锰渣微粉-石灰石粉作为水泥混合材的试验

以锰渣微粉和石灰石粉按照不同比例进行复掺,研究其物理性能及水化性能。结果表明：锰渣微粉-石灰石粉可以有效减小标准稠度用水量,缩短水泥凝结时间,并且在水泥水化过程中能够很好地发挥其物理、化学综合性能,保证水泥早期和后期的强度。     

石灰石替代部分矿渣作为水泥混合材的应用探讨

随着我国水泥行业的高速发展,用于水泥生产的主要原料——矿渣已明显表现出供应紧张的趋势．在这种形势下,能否采用其他廉价资源替代矿渣作为混合材生产水泥,已成为水泥行业亟待解决的问题之一．本文结合本厂实际,比较石灰石掺加前后水泥各项指标的变化情况,探讨石灰石掺加量对水泥性能和混凝土性能的影响;验证了石灰石替代部分矿渣作为水泥混合材的有效性和可行性,对提高水泥质量和降低生产成本有一定的借鉴意义．     

Strength of limestone-based non-calcined cement and its properties

A new type of cement was prepared with ground limestone powder, blastfurnace slag, steel slag and gypsum without calcination. The fraction of ground limestone powder in the cement was as high as 40 wt%–60 wt% without Portland clinker. All of its physical properties can meet the requirements of masonry cement standards. The impact of limestone content on physical properties of the cement and determined its impact on law was investigated. The steel slag can excit the aquation activity of this cement effectively, and the influence of its quantity on the strength of the materials was studied, which shows that the optimum quantity of mixing is 10%. By way of changing the different content of the lime stone by quartzy sample, the law of the compression strength and the PH value was determined, confirming that the lime stone can promote the early aquation of the slag and improve the early strength. The main hydration product of this cement is calcium aluminate hydrate, ettringite and calcium silicate hydrate, as indicated by XRD and SEM analysis.     

粉煤灰矿渣复合水泥试验研究及其应用

通过试验研究了粉磨方式、细度、复合组分比例及添加剂对粉煤灰、矿渣、石灰石与少量熟料组成的复合水泥性能的影响 .研究结果表明 :当以上三组分比例适当时 ,通过添加剂的有效作用 ,采取合理的粉磨工艺和制度 ,在熟料掺量 5 0 %时可以配制出 6 2 5R或 6 2 5复合水泥 ,熟料掺量 4 0 %可以配制出 6 2 5或 5 2 5R复合水泥 ,熟料掺量 30 %可以配制出 5 2 5或 4 2 5R复合水泥 .同时 ,对上述部分水泥配制的高性能混凝土进行了试验研究     

高强度复合硅酸盐水泥的研制

研究了一种高强度复合硅酸盐水泥.利用矿渣和硅质渣制备一种高强度的复合硅酸盐水泥,探讨不同掺量对水泥性能的影响,获得水泥基材料性能的互补效应.研究混合材对复合水泥体系的化学成分与物理性能的影响.通过对试验数据的分析,获得最优的混合材配比方案.     

Preparation of Super Composite Cement with a Lower Clinker Content and a Larger Amount of Industrial Wastes

The effects of the grinling mode ,finencess,gypsum kinds and dosage,mix proportions on properties of the composite composite cements consisting of slag ,fly ash ,limestone and a lowr content clinker were investigated,respectively ,The results show that when thre proportions among slag ,fly ash and limestone are appropriate ,the grinding technology and system are reasonable ,the optinized gypsums and addities are effective,the 52.5R grade cement (52.5R grade cement menas a higher strength than 52.5 at ealy age) can be prepared by clinker dosage of 50% in weight,the 42.5R or 42.5 ,32.5 grade composite cement containing 40% and 30% clinker also may be made ,respectively ,Moreover,the high perfomance concrete preparde from the abover composite cements was studied experimentally.     

镁渣替代石灰石配料外加剂的选择及掺量的研究

镁渣替代石灰石配料制备水泥熟料时，分别掺入和同时掺入2种自制外加剂，通过生料易烧性实验和熟料物理性能及XRD图谱的测定，确定外加剂和镁渣的最佳掺量。实验结果表明：同时掺入2种外加剂能大幅度改善生料易烧性，此时镁渣可以代替20％石灰石，烧成的硅酸盐水泥28d强度可达65．2MPa。     

提高矿渣水泥早期强度的试验研究

采用双掺法在矿渣水泥中加入适量的石灰石,可使矿渣水泥的早期强度及后期强度都略有提高.本文通过大量的对比试验,给出石灰石的最佳掺量;同时通过试样强度比值百分数的对比,分别提出掺入适量石灰石后7 d,28d抗折强度、抗压强度的提高幅度.这对克服矿渣水泥早期强度发展慢及施工期长的缺点具有一定的现实意义.     

