共查询到20条相似文献,搜索用时 62 毫秒
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通过St(o)ber法制备粒径约100 nm的SiO2纳米粒子,并以非离子表面活性剂嵌段共聚物为模板剂在纳米粒子表面再合成介孔SiO2层.在磷酸盐诱导剂的作用下可使核/壳结构的纳米粒子快速沉淀出来.再通过煅烧除去表面活性剂获得粒径均匀的球形介孔纳米载体.通过动态光散射(DLS)、扫描电镜(SEM)、透射电镜(TEM)、X射线衍射(XRD)、比表面积测定(BET)和氮气吸附脱附测定等技术对材料进行表征.纳米载体的平均有效粒径约为183 nm,介孔孔道为5.5 nm,具有良好的分散性(PDI:0.076),比表面积高达158.6 m2/g,孔容积0.22 cm3/g.结果表明,该法可以简单快速地制备纳米载体. 相似文献
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采用溶胶-凝胶法,以正硅酸乙酯为硅源、十六烷基三甲基溴化铵(CTAB)为模板,在碱性条件下合成了尺寸均匀、形状规则的花状形貌的介孔状二氧化硅微球。基于二氧化硅花球特殊的表面褶皱和内部的介孔孔道,将其作为载体负载模型药物布洛芬,探究其药物缓释性能。结果表明,所制备的介孔二氧化硅花球对布洛芬模型药物的负载量为701.63 mg·g~(-1),明显高于传统药物载体材料。此外,对介孔二氧化硅/布洛芬复合粒子进行缓释实验研究,发现10 h后布洛芬的释放量为74.60%,表明其具有较好的药物缓释性能。 相似文献
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本文采用表面活性剂导向溶胶-凝胶法,在碱性条件下,通过两种硅源成功制备了乙烷桥联型介孔纳米粒子(MSN)。在合成MSN的基础上,以γ-(甲基丙烯酰氧基)丙基三甲氧基硅烷(MPS)为改性剂对MSN表面进行了修饰。结果表明:合成的MSN呈规整的纳米级球体,界面高度交联,具有直径分布均匀(260nm)的无机-有机杂化骨架,其比表面积、介孔尺寸和孔容分别为540m~2/g、3.7nm和0.52cm~3/g。 相似文献
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利用介孔二氧化硅(SBA-15)为模板、蔗糖为碳源,制备了有序介孔碳材料CMK-3,然后以CMK-3为载体,利用浸渍还原法得到介孔碳负载Pd纳米粒子的复合催化剂(Pd/CMK-3),通过XRD、TEM以及氮气吸附-脱附等手段对催化剂的微结构和组分进行分析,结果表明CMK-3为有序介孔结构,孔径约为5nm,Pd/CMK-3保留了介孔结构,且孔道中负载有不同尺寸的Pd粒子。应用于无配体催化的Suzuki-Miyaura相似文献
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Silvia Schicker Daniel E. García Igor Gorlov Rolf Janssen Nils Claussen 《Journal of the American Ceramic Society》1999,82(10):2607-2612
Wet milling of Al2 O3 -aluminide alloy (3A) precursor powders in acetone has been investigated by milling Fe/Al/Al2 O3 and Fe2 O3 /Al/Al2 O3 powder mixtures. The influence of the milling process on the physical and chemical properties of the milled powders has been studied. Particle refinement and homogenization were found not to play a dominant role, whereas plastic deformation of the metal particles leads to the formation of dislocations and a highly disarranged polycrystalline structure. Although no chemical reactions among the powder components in Fe2 O3 /Al/Al2 O3 powder mixtures were observed, the formation of a nanocrystalline, ordered intermetallic FeAl phase in Fe/Al/Al2 O3 powder mixtures caused by mechanical alloying was detected. Chemical reactions of Fe and Al particle surfaces with the atmosphere and the milling media lead to the formation of highly porous hydroxides on the particle surfaces. Hence the specific surface area of the powders increases, while the powder density decreases during milling. The fraction of Fe oxidized during milling was determined to be 0.13. The fraction of Al oxidized during milling strongly depends on the metal content of the powder mixture. It ranges between 0.4 and 0.8. 相似文献
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A new ampholytic homopolypeptide, , which has one tertiary amino and two carboxyl groups in the side chain has been derived from a hydrochloride salt of poly(L-lysine). The polymer in aqueous solution seems to be in the coil form with locally extended structure (LES) at neutral pH. In both the acidic and alkaline regions, the molar ellipticity of the polymer changes as a result of change in net charge on the side chain. The conformational changes may be from the coil with LES to other coiled forms. 