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本文跟踪碳纳米管非共价键功能化修饰的研究进展,对功能化碳纳米管在传感器领域中的应用进行了综述。 相似文献
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多壁碳纳米管接枝超支化聚(胺-酯) 总被引:1,自引:0,他引:1
采用混酸氧化,使碳纳米管表面产生羧基,再分别以接出法(grafting from)的方式在碳纳米管表面"长出"超支化大分子;以接入法(grafting to)的方式将由"一步法"合成的超支化聚(胺-酯)通过酯化反应接枝到碳纳米管表面。通过SEM、FTIR、TGA-DSC以及XRD等表征手段并结合酸碱滴定法测定修饰后碳纳米管表面的羟基密度,对功能化修饰的碳纳米管进行分析。结果表明,分别以"grafting from"和"grafting to"方式接枝超支化聚(胺-酯)后,碳纳米管的羟基密度分别为24.74 mmol/g和20.04 mmol/g,修饰后的碳纳米管分散性能明显提高,同时末端丰富的官能团为碳纳米管的进一步功能化修饰创造了条件。 相似文献
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李红艳;季铁正;李佳;李博;莫翔友 《中国塑料》2011,25(5):11-16
简要介绍了环氧树脂/碳纳米管复合材料的组成以及碳纳米管在环氧树脂中的分散方法;综述了环氧树脂/碳纳米管复合材料的制备方法,包括溶液浇铸法、原位聚合法、化学改性法、混合固化剂辅助叠层法和树脂传递模塑法;总结了国内外对环氧树脂/碳纳米管复合材料导电性能的研究现状,并分析了影响其导电性能的因素,包括碳纳米管的比表面积、表面功能化和制备方法,剪切速率及固化条件等。 相似文献
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Mark Bissett Anders Barlow Cameron Shearer Jamie Quinton Joseph George Shapter 《Carbon》2012,50(7):2431-2441
Substrates with four different nanotube modifications have been prepared and their electron transport properties measured. Two modification techniques were compared; covalent chemical attachment of both single and multi-walled carbon nanotubes to transparent conductive (fluorine doped tin oxide) glass surfaces and chemical vapour deposition (CVD) growth of both single and multi-walled carbon nanotubes on highly doped conductive silicon wafers. These carbon nanotube modified substrates were investigated using scanning electron microscopy and substrates with nanotubes grown via CVD have a much higher density of nanotubes than substrates prepared using chemical attachment. Raman spectroscopy was used to verify that nanotube growth or attachment was successful. The covalent chemical attachment of nanotubes was found to increase substrate electron transfer substantially compared to that observed for the bare substrate. Nanotube growth also enhanced substrate conductivity but the effect is smaller than that observed for covalent attachment, despite a lower nanotube density in the attachment case. In both modification techniques, attachment and growth, single-walled carbon nanotubes were found to have superior electron transfer properties. Finally, solar cells were constructed from the nanotube modified substrates and the photoresponse from the different substrates was compared showing that chemically attached single-walled nanotubes led to the highest power generation. 相似文献
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This study focuses on in situ synthesis of CdS nanoparticles on the surfaces of multiwalled carbon nanotubes. By chemical reaction of cadmium chloride and thioacetamide in the solution with carbon nanotubes, which were pretreated by air oxidization and acid modification, cadmium sulfide nanoparticles densely supported on carbon nanotubes with 10 nm size and homogeneous distribution were prepared. The composite material with the composite structure of CdS decorating the nanotube surfaces was characterized using scanning electron microscopy, high-resolution transmission electron microscopy, X-ray diffraction and electron diffraction pattern. The CdS nanoparticles are of cubic crystal structure, show good adhesion to the nanotubes. This method can be extended to prepare other inorganic nanoparticle-carbon nanotube composites. 相似文献
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The processing of carbon nanotube based nanocomposites is one of the fastest growing areas in materials research due to the potential of significantly changing material properties even at low carbon nanotube concentrations. The aim of our work is to study the curing and thermomechanical behavior of carbon nanotube/epoxy nanocomposites that are critical from an application standpoint. Multiwall carbon nanotubes–epoxy composites are prepared by solvent evaporation based on a commercially available epoxy system and functionalized multiwalled carbon nanotubes. Three weight ratio configurations are considered (0.1, 0.5, and 1.0 wt%) and compared to both the neat epoxy to investigate the nano‐enrichment effect. We focus here on the modification of the curing behavior of the epoxy polymer in the presence of carbon nanotubes. It has been observed that introducing the multiwall carbon nanotubes delays the polymerization process as revealed by the modification of the activation energy obtained by differential scanning calorimetry. The viscoelastic response of the nanocomposites was studied from the measurements of storage modulus and the loss factor using dynamic mechanical analysis to evaluate the effect of the interface in each matrix/carbon nanotube system with changing matrix mobility. These measurements provide indications about the increase in the storage modulus of the composites, shift in the glass transition temperature due to the restriction of polymer chain movement by carbon nanotubes. POLYM. COMPOS., 35:441–449, 2014. © 2013 Society of Plastics Engineers 相似文献
