Capillary-based water removal cathode for an air-breathing micro direct methanol fuel cell

This paper presents a capillary-based water removal cathode for an air-breathing micro direct methanol fuel cell (μDMFC). The mechanism of water removal from the cathode is studied and an array of capillaries with hydrophilic surface is designed on the ribs of the cathode structure. Microfabrication techniques, including double-side lithography and ICP, were used to fabricate the anode and cathode plates of the μDMFC on the same silicon wafer simultaneously. The surface of capillary structure was treated by low temperature oxygen plasma to improve the hydrophilicity. One μDMFC with capillary-based water removal cathode and another regular one without were both assembled and characterized. Measured results show that the μDMFC with water removal cathode achieves a power density of 2.35 mW/cm², 12 % larger than that of the regular one with the value of 2.10 mW/cm². And the maximum current density of the novel μDMFC is 30 mA/cm², 20 % larger than that of the regular one, 25 mA/cm². It is also clearly observed during the μDMFC operation that the water is drawn out from the capillary-based water removal cathode expectantly.     

Optimization of specific energy consumption for Bomaplex Red CR-L dye removal from aqueous solution by electrocoagulation using Taguchi-neural method

In this investigation, firstly, Taguchi method was applied to determine the optimum specific energy consumption (SEC) for dye removal from aqueous solution by electrocoagulation using aluminum electrodes. An orthogonal array (OA₁₆) experimental design that allows to investigate the simultaneous variations of five parameters (Initial dye concentration, Initial pH of the solution, Supporting electrolyte concentration, Supporting electrolyte type and Current density) having four levels was employed to evaluate the effects of experimental parameters with two replicates. According to Taguchi-neural method, while the optimum conditions that dye removal efficiency equals to 62.71 % were found to be initial dye concentration 600 mg/L, initial pH of the solution 6, supporting electrolyte concentration 7.0 mM, supporting electrolyte type NaCl, and current density 0.10 mA/cm². Under these optimum conditions, energy consumption is 0.38 kW h/m³. Alternatively, it can be said that optimum conditions can be modified as follows supporting electrolyte concentration of 10.0 mM and supporting electrolyte type CaCl₂, for 600 mg/L, initial dye concentration initial pH of the solution 6, and current density 0.10 mA/cm². Under these optimum conditions, SEC and dye removal efficiency are 0.45 kW h/m³ and 69.18 %, respectively.     

Development and characterization of a microthermoelectric generator with plated copper/constantan thermocouples

This work reports the development and the characterization of a microthermoelectric generator (μTEG) based on planar technology using electrochemically deposited constantan and copper thermocouples on a micro machined silicon substrate with a SiO₂/Si₃N₄/SiO₂ thermally insulating membrane to create a thermal gradient. The μTEG has been designed and optimized by finite element simulation in order to exploit the different thermal conductivity of silicon and membrane in order to obtain the maximum temperature difference on the planar surface between the hot and cold junctions of the thermocouples. The temperature difference was dependent on the nitrogen (N₂) flow velocity applied to the upper part of the device. The fabricated thermoelectric generator presented maximum output voltage and power of 118 mV/cm² and of 1.1 μW/cm², respectively, for a device with 180 thermocouples, 3 kΩ of internal resistance, and under a N₂ flow velocity of 6 m/s. The maximum efficiency (performance) was 2 × 10^?3 μW/cm² K².     

Enhanced electromigration reliability via Ag nanoparticles modified eutectic Sn–58Bi solder joint

A comprehensive study on the effect of Ag nanoparticles doping on the electromigration related microstructure evolution in Sn–58Bi solders is reported. Doped Sn–58Bi solders were prepared by mechanically dispersing Ag nanoparticles additive in Sn–58Bi solders. The interfacial morphologies of the undoped and doped Sn–58Bi solders under a direct current of 2.5 A (10³ A/cm²) at 75 °C temperature with Cu pads and Au/Ni/Cu pad on daisy chain type ball grid array substrates for up to 20 days, were analysed. Unlike the undoped solder, there is no obvious formation of Bi-rich IMC growth on the anode side. The Cu–Sn and Au–Sn intermetallic compounds were formed on the Cu and Au pad, respectively, near the cathode and anode interface after the first reflow. Ag₃Sn particles were found dispersed in the solder matrix, which behaved like barriers, blocking the diffusion of metal atoms during current stressing. In addition, during the shear test, fracture occurred at the intermetallic compound interface showing a ductile fracture mode. In the solder ball region of Sn–58Bi solder joint, β-Sn matrix with a refined microstructure and nano Ag intermetallic compound were observed, which resulted in an increase in the shear strength, due to a second phase dispersion strengthening mechanism.     

