM and FE-SEM results showed a good dispersion of nanoscale inorganic particles in the polymer matrix. 相似文献
20.
Novel high-strength montmorillonite/polyvinyl alcohol composite film enhanced by chitin nanowhiskers
Nanomaterials can be used as reinforcement phase to improve the performance of polymers. A simple method to prepare a composite film with super high tensile strength was used in this study. The properties of montmorillonite (MMT)/polyvinyl alcohol (PVA) films reinforced by chitin nanowhisker (CNW) have been evaluated. The structures and properties of films were analyzed by atomic force microscope (AFM), Fourier transforms infrared spectroscopy (FT-IR), X-ray diffraction (XRD), thermogravimetric analysis (TGA), scanning electron microscopy (SEM), and tensile testing. The results of FTIR and XRD showed that no chemical interaction occurred among MMT, PVA, and CNW. The SEM and AFM images suggested that the obtained composite films with the three substances had a relatively uniform layered structure and relatively smooth. The temperature at the onset of decomposition of the composite films was increased from 262.0 to 282.3°C by the addition of CNW. The tensile strength of the MMT/PVA/CNW film was reached 263.5 MPa, which was increased approximately 382% compared with the MMT/PVA film. According to these results, the composite film could be potentially used in packaging materials. 相似文献