In-tube condensation of mixture of R134a and ester oil: empirical correlations

This paper presents a comparative study of the condensation heat transfer coefficients in a smooth tube when operating with pure refrigerant R134a and its mixture with lubricant Castrol “icematic sw”. The lubricant is synthetic polyol ester based oil commonly used in lubricating the compressors. Two concentrations of R134a-oil mixtures of 2% and 5% oil (by mass) were analysed for a range of saturation temperatures of refrigerant R134a between 35 °C and 45 °C. The mass flow rate of the refrigerant and the mixtures was carefully maintained at 1 g/s, with a vapour quality varying between 1.0 and 0. The effects of vapour quality, flow rate, saturation temperature and temperature difference between saturation and tube wall on the heat transfer coefficient are investigated by analysing the experimental data. The experimental results were then compared with predictions from earlier models [Int J Heat Mass Transfer (1979), 185; 6th Int Heat Transfer Congress 3 (1974) 309; Int J Refrig 18 (1995) 524; Trans ASME 120 (1998) 193]. Finally two new empirical models were developed to predict the two-phase condensation heat transfer coefficient for pure refrigerant R134a and a mixture of refrigerant R134a with Castrol “icematic sw”.     

Enhancement of R123 pool boiling by the addition of hydrocarbonsAmélioration de l'ébullition libre du R123 par l'ajout d'hydrocarbures

This paper presents pool boiling heat transfer data for 10 different R123/hydrocarbon mixtures. The data consisted of pool boiling performance of a GEWA-T^™ surface for pure R123 and for 10 dilute solutions of five different hydrocarbons: (1) pentane, (2) isopentane, (3) hexane, (4) cyclohexane, and (5) heptane with R123. The heat flux and the wall superheat were measured for each fluid at 277.6 K. A maximum (19±3.5)% increase over the pure R123 heat flux was achieved with the addition of 0.5% mass isopentane to R123. Other mixtures of isopentane, pentane, hexane, and cyclohexane with R123 exhibited smaller maximums than that of the R123/isopentane (99.5/0.5) mixture. Presumably, a layer enriched in hydrocarbon at the heat transfer surface caused the heat transfer enhancement. Conversely, an R123/heptane (99.5/0.5) mixture and an R123/cylcohexane (99.5/0.5) mixture exhibited only degradations with respect to the pure component performance for all test conditions. Several characteristics of the hydrocarbons were examined to determine their influence on the boiling heat transfer performance: molecular weight, molecular structure, composition, surface tension, and vapor pressure.     

Flow-boiling of R22, R134a, R507, R404A and R410A inside a smooth horizontal tube

Flow boiling heat transfer coefficients of R22, R134a, R507, R404A and R410A inside a smooth horizontal tube (6 mm I.D., 6 m length) were measured at a refrigerant mass flux of about 360 kg/m² s varying the evaporating pressure within the range 3–12 bar, with heat fluxes within the range 11–21 kW/m². The experimental data are discussed in terms of the heat transfer coefficients as a function of the vapour quality. The experimental results clearly show that the heat transfer coefficients of R134a are always higher than those pertaining to R22 (from a minimum of +6 to a maximum of +45%).     

Effect of refrigerant oil additive on R134a and R123 boiling heat transfer performance

This paper investigates the effect that an additive had on the boiling performance of an R134a/polyolester lubricant (POE) mixture and an R123/naphthenic mineral oil mixture on a roughened, horizontal flat surface. Both pool boiling heat transfer data and lubricant excess surface density data are given for the R134a/POE (98% mass fraction/2% mass fraction) mixture before and after use of the additive. A spectrofluorometer was used to measure the lubricant excess density that was established by the boiling of the R134a/POE lubricant mixture before and after use of the additive. The measurements obtained from the spectrofluorometer suggest that the additive increases the total mass of lubricant on the boiling surface. The heat transfer data show that the additive caused an average and a maximum enhancement of the R134a/POE heat flux between 5 kW m⁻² and 22 kW m⁻² of approximately 73% and 95%, respectively. Conversely, for nearly the same heat flux range, the additive caused essentially no change in the pool boiling heat flux of an R123/mineral oil mixture. The lubricant excess surface density and interfacial surface tension measurements of this study were used to form the basis of a hypothesis for predicting when additives will enhance or degrade refrigerant/lubricant pool boiling.     

