微波遥感的发展与应用

微波遥感作为遥感技术的一个分支,是20世纪70年代发展起来的一门年轻的学科.着重以我国微波遥感发展的历程为例,回顾了三十多年来微波遥感领域学术与技术的迅速发展,比较分析了微波遥感对于可见光和红外遥感有着不可比拟的优越性,因而在海洋、冰雪、大气、测绘、农业、灾害监测等方面都有着广泛的应用.同时提出了目前我国在微波遥感领域存在的若干不足并指出了今后的研究方向.     

Sand deposit-detecting method and its application in model test of sand flow

Against the background of the sand-flow foundation treatment engineering of Guangzhou Zhoutouzui variable cross-section immersed tunnel, a kind of sand deposit-detecting method was devised on the basis of full-scale model test of sand-flow method. The real-time data of sand-deposit height and radius were obtained by the self-developed sand-deposit detectors. The test results show that the detecting method is simple and has high precision. In the use of sand-flow method, the sand-carrying capability of fluid is limited, and sand particles are all transported to the sand-deposit periphery through crater, gap and chutes after the sand deposit formed. The diffusion range of the particles outside the sand-deposit does not exceed 2.0 m. Severe sorting of sand particles is not observed because of the unique oblique-layered depositing process. The temporal and spatial distributions of gap and chutes directly affect the sand-deposit expansion, and the expansion trend of the average sand-deposit radius accords with quadratic time-history curve.     

Undrained dynamical behavior of Nanjing flake-shaped fine sand under cyclic loading

A series of dynamic behavior tests on Nanjing flake-shaped fine sand were performed by using the WFI cyclic triaxial apparatus made in England. The dynamic behaviors of Nanjing flake-shaped fine sand under different static deviator stress levels and cyclic stress ratios were studied. Through comparing the effective stress path under cyclic loading with static loading, the processes of liquefaction of saturated Nanjing flake-shaped fine sand with development of dynamic pore-water pressure, including the initial compact state, compression state and dilative state, were investigated. The variation of the shear stiffness with the number of cycles and cyclic strain was investigated by analyzing the secant shear modulus in each unload-reload loop of dynamic stress-strain relationship. And by means of the exponential function, the empirical equations of the relationship between secant shear modulus Gsec, shear modulus ratio Gsec/Gmax and cyclic strain ε were established based on series of test results. The results show that according to different combinations of static deviator stress and cyclic stress, two kinds of failure patterns with deviator stress reversal or no deviator stress reversal are observed in the samples tested in this series, including cyclic mobility and the failure of accumulation residual strain. In addition, the degradation of dynamic shear modulus is due to the development of vibration pore-water pressure and it is observed that the shear modulus reduces with the progressive number of cycles.     

Field study of plastic tube cast-in-place concrete pile

The compositions, technical principles and construction equipments of a new piling method used for ground improvement plastic tube cast-in-place concrete pile were introduced. The results from static load tests on single piles with different forms of pile shoes and on their composite foundations were analyzed. The distribution patterns of axial force, shaft friction and toe resistance were studied based on the measurements taken from buried strain gauges. From the point of engineering application, the pile has merits in convenient quality control, high bearing capacity and reliable quality, showing higher reasonability, advancement and suitability than other ground improvement methods. The pile can be adopted properly to take place of ordinary ground improvement method, achieving greater economical and social benefits.     

Research advances of un-symmetric constitutive theory of anisotropic viscoelastic liquids and its hydrodynamic behavior

Research advances of un-symmetric constitutive equation of anisotropic fluid,influence of un-symmetric stress tensor on material functions,vibrational shear flow of the fluid with small amplitudes and rheology of anisotropic suspension were reported.A new concept of simple anisotropic fluid was introduced.On the basis of anisotropic principle,the simple fluid stress behaviour was described by velocity gradient tensor F and spin tensor W instead of velocity gradient tensor D in the classic Leslie-Ericksen continuum theory.Two relaxation times analyzing rheological nature of the fluid and using tensor analysis a general form of the constitutive equation of co-rotational type was introduced.More general model LCP-H for the fluid was developed.The unsymmetry of the shear stress was predicted by the present continuum theory for anisotropic viscoelastic fluid-LC polymer liquids.The influence of the relaxation times on material functions was specially studied.It is important to study the unsteady vibrational rotating flow with small amplitudes,as it is a best way to obtain knowledge of elasticity of the LC polymer,i.e.dynamic viscoelasticity.For the shear-unsymmetric stresses,two shear stresses were obtained thus two complex viscosities and two complex shear modulus(i.e.first and second one) were introduced by the constitutive equation which was defined by rotating shear rate introduced by author.For the two stability problems of fluid,such as stability of hydrodynamic flow and orientational motion,were discussed.The results show that the polymer suspension systems exhibit anisotropic character.The PNC systems can exhibit significant shear-thinning effects.For more concentrated polymer nano-suspensions,the first normal stress difference change from positive to negative,which is similar to LC polymer behavior.     

