Influence of ZrO2 on sintering and crystallization of CaO-Al2O3-SiO2 glass-ceramics

ZrO2 was added into CaO-Al2O3-SiO2 glass-ceramics and the effect of ZrO2 on sintering and crystallization of CaO-Al2O3-SiO2 glass ceramics was investigated. The results show that the sintering shrinkage ratio of glass particles decreases with the increase of the content of ZrO2. ZrO2 has an unfavourable effect on sintering shrinkage ratio of glass particles. The sintering shrinkage ratio of glass particles increases with the increase of sintering temperature. The increase of sintering temperature favors the decrease of the liquid phase viscosity of glass particles. ZrO2 has little effect on crystallization of main crystalline phase （β-wollastonite）. However, it promotes the crystallization at relatively low temperature.     

RESEARCH AND PRODUCTION OF GLASS-CERAMIC DECORATED MATERIAL CONTAINING CHROMIUM

In this paper, the influences of catch-color agent content on glass-ceramic decorated material in the system of CaO-Al_2O_3-SiO_2 were studied. By ladder temperature furnace and sintering shrinkage curve measurement, the influence of catch-color agent content on sintering and crystallization temperature was discussed. By means of XRD, three point bending strength and density measurement, the properties of the decorated material were investigated.     

THE AUTOMATIC CRYSTALLIZATION OF MgO DURING THE SINTERING Si_3N_4-MgO-CeO_2 CERAMICS

The automatic crystallization of MgO duringthe sintering of Si_3N_4-MgO-CeO_2 is first discovered.ForSi_3N_4-MgO-CeO_2,ceramics,the MgO-CeO_2 would reactwith SiO_2 to form liquid at 1450℃ and then transform intoglassy phase in the sintered bodies after cooling down.Above1550℃,MgO would crystallize automatically during sinter-ing.So the glassy phase which is harmful to the high temper-ature properties is then eliminated.The present work is ofgreat value for theoretical study and application.     

THE CHARACTERISTICS OF THE PRESSURELESS SINTERED Si_3N_4-MgO-Ce0_2 CERAMICS

An investigation of the pressureless sintering of Si3N4 with MgO-CeO2 revealed that MgO-CeO2 is a most effective sintering aid for silicon nitride. The amount of MgO-CeO2 and sintering conditions have a strong influence on the densification behaviour and mechanical properties of the sintered materials. The effect of the additive and sintering conditions are discussed. The silicon nitride pressureless sintered with MgO-CeO2 retained a relative density of 98. 5% and a bending strength of 950 MPa. The Si Mg-Ce-O-N system is of great value for application and theoretical study.     

STRUCTURE AND PROPERTY OF PIEZOELECTRIC CERAMICS OF QUATERNARY SYSTEM

Composite perovskite piezoelectric ceramicsof PMMN quaternary system were prepared by cold-pressingand solid-phase sintering.Piezoelectric modulus and densityof the samples were measured after polarization.X-raydiffraction analysis and SEM were used to prove the resultthat the major phase of the piezoelectric ceramic spectimenbased on PZT is PZT phase,which is tetragonal system andP_(4mm) space group.     

Effect of heat treatment method on microstructure of tailings glass ceramics

A Cao-Mgo-Al2O3-SiO2 quaternary system was established with the main crystal phase design based on Diopside, and the effect of once-through sintering heat treatment on microstructure of iron railings glass ceramics was studied by using DTA, SEM along with measurement of microhardness and volume density. The experimental results show that, when the total amount of FeO and Fe2O3 exceeds 10wt%, a large number of fine nuclei are produced in the annealing process, and the phenomenon of nucleus resorption happens during the process of nucleation heat treatment, which is unfavorable for preparing iron tailings glass ceramics through once-through sintering method. When the annealing temperature from 1250 ℃ to 830 ℃, setting crystallization time for 4h, without heat treatment, crystals are well grown with arrangement and interlocking in glass phase. At 830 ℃ the crystals are well developed, well distributed and of good size; with crystallization time of 4 h the crystals with radial shape have high content and regular arrangement.     