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Various purification processes were applied to single-wall carbon nanotubes synthesized by metal catalyzed laser ablation. Structure modifications introduced by these processes were investigated by high-resolution transmission electron microscopy and Raman spectroscopy. An apparent structure modification after purification was the increase of bundle size although breaking of nanotubes and a change of nanotube diameter distribution were also observed. More vigorous attacking of single-wall carbon nanotube structure was identified by a strong mixed-acid treatment. 相似文献
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《Carbon》2013
Multiwall carbon nanotubes (MWCNTs) were activated by microwave irradiation and covalently functionalized with poly(glycidyl methacrylate) (PGMA) through free radical polymerization using ‘fishing process’ when the propagating polymer radicals were attached onto the graphitic surface of the nanotube. The PGMA-functionalized MWCNTs were then used as a precursor to non-covalently wrap polyaniline (PAni) nanofiber onto them. The functionalized nanotubes exhibited stable dispersion up to 180 days in tetrahydrofuran, dimethyl formamide and dimethyl sulfoxide. Fourier transform infrared analyses indicated the attachment of the epoxide and benzenoid–quinoid functional moieties onto the nanotube surface. The PGMA coating on the nanotube and surrounding PAni nanofiber on the MWCNT scaffold were confirmed by transmission electron microscopy. The Raman spectroscopy confirmed the phonon-assisted modification of the nanotube. The differential action of the pristine and functionalized MWCNTs against an opportunistic bacterium (Escherichia coli ) and its plasmid deoxyribonucleic acid was also investigated. Pristine nanotubes exhibited bacterial inhibitory action and no condensation with the pET-32α(+) plasmid. On the other hand, the anti-bacterial PAni nanofiber and functionalized nanotubes showed complex formation with the bacterial plasmid. 相似文献
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Effects of surface modification on rheological and mechanical properties of CNT/epoxy composites 总被引:7,自引:0,他引:7
Jin Ah Kim 《Carbon》2006,44(10):1898-1905
Despite superior properties of carbon nanotubes (CNTs), physical properties of the CNT/epoxy composites are not improved significantly because interfacial bonding between the CNTs and the polymer matrix is weak. CNTs were treated by an acidic solution to remove impurities and modified subsequently by amine treatment or plasma oxidation to improve interfacial bonding and dispersion of nanotubes in the epoxy matrix. The functional groups on the surface of treated CNTs were investigated by X-ray photoelectron spectroscopy. The surface modified CNTs were embedded in the epoxy resin by ultra-sonication and the cured nanotube containing composites were characterized by field emission scanning electron microscopy. Rheological properties of nanotube containing epoxy resin and mechanical properties of the modified CNT/epoxy composites were improved because the modification of CNTs improved dispersion and interaction between the CNT and the epoxy resin. 相似文献
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BACKGROUND: The development of carbon nanotube‐reinforced composites has been impeded by the difficult dispersion of the nanotubes in polymers and the weak interaction between the nanofiller and matrices. Efficient dispersion of carbon nanotubes is essential for the formation of a functional nanotube network in a composite matrix. RESULTS: Multiwalled carbon nanotubes (MWNTs) were incorporated into a polyimide matrix to produce MWNT/polyimide nanocomposites. To disperse well the MWNTs in the matrix and thus improve the interfacial adhesion between the nanotubes and the polymer, ‘branches’ were grafted onto the surface of the nanotubes by reacting octadecyl isocyanate with carboxylated MWNTs. The functionalized MWNTs were suspended in a precursor solution, and the dispersion was cast, followed by drying and imidization to obtain MWNT/polyimide nanocomposites. CONCLUSION: The functionalized MWNTs appear as a homogeneous dispersion in the polymer matrix. The thermal stability and the mechanical properties are greatly improved, which is attributed to the strong interactions between the functionalized MWNTs and the polyimide matrix. Copyright © 2009 Society of Chemical Industry 相似文献
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碳纳米管具有优异的力学性能、热性能及电性能,因此在聚合物复合材料领域具有巨大的应用潜力。本文侧重介绍碳纳米管在聚合物中作为增强相、功能填料和智能元件方面的应用研究情况,讨论了碳纳米管聚合物复合材料界面、力学性能及应用研究存在的问题,展望了碳纳米管在航空航天复合材料领域的应用前景。 相似文献
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The cyclic voltammetric behaviors of empty nanotubes and toluene-filled nanotubes were described. When the nanotube films exposed to air for one night, a pair of redox waves was observed that is probably ascribed to the presence of oxygen-containing groups bound to the surface of the nanotubes. Toluene-filled nanotube film is demonstrated to catalyze the electrochemical response of biomolecules such as dopamine and epinephrine, while empty multi-wall carbon nanotube film shows no or less electrocatalytic behavior to these biomolecules. This suggests that filled nanotubes have some particular properties compared to empty multi-wall carbon nanotubes and the development of filled nanotubes is necessary. 相似文献