R404A condensing under forced flow conditions inside smooth, microfin and cross-hatched horizontal tubes

Two-phase heat transfer coefficient characteristics of R404A condensing under forced flow conditions inside smooth, microfin and cross-hatched horizontal tubes are experimentally investigated. Experimental parameters include a lubricating polyol ester oil concentration varied from 0 to 4%. The test runs were done at average inlet saturated condensing temperatures of 40 °C. The inlet vapor was kept at saturation (quality=1.0). The mass fluxes were between 200 and 600 kg/m² s, and the heat fluxes were selected to obtain a quality of 0.0 at the outlet of the test section, varying from 5 to 45 kW/m². The heat transfer enhancement factor varied between 1.8 and 2.4 for both microfin and cross-hatched tubes. The larger values applied for larger mass fluxes for the cross-hatched tube and smaller mass fluxes for the microfin tube. Enhancement factors increased as oil concentration increased up to oil concentrations of 2%. For higher oil concentrations the enhancement decreased especially at high mass fluxes, the cross-hatched tube being less sensitive to oil contamination. Pressure drop in the test section increased by approximately 25% as the oil concentration increased from 0 to 4%. The results from the experiments are compared with those calculated from correlations reported in the literature. Moreover, modified correlations for the condensation heat transfer coefficient are proposed for practical applications.     

Condensation heat transfer coefficients of R22, R407C, and R410A on a horizontal plain, low fin, and turbo-C tubes

In this study, condensation heat transfer coefficients (HTCs) were measured on a horizontal plain tube, low fin tube, and Turbo-C tube at the saturated vapor temperature of 39 °C for R22, R407C, and R410A with the wall subcooling of 3–8 °C. R407C, a non-azeotropic refrigerant mixture, exhibited a quite different condensation phenomenon from those of R22 and R410A and its condensation HTCs were up to 50% lower than those of R22. For R407C, as the wall subcooling increased, condensation HTCs decreased on a plain tube while they increased on both low fin and turbo-C tubes. This was due to the lessening effect of the vapor diffusion film with a rapid increase in condensation rate on enhanced tubes. On the other hand, condensation HTCs of R410A, almost an azeotrope, were similar to those of R22. For all refrigerants tested, condensation HTCs of turbo-C tube were the highest among the tubes tested showing a 3–8 times increase as compared to those of a plain tube.     

Evaporation heat transfer for R-22 and R-407C refrigerant–oil mixture in a microfin tube with a U-bendTransfert de chaleur lors de l'évaporation de R-22 et de R-407C mélangés avec de l'huile dans un tube à micro-ailettes avec un coude en U

Evaporation heat transfer experiments for two refrigerants, R-407C and R-22, mixed with polyol ester and mineral oils were performed in straight and U-bend sections of a microfin tube. Experimental parameters include an oil concentration varied from 0 to 5%, an inlet quality varied from 0.1 to 0.5, two mass fluxes of 219 and 400 kg m⁻²s⁻¹ and two heat fluxes of 10 and 20 kW m⁻². Pressure drop in the test section increased by approximately 20% as the oil concentration increased from 0 to 5%. Enhancement factors decreased as oil concentration increased under inlet quality of 0.5, mass flux of 219 kg m⁻² s⁻¹, and heat flux of 10 kW m⁻², whereas they increased under inlet quality of 0.1, mass flux of 400 kg m⁻² s⁻¹, and heat flux of 20 kW m⁻². The local heat transfer coefficient at the outside curvature of an U-bend was larger than that at the inside curvature of a U-bend, and the maximum value occurred at the 90° position of the U-bend. The heat transfer coefficient was larger in a region of 30 tube diameter length at the second straight section than that at the first straight section.     