PHASE SEPARATION AND CRYSTALLIZATION OF CHALCOGENIDE GLASSES

In this paper the experimental resultsassociated with the phase separation and nucleation andcrystallization of chalcogenide glasses are described.Experi-ments demonstrate that the phas separation may be affectedby small amount of additives.It has been found that somechalcogenide glasses could be converted into glass-ceramicswithout phase separation.The different mechanisms ofnucleated crystallization of chalcogenide glasses are discussedand propossed.     

Relationship betwccn Liquid Phase Content and the Orientation of PMNT Ceramies by TGG Method

The effects of glass flit on the sintering and electric properties of PMN-PT textured ceramics were investigated. The glass frits, including PbO, Bi2O3 and ZnO, were selected since liquid phase sintering lowered the PMN-PT sintering temperature. The piezoelectric properties of PMN-PT ceramics with glass frit addition are strongly dependent on the densification. The addition of glass frits into PMN-PT matrix reduced the sintering temperature to 1 100℃ instead of 1 150 ℃ for samples without glass. The piezoelectric coefficients （d33） of PMN-PT textured ceramics achieved 568 pc/N with 1 wt% excess PbO.     

Relationship between Liquid Phase Content and the Orientation of PMNT Ceramics by TGG Method

The effects of glass frit on the sintering and electric properties of PMN-PT textured ceramics were investigated. The glass frits, including PbO, Bi2O3 and ZnO, were selected since liquid phase sintering lowered the PMN-PT sintering temperature. The piezoelectric properties of PMN-PT ceramics with glass frit addition are strongly dependent on the densification. The addition of glass frits into PMN-PT matrix reduced the sintering temperature to 1 100 ℃ instead of 1 150 ℃ for samples without glass. The piezoelectric coefficients (d33) of PMN-PT textured ceramics achieved 568 pc/N with 1 wt% excess PbO.     

STUDY ON STRENGTH AND PETROGRAPHIC STRUCTURE OF CLINKER BY LOW-TEMPERATURE BURNING

In this paper,the strength and petrographicstructure of clinker by low-temperature burning are studied.The results show that both the calcining temperature of Ca-CO_3,and sintering temperature clinker decreases by 150℃com-pared with those in traditional rotary kiln,the rate of f-CaOin the clinker sintered at 1300℃ is 0.29%～2.81%,thestrength of the clinker is 62.5MPa with maxium 69.4MPa ata specific area of 2900～3400cm~2/g.The results also showthat the types of petrographic structure of the clinker can beclassified as:homogeneous structure,inlaid or edged struc-ture,stain-melting structure and porous strncture.The clinkersintered at 1300±15℃ temperature and with enough reten-tion period is mainly in homogeneous structure.     

EFFECTS OF In_2O_3 DOPING AND SINTERING TEMPERATURE ON THE ELECTRICAL PROPERTIES OF ZnO VARISTORS

ZnOvaristorshaveexcellentnon--linearcurrent--voltage(IV)characteristicsandenergyabsorptionability,makingthemvaluableasvoltagesuppressersinpowersystemsandelectroniccircuitsLlj.Thecurrentvoltagedependenceofvaristorsisdescribedbytherelation:I=C(V)"whereIisthecurrentdensity,Caconstant,Vthevoltage,andathecoefficientofnon--linearity.ThestudyresultsshowthatpureZnOgrainhasnottheelectricalconductivity.Intheprocessofitspreparation,thedefectisproducedinthegrain,andmakeitann--typesemiconductor.Thecer…     

PREPARATION AND PROPERTIES OF CRYSTAL GLASSES WITHOUT LEAD CONTENT

BaO is the most common consideration in the preparation of new crystal glass jor getting rid of lead content in the glass and ceramic mares to protect hu-man health and environment. But for keeping the glass products' properties to meet the requirements oj the traditional crystal glass, B2O3,A12O3, TiO2,SrO and ZnO etc ( at a special ratio ) had been researched with BaO to constitute a mixture to replace the lead content in the glass compositions. The results Amu that both using the mixture and adding Less lead in the hatches could make the new glass products to reach the requirement of the properties oj the common crystal glass but with less or no lead content and the corresponding poisons.     