Leakage current in a Si-based nanopore structure and its influence on noise characteristics

We have measured leakage current in a silicon substrate-based nanopore membrane device immersed in an aqueous environment which typically shows the current level of few nA. This current level is compared with the measured current density (400 nA/cm² at 1 V) from the pristine Si wafer (p-type, 10¹⁶/cm³ boron doping) indicating that the exposed Si surface in a nanopore membrane device acts as an electrochemical reaction site. The leakage current is drastically reduced from >10 nA to <100 pA at 1 V by the deposition of a dielectric layer to the Si-based nanopore membrane device. We also noted that the root-mean-square noise of the ionic current is also reduced from 38 to 28 pA in correlation with the reduction of leakage current, indicating that electrochemical reaction provides one of the major sources of noise.     

High-aspect-ratio through-hole array microfabricated in a PMMA plate for monodisperse emulsion production

Microchannel (MC) emulsification is a promising technique for producing monodisperse emulsions consisting of highly uniform droplets. The authors developed a high-aspect-ratio microstructure (HARMST) made of poly(methyl methacrylate) (PMMA) as a new MC emulsification device. A PMMA straight-through MC array plate consisting of 31,250 through-holes with a 7.3 × 22.9-μm oblong section and a 200-μm depth was fabricated by a process of synchrotron radiation (SR) lithography and etching. Oblong MCs fabricated in a PMMA straight-through MC array were highly uniform with a coefficient of variation of less than 2%. The fabricated PMMA straight-through MC array plate was used to produce water-in-oil (W/O) emulsions. Monodisperse W/O emulsions with average droplet diameters of approximately 25 μm and a minimum coefficient of variation of 3.2% were produced via a hydrophobic PMMA straight-through MC array. The PMMA straight-through MC array plate also produced monodisperse W/O emulsions at droplet production rates of up to 1.7 × 10⁴/s. The PMMA straight-through MC array plates developed in this work are expected to expand the application field of emulsification using straight-through MC array plates, which have previously been made of single-crystal silicon.     

Zone electrophoresis of proteins in poly(dimethylsiloxane) (PDMS) microchip coated with physically adsorbed amphiphilic phospholipid polymer

The zone electrophoresis of protein in poly(dimethylsiloxane) (PDMS) microchip coated with the physically adsorbed amphiphilic phospholipid polymer (PMMSi) was investigated. PMMSi was composed of 2-methacryloyloxyethyl phosphorylcholine (MPC) and 3-(methacryloyloxy) propyltris (trimethylsiloxy) silane (MPTSSi) units in a random fashion. The membrane of PMMSi can be formed on the PDMS surface by a simple and quick dip-coating method. The membrane showed high hydrophilicity and good stability in water, as determined by contact angle measurement, fourier-transformed infrared absorption by attenuated total reflection (ATR-FTIR), and X-ray photoelectron spectroscopy (XPS) analysis. High suppression of protein adsorption to the PDMS surface and reduction in electroosmotic flow (EOF) were achieved by PMMSi coating due to an increase of hydrophilicity, and a decrease of the ζ-potential on the surface of PDMS. For zone electrophoresis, the PMMSi30 containing 30 % hydrophilic MPC was the most suitable molecular design in terms of the stability of the coated membrane on PDMS surface. The average value of EOF mobility of PDMS microchip coated with PMMSi30 was 1.4 × 10^?4 cm² V^?1 s^?1, and the RSD was 4.1 %. Zone electrophoresis of uranine was further demonstrated with high repeatability and reproducibility. Separation of two FITC-labeled proteins (BSA and insulin) was performed with high efficiency and resolution compared with non-treated PDMS microchip.     