当前民办高校融资难的成因及对策

针对民办高校所需办学经费无国家财政拨款,全部为自筹资金的现状,分析了形成当前民办高校融资难的原因,既有信贷政策、银行方面的因素,也有民办高校自身的因素.提出民办高校要生存,要发展,光靠举办者投入或捐赠以及每年的学费收入是不够的,还需要积极拓展更多融资渠道解决办校融资难的问题.     

爱的阶梯——析克里斯蒂娜·罗塞蒂诗歌主题变换

克里斯蒂娜一生孤独迷离,她弃绝人间的舒适享乐全心追求永恒的精神快乐.诗歌是她生活的真实写照:从初恋失败,父亲病逝,到中年全方位的社交活动,再到孤独的晚年隐退.她的诗歌也呈现出统一协调的三部曲:从温婉细腻的抒情诗,到内涵丰富的叙事诗,再到热烈苍凉的祈祷文.爱是诗人背后最隐秘的缘由.为寻求心灵的平静,她试图在爱中找到永恒,却一次次被爱推着向前走:从人世爱恋到社会爱心,再回归上帝.     

予岂好辩哉?予不得已也——《孟子》一书对孟子辩者形象的塑造

长于论辩,是《孟子》散文的突出特征.《孟子》一书通过对孟子言行的记录,不仅表现了孟子的思想和理论,亦成功地为后人展示了一个鲜活的辩者形象.孟子与时人的论辩涉及政治、经济、伦理道德、哲学等诸多领域;通过对旁征博引、因势利导、诱敌入彀、归谬反驳、执经行权等论辩方法的娴熟驾驭,表现出鲜明的个性特点.     

Influencing factors of compressive strength of solidified inshore saline soil using SH lime-ash

Through unconfined compressive strength test,influencing factors on compressive strength of solidified inshore saline soil with SH lime-ash,ratio of lime-ash(1-K),quantity of lime-ash,age,degree of compression and salt content were studied.The results show that because inshore saline soil has special engineering characteristic,more influencing factors must be considered compared with ordinary soil for the perfect effect of solidifying.     

一种风幕式抽油烟机的实验研究

通过对厨房油烟扩散机理的分析和模型实验,研究了影响油烟控制的各种因素,采用实验与计算流体力学仿真技术相结合的方法,对不同情况下油烟罩的油烟控制性能进行了比较、分析,设计出了一种新型节能型抽油烟机。     

Effect of thermal oxidation on microstructures and mechanical properties of nanoporous coppers

Nanoporous copper oxides were formed by thermal oxidation of nanoporous copper at 150°C–270°C. The oxidation process of nanoporous copper was investigated by using XRD, SEM, nitrogen adsorption, HRTEM and nanoindentation. The variation of microstructures and mechanical properties was analyzed. The results showed that the content of copper oxides increased, the ligament gradually coarsened, and the mechanical properties of nanoporous structure were improved with the increase of oxidation temperature. When the oxidation temperature was below 210°C, the ligament surface was oxidized to Cu_2O, and the composite structure of Cu_2O@Cu was formed. The formation of CuO occurred since 220°C, and the composite structure of CuO/Cu_2 O@Cu was formed. CuO nanowires were grown on the ligament surface at 250°C; the specific surface area, elastic modulus and hardness of nanoporous structure are 1.37, 3.31 and 7.58 times that of the nanoporous copper, respectively.     

Liquid metal assisted regulation of macro-/micro-structures and mechanical properties of nanoporous copper

Nanoporous metals have received significant attention as a new class of structural and functional materials. However, the macroscopic brittle fracture under the tensile test is an impediment to their practical applications. Thus, it is of central importance to develop nanoporous materials with low cost and high tensile ductility. Herein, a nanoporous Cu film supported on a pure Cu substrate (NPC@Cu) was fabricated by utilizing a liquid Ga assisted alloying-dealloying strategy, and the thickness of NPC film can be precisely regulated by changing the mass loading of liquid Ga. In-situ X-ray diffraction was performed to further explore the alloying/dealloying mechanisms. The NPC@Cu films show good tensile mechanical properties with a minimum elongation of 13.5 %, which can be attributed to the good interface bonding and certain modulus matching between the nanoporous Cu layer and the Cu substrate. Our findings demonstrate that the design of film-substrate structure provides a feasible strategy for enhancing the mechanical properties of nanoporous metals.