利用工业废石灰制作激发剂的特性分析

在无熟料水泥中,激发剂的种类和数量是决定其水化反应速度和品质的关键。研究中,为尽可能利用工业废弃物来制造激发剂,对工厂的废石灰(简称WL)进行了物理化学分析。结果表明,WL的pH为12.1,满足无熟料高炉矿渣水泥的碱度标准,但使用前应进行干燥处理;WL的主要成分是石灰石,CaO的含量为40%~42%,当用作无熟料高炉矿渣水泥的激发剂时,应添加部分消石灰或增加其用量,以满足碱性成分的数量;WL的溶解实验几乎未发现重金属的溶出现象,即使是溶出都在环保允许范围之内。     

煤矸石代黏土煅烧水泥熟料配方优化试验研究

为获得煤矸石代黏土配料应用于水泥生产的煅烧热工条件和合理配方,选取不同煤矸石和不同品位的石灰石等原料配制6种水泥生料,在实验室熟料煅烧试验台中进行不同温度下煅烧水泥熟料的试验研究,对试验所得的熟料样品分别进行了游离CaO质量分数的测定和矿物组成的X射线衍射（XRD）分析.试验结果表明：煤矸石代黏土与中钙石灰石和高中钙石灰石配料,都能烧制出合格的水泥熟料,烧成温度比黏土配料的烧成温度降低50 ℃以上;而煤矸石与高钙石灰石的配方则在烧成温度上没有明显优势,说明煤矸石与中钙石灰石或高中钙石灰石配料更能烧制出高质量的水泥熟料.     

利用低品位石灰石生产低碱水泥的研究与实践

介绍了碱集料反应和国内外碱集料反应对混凝土的破坏情况,在试验基础上,突破传统的水泥配料模式,利用低品位石灰石、砂岩、矾士渣等生产出了高性能低碱水泥。     

掺矿粉水泥的水化机理研究

研究利用在硅酸盐水泥中掺加矿粉来提高水泥的抗折强度,降低脆性,并通过ＴＧ－ＤＴＡ、Ｘ－衍射及ＳＥＭ等微观分析方法对掺矿粉水泥的水化机理进行研究,结果表明,矿粉的掺入不权可以提高水泥的水化程度,增加水泥石的密实度,同时也可以降低水泥石的脆性。     

矿渣微粉应用性能分析研究

矿渣是水泥行业传统的混合材料，将矿渣制成微粉是水泥生产的新工艺。结合昆钢嘉华公司矿渣微粉的应用实际，对矿渣微粉在水泥和混凝土中的应用性能进行了分析。矿渣微粉无论是作为混合材在水泥中使用或是在作为掺和料在混凝土中使用，在提高强度、降低成本、保护环境等诸多方面都有理想的使用效果。     

矿渣和石膏混合制备墙体材料的试验研究

以大量的石膏和矿渣为原料,适当掺入水泥和其他组分制备不同配比的试块,选择凝结时间合理且强度较高的一组试块进行XRD分析和SEM照片分析．研究表明配比为矿渣：石膏：水泥=48：40：12,水灰比为0．42的试块性能最好．由于水泥、矿渣以及其他添加剂的加入,能够很好地调节墙体材料的耐水性．矿渣中含有Si和Al,通过石膏的激发作用,石膏与矿渣中的Al形成钙矾石,钙矾石呈凝胶状态,具有很好的强度和耐水性．     

矿物掺合料及硫酸钠对混凝土早期电导率的影响

目的研究混凝土中掺入粉煤灰、矿渣微粉及硫酸钠的电导率变化规律.方法利用电导率仪,测定混凝土从成型开始48h电导率的变化规律.结果硫酸钠的掺入使水泥混凝土电导率峰值滞后;随着粉煤灰、矿渣微粉掺量的增加,混凝土的电导率呈下降趋势;而加入硫酸钠后,粉煤灰电导率随掺量增加而增加,矿渣微粉电导率整体规律并无变化.结论电导率曲线表明了硫酸钠对普通水泥除具有缓凝作用外,还为其早强作用提供了新证据;矿物掺合料的活性低于水泥且矿渣微粉的活性高于粉煤灰,硫酸钠对粉煤灰及矿渣微粉具有较好的激发作用.     