Heat transfer characteristics of refrigerant-based nanofluid flow boiling inside a horizontal smooth tube

The objective of this paper is to investigate the influence of nanoparticles on the heat transfer characteristics of refrigerant-based nanofluid flow boiling inside a horizontal smooth tube, and to present a correlation for predicting heat transfer performance of refrigerant-based nanofluid. For the convenience of preparing refrigerant-based nanofluid, R113 refrigerant and CuO nanoparticles were used. Experimental conditions include an evaporation pressure of 78.25 kPa, mass fluxes from 100 to 200 kg m⁻² s⁻¹, heat fluxes from 3.08 to 6.16 kW m⁻², inlet vapor qualities from 0.2 to 0.7, and mass fractions of nanoparticles from 0 to 0.5 wt%. The experimental results show that the heat transfer coefficient of refrigerant-based nanofluid is larger than that of pure refrigerant, and the maximum enhancement of heat transfer coefficient is 29.7%. A heat transfer correlation for refrigerant-based nanofluid is proposed, and the predictions agree with 93% of the experimental data within the deviation of ±20%.     

Flow boiling heat transfer to carbon dioxide: general prediction method

An updated version of the Kattan–Thome–Favrat flow pattern based, flow boiling heat transfer model for horizontal tubes has been developed specifically for CO₂. Because CO₂ has a low critical temperature and hence high evaporating pressures compared to our previous database, it was found necessary to first correct the nucleate pool boiling correlation to better describe CO₂ at high reduced pressures and secondly to include a boiling suppression factor on the nucleate boiling heat transfer coefficient to capture the trends in the flow boiling data. The new method predicts 73% of the CO₂ database (404 data points) to within ±20% and 86% to within ±30% over the vapor quality range of 2–91%. The database covers five tube diameters from 0.79 to 10.06 mm, mass velocities from 85 to 1440 kg m⁻² s⁻¹, heat fluxes from 5 to 36 kW m⁻², saturation temperatures from −25 °C to +25 °C and saturation pressures from 1.7 to 6.4 MPa (reduced pressures up to 0.87).     

Experimental investigations on boiling of n-pentane across a horizontal tube bundle: two-phase flow and heat transfer characteristicsEtude expérimentale de l'ébullition de n-pentane à travers un faisceau de tubes horizontal: écoulement diphasique et caractéristiques de transfert de chaleur

This paper presents the heat transfer characteristics obtained from an experimental investigation on flow boiling of n-pentane across a horizontal tube bundle. The tubes are plain with an outside diameter of 19.05 mm and the bundle arrangement is inverse staggered with a pitch to diameter ratio of 1.33. The test conditions consist of reduced pressure between 0.006 and 0.015, mass velocity from 14 to 44 kg/m²s, heat flux up to 60 kW/m² and vapor quality up to 60%. The convective evaporation is found to have a significant effect on the heat transfer coefficient, coexisting with nucleate boiling. An asymptotic model allows the prediction of the heat transfer data with a fitted value of n=1.5. A strong mass velocity effect is observed for the enhancement factor, implying that the correlations available from the literature for the convective evaporation will fail in predicting the present data. This effect decreases as the mass velocity increases.     

Flow boiling of ammonia in a plain and a low finned horizontal tubeEbullition en éncoulement d'ammoniac dans un tube lisse ou un tube ailetté

Experimental data of the local heat transfer coeffcient of flow boiling ammonia in dependence of vapor fraction, mass flux and local heat flux is presented. Two horizontal test sections of 450 mm length and an inner diameter of 10 mm have been used, one being a plain tube, one being a spirally low finned tube. A constant wall temperature boundary has been aimed for the test section by heating with a fluid condensing on the tube outside. Local heat transfer coeffcients and pressure drops have been measured in the range −40 < T_sat < 4°C, 0 < x< 0.9, 50 < < 150 kg/m² s and 2 < ΔT_w < 15 K with resulting heat fluxes of 17 < < 75 kW/m². The vapor quality is denoted as x, is the mass flux and ΔT_w the wall superheat. The measured data is carefully evaluated using a finite element model of the tube with regard to the circumferential heat flow distribution. The smooth tube results are compared with recently published data and the correlation from Zürcher (Zürcher, O., Thome, J.R., Favrat, D. Evaporation of ammonia in a smooth horizontal tube: heat transfer measurements and predictions. Journal of Heat Transfer, 1999;121:89–101), and with the correlations of Steiner (Steiner D. Strömungssieden gesättigter Flüssigkeiten. VDI-Wärmeatlas, vol. 8. VDI-Verlag, 1997) and Kattan (Kattan N, Thome JR, Favrat D. Flow boiling in horizontal tubes: part 3 — development of a new heat transfer model based on flow pattern. Transactions of the ASME, 1998;120). The results of the low finned tube are not matched by any known correlation.     