     

Effects of atmospheres and precursors on MnO x /TiO2 catalysts for NH3-SCR at low temperature

The effects of atmospheres and precursors on MnO _x /TiO₂ catalysts were studied, which were prepared by the impregnation method and tested for their NO _x conversion activity in ammonia selective catalytic reduction (NH₃-SCR) reactions. Results showed that the manganese carbonate (MC) precursor caused mainly Mn₂O₃, while the manganese nitrate (MN) precursor resulted primarily in MnO₂ and the manganese sulfate (MS) precursor was unchanged. The manganese acetate (MA) precursor leaded obtaining a mixture of Mn₂O₃ and Mn₃O₄. NO _x conversion decreased in the following order: MA/TiO₂ > MC/TiO₂ > MN/TiO₂ > MS/TiO₂ > P25, with a calcination temperature of 773 K in air. Catalysts that were prepared by MA and calcined in oxygen performed strong interaction between Ti and Mn, while MnTiO₃ was observed. Compared to the catalysts calcined in nitrogen, those calcined in oxygen had larger diameter and smaller surface area and pore. Catalysts that were prepared by MA and calcined in nitrogen tended to gain higher denitration rates than those in air, since they could be prepared with significant specific surface areas. NO _x conversion decreased with calcination atmospheres: Nitrogen> Air> Oxygen. Meanwhile, amorphous Mn₂O₃ turned into crystalline Mn₂O₃, when the temperatures increased from 673 to 873 K.     

Local segregation in Cu-In precursors and its effects on microstructures of selenized CuInSe2 thin films

Local segregation in Cu-In precursors and its effects on the element distribution and microstructures of selenized CuInSe₂ thin films were investigated. Cu-In precursors with an ideal total mole ratio of Cu to In of 0.92 were prepared by middle frequency alternating current magnetron sputtering with Cu-In alloy target, then CuInSe₂ absorbers for solar cells were formed by selenization process in selenium atmosphere. Scanning electron microscope and energy dispersive X-ray spectroscope were used respectively to observe the surface morphologies and determine the compositions of both Cu-In precursors and CuInSe₂ thin films. Their microstructures were characterized by X-ray diffractometry and Raman spectroscope. The results show that Cu-In precursors are mainly composed of Cu₁₁In₉ phase with In-rich solid solution. Stoichiometric CuInSe₂ thin films with a homogeneous element distribution and single chalcopyrite phase can be synthesized from a segregated Cu-In precursor film with an ideal total mole ratio of Cu to In of 0.92. CuInSe₂ thin film shows P-type conductivity and its resistivity reaches 1.2×10³ Θ·cm. Foundation item: Project(2004AA513023) supported by the National High Technology Research and Development Program of China     

Preparation and mechanical behavior of Mg-based bulk metallic glasses and their matrix composite

Mg87-xCuxDy13(x=22,27,32) bulk metallic glasses (BGMs) with a diameter of 6-8 mm and in-situ Mg phase reinforced Mg70Cu17Dy13 BMG matrix composite with a diameter of 3 mm have been prepared by copper mould casting. The glass forming ability (GFA) of Mg-Cu-Dy alloys have been investigated by differential scanning calorimetry (DSC) and X-Ray diffraction (XRD) and tne mechanical properties have been measured. Results show that Mg87-xCuxDy13(x=22,27,32) alloys in the Mg-Cu-Dy alloy system exhibit excellent GFA, and Mg60Cu27Dy13 alloy has the largest GFA among these alloys. And In-situ Mg phase reinforced Mg70Cu17Dy13 BMG matrix composite exhibits some work hardening and a high fracture compressive strength of 702.38 MPa and some plastic strain of 0.81%. The improvement of the mechanical properties is attributed to the fact that the Mg phase distributed in the amorphous matrix of the alloy has some effective load bearing and plastic deformation ability to restrict the expanding of shear bands and cracks and produce its own plastic deformation.     

Highly sensitive glucose sensor based on hierarchical CuO

The fabrication of high performance CuO based glucose sensors remains a great challenge due to the "trade-off effect" between sensitivity and linear range. In this study, a hierarchical CuO nanostructure with a great number of firecracker-shaped nanorods along the ligament and three-dimensional interconnected nanoporous is obtained by dealloying and post oxidation process of Al-33.3 wt% Cu eutectic alloy ribbons. Because of the precise structural design, not only the number of active sites for glucose electro-oxidation is significantly increased but also the glucose diffusion under high concentration is greatly accelerated, leading to a high sensitivity of 1.18 mA cm~(-2) mM~(-1) and a wider linear range up to 5.53 mM for glucose detection. This work provides a potential approach to design hierarchical nanostructure for other metal oxides with desirable properties for electrocatalytic applications.     

