阳极材质对电刷镀铁镀液氧化的影响

本文研究了电刷镀铁镀液存在的主要问题,可溶性阳极和不溶性阳极对电刷镀铁不同类型镀液氧化的影响及原因。为电刷镀铁合理选择镀液和阳极提供了依据。     

Sol-Gel法制备择优取向铁电陶瓷薄膜的研究进展

综述了溶胶—凝胶法制备择优取向铁电陶瓷薄膜的研究现状,主要介绍了制备过程中衬底材料、热处理工艺、前驱体以及掺杂等因素对铁电陶瓷薄膜择优取向的影响以及铁电陶瓷薄膜的择优取向与铁电性能的关系。     

Sol-Gel法制备择优取向铁电陶瓷薄膜的研究进展

综述了溶胶—凝胶法制备择优取向铁电陶瓷薄膜的研究现状,主要介绍了制备过程中衬底材料、热处理工艺、前驱体以及掺杂等因素对铁电陶瓷薄膜择优取向的影响以及铁电陶瓷薄膜的择优取向与铁电性能的关系。     

等离子喷焊ZrC增强铁基喷焊层Q345复合板的制备

对Q345钢板进行等离子喷焊表面处理,通过正交实验优化了Q345表面处理的最佳工艺参数,优化的喷焊工艺为电流60 A、焊枪行走速度20 mm/min、送粉量为35 %、离子气流量为1.2-1.4 L/min、保护气流量为10-12 L/min。结果表明,Q345基板的组织正常,为珠光体+铁素体组织,热影响区处金相组织仍为珠光体+铁素体,喷焊层组织为铁基体及共晶(Cr,Fe)₇C₃相。其中,喷焊层中的ZrC可以作为铁基体的异质核心,细化了铁基体晶粒尺寸,力学性能得以大幅提高。对最优工艺制备的复合板进行冲击试验测得其冲击韧度为192.8 J/cm²,在冲击过程中高强层的断裂方式为准解理断裂;在基体层位置处断裂方式为解理断裂。     

“不对称交流——直流电低温镀铁”新工艺在油田上应用所见

<正> 一、前言 十九世纪六十年末,用电解法获得化学纯铁,从而产生直流电镀铁技术,但它作为一项修复或表面强化手段,最早是由苏联学者[Ⅰ]在本世纪四十年代首先提出,并广泛用于汽车、拖拉机等零件的修复。等人还用镀铁技术对普通低碳钢零件进行表面强化处理,以代替某些优质合金钢。本世纪七十年代以来,美、日等国家也开始广泛研究这一技术问题,出现了一些镀铁工艺及应用的专利和文献。并很快形成很大的     

1,10-菲绕啉对织物化学镀铜的影响

研究1,10-菲绕啉对织物化学镀铜沉积速率、镀层成分、微观结构、表面形貌和表面电阻的影响。结果表明:添加适量的1,10-菲绕啉可以有效提高沉积速率,表面电阻明显降低,使镀层变得致密均匀,颜色由棕黑色变成亮铜色。添加1,10-菲绕啉还可使镀层中的铜含量增高,改善镀层微观结构,减小晶粒尺寸,可起到细化晶粒的作用,镀层由原来的(111)晶面择优取向转变为(220)和(311)晶面择优取向。     

电磁作用对镁合金焊缝金属组织性能的影响

将纵向交流磁场应用于5mm厚的AZ31镁板GTAW焊接过程中，通过对焊接接头力学性能和显微组织的分析试验，找到了磁场参数对AZ31焊接接头组织和性能的影响规律，并对磁场作用机理进行了分析研究.结果表明，外加纵向磁场的电磁搅拌作用从 4个方面影响晶粒的形核及长大过程，使焊缝中晶粒组织得到细化，进而使焊接接头的抗拉强度和硬度等性能得到改善，同时磁场的电磁搅拌作用可以净化熔池中液态镁合金(使杂质球化并弥散分布)，促进气泡上浮，降低镁合金焊缝气孔及焊接热裂纹敏感性，抑制热裂纹及气孔的产生.     

电刷镀Ni - P合金镀层的高温摩擦磨损性能

对电刷镀Ni - P合金镀层的高温摩擦磨损性能进行了研究.实验结果表明,在20CrMo钢基体上,电刷镀Ni - P合金镀层能有效降低试样在高温(450 ℃)下的摩擦因数,减小高温磨损量.其中,12 min电刷镀试样在高温摩擦测试前80 min内,摩擦因数基本维持在平均值约0.30,仅为20CrMo钢基体(0.60)的50%;80～120 min因镀层局部被磨损穿透,其摩擦因数缓慢增长;120 min后,基本维持在平均值约0.50,测试完成后质量磨损量为同等测试条件下20CrMo钢基体的19.99%;24 min电刷镀试样在450℃下摩擦测试180 min的整个过程中,摩擦因数均较稳定,平均值为0.30,高温摩擦磨损测试后的质量磨损量仅为20CrMo钢基体的6.36%.     