Effects of In2O3 doping and sintering temperature on the electrical properties of ZnO varistors

ZnO varistors are prepared using the 0.1–0.3 mm ZnO powders. The effects of the sintering temperature, contents of In₂O₃ doping on the non-linear properties of ZnO varistors have been investigated. The results show that this kind of ZnO powder has a high sintering activity. It is suitable for making the low voltage varistors. The V _c decreases with the increase of sintered temperature, when the In₂O₃ content is fixed (0.98%, mass fraction), and increases with the increase of In₂O₃ contents when the temperature is steady. Project supported by the Nonferrous Metals Industry Corporation of China Synopsis of the first anthor Zhao Ruirong, born in Jan. 1935, majoring in nonferrous metal metallurgy and products exploition.     

碳酸根含量对碳酸羟基磷灰石形貌和热处理的影响分析

采用沉淀法制备了两种不同碳酸根〈CO3^2-）含量的纳米碳酸羟基磷灰石（nanosized carbonated hydroxyapatite,CHA）,研究了碳酸根含量对CHA晶体形貌、烧结和热稳定性的影响,用X射线衍射和透射电镜表征了样品的物相组成与形貌．结果表明：随着碳酸根含量的减小,CHA晶粒尺寸和长径比增加;CHA坯体的烧结温度和粉体的热稳定性与初始的碳酸根含量有关,含量越高,烧结温度越低,热稳定性越差．     

BaO-MgO-Al2O3-SiO2系统微晶玻璃的研究

以MgO-Al2O3-SiO2系统为基础玻璃组成,TiO2为晶核剂,用少量的BaO取代MgO,制备出顽辉石/堇青石基微晶玻璃.采用差热分析、X射线衍射分析、扫描电镜等测试手段研究了BaO对玻璃析晶性能和显微结构等性能的影响,并探讨了不同量的BaO取代MgO对其电导率的影响.结果表明,在1 480℃通过熔融法制备玻璃试样...     

BaO改善高钛型高炉渣起泡性能的研究

着重探讨了渣中BaO含量与钛渣起泡性能的关系,指出适宜BaO含量对改善钛渣起泡性能,对钒钛矿冶炼是很有好处的。     

MC尼龙6／纳米ZnO复合材料等温结晶动力学的研究

采用原位聚合反应制备了MC尼龙6／纳米ZnO复合材料,并用差示扫描量热法（DSC）研究了MC尼龙6／纳米ZnO复合材料的等温结晶动力学。结果表明,在188～196℃时MC尼龙6及MC尼龙6／纳米ZnO复合材料结晶速率主要由成核过程控制。MC尼龙6／纳米ZnO复合材料的结晶速率G比MC尼龙6提高了0．1～0．3min^-1.研究发现,纳米ZnO的加入起到了异相成核的作用,提高了MC尼龙6的结晶速率。MC尼龙6和MC尼龙6／纳米ZnO复合材料的结晶速率G和结晶速率常数k均随结晶温度的升高而降低,半结晶时间t1/2和达到最大结晶速率的时间tmax随结晶温度的升高而缩短。但是MC尼龙6／纳米ZnO复合材料比MC尼龙6降低的幅度更大。     

Forming regularity and relation between composition and property of B2O3-BaO-ZnO glass

B2O3-BaO-ZnO glass was prepared by using conventional melt quenching technology. The forming regularity and the relationship between the composition and the property of B2O3-BaO-ZnO glass were investigated. The results show that the composition range for forming B2O3-BaO-ZnO glass is very wide, but the content of B2O3 has a limit within mole fraction of 25%-75%. When the content of B2O3 is over the limit, the melt will be divided into two phases with different compositions and structures, whereas too low content of B2O3 will result in the crystallization of the melt during the cooling process. The thermal expansion coefficient, the transition temperature and the resistivity of the glass at room temperature are (5-10)×10-6 ℃-1, 480-620 ℃ and (1.5-3.0)×1010 Ω·m, respectively.