5–7 M NaClO4 and 80% aqueous methanol induce the α-helix in the polymer at neutral pH. Divalent cations, Cu2+ and Ca2+, do not induce any remarkably ordered structures such as α-helix or β-structure in the polymer in aqueous solution at any pH. Ultraviolet absorption studies show an absorption peak of the polymer-Cu2+ complex near 240 nm. Dependence of the peak intensity on pH at various q values () indicates the two steps of the complex formation. At q less than 0.64, the formation is described only with the first step. An average coordination number for Cu2+ at the first step was calculated to be about 2 by the method of Mandel and Leyte. The association constant of Cu2+ with the residue at the step was determined from the absorption data to be far smaller than that for the Cu2+-EDTA complex. The second step of the formation occurs in the case of large q but the absorption data for the second step cannot be obtained exactly due to precipitation. 相似文献
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Akira Akimoto 《Polymer》1974,15(4):216-218
The polymerization of vinyl chloride has been investigated using an catalyst system in the presence of various Lewis bases. Effective Lewis bases are γ-butyrolactone, diglyme and diethylenetriamine which are multidentate. The rate of polymerization is dependent not only on the basicity of the Lewis base used but also on a coordination number of one. The latter is the predominant factor. For the effect of polymeric amines, a tentative hypothesis is discussed. 相似文献
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Won-Hyuk Lee Yoshihiro Abe Eikichi Inukai 《Journal of the American Ceramic Society》1993,76(4):849-856
Ag2 O-doped superconducting Bi2 Sr2 Ca1 Cu2 O x ceramics were prepared by a melt-quenching–reheating method. It is found that the Ag2 O-doped, as-cast specimens exhibit superconductivity ( T c = around 80 K) by heat treatment at temperatures around 800°C even in an evacuated and sealed silica glass tube, while the undoped specimens do not and vaporize by the corresponding heat treatment. Conversion of the Ag2 O-doped, as-cast specimens into superconducting ceramics when heated in an evacuated vessel is explained in terms of the oxygen donor of Ag2 O in the specimen. This finding enables us to fabricate a desired shape of superconducting Bi2 Sr2 Ca1 Cu2 O x ceramics sealed in metals or glasses. The addition of Ag2 O to Bi2 Sr2 Ca1 Cu2 O x melt, however, had deleterious influences on the superconducting properties ( T c and J c ) of the resultant ceramics when obtained by heat treatment in air. 相似文献
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Mats Carlsson Mats Johnsson Mats Nygren 《Journal of the American Ceramic Society》1999,82(8):1969-1976
Ta0.33 Ti0.33 Nb0.33 C and Ta0.33 Ti0.33 Nb0.33 C x N1− x whiskers were synthesized via a carbothermal vapor-liquid-solid growth mechanism in the temperature range 900°-1450°C in Ar or N2 . The optimum temperature was 1250°C. Whiskers were obtained in a yield of 70-90 vol%. The whiskers were 0.5–1 µm in diameter and 10–30 µm in length. The starting materials that produced the highest whisker yield were: TiO2 , Ta2 O5 , Nb2 O5 , C, Ni, and NaCl. C was added to reduce the oxides, and Ni to catalyze whisker growth. NaCl was used as a source of Cl for vapor-phase transportation of Ta and Nb oxochlorides and Ti chlorides to the catalyst. The catalyst metal was recycled several times during the synthesis and was transported as NiCl2 ( g ) according to thermodynamic calculations. The rate of formation and the chemical composition of the whiskers depended on the synthesis temperature, the choice of catalyst, and the atmosphere. At low temperatures, the whiskers were enriched in Nb and Ta, whereas the Ti content increased with increased synthesis temperature. 相似文献