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锡偶联型SSBR的动态行为 总被引:7,自引:2,他引:5
研究了锡产型SSBR混炼胶及其硫化胶的动态力学性能,并与ESBR做了对比。结果表明,锡偶联型SSBR混炼胶比ESBR,的弛豫速度快,挤出胀在效应小,塑/弹比随频率减小的幅度大;锡偶联型SSBR硫化胶的tanδ比ESBR的小,生热低;日本产牌号为SL552胶料的tanδ随形变而增值幅度小的现象的体现了锡偶联结构有助于炭黑的高度分散及提高大分子与炭黑间结合强度。 相似文献
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锡偶联型溶聚丁苯胶性能评价 总被引:7,自引:0,他引:7
本文研究了具有适宜的苯乙烯、乙烯基含量及其配比的15立升釜聚合的锡偶联型溶聚丁苯橡胶(S-SBR)的硫化及力学性能、古德里奇疲劳温升、动态力学及摩擦性能,并与低温乳聚丁苯橡胶(E-SBR)进行了平行对比。结果表明,锡偶联型S-SBR是一种集较佳的静态性能、优异的动态性能、令人满意的安全及低能耗性为一体的新型胎面材料。 相似文献
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研究了用全SR制做7.50-16(人)拖拉机轮胎胎面。结果表明,胎面胶胶料生胶采用SBR1500/SBR1712(60/40)或SBR1500/BR/SBR1712(50/30/20)并用体系均可;炭黑选用炭黑N339最好;软化剂选用芳烃油,用量宜较高;增粘剂选用RX-80树脂。全SR胎面硫化胶的强撕性能、耐磨性能较好,成品轮胎性能符合国家标准,实际里程试验的花纹磨耗量低于现在生产轮胎。 相似文献
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稀土顺丁橡胶与丁苯橡胶(SBR)共混,可以改善SBR的耐低温性能。当稀土顺丁橡胶/SBR(质量比)这20/80时,-30℃的tanδ仅小于SBR,60℃的tanδ最小。其共混胶的应力-应变性能、湿滑指数、磨耗及生热性能均优于镍系顺丁橡胶/SBR共混体系。 相似文献
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TPI/HVBR共混物用于胎面胶的研究 总被引:2,自引:1,他引:2
在传统的胎面胶配方NR/SBR1500(并用此为60/40)和SBR1712/SBR1500(并用比为60/40)的基础上,采用高反式-1,4-聚异成二烯(TPI)和/或高乙烯基聚丁二烯橡胶(HVBR)取代或部分取代SBR1500,研究共混物的物理性能和动态粘弹性。结果表明,添加了TPI和HVBR的胎面胶,其力学性性能可满足使用要求,定伸应力和抗屈挠疲劳性较大提高,滚动阻力和动态生势明显降低,而抗湿滑性仍有较高的保持率,达到了滚动阻力和抗湿润性能的良好兼备。相对而言,NR/TPI/HVBR并用胎面胶具有量的滚动阻力和生热,而SBR/TPI/HVBR并用胎面胶具有更好的抗湿滑性、抗屈挠疲劳性和耐磨性。 相似文献
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The purpose of this article is that the silica‐modified SBR/BR blend replaces natural rubber (NR) in some application fields. The styrene‐butadiene rubber (SBR) and cis‐butadiene rubber (BR) blend was modified, in which silica filler was treated with the r‐Aminopropyltriethoxysilane (KH‐550) as a coupling agent, to improve mechanical and thermal properties, and compatibilities. The optimum formula and cure condition were determined by testing the properties of SBR/BR blend. The properties of NR and the silica‐modified SBR/BR blend were compared. The results show that the optimum formulawas 80/20 SBR/BR, 2.5 phr dicumyl peroxide (DCP), 45 phr silica and 2.5 mL KH‐550. The best cure condition was at 150°C for 25 min under 10 MPa. The mechanical and thermal properties of SBR/BR blend were obviously modified, in which the silica filler treated with KH‐550. The compatibility of SBR/BR blend with DCP was better than those with benzoyl peroxide (BPO) and DCP/BPO. The crosslinking bonds between modified silica and rubbers were proved by Fourier transform infrared analysis, and the compatibility of SBR and BR was proved by polarized light microscopy (PLM) analysis. The silica‐modified SBR/BR blend can substitute for NR in the specific application fields. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2011. 相似文献
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A novel tin‐coupled star‐shaped block copolymer (SB‐B)4Sn was synthesized by anionic polymeric techniques. This new copolymer exhibited two different types: One was star‐shaped polybutadiene‐b‐poly(butadiene‐ran‐styrene) (S‐PB‐PSB), and the other was star‐shaped polybutadiene‐b‐poly(butadiene‐ran‐styrene)‐b‐polystyrene (S‐PB‐PSB‐PS). In this article, properties of (SB‐B)4Sn were contrasted with that of tin‐coupled star‐shaped random styrene‐butadiene rubber (S‐SBR) and S‐SBR/cis‐BR blend rubbers. Physical property testing results showed that (SB‐B)4Sn possessed good mechanical properties like S‐SBR. Rheological study indicated that these star‐shaped block copolymers had good processing properties. Rubber processing analyzer (RPA) spectra showed that the dispersion of additives in (SB‐B)4Sn and S‐SBR/cis‐BR blend rubber was much better than that in S‐SBR. Dynamic mechanical thermal analyzer (DMTA) spectra showed that (SB‐B)4Sn had a good combination of low rolling resistance and high wet skid resistance, which made it satisfactory materials to produce high performance tire tread. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2009 相似文献