Utilization of Coal Gangue and Copper Tailings as Clay for Cement Clinker Calcinations

In order to avoid environmental pollution from Coal gangue (CG) and copper tailings (CT), the utilization as cement clinker calcinations was experimentally investigated. Low-calcium limestone was also selected as another raw material. The clinker component and microstructure were analyzed by XRD and SEM. The experimental results showed that qualified cement clinker could be generated by substituting CG and CT compound for clay. While mixed with high-calcium limestone and low-calcium limestone, the calcinati...     

再生混凝土的环境评价

对再生混凝土的资源消耗、能量消耗和二氧化碳的排放量进行了量化分析，结果表明，利用再生粗骨料配制混凝土比完全使用天然集料配制的混凝土可节约62％的石灰石资源；利用废弃混凝土作制造水泥的原料与再生粗集料，可节省配制混凝土的62％石灰石资源，还可节省制造水泥的优质石灰石60％、粘土40％和铁粉35％的资源，同时，可减少20％C02的排放量。研究还表明，配制再生混凝土的能耗与配制普通混凝土的能耗相当。     

冶金渣制备生态型人工鱼礁混凝土的试验研究

通过正交试验研究了矿渣钢渣熟料石膏体系胶凝材料的强度。胶凝材料正交试验表明：矿渣：钢渣的复合比为7∶1,矿渣和钢渣的比表面积分别为480 m 2·kg -1和550 m 2·kg -1,并与10%的水泥熟料和10%的脱硫石膏复合的胶凝材料具有较高的强度。以优化后的胶凝材料代替水泥,并以热闷法稳定化的钢渣颗粒为骨料,可以制备出抗压强度达到65 MPa以上的人工鱼礁混凝土。利用XRD和SEM方法分析胶凝材料的水化过程,结果表明,水化反应主要生成AFt相和C-S-H凝胶,钢渣、水泥熟料和脱硫石膏的协同作用对矿渣的火山灰活性反应具有重要促进作用。     

矿粉对水泥和混凝土性能的影响

为了探寻矿粉细度及掺入量对水泥和混凝土性能的影响,通过试验测试方法,分析了矿粉和水泥的基本性质,研究了超细矿粉和普通矿粉的掺量对水泥基材料标准稠度、凝结时间、流动度和力学性能的影响.结果表明：普通矿粉使水泥净浆标准稠度需水量下降,而超细矿粉则增加标准稠度需水量,两种矿粉都使水泥净浆凝结时间略微延长.普通矿粉可以改善水泥净浆的流动度,超细矿粉的加入则降低了水泥净浆的流动度.普通矿粉和超细矿粉降低水泥净浆早期（7 d）抗压强度,提高后期（28 d）抗压强度,掺10％～50％的普通矿粉的水泥净浆28 d抗压强度提高2.9％～9.7％,掺入超细矿粉28 d抗压强度提高3.9％～20.1％,普通矿粉和超细矿粉的最佳掺量为10％～30％;两种矿粉替代10％～50％水泥所配制的混凝土的强度得到了明显的提高.     

Resource utilization of slag from desulphurization and slag skimming: A comprehensive recycling process of all components

In order to make the slag from desulphurization and slag skimming (SDSS) to be comprehensively recycled and utilized, a combined process of beneficiation and building materials preparation was proposed to recover iron from SDSS, meanwhile to apply the remaining slag tailings as cement admixture. From this process, three iron-rich products were recovered in stages by clean gravity - magnetic separation, slag tailings were left. Slag powder was prepared by ultrafine grinding of slag tailings. The stability, setting time and cement mortar strength of the slag tailings cements (STC) which were mixed with Portland cement and slag powder were studied respectively. The results showed that a proper overall performance still could be obtained at the slag powder content of 30%. Chemical composition analysis, X-ray diffraction (XRD) analysis, metallographic microscope and scanning electron microscope (SEM) analysis were employed to assess the characteristics of the SDSS and the products obtained from the whole process. The results indicated that the three iron-rich products could be used as a raw material for steelmaking and ironmaking and the relatively large amount of calcium silicate (C₂S) and tricalcium silicate (C₃S) in the slag tailings make the addition of slag powder into the Portland cement feasible.