Crystallization kinetics and magnetic properties of Fe73.5Si13.5B9Cu1Nb1V2 nanocrystalline powder cores

Amorphous ribbons of the alloy Fe_73.5Si_13.5B₉Cu₁Nb₁V₂ were prepared by the standard single copper wheel melt spinning technique in the air atmosphere. The crystallization kinetics of amorphous ribbons was analyzed by non-isothermal differential scanning calorimetry (DSC) measurements. The crystallization activation energies of amorphous ribbons calculated by using Kissinger model were 364 and 337 kJ/mol for the first and the second crystallization, respectively. The Avrami exponent n was calculated from the Johnson-Mehl-Avrami (JMA) equation. The value of the Avrami exponent showed that the crystallization mechanism in the non-isothermal primary crystallization of amorphous ribbons was all shapes growing from small dimensions controlled by diffusion at decreasing nucleation rate. The variation of soft magnetic properties of nanocrystalline Fe_73.5Si_13.5B₉Cu₁Nb₁V₂ alloy powder cores as a function of milling times has been investigated. It is found that the effective permeability of the cores shows high frequency stability and decreases with the increase of milling times. The quality factor increases with increasing frequency in lower frequency range, and reaches a maximum at the frequency of 80 kHz then decreases gradually with increasing frequency.     

Interfacial characteristics of high frequency induction brazed Cu and pre-metalized graphite joints

Oxygen-free copper and pre-metalized graphite were brazed using CuNiSnP braze alloy by high frequency induction heating method. Interfacial microstructures and reaction phases were analyzed by scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDS). The strength and resistance of the joints were tested. It is found that when the brazing parameters are optimized, the structures of the joints are graphite/(Cu,Ni)/Ni(s.s)+Ni _x P _y /Cu₃P+Cu(s.s) (including Sn)+eutectic structures (Cu₃P+Ni₃P+Cu(s.s)/Cu (s.s)/Cu). When the temperature increases to 750 °C or the holding time prolongs to 300 s, the eutectic structures disappear and the amount of Cu₃P increases. The maximum shear strength of the joints is 5.2 MPa, which fracture at the interface of graphite and metallization. The resistance of the joints is no more than 5 mΩ.     

Zr41 Ti14 Ni12.5 Cu10 Be22.5非晶合金冲击压缩行为理论与实验研究

为研究Zr_(41)Ti_(14)Ni_(12.5)Cu_(10)Be_(22.5)非晶合金的冲击压缩响应及物态方程,利用平板冲击试验,测试了受到速度为350 m/s～550 m/s的铜板冲击时,非晶合金试样的自由面粒子速度;采用阻抗匹配法得到了材料的雨贡纽参数,并利用理想混合物模型对材料的雨贡纽参数进行预估,分析对比了理论计算结果与实验结果;将求材料格林艾森物态方程转化为非线性最优化问题,提出了基于模拟退火算法的材料格林艾森物态方程计算方法,设计了退火参数表,并采用解析法计算了材料的布里希-默纳罕物态方程和三项式物态方程,对比研究了三种物态方程与实验结果.理论和实验结果表明,5～10 GPa压力范围内,Zr_(41)Ti_(14)Ni_(12.5)Cu_(10)Be_(22.5)非晶合金的零压体积声速为4 267 m/s,D-u曲线斜率为4.376,曲线斜率远大于一般金属材料,其雨贡纽极限强度为5.60 GPa左右;理想混合物模型仅适用于计算高压区Zr基非晶合金的雨贡纽参数,低压区理论计算结果与实验结果误差较大;在5～10 GPa压力范围内,格林艾森物态方程、三项式物态方程与实验结果吻合度较高,而布里希-默纳罕物态方程误差较大,不适用于计算材料状态参量.     

Resource assessment of copper deposits in China

Copper-bearing deposits of China are statistically analyzed in terms of ore grade, metal amount and ore tonnage. Each of grade and metal amount shows more or less a lognormal distribution. Analysis gives 10 copper metallogenic districts, each having specific densities of deposit numbers and copper reserves larger than 3. Based on the ratio of copper in ore value (R _Cu), Chinese copper deposits are classified into two groups: mainly copper-producing deposits (MC: R _Cu⩾0.5) and accessorily copper-producing deposits (AC: R _Cu<0.5). The grade-tonnage relation of MC deposits can be combined by two exponential functions approximating high grade (>3.0%) and low grade (<2.0%) parts. The critical copper grade, which is obtained from the low grade part of the relation, is 0.34%. Chinese copper resources are concluded to become pessimistic, because some mines are working with grades close to this critical value. Taking account of the fact that many copper deposits are actually polymetallic, Cu-equivalent grades, which are converted from ratios of metal prices to the copper price, are also introduced. The critical Cu-equivalent grade of MC deposits (0.43%) also suggests that Chinese copper resources are pessimistic.