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三组分可逆热致变色材料由于其材料选择的多样性,是目前在染料、印刷、示温材料、记录材料等领域应用最为广泛的有机可逆热致变色材料。专利申请中涉及三组分可逆热致变色材料的优化技术主要包括了组分的选择、助剂的添加、粘结剂的改进、添加保护层、微胶囊技术的改进。本文综述了专利申请在三组分可逆热致变色材料的发色剂、显色剂和溶剂上的研究以及相关性能的改进状况。 相似文献
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以隐色染料结晶紫内酯、酚酞、苯酚红、甲基红为电子给予体、显色剂双酚A为电子接受体和十二醇为溶剂,制备了可逆热致变色复配物,以密胺脂为壁材,通过原位聚合法进行微胶囊化研究,并对制备条件进行了优化。利用扫描电子显微镜、热重分析法等对微胶囊进行了结构与性能表征。 相似文献
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可逆热致变色是指一种颜色受热升温时变为另一种颜色,冷却后又恢复为原来的颜色的现象。热致变色材料主要由电子给予体、电子接受体和溶剂性化合物3类物质组成。其中决定颜色的是电子给予体,决定显色深浅的是电子接受体.溶剂则决定变色温度。当电子给予体与电子接受体之间发生电子转移平衡反应时。表现为可逆热致变色现象目。国内在可逆热致变色材料研究方面报道较少,近年来,国内有关科研单位,如北京航空航天大学、中科院化学所等已研制出了几种可逆热致变色材料四。研究开发出具有灵敏度高、可逆性好、稳定性强、使用寿命长、合成工艺简单实用的有机可逆热致变色材料已是备受国内外关注的研究领域。
对可逆热致变色复配物进行微胶囊化包覆。对其变色性能没有明显影响,但这样可将热致变色复配物与外界隔离。减少外界物质对其变色性能的影响,同时可避免受热变色时组分材料的流失,较好地保持其变色性能等刚,这将大大促进此类可逆热致变色性材料在测量、电子、医疗等领域的应用。本试验对热敏玫红TF-R1可逆热致变色复配物的微胶囊化采用原位聚合法,其壁材选用脲醛树脂。 相似文献
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针对传统环氧树脂涂料颜色单一,难以满足室内装饰美观的问题,提出用改性环氧树脂PEM结合热致可逆变色微胶囊制备热致可逆变色环氧树脂涂料,并考察了微胶囊乳液含量和固化剂种类对热致可逆变色环氧树脂乳液和其涂装后漆膜性能的影响。结果表明,微胶囊乳液含量在15%内,涂料稳定性较高,储存时间长;且微胶囊乳液含量在15%范围内,涂料漆膜光泽度、抗冲击强度、附着力和弹性随微胶囊乳液含量的增加而下降,硬度有所上升;用环己二胺作为固化剂制备的涂料漆膜光泽度和弹性较好;以此条件制备的热致可逆变色环氧树脂涂料,涂装漆膜随温度的升高,颜色变浅,且升温、降温都表现出相同的颜色变化规律,证实热致可逆变色性良好。 相似文献
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介绍了由微胶囊化的碱性隐色染料和酚显色剂构成的热记录材料的热记录特性及微胶囊壁和其他成分的热特性.由于酚系显色剂和微胶囊壁的相互作用,酚系显色剂的熔化温度Tm及微胶囊的玻璃化温度Tg大大降低.最低的显色温度和降低了的Tm和Tg两者中较高的温度一致. 相似文献
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介绍了由微胶囊化的碱性隐色染料和酚显色剂构成的热记录材料的热记录特性及微胶囊壁和其他成分的热特性。由于酚系显色剂和微胶囊壁的相互作用,酚系显色剂的熔化温度 Tm及微胶囊的玻璃化温度 Tg大大降低。最低的显色温度和降低了的 Tm和 Tg两者中较高的温度一致。 相似文献
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热敏材料微胶囊及热敏油墨的制备 总被引:6,自引:0,他引:6
用明胶 -阿拉伯树胶做壁材 ,热敏变色材料做心材制热敏材料微胶囊。阿拉伯树胶、明胶和心材三者质量比为 1∶1∶1,用甲醛固化壁材。固化前将体系调至pH =9。加入明胶质量 2 %的纳米级二氧化硅作隔离剂。与不加二氧化硅相比 ,加入二氧化硅后 ,彼此发生粘连的微胶囊数由占总数的 2 0 %降至 5 % .与不经包敷的热敏材料做的油墨相比 ,用热敏材料微胶囊做的油墨在 6 0℃下的储存期由 72h延长至 36 0h ;在 40℃由嫩黄色变成深桔红色前者需 4s,后者则需 3s;离开热源在 2 0℃室温下 ,前者 6s恢复原色 ,后者需 4s 相似文献
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Ilana Malherbe 《Polymer》2010,51(22):5037-5043
A ‘solvent facilitated’ coaxial electrospinning process was used to produce reversible narrow temperature gap thermochromic, core-shell fibres. A thermochromic composite composed of crystal violet lactone (the leuco dye), bisphenol A (the developer) and 1-dodecanol (the phase-change solvent) was entrained as core material inside poly(methyl methacrylate) shells. A mutual core and shell solvent (chloroform) was used to obtain low interfacial tension between the core and shell spinning solutions. This enabled room temperature entrainment of the low molecular weight, low viscosity core fluid. In order to minimize the effect of light scattering and subsequently produce fibres with visible colour transitions, the fibres were produced with external diameters of 3-8 μm and core diameters of 1.7-5.7 μm. In order to produce core-shell fibres with repeated, reversibly thermochromic behaviour and a stable colour developed state, it was necessary to entrain a dye composite that contained an excess developer, essentially making this composite non-thermochromic prior to entrainment. The fibres were analyzed using SEM and DSC. 相似文献
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Yoshiumi Kohno Yoshinori Shibata Nobuyuki Oyaizu Keiko Yoda Masashi Shibata Ryoka Matsushima 《Microporous and mesoporous materials》2008,114(1-3):373-379