DCVD TiN形核长大机制的研究

实验对TiN沉积膜和基体复层膜采用了透射电镜衍射及x射线衍射分析方法,确立了TiN晶体与基体各相的位向关系。即TiN在初始形核时,在钢基体母相与碳化物上呈多晶紊乱位向形核,以[200]择优取向长大,以此建立PCVD TiN沉积膜生长模型。     

等离子喷焊铁/镍混合基喷焊层Q345复合板的制备

通过在铁合金粉末中加入5%质量分数的镍合金粉末来制备铁镍合金粉末。使用等离子喷焊技术在以Q345为基体的低合金钢表面制备铁/镍混合基喷焊层。通过设计正交实验,使用金相显微镜,物相显微镜以及扫描电镜,来研究铁/镍混合基喷焊层的物相以及微观组织,判断其基体和喷焊层的结合性是否良好以及对基体,融合线,喷焊层的金相组织进行观察与分析。在判断喷焊层显微硬度时,使用维氏显微硬度计,对试样的喷焊层,融合线以及基体进行测试,并对其数据进行分析。使用软件对试样的金相图进行晶粒分析,通过对试样的硬度,成型系数,焊缝宏观样貌,裂纹等数据进行分析,优化出具有高性能的铁/镍混合基Q345复合板工艺参数。     

铸造-热变形Nd-Fe-B永磁合金显微组织及性能的研究

对铸造NdFeB磁体进行了不同变形温度、不同变形量的热压及压后热处理的实验.研究了不同工艺下磁体的显微组织以及与磁性能的关系.结果表明,NdFeB永磁合金的磁性能和磁体的微观组织有密切关系.铸态组织对制造铸造-热压NdFeB永磁材料具有重要的影响,最终组织晶粒细小、均匀,主相被富Nd相薄层包围,晶界平直,高C轴取向,可以获得高磁性所要求的微观组织.     

衬底和热处理温度对ZnO薄膜的微观结构的影响

采用Sol-gel法,在普通载玻片和Si（100）上使用旋转涂覆技术制备了具有c轴择优取向生长的ZnO薄膜。利用XRD和SEM研究了衬底和热处理温度对ZnO薄膜的物相结构、表面形貌和（002）定向性的影响。结果表明,sol—gel旋涂法制备的ZnO薄膜为六角纤锌矿结构,玻璃衬底上生长的ZnO薄膜为多晶形态,Si（100）衬底表现出更优取向生长特性。随着热处理温度的升高,c轴择优取向程度逐渐增强,晶粒尺寸逐渐增大,ZnO的晶格参数先增加后减小。当温度在700℃时长出明显的柱状晶粒。     

Analysis and characterization of orientation structure of pre-oxidized PAN fibers in high magnetic fields

PAN fibers pre-oxidized at 240 ℃, 260 ℃, 280 ℃, 300 ℃ were treated in 8 T, 12 T, 16 T high magnetic fields, respectively. The experimental result implied that there were two kinds of magnetic units cyan and carbon-nitrogen heterocycle in pre-oxidized PAN fibers, and the movement of magnetic units resulted in changes of orientation structure of pre-oxidized PAN fibers in high magnetic fields. Overall orientation increased with increase of magnetic field intensity and extension of processing time, whereas change of crystalline orientation depended on magnetic field intensity and content of carbon-nitrogen heterocycle due to the competition of two magnetic units. Furthermore, magnetic fields induced the conversion from amorphous region to crystal region and improved crystalline properties of pre-oxidized PAN fibers.     

巨磁致伸缩材料Terfenol-D的磁致伸缩计算

考虑在压应力作用下磁畴的择优分布,应用磁畴转动模型,建立了在压应力作用下材料的磁致伸缩与磁场强度的关系,当H≤80KA/m、在较大压应力作用下时,计算结果与实验值基本符合,表明该表达式反映了在压应力作用下磁化机制,可以应用该式来描述材料在较低磁场强度下的磁致伸缩。     

Research of Current Mode Atomic Force Microscopy (C-AFM) for Si/SiC Heterostructures on 6H-SiC(0001)

Si/SiC heterostructures with different growth temperatures were prepared on 6 HSiC(0001) by LPCVD. Current mode atomic force microscopy and transmission electron microscopy were employed to investigate the electrical properties and crystalline structure of Si/SiC heterostructures. Face-centered cubic(FCC) on hexagonal close-packing(HCP) epitaxy of the Si(111)/SiC(0001) heterostructure was realized at 900°C. As the growth temperature increases to1 050°C, the 110 preferred orientation of the Si film is observed. The Si films on 6 H-SiC(0001)with different growth orientations consist of different distinctive crystalline grains: quasi-spherical grains with a general size of 20 μm, and columnar grains with a typical size of 7 μm×20 μm. The electrical properties are greatly influenced by the grain structures. The Si film with 110 orientation on SiC(0001) consists of columnar grains, which is more suitable for the fabrication of Si/SiC devices due to its low current fluctuation and relatively uniform current distribution.     