Somatic and stem cell pairing and fusion using a microfluidic array device

There is considerable excitement about the prospect of tissue repair and renewal through cell replacement therapies. Nonetheless, many of these techniques may require the reprogramming of somatic and stem cells through cell fusion. Previous fusion methods often suffer from random cell contacts, poor fusion yields, or complexity of design. We have developed a simplified cell-electrofusion chip that possesses a dense microelectrode array, which enables the simultaneous pairing and electrofusion of thousands of cells by manipulation dielectrophoretic force and electroporation. Human embryonic kidney 293 (HEK293) cells, mouse fibroblasts (NIH3T3 cells), and mouse embryonic stem cells were arranged for cell fusion with the same and mixed cell type. The pairing efficiency for a 2-cell alignment of mixed cells was ~35%, and a fusion efficiency of ~46% in cell pairs was achieved. Significant cell death occurs with fusion voltages ?? 10 V, and electrofusion with our chip was achieved on a ~1000 V cm^?1 electric field strength induced by a low intensity voltages (9 V). Therefore, the chip used in this study provides a simple, low voltage alternative with sufficient throughput for hybrid cell experiments and somatic cell reprogramming research.     

Novel back-contact back-junction SiGe (BC-BJ SiGe) solar cell for improved power conversion efficiency

In this paper, a SiGe based Back-Contact Back-Junction (BC-BJ) device structure called BC-BJ SiGe solar cell has been proposed. Photo reflection is significantly reduced in UV/Visible spectrum region in case of SiC/Si₃N₄/SiO₂ passivated BC-BJ SiGe solar cell. Result, indicates that presence of SiC play an important role in photoelectric conversion. Ray tracing and finite difference time domain (FDTD) algorithms are used to simulate optoelectronics characteristics of the device. Simulation achieves the barrier height of 0.8 eV for holes at the interface which results in a higher field. The lower interface recombination rate of the order of 10¹⁷ cm^?3 s^?1 has been obtained. The device shows improved photovoltaic parameters. External quantum efficiency >84 % in the spectrum range of 450–700 nm wavelength and more than 80 % in the range of 350–700 nm wavelength is obtained. Further, we obtained the fill-factor (FF) and power conversion efficiency (PCE), 79 %, 17.8 % and 79 %, 14.8 %, using FDTD and ray tracing methods, respectively. All the simulations have been done using atlas and devedit device simulator.     

Fabrication of cone-like microstructure using UV LIGA-like for light guide plate application

The microlens array is usually formed by thermal reflow of polymer disks and can be one microstructure of the light guide plate (LGP). Here, we propose an ultraviolet (UV) backside exposure technology to fabricate the photoresist cone-like microstructure on the PMMA substrate at room temperature and then use UV LIGA-like process to transfer the microstructure for the application of 3.6 in. (72 mm × 57.5 mm) LGP. The electroforming was used to transfer UV master mold to the inverse cone-like microstructure of nickel metal mold and then hot embossing was used for one more pattern transfer to the same cone-like microstructure on PMMA substrate. The optical microscope and alpha-stepper profiler were used to examine the morphology and profile of LGP microstructure. The optical luminance and uniformity of LGP were measured using BM9 luminance meter in comparison with commercial product. The light uniformity and luminance of the cone-like LGP microstructure reach 75–80% and 2,800–3,000 cd/cm², respectively which meet the requirements of commercial LGP.     

Feasibility of a specialized ground light source for night-time low-light calibration

The day/night band (DNB) of the Visible Infrared Imaging Radiometer Suite can not only identify surface characteristics when illuminated by moonlight, but can also detect night-time radiation from ground active light sources. Accordingly, the low-light sensor can be calibrated by comparing upward active radiation with actual observed digital counts, which has attracted new research interest. In this article, the first attempt to calibrate the high-gain stage of the DNB using a specialized ground light source was introduced. The DNB imaging rule of the target pixel at various observation geometries was analysed based on the long-term monitoring of a light source set in Dunhuang, Gansu Province, China. The radiance caused by emissive radiation varied greatly over time in a 16-day cycle. To solve the major problem of the Dunhuang light source when used for low-light calibration, a light source that emits homogenous radiation intensity in most upward directions was custom designed. Based on this device, a comprehensive low-light calibration scheme was proposed and three verification experiments were performed in Mingguang, Anhui Province, China. The predicted in-band DNB at-aperture radiance values of the 3-day experiments were 3.86 × 10^?9, 4.38 × 10^?9, and 5.27 × 10^?9 W cm^?2 sr^?1, respectively, while the actual observed DNB radiance values were 4.53 × 10^?9, 5.06 × 10^?9, and 5.57 × 10^?9 W cm^?2 sr^?1, respectively. With deviations of 14.8%, 13.4%, and 5.4%, respectively, the calibration result based on the specialized light source was generally in good agreement with the operational calibration result, and thus the feasibility of the device for low-light calibration had been preliminarily verified.     