Flavylium dye, a model compound of natural anthocyanin, has a defect that its color stability is very poor. We have complexed the flavylium dye with protonated zeolites and succeeded to enhance both the thermal and chemical stability of the dye. The aqueous dispersion of the flavylium/zeolite complex maintains its color even at 353 K or at pH 9, under which conditions the aqueous solution of the flavylium loses its color immediately. The stability is enhanced when the dye is incorporated into the pore of the zeolites, and a large stabilization effect is obtained by a tight adsorption with a narrow pore, as long as the dye is incorporated into the pore. Because of its enhanced color stability, the flavylium dye incorporated in the zeolite pore can be a candidate for an environmentally friendly coloring material. 相似文献
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Martina Štaffová František Kučera Jiří Tocháček Petr Dzik František Ondreáš Josef Jančář 《应用聚合物科学杂志》2021,138(4):49724
Dynamic color and phase change of chosen thermochromic systems were deeply investigated and their incorporation into polyurethane textile coating was developed. The colorimetric properties of three commercial reversible leuco dyes-based thermochromic pigments (TPs) with activation temperature at 38, 50, and 60°C were studied. Color change as a function of temperature was evaluated and colorimetric values were related to phase transition temperatures via differential scanning calorimetry (DSC) measurement. Light fastness of commercial TPs in polyurethane coating was determined by accelerated aging measurement and the color stability has been improved by using ultraviolet absorber (UVA). This research opens new possibilities for smart textiles, which is a very promising field in high-technology materials. 相似文献
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An organic‐solvent‐soluble disperse dye was introduced into an aqueous phase by a reaction with a self‐emulsified, aqueous‐based polyurethane (PU), and this resulted in the formation of a homogeneous, aqueous polymeric dye dispersion. This aqueous polymeric dye was stable in a water phase with excellent color extension upon application. It was formulated with a latent curing agent, polyaziridine (e.g., TMPTA‐AZ), as a single‐component, self‐curable, aqueous polymeric dye. The curing reaction took place between PU carboxylic acid and the latent curing agent upon drying. A self‐cured polymeric dye was obtained with excellent color extension and fastness and resistance to organic solvents and water after drying. This single‐component, self‐curable, aqueous‐based PU system containing a dye has potential for printing, writing, and dyeing applications. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 2006 © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 3741–3747, 2006 相似文献
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氧气液相催化氧化孔雀绿隐色体的环境友好工艺研究 总被引:1,自引:0,他引:1
研究了催化剂种类及用量、循环氧化剂四氯苯醌的用量、溶剂、底物初始浓度、醋酸用量、反应温度和反应时间对氧气液相氧化孔雀绿隐色体的影响。发现在乙醇介质中以金属络合物为催化剂、氧气为氧化剂、催化剂用量为底物质量的 3 %、四氯苯醌用量为底物质量的 0 91%、隐色体初始浓度为 3 3mol/L、醋酸用量与溶剂总量的体积比为 1∶6、于 5 0℃下反应 10h ,可以获得76 72 %的产品收率。工艺过程由于使用了价廉易得、无污染的氧气为氧化剂 ,因而对环境友好。氧化产物的结构经过核磁共振谱得以确认。 相似文献
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将市售固色剂、抗染料迁移剂分别配入洗衣液中,通过固色实验、抗染料迁移实验、配伍性实验,考察了不同护色剂在洗衣液中的护色效能。实验结果表明,洗衣液中加入质量分数为0.25%护色剂X时,固色性能、抗染料迁移性能较好。在此基础上配伍0.25%HP66K时,洗衣液抗染料迁移性能更佳。洗衣液配方(添加护色剂X和HP66K)采用完全非离子表面活性剂体系时,其固色性能、抗染料迁移性能较佳。 相似文献