Effects of submicron diamonds on the growth of copper in Cu-diamond co-deposition

Submicron diamonds were co-deposited on aluminum substrates with copper from the acid copper sulfate electrolyte by electrolyte-suspension co-deposition.After submicron diamonds were added to the electrolyte,the shape of copper grains transformed from oval or round to polyhedron,the growth mode of copper grains transformed from columnar growth to gradual change in size,and the preferred orientation of copper grains transformed from (220) to (200).Analyzing the variation of cathodic overpotential,it was found that the cathodic overpotential tended to remain unchanged when copper plane (220) grew in the process of electrodepositing pure copper,while it tended to decrease with time when copper plane (200) grew m the process of co-deposition.It was inferred that copper plane (200) was propitious to the deposition of submicron diamonds.     

Microstructure and texture of electroformed copper liners of shaped charges

The microstructures of copper liners of shaped charges prepared by electroforming technique were investigated by trans-mission electron microscopy (TEM). Meanwhile, the orientations distributing of the grains in the electroformed copper liners of shaped charges was examined by the electron backscattering Kikuchi pattern (EBSP) technique. TEM observations have revealed that these electroformed copper liners of shaped charges have the grain size of about 1-3μm and the grains have a preferential orientation distribution along the growth direction. EB SP analysis has demonstrated that the as-formed copper liners of shaped charges exhibit a micro-texture,i.e. one type of fiber texture, and the preferred growth direction is normal to the surface of the liners.     

添加钬的钕铁硼烧结磁体的结构与磁性能

在工业生产线上制备（33-X）（Pr-Nd）-xHo-64．90Fe-0．20Cu-0．75Al-1．15B（wt％,x=0、1、3、5）烧结磁体,分析了其显微组织、取向度、磁性能与钬添加数量的关系。结果表明,添加钬制备的钕铁硼烧结磁体,其取向度提高;磁体显微组织致密,富钕相在主相晶粒边界的分布比较均匀;磁体内禀矫顽力明显上升,而剩磁小幅度下降。通过优化合金成分设计与改进工艺过程控制,实现了45M性能档次的Pr-Nd-Ho-Fe-Cu-Al-B烧结磁体的批量生产。     

Struetural and Magnetic Properties of Electrodeposited Ni70Fe30 Nanowire Array

Ordered Ni70Fe30 nanowire array was fabricated in a porous alumina template by altemating current electrodeDositiOn.The structural and magnetic properties of the as-obtained nanowire array were investigated by SEM,TEM,XRD,EDS and VSM.The results indicate that the as-obtained Ni70Fe30 nanowires exhibit a diameter of about 69.9 nm and aspect ratio of more than 60.Meanwhile,a preferred orientation[110]of bcc lattice was observed.The as-obtained nanowire array has an obvious magnetic anisotropy,of which the easy direction is perpendicular to the surface of the array.Moreover,after annealed,the Ni70Fe30 nanowire array exhibits an enhanced magnetic anisotropy.     

选区激光熔化3D打印钛合金及其复合材料研究进展

综述：生物医用铁基磁性纳米颗粒的制备研究进展

毛宇,李艳,顾宁

（东南大学 生物科学与医学工程学院,江苏省生物材料与器件重点实验室,生物电子学国家重点实验室,南京 210096）

摘要：磁性纳米材料具有独特的物理性能、化学性能以及生物效应,是一类重要的功能材料,可以应用于很多领域。在过去的几十年,铁基磁性纳米材料由于其优越的磁性能和巨大的生物医用潜力在生物医学领域引起了大量的关注。特别是具有诊断和治疗功能的磁性氧化铁纳米颗粒一直在生物医学领域发挥着重要作用。磁性氧化铁纳米颗粒是良性的、低毒的、生物相容且生物可降解的,是目前美国食品及药物管理局批准的唯一可用于临床的无机磁性纳米材料。本综述主要介绍了生物医用铁基纳米材料包括铁单质纳米颗粒、铁基合金纳米颗粒及磁性氧化铁纳米颗粒的制备研究进展,重点介绍了磁性氧化铁纳米颗粒的制备方法,并总结指出了磁性氧化铁纳米颗粒制备方法发展的重要性。

关键词: 铁基磁性纳米材料;生物医用;磁性氧化铁纳米颗粒;诊断和治疗功能;制备方法