Experimental studies on the evaporative heat transfer and pressure drop of CO2 in smooth and micro-fin tubes of the diameters of 5 and 9.52 mm

Carbon dioxide among natural refrigerants has gained a considerable attention as an alternative refrigerant due to its excellent thermophysical properties. In-tube evaporation heat transfer characteristics of carbon dioxide were experimentally investigated and analyzed as a function of evaporating temperature, mass flux, heat flux and tube geometry. Heat transfer coefficient data during evaporation process of carbon dioxide were measured for 5 m long smooth and micro-fin tubes with outer diameters of 5 and 9.52 mm. The tests were conducted at mass fluxes of from 212 to 656 kg m⁻² s⁻¹, saturation temperatures of from 0 to 20 °C and heat fluxes of from 6 to 20 kW m⁻². The difference of heat transfer characteristics between smooth and micro-fin tubes and the effect of mass flux, heat flux, and evaporation temperature on enhancement factor (EF) and penalty factor (PF) were presented. Average evaporation heat transfer coefficients for a micro-fin tube were approximately 150–200% for 9.52 mm OD tube and 170–210% for 5 mm OD tube higher than those for the smooth tube at the same test conditions. The effect of pressure drop expressed by measured penalty factor of 1.2–1.35 was smaller than that of heat transfer enhancement.     

Experimental measurements for condensation of downward-flowing R123/R134a in a staggered bundle of horizontal low-finned tubes with four fin geometriesMesures expérimentales de la condensation lors de l'éoulement vertical d'un mélange de R123 et de R134a sur un faisceau de tubes en quinconce munis de quatre types d'ailettes

Experiments were conducted to obtain row-by-row heat and mass transfer data during condensation of downward-flowing zeotropic mixture R123/R134a in a staggered bundle of horizontal low-finned tubes. The vapor temperature and the mass fraction of R134a at the tube bundle inlet were about 50°C and 14%, respectively. The refrigerant mass velocity ranged from 9 to 34 kg m⁻² s⁻¹, and the condensation temperature difference from 1.9 to 12 K. Four kinds of low-finned tubes with different fin geometry were tested. The highest heat transfer coefficient was obtained with a tube which showed the highest performance for R123. However, the diference among the tubes was much smaller for the mixture than for R123. The heat transfer coefficient and the vapor-phase mass transfer coefficient decreased significantly with decreasing mass velocity. The mass transfer coefficient increased with condensation temperature difference, which was due to the effect of suction associated with condensation. On the basis of the analogy between heat and mass transfer, a dimensionless correlation of the mass transfer coefficient was developed for each tube.     

Refrigerant R134a vaporisation heat transfer and pressure drop inside a small brazed plate heat exchanger

This paper presents the experimental heat transfer coefficients and pressure drop measured during refrigerant R134a vaporisation inside a small brazed plate heat exchanger (BPHE): the effects of heat flux, refrigerant mass flux, saturation temperature and outlet conditions are investigated. The BPHE tested consists of 10 plates, 72 mm in width and 310 mm in length, which present a macro-scale herringbone corrugation with an inclination angle of 65° and corrugation amplitude of 2 mm.The experimental results are reported in terms of refrigerant side heat transfer coefficients and frictional pressure drop. The heat transfer coefficients show great sensitivity both to heat flux and outlet conditions and weak sensitivity to saturation temperature. The frictional pressure drop shows a linear dependence on the kinetic energy per unit volume of the refrigerant flow.The experimental heat transfer coefficients are also compared with two well-known correlations for nucleate pool boiling and a correlation for frictional pressure drop is proposed.     