Design and optimization of cantilever based piezoelectric micro power generator for cardiac pacemaker

Piezoelectric micro-power generator (PMPG) converts mechanical vibration energy into electric energy via piezoelectric effects. In cardiac pace makers, the use of PMPG eliminates the need for a traditional lithium iodide battery replacement. In this paper we design and optimize PMPG that is able to harvest the mechanical movement of the heart beat to be converted into usable electrical power in frequency range 1–1.7 Hz. Eight control parameters are selected: which are proof mass material, piezoelectric material, proof mass length, proof mass thickness, piezoelectric layer width, piezoelectric layer thickness, silicon nitride layer width, silicon nitride layer thickness. Orthogonal arrays of Taguchi method for these eight parameters mentioned with three levels and signal-to-noise (S/N) ratio, and ANOVA analysis is studied to determine the optimum design. COMSOL Multiphysics ver. 4.2 is used in 18 different simulations. The maximum output power and highest efficiency designed at 1.2 Hz is equivalent to 72 beat per min. Both Taguchi and ANOVA confirms the same results of determining the parameter of having the most influence on the generated output power at 1.2 Hz in descending order: which are piezoelectric material of PZT-5A, proof mass length of 5 mm, piezoelectric layer thickness of 30 µm, proof mass thickness of 4 mm, piezoelectric layer width of 0.12 mm, silicon nitride layer width of 0.16 mm, silicon nitride layer thickness of 30 µm, and proof mass material of aluminum. Eigen frequency analysis for the first six modes of operation for PMPG frequencies are: 1.2 HZ, 5.4 Hz, 6.9 Hz, 29,7 Hz, 694.8 Hz, 708.3 Hz. The first mode of operation is selected as operation mode and shows that 93 % of PMPG’s total displacement and output power was produced in the range of 1–1.4 Hz, therefore PMPG can work when the heart rate between 60 and 84 bpm. Transient analysis performed at 1.2 Hz reaches the steady state before the first 10 cycles with output power density of 23.13 µW/cm³, which is suitable for powering cardiac pace maker.     

Alternative technology used to manufacture semitransparent monocrystalline silicon solar cells

This paper presents the manufacturing technology of a new semitransparent solar cell that can be used for building integrated applications. Diluted tetramethylammonium hydroxide and isopropyl alcohol mixture is used to create uniform and reproducible pyramidal textures on the silicon wafers, thus reducing surface reflectance. Arbitrary pattern of holes can be etched using 5 wt % tetramethylammonium hydroxide solution. Ammonium persulfate powder has to be dissolved in the bulk etchant in order to maintain a stable 1.34 μm/min etching rate over the 3.5 h etching process. The ARC layer is the 90 nm thick silicon dioxide remaining after the anisotropic etching. The efficiency of the semitransparent solar cell is 6.12 % including grid contact and silicon through-hole areas, the transparency reached is 6.7 %, weighted surface reflectance is 4.31 %.     

Optoelectronic properties of poly(fluorene) co‐polymer light‐emitting devices on a plastic substrate*

Abstract— The optoelectronic properties of red, green, and blue poly(fluorene) co‐polymer light‐emitting devices (PLEDs) on a plastic substrate having a multi‐layered structure with water vapor and oxygen transmission rates of less than 10^?5 g/cm²‐day‐atm and 10^?7 cc/cm²‐day‐atm, respectively, is reported. A semitransparent thin metal multi‐layer (i.e., Au/Ag/Au or Ag/Au/Ag) is placed between the plastic substrate and the ITO coating, achieving a low sheet resistance of 12–13 Ω/□ and an adequate optical transmission greater than 75%. A wider color gamut and a maximum emission efficiency of 0.7, 10, and 1.7 cd/A for red, green, and blue PLEDs, respectively, was obtained. Finally, a simple equivalent‐circuit model was used to simulate the current‐density—voltage characteristics of PLEDs.     

