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环氧树脂涂层因其优异的耐蚀性能、对金属表面良好的附着力而在金属防腐领域得到广泛应用。但涂层固化过程中会形成缺陷和孔洞,腐蚀介质可以直接接触到金属表面。为了开发出具有优良耐久性的防腐涂层,研究人员使用不同的方法和材料制备了多种环氧树脂防腐涂层。该文综述了纳米粒子改性环氧防腐涂层、超疏水型环氧防腐涂层、自修复型环氧防腐涂层、导电聚合物改性环氧防腐涂层及生物基材料改性环氧防腐涂层的制备及性能。但这5种防腐涂层各有局限性,未来应该探究出新的环氧防腐涂层,在提升涂层防腐性能的同时,兼顾其他性能,使环氧树脂基防腐涂层朝着功能化、智能化的方向发展。 相似文献
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研究了锌铝合金涂层与有机涂层的耐盐雾性能,在防腐涂层体系中,锌铝合金涂层的耐盐雾防腐性能好于有机涂层;而在防腐防污涂层体系中由于防污漆含有铜,锌铝涂层与铜离子可形成原电池加速腐蚀,锌铝合金涂层的防腐性能差于有机涂层体系。 相似文献
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钢顶管外防腐因顶进过程涂层摩擦、难以修补而具有独特要求,该文综合比较环氧煤沥青涂层、环氧玻璃鳞片涂层和熔结环氧粉末涂层这三种涂层的性能,价格,施工要求等因素,选用熔结环氧粉末涂层作为南汇支线钢顶管外防腐涂层;经过工程的验证,此材料的选用可以提高钢顶管防腐涂层的质量和适用性,保障工程的安全运行。 相似文献
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《中国石油和化工标准与质量》2007,27(3):55-55
大港油田承担的中国石油股份公司科研项目“快速固化防腐涂层应用研究”,通过专家验收评定。专家组认定,该产品质量性能达到国际同类产品标准,填补了国内防腐涂料领域的一项空白。据中国环氧树脂行业协会专家介绍,该项目的主要内容是研究和开发100%固体含量刚性环氧树脂一聚氨酯防腐涂料及其涂层施工技术,具有无毒无公害、施工工艺方法简便快捷、涂层防腐性能优异等特点,并具备多种防腐涂层的技术优势。 相似文献
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常温固化环氧改性有机硅耐高温涂料的研制 总被引:1,自引:0,他引:1
用环氧树脂E-20和有机硅低聚物(PS)合成了一种环氧树脂改性有机硅树脂,采用红外光谱(IR)、热失重分析(TGA)等方法对产物进行了表征和分析。探讨了有机硅含量对涂料耐热性能的影响,优选了综合性能优良的固化剂和颜填料制得了耐高温涂料,同时对涂膜性能进行了测试。结果表明,当m(E-20):m(PS)=2:8时,改性有机硅树脂的综合性能得到了明显改善。采用改性芳香胺固化剂,硅烷偶联剂KH550以及适当的颜填料制备的涂料具有良好的耐热防腐性能,可常温固化,能在500℃环境下长期使用。 相似文献
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Epoxy resin is chosen for our present study owing to its exceptional combination of properties such as easy processing, high safety, excellent solvent and chemical resistance, toughness, low shrinkage on cure, good electrical, mechanical and corrosion resistance with excellent adhesion to many substrates. This versatility in formulation made epoxy resins widely applied for surface coatings, adhesives, laminates, composites, potting, painting materials, encapsulant for semiconductor and insulating material for electric devices. There are numerous paint/coating systems based on epoxy resin available for corrosion and fouling prevention. They however are not completely satisfactory in field applications, where high corrosion, fouling and flame resistance are required. The demand for epoxy resin as corrosion/fouling resistant coatings is restricted mainly due to its inferior characteristics like poor impact strength, high rigidity, and moisture absorbing nature besides inadequate flame retardant properties. It is for this reason that silicones and phosphorus-based compounds are used as modifier in this work by intercrosslinking network mechanism (ICN) to obtain epoxy resin with desired properties ideally suitable for field applications for preventing corrosion and fouling with flame retardantancy. The present work involves the development of solvent free silicone/phosphorus modified epoxy coating systems, since solvent free coating systems are widely used for numerous applications due to their lower cost per unit film thickness, freedom from fire and pollution hazard and ability to provide better performance. For the development of coating systems, epoxy resin (X) serves as base material, hydroxyl terminated polydimethylsiloxane (HTPDMS) as modifier, γ-aminopropyltriethoxysilane (γ-APS) as crosslinking agent and dibutyltindilaurate (DBTDL) as catalyst. Polyamidoamine (A), aromatic amine adducts (B) and phosphorus-containing diamine (C) were used as curing agents. The study also describes the evaluation of corrosion resistant behaviour of unmodified epoxy and siliconized epoxy coatings by potentiodynamic polarization method, electrochemical impedance spectroscopy (EIS), salt-spray and antifouling tests. The results are discussed. 相似文献