Two-phase heat transfer to a refrigerant in a 1 mm diameter tubeTransfert de chaleur vers un frigorigène circulant dans un tube d'un diamètre d'un mm

A study of two-phase flow and heat transfer in a small tube of 1 mm internal diameter has been conducted experimentally as part of a wider study of boiling in small channels. R141b has been used as the working fluid. The boiling heat transfer in the small tube has been measured over a mass flux range of 300–2000 kg/m² s and heat flux range of 10–1150 kW/m². In this paper the boiling map for a mass velocity of 510 kg/m² s and heat flux of 18–72 kW/m² is discussed and the problems of determining heat transfer coefficients in small channels are highlighted.     

Coefficients d'échange locaux au cours de l'ébullition du R22 et du R407C dans des tubes horizontaux, lisse ou micro-ailetéLocal heat transfer coefficients during boiling of R22 and R407C in horizontal smooth and microfin tubes

The purpose of this study is to experimentally investigate forced convective boiling. The heat transfer coefficients of pure refrigerant R22 and non azeotropic refrigerant mixture R407C were measured in both a smooth tube and a microfin tube. The tests have been carried out with a uniform heat flux all along the tube length. The refrigerant mass flux was varied from 100 to 300 kg m⁻² s⁻¹ and heat fluxes from 10 to 30 kW m⁻². Local heat transfer coefficients depend strongly on heat flux at a low quality and on mass fluxes at a high quality. When compared to smooth tube, the microfin tubes exhibit a significant heat transfer enhancement, up to 180%. In comparison to R22, the R407C heat transfer coefficients of smooth and microfin tubes are 15 to 35% lower, respectively. The best heat transfer enhancement is obtained at low heat flux and mass flow rate.     

Effect of bulk lubricant concentration on the excess surface density during R134a pool boiling

This paper investigates the effect that the bulk lubricant concentration has on the non-adiabatic lubricant excess surface density on a roughened, horizontal flat pool-boiling surface. Both pool boiling heat transfer data and lubricant excess surface density data are given for pure R134a and three different mixtures of R134a and a polyolester lubricant (POE). A spectrofluorometer was used to measure the lubricant excess density that was established by the boiling of an R134a/POE lubricant mixture on a test surface. The lubricant is preferentially drawn out of the bulk refrigerant/lubricant mixture by the boiling process and accumulates on the surface in excess of the bulk concentration. The excess lubricant resides in an approximately 40 μm layer on the surface and influences the boiling performance. The lubricant excess surface density measurements were used to modify an existing dimensionless excess surface density parameter so that it is valid for different reduced pressures. The dimensionless parameter is a key component for a refrigerant/lubricant pool-boiling model given in the literature. In support of improving the boiling model, both the excess measurements and heat transfer data are provided for pure R134a and three R134a/lubricant mixtures at 277.6 K. The heat transfer data show that the lubricant excess layer causes an average enhancement of the heat flux of approximately 24% for the 0.5% lubricant mass fraction mixture relative to pure R134a heat fluxes between 5 and 20 kW/m². Conversely, both 1 and 2% lubricant mass fraction mixtures experienced an average degradation of approximately 60% in the heat flux relative to pure R134a heat fluxes between approximately 4 and 20 kW/m². This study is an effort toward generating data to support a boiling model to predict whether lubricants degrade or improve boiling performance.     

Characteristics of evaporative heat transfer and pressure drop of carbon dioxide and correlation development

Carbon dioxide among natural refrigerants has gained considerable attention as an alternative refrigerant due to its excellent thermophysical properties. In this study, transcritical refrigeration cycle using carbon dioxide is of great interest, and the evaporation process is investigated by experiment and analysis. This paper presents the measured heat transfer coefficients and pressure drop during evaporation process of carbon dioxide in a horizontal smooth tube. The test section was made of a seamless stainless steel tube with the inner diameter of 7.53 mm, and length of 5 m. Heat is provided by a direct heating method to the test section. Experiments were conducted at saturation temperatures of −4 to 20 °C, heat fluxes of 12 to 20 kWm⁻² and mass fluxes of 200 to 530 kgm⁻² s⁻¹. A comparison of different heat transfer correlations applicable to evaporation of carbon dioxide has been made. Based on the experiments for the evaporation heat transfer, useful correlation is developed.     