Mesoporous silicon-based miniature fuel cells for nomadic and chip-scale systems

We report here the fabrication of a new miniature fuel cell for nomadic applications and chip-scale power supply based on a Nafion^®-filled porous silicon self-supported membrane. Combining advantages of Nafion^® for its great proton conduction and silicon for an easier integration and standard microfabrication techniques, this solution enables the integration of gas feed and electrical contacts into the membrane etching process thanks to simple KOH wet etching processes and metal sputterings. The encapsulation is also possible. Compared to simple Nafion^® membranes, this technique may reduce the lateral water diffusion through the membrane. Experiments have been carried out at room temperature and gas feed H₂ is provided by the electrolysis of a NaOH solution. A long-term power density of 18 mW cm^?2 has been achieved after stabilization with a maximum current density of 101 mA cm^?2 and an open circuit voltage of 0.8 V.     

Water‐vapour retrieval from Meteosat 8/SEVIRI observations

This paper aims to propose operational algorithms to retrieve the total atmospheric water vapour content (W) using the Spinning Enhanced Visible and Infrared Imager (SEVIRI) on‐board Meteosat 8. MODTRAN3.5 was used to obtain simulated data in the thermal infrared channels IR10.8 and IR12.0, in order to determine the numerical values of the coefficients of the algorithms. The algorithm proposed for land pixels takes into account the SEVIRI observation geometry and the radiometric temperatures obtained in the split‐window channels at two different times during a day and requires a minimum difference of 10 K in terms of temperature between the two situations. Comprehensive error analyses gave rms errors lower than 0.5 g cm^?2 when observations were taken between the nadir and 50°. The algorithm is validated with in situ values, i.e. radiosondes and W measurements with a CIMEL CE318 sun photometer, both obtained from a field campaign, with rms validation errors of 0.2 and 0.7 g cm^?2, respectively. Additionally, six stations all over the SEVIRI field of view were selected to validate the algorithm from radiosondes data, providing an rms error of 0.4 g cm^?2. Concerning sea pixels, the linear atmosphere–surface temperature relation is adapted to SEVIRI and takes into account the sea‐surface temperature, the atmospheric effective temperature, and the radiometric temperature in the IR10.8 channel. The total error obtained from this methodology has a value between 0.8 and 1.1 g cm^?2, and the validation is carried out using radiosonde data from four stations near the sea, providing rms errors lower than 0.6 g cm^?2.     

Electromagnetic MEMS microspeaker for portable electronic devices

This work presents the conception, the microfabrication, and the electroacoustic characterization of a new electromagnetic microspeaker based on silicon. The objectives are to get improved sound quality compared to that of conventional microspeakers, while keeping the electroacoustic efficiency as high as possible. An optimized stiffening silicon microstructure let the sound radiator be extremely light and rigid. The mobile part is suspended to the fixed part by silicon suspension springs, which enable large out-of-plane displacement. The acoustic radiator is actuated by an electromagnetic motor, composed of a fixed permanent magnet and a planar coil located on top of the silicon radiator. The piston-like motion of the radiator favored by this structure is very beneficial for the sound quality. Electro–mechano–acoustic characterization of the microfabricated microspeaker showed that the radiator surface could run out-of-plane with displacements higher than ±400 μm, with no mechanical and electrical failure. For an electrical power of 0.5 W, the microspeaker was capable to generate a sound pressure level of 80 dB at 10 cm, from 330 Hz up to 20 kHz frequency. The efficiency reaches 3 × 10^?5, that is to say three times more than typical efficiency of conventional microspeakers. Moreover, as characterization results showed, the existence of very few structural modes and the low electroacoustic distortions evidence the high sound quality of the microspeaker.     