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Phenolic coatings are usually a convenient and economical way to protect metallic materials against wear and corrosion. Furan resins are analogous to phenolics, as they are obtained by replacing formaldehyde by furfural in their formulation. In this work, a furan resin based on furfural and phenol was synthesized and used as an aluminum coating. Thus, toxic emissions of formaldehyde were avoided, while a biobased derivative was used instead. The performance of the proposed resin was compared with the one of a traditional phenolic resin. Physicochemical characteristics including chemical structure, surface polarity and glass transition temperature were evaluated by means of Fourier transform infrared spectroscopy, contact angle measurements and dynamic–mechanical analysis, respectively. Nanomechanical and nanotribological properties were assessed by depth sensing indentation techniques. As well, the corrosion resistance of the furan coating was determined by potentiodynamic polarization tests. The obtained results validate the furan resin as a feasible alternative to phenolics to protect aluminum. 相似文献
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Hongyue Wang Shiyang Zhu Hongyan Yao Yizeng Di Meng Shu Jiahao Li Bo Zhang Guangzhao Cao Shaowei Guan 《应用聚合物科学杂志》2021,138(32):50758
In order to prepare a coating with better corrosion resistance, the double-layer coatings are designed to work together in this article. The double-layer coatings are made of polyethersulfone and epoxy resin as the matrix resin. Polyaniline (PANI) of different contents was added to the matrix resin by weight to form the primer coats, which was named as d-0, d-20, d-40, d-60. And polytetrafluoroethylene was introduced into the matrix resin to prepare the surface coats. A two-layer coating was prepared by coating the surface layer on the primer layer, named as S-0, S-20, S-40, S-60. The surface morphology of the primer coatings and the cross section morphology of the two-layer coatings were determined by field emission scanning electron microscopy. The anticorrosion property of the coatings was studied by water absorption, adhesion, salt spray corrosion acceleration test and electrochemical impedance test. The results indicate that the 40 wt% PANI composite coating shows the best corrosion resistance. 相似文献
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Nima Moazeni Zurina Mohamad Nor Liyana Izzati Faisal Mahsa A. Tehrani Nazila Dehbari 《应用聚合物科学杂志》2013,130(2):955-960
In this study, the performance of an epoxy coating with hybrid nanozinc dust and halloysite nanotube (HNT) fillers on the corrosion protection of a carbon steel substrate was investigated. The epoxy resin was mixed with a constant amount of nanozinc dust (1%) and different contents of HNTs (0, 0.5, 1, and 1.5%) with a high speed mixer. Fourier transform infrared spectroscopy and thermogravimetric analysis were used to analyze the interactions between the components in the coating material and the thermal stability of the epoxy coating, respectively. Open‐circuit potential, salt spray testing, and microscopy were also used to assess the corrosion resistance of the carbon steel substrate coated with these coating materials. The incorporation of nanozinc in the epoxy coating enhanced the corrosion protection of the carbon steel substrate compared with the pure coating. Furthermore, HNTs further enhanced the corrosion protection. The best protection was achieved when 1% nanozinc and 1% HNT were used. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 130: 955‐960, 2013 相似文献