Evaporating heat transfer of R22 and R410A in horizontal smooth and microfin tubes

An experimental investigation of condensation heat transfer in 9.52 mm O.D. horizontal copper tubes was conducted using R22 and R410A. The test rig had a straight, horizontal test section with an active length of 0.92 m and was cooled by the heat transfer fluid (cold water) circulated in a surrounding annulus. Constant heat flux of 11.0 kW/m² was maintained throughout the experiment and refrigerant quality varied from 0.9 to 0.1. The condensation test results at 45 °C were reported for 40–80 kg/h mass flow rate. The local and average condensation coefficients for seven microfin tubes were presented compared to those for a smooth tube. The average condensation coefficients of R22 and R410A for the microfin tubes were 1.7–3.19 and 1.7–2.94 times larger than those in smooth tube, respectively.     

Effect of bulk lubricant concentration on the excess surface density during R123 pool boiling

This paper investigates the effect that bulk lubricant concentration has on the non-adiabatic lubricant excess surface density on a roughened, horizontal flat (plain) pool-boiling surface. Both pool boiling heat transfer data and lubricant excess surface density data are given for pure R123 and three different mixtures of R123 and a naphthenic mineral oil. A spectrofluorometer was used to measure the lubricant excess density that was established by the boiling of a R123/lubricant mixture on a test surface. The fluorescent technique was used to measure the effect of bulk lubricant concentration on the lubricant excess layer during refrigerant/lubricant mixture boiling. The refrigerant preferentially boils, thus, concentrating and accumulating the lubricant on the surface in excess of the bulk concentration. The excess lubricant resides in a very thin layer on the surface and influences the boiling performance. Accordingly, the ability to measure the effect of bulk lubricant composition on the lubricant excess density and in turn the effect on the heat transfer would lead to a fundamental understanding of the mechanism by which lubricants can degrade or improve boiling performance. In support of this effort, heat transfer data are provided for pure R123 and three R123/lubricant mixtures at 277.6 K. For heat fluxes between approximately 25 to 45 kW/m², an average enhancement of the heat flux of 9 and 5% was achieved for the 0.5 and 1% lubricant mass fractions, respectively, and an average degradation of 5% in the heat flux was obtained for the 1.8% lubricant mass fraction mixture.

Résumé

This paper investigates the effect that bulk lubricant concentration has on the non-adiabatic lubricant excess surface density on a roughened, horizontal flat (plain) pool-boiling surface. Both pool boiling heat transfer data and lubricant excess surface density data are given for pure R123 and three different mixtures of R123 and a naphthenic mineral oil. A spectrofluorometer was used to measure the lubricant excess density that was established by the boiling of a R123/lubricant mixture on a test surface. The fluorescent technique was used to measure the effect of bulk lubricant concentration on the lubricant excess layer during refrigerant/lubricant mixture boiling. The refrigerant preferentially boils, thus, concentrating and accumulating the lubricant on the surface in excess of the bulk concentration. The excess lubricant resides in a very thin layer on the surface and influences the boiling performance. Accordingly, the ability to measure the effect of bulk lubricant composition on the lubricant excess density and in turn the effect on the heat transfer would lead to a fundamental understanding of the mechanism by which lubricants can degrade or improve boiling performance. In support of this effort, heat transfer data are provided for pure R123 and three R123/lubricant mixtures at 277.6 K. For heat fluxes between approximately 25 kW/m² to 45 kW/m², an average enhancement of the heat flux of 9% and 5% was achieved for the 0.5% and 1% lubricant mass fractions, respectively, and an average degradation of 5% in the heat flux was obtained for the 1.8% lubricant mass fraction mixture.