Metal (IV) tetras (8‐hydroxyquinoline) (M = Zr,Hf) used as electroluminescent material and electron‐transport layer in OLEDs

Abstract— In this paper, we report on the utilization of zirconium (IV) tetras (8‐hydroxyquinoline), Zrq₄, and hafnium (IV) tetras (8‐hydroxyquinoline), Hfq₄, as an electroluminescent material in fluorescent organic light‐emitting diodes (OLED) and as electron transport layer (ETL) for high‐efficiency electrophosphorescent organic light‐emitting diodes (PHOLEDs). Structural studies show that the metal tetraquinolates (Mq₄) have a very low dipole moment (<0.1 D), in contrast to Alq₃ which has an estimated dipole moment of 4.7 D. Mobility measurements show that Mq₄ complexes give mobilities of (3.5 ± 0.5) × 10^?6 cm²/V‐sec, which are close to the values reported for Alq₃, i.e., (2.3–4.3) × 10^?6 cm²/V‐sec. OLEDs were prepared with the structure ITO/NPD (400 Å)/Mq_n (500 Å)/LiF/Al (NPD = 4‐4′‐bis[N‐(1‐naphthyl)‐N‐phenyl‐amino]bi phenyl, Mq_n = Alq₃, Zrq₄, Hfq₄. The Mq₄‐based OLEDs gave external efficiencies of 1.1%, while the Alq₃‐based devices of the same structure gave efficiencies of 0.7%. PHOLEDs have been fabricated with the structure ITO/NPD (500 Å)/CBP‐8% Ir(ppy)³ (250 Å)/BCP (150 Å)/Mq_n (250 Å)/LiF/Al (CBP = N,N′‐dicarbazolyl‐4‐4′‐biphenyl, Ir(ppy)³ = fac‐tris(2‐phenylpyrridine)iridium, BCP = bathocruprione). PHOLEDs with Mq₄ ETLs showed a greatly improved efficiency, when compared to Alq₃‐based PHOLEDs. The Zrq₄‐based PHOLEDs gave a peak external quantum efficiency of 14% at 0.3 mA/cm² (150 cd/m²), while the Hfq₄ based PHOLED gave a peak external quantum efficiency of 15% at 0.6 mA/cm² (300 cd/m²). Comparable PHOLEDs with an Alq₃ ETL give peak external quantum efficiencies of 8.0% at 0.5 mA/cm². The devices gave an electroluminescence (EL) spectrum consisting only of fac‐tris(2‐phenylpyrridine)iridium (Ir(ppy)³) dopant emission (CIE coordinates of 0.26, 0.66), with no Mq₄ emission observed at any bias level.     

MEMS design and fabrication of an electrostatic vibration-to-electricity energy converter

This paper presents a micro electrostatic vibration-to-electricity energy converter based on the micro-electromechanical system. For the 3.3 V supply voltage and 1 cm² chip area constraints, optimal design parameters were found from theoretical calculation and Simulink simulation. In the current design, the output power is 200 μW/cm² for the optimal load of 8 MΩ. The device was fabricated in a silicon-on-insulator wafer. Mechanical and electrical measurements were conducted. Residual particles caused shortage of the variable capacitor and the output power could not be measured. Fabrication processes are being refined to remove the back silicon substrate to eliminate residual particles and parasitic capacitance.     

A comparison of algorithms for Near‐Real Time water vapour retrieval from MODIS

When studying the Earth's surface from space it is important that the component of the signal measured by the satellite‐based sensor due to the atmosphere is accurately estimated and removed. Such atmospheric correction requires good knowledge of atmospheric parameters including precipitable water (PW), ozone concentration and aerosol optical depth. To make full use of the capabilities of satellite sensors such as the Moderate Resolution Imaging Spectroradiometer (MODIS) these parameters should be accurately estimated in Near‐Real Time (NRT) with complete global coverage approximately every two days. NRT retrieval of the required ancillary information facilitates the atmospheric correction of such direct broadcast data from the MODIS instrument in the operational environment. In this paper three Near Infrared (NIR) algorithms for PW retrieval from MODIS are compared to determine which is most suitable for use in an operational MODIS‐based process for the atmospheric correction of spectral reflectance data. Two of the algorithms estimate PW in NRT and gave RMS errors of approximately 0.48 g cm^?2 (23%) and 0.59 g cm^?2 (28%), respectively, when compared against radiosonde data and modelled PW fields over Western Australia. The third algorithm was the NIR PW product from MODIS (MOD05) archived by the Distributive Active Archive Centre (DAAC). For the same locations the MOD05 NIR PW dataset gave an RMS error of approximately 0.95 g cm^?2 (44%). In each of the cases the best results were obtained after optimal cloudmasking of the NIR data. In this paper, the accuracy and suitability of the three algorithms for use in the operational atmospheric correction of MODIS data are evaluated and the importance of an accurate cloudmask for atmospheric correction in NRT is discussed.