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Given the environmental benefits, poly(vinylidene fluoride) (PVDF)-based composite powder coating was developed without using any harmful solvent. However, it still remains poor adhesion to substrates and low compatibility to acrylic resin issues. To address these challenges, PVDF was grafted with glycidyl methacrylate (GMA) through a facile and scalable reactive extrusion method. The resulting product, PVDF-g-GMA, was then mixed with different contents of polymethyl methacrylate (PMMA), and the mixing was sprayed onto aluminum substrates. The PVDF-g-GMA/PMMA powder coating shows the excellent adhesion and corrosion resistance, particularly when the PMMA content is 30 wt%, owning to the good compatibility of PVDF-g-GMA and PMMA. This work opens up a new possibilities for the development of advanced composite powder coatings with improved performance characteristics. 相似文献
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He Sili Li Yuntao Zhao Chunxia Wu Jiaojiao Li Hui Xiang Dong 《Polymer Engineering and Science》2020,60(8):1812-1821
In this study, a new type of coating comprising benzoxazine and siloxane-containing epoxy (SiEP) resin was prepared by the thermal curing method. The FTIR (Fourier transform infrared) analysis not only confirmed the complete reaction between polybenzoxaine and SiEP resin after heat curing, but also found the hydrogen-bonding interactions between them. The addition of SiEP resin significantly enhanced the hydrophobicity and adhesion ability of the coating and greatly improved the water contact angles of the blend coatings (>108°), compared to that of the pristine PBa coating, which attributed to the introduction of a Si O Si network structure in the matrix. In addition, the corrosion resistance of the coating was tested though a series of electrochemical experiment. According to the results, the corrosion current values of the blend coatings decreased by about four orders of magnitude compared to that of the pristine carbon steel, and the corrosion protection efficiency of the blend coatings were >99%, indicating good application prospect of these blend coatings. 相似文献
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以油酸、二乙烯三胺和氯化苄为原料,合成了咪唑啉季铵盐缓蚀剂。通过FT-IR、1H-NMR对季铵盐结构进行了表征。并将其离子交换至钠基蒙脱土(DK0)层间,制备缓蚀剂改性有机蒙脱土QACDK0。通过XRD,TGA和UV-Vis对QACDK0的结构、组成及层间缓蚀剂释放性能进行了表征,结果表明季铵盐缓蚀剂的插入使蒙脱土层间距由12.8 ?扩大到39.8 ?,蒙脱土中缓蚀剂负载量约为39.0 wt%。为研究在同种基质中使用不同纳米粘土对水性环氧涂层防腐性能的影响,将缓蚀剂改性有机蒙脱土、无机蒙脱土及市售普通有机改性蒙脱土加入到环氧树脂E-51中,通过相反转法制备了水性环氧树脂/蒙脱土纳米复合乳液。利用DLS和Zeta电位对环氧乳液的稳定性进行表征,其中咪唑啉季铵盐缓蚀剂改性蒙脱土/环氧乳液Zeta电位为-27.8 mV,稳定性最高。电化学阻抗谱(EIS)测试表明,在腐蚀介质中浸泡30天后,基于QACDK0制备的防腐清漆漆膜阻抗模值仍保持最高,具有2.29×108 Ohm.cm2的高阻抗值,表明季铵盐缓蚀剂的释放使涂层具有更好的主动防腐性能。在耐中性盐雾测试中,QACDK0对应的防腐色漆耐盐雾时间更长,验证了该涂层具有良好的耐盐雾性能。此外,该涂层表面平整致密,具有良好的阻隔性能。 相似文献
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Effect of nano-sized mesoporous silica MCM-41 and MMT on corrosion properties of epoxy coating 总被引:1,自引:0,他引:1
This study investigated the effect of co-incorporation of two different kinds of nano materials with different forms, layers (Na-MMT) and mesoporous silica particles (MCM-41), into the polymer matrix on the corrosion performance of epoxy resin. Correspondingly corrosion performance of the coatings was studied by electrochemical impedance spectroscopy (EIS) in 3.5% NaCl aqueous solution and salt spray test. The X-ray diffraction (XRD) measurement showed that the Na-MMT layers were exfoliated and the hexagonal framework structure of MCM-41 was retained during and after the composite preparation. The co-incorporation of Na-montmorillonite (Na-MMT) and MCM-41 into the epoxy coating possessed the best corrosion resistance than incorporating either Na-MMT or MCM-41 particles separately due to different interfacial structures between the fillers and the matrix. 相似文献