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This paper discusses the influence of partitioning of carbon black (CB) with its increasing concentration (i.e., 10, 20, 30, 40, and 50 phr) on physical and static mechanical properties of Styrene Butadiene Rubber (SBR)/Butadiene Rubber (BR) rubber–rubber blends (RRB's) in 70SBR:30BR blend ratio. Partitioning of CB towards BR in CB-filled SBR/BR RRB's is quantitatively determined via dynamic mechanical analysis (DMA). DMA confirmed increased partitioning of CB towards BR phase with increasing CB. DMA data on the partitioning of CB towards BR were in good agreement with nuclear magnetic spectra obtained by solid-state nuclear magnetic resonance spectroscopy (SS-NMR spectroscopy). Curing properties, relative density, hardness, tensile test, tear test, and transmission electron microscopy (TEM) on CB filled SBR/BR RRB's were carried out to determine the effect of increasing concentration of CB on physical, mechanical, and dispersion characteristics in comparison to neat SBR/BR RRB's. 相似文献
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Biing-Lin Lee 《应用聚合物科学杂志》1982,27(9):3379-3392
The crack growth of a highly carbon-black-loaded SBR—cis-polybutadiene (BR) blend is investigated as a function of the distribution of carbon black in the individual rubber phases. The blend compound consists of SBR/BR/carbon black/oil = 60/40/85/60 by weight ratio and curatives. A new “old process” is devised to control the carbon black distribution in the individual rubber phases, that is, cross mixing the SBR and BR black master batches with different amounts of carbon black in the SBR and BR patches. The results show that crack growth is very sensitive to the carbon black distribution. A better crack growth resistance compound is seen containing proportionately more carbon black in the major rubber SBR phase. A simple analogy of rubber blends to the rubber-modified thermoplastics is proposed to interpret these findings. The heat buildup of the blends is also affected by the carbon black distribution. A low heat buildup compound is observed in the system in which more carbon black is in the SBR batch, which is also a better crack growth resistance compound. It is not unexpected that the strength of rubbers decreases with increase of temperature, and so the rate of crack growth becomes faster as heat builds up. 相似文献
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Polyglycidylmethacrylate grafted butadiene rubber (PGMA‐g‐BR) was synthesized by a graft solution copolymerization technique. The PGMA content was determined through titration against HBr. The PGMA‐g‐BR was blended with styrene butadiene rubber/butadiene acrylonitrile rubber (SBR/NBR) blends with different blend ratios. The SBR/NBR (50/50) blend was selected to examine the compatibility of such blends. Compatibility was examined using scanning electron microscopy (SEM), differential scanning calorimetry (DSC), and viscosity measurements. The scanning electron micrographs illustrate the change of morphology of the SBR/NBR rubber blend as a result of the incorporation of PGMA‐g‐BR onto that blend. The Tgs of SBR and NBR in the blend get closer upon incorporation of PGMA‐g‐BR 10 phr, which indicates improvement in blend homogeneity. The intrinsic viscosity (η) versus blend ratio graph shows a straight‐line relationship, indicating some degree of compatibility. Thermal stability of the compatibilized and uncompatibilized rubber blend vulcanizates was investigated by determination of the physicomechanical properties before and after accelerated thermal aging. Of all the vulcanizates with different blend ratios under investigation, the SBR/NBR (25/75) compatibilized blend possessed the best thermal stability. However, the SBR/NBR (75/25) compatibilized blend possessed the best swelling performance in brake fluid. The effect of various combinations of inorganic fillers on the physicomechanical properties of that blend, before and after accelerated thermal aging, was studied in the presence and absence of PGMA‐g‐BR. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 99: 1559–1567, 2006 相似文献