SiC和Si_3N_4粉体的太赫兹时域光谱研究

采用太赫兹时域光谱装置测试SiC和Si3N4粉体在0.4～2.4 THz的透射光谱,研究SiC和Si3N4粉体对太赫兹波的吸收性能与其电导率的关系,分析SiC和Si3N4粉体对太赫兹波的散射特性。结果表明,SiC是一种半导体材料,其内部含有较多可以自由移动的载流子,对太赫兹波的吸收较强;Si3N4是绝缘性很好的材料,对太赫兹波的吸收很小;SiC和Si3N4粉体对太赫兹波的散射作用属于瑞利散射,但是测试波长比粉体粒径大得多,散射效果不明显。     

混浊海水声吸收与温度、盐度、压强关系

混浊海水的声吸收和声散射特性对水声探测设备工作性能的影响较大。通过经验公式仿真分析了温度、盐度和压强对低频段、低悬浮泥沙颗粒浓度混浊海水声吸收的影响。结果表明:温度和盐度对混浊海水声吸收的影响较大,而压强对混浊海水声吸收的影响可以忽略。构建并研制了一套混浊海水声吸收特性测量系统,实验研究了温度对混浊海水声吸收的影响,声吸收系数随温度的变化规律与仿真结果吻合较好。此研究成果可对混浊海水中的声传播建模、声纳探测系统设计及声纳性能的评估等提供一定参考。     

基于多方法集成的烟气、烟尘排放监测系统

根据SO2和NOx以及烟尘分别在不同光谱波段具有吸收和散射特性的特点,对同一测量光谱分别用差分吸收光谱法(DOAS)和多波长消光法进行数据处理,并辅之互相关法,可同时监测SO2、NOx和烟尘的浓度、烟尘粒度以及总排放量。基于这些方法,研制了一套直接在线烟气连续监测系统(CEMS)。在一采暖锅炉上成功地进行了不同运行工况下现场较长时间连续监测。     

光纤式动态光后向散射纳米颗粒粒度测量装置

提出并制备了一种新颖的光纤式动态光后向散射纳米颗粒粒度测试装置,装置采用多模光纤和单模光纤分别传输激光和接收散射光,光纤以探针形式直接插入样品中进行浸入式测量,具有散射角度可调和便于集成化等优点。利用搭建的装置对50nm、100nm、500nm、1000nm的聚苯乙烯纳米颗粒进行了测量,实验结果与样品的标称值相符,验证了装置的可行性。     

扫描式多光谱涡轮叶片表面温度场测量试验研究

为了解决涡轮叶片表面温度场的准确测量问题,本文采用了结合多光谱测温法和扫描式温度场测量方法的扫描式多光谱温度场测量装置,在某型燃烧室试验器上对被测样件进行了测试,并将测试结果与被测样件上布置的热电偶的指示温度进行对比。试验结果显示,扫描式多光谱温度场测量装置的测温结果与热电偶的测温结果较为吻合,能够准确得到涡轮叶片的表面温度场。     

第四代光谱辐射度和色温度国家基准装置的研制

基于高温黑体辐射源BB3500M研究并建立了第四代光谱辐射度和色温度国家基准装置。采用稳流和稳温相结合的反馈工作模式,开启后3 h即达到温度稳定。3 016 K时,1 h内的温度变化小于0.59 K。温度测量直接溯源至Pt-C和Re-C高温共晶点黑体,2 980 K时的测量不确定度为0.64 K(k=1)。光谱辐射亮度和光谱辐射照度的波长范围向短波分别扩展至220 nm、230 nm,长波扩展至2 550 nm,达到全波段光谱辐射亮度CCPR-S1比对的能力。新基准增加了分布温度参数的测量能力,2 353 K和2 856 K的测量不确定度(k=1)分别改善为1.6 K和2.1 K。对基准装置入射光学系统的辐照不均匀性以及短波紫外大气传输过程所带来的散射和吸收进行了数值计算,提出理论修正方法,将辐照不均匀性测量误差减小0.3%,大气传输误差减小0.29%。     

热电偶自动检定和热处理炉温现场测试装置建立的方案

本文阐述了由计算机控制实现的热电偶自动检定和热处理炉温现场测试装置的原理,以及测量装置的硬件设计与编程原理,并对测量装置的不确定度进行了分析.     

同步辐射与分析测试

本文介绍一种大科学装置——同步辐射装置。这是一种数百人可同时在其上进行不同的科学技术实验的设备，其可达到的水平比实验室的极限水平高许多，从某些角度代表了国家的科学和技术水平。本文扼要介绍了同步辐射的特性，同步辐射装置的构造及一些主要的分析测试技术，如：X射线吸收精细结构光谱，X射线散射，高分辨X射线衍射，能量色散与时间分辨技术，聚集与微分析，成像与显微放大，综合测试原位测试及作铯对标定等。     

水中石油类污染物的光纤荧光在线测量技术研究

根据水中石油类污染物质的光谱特性,采用荧光光谱技术,结合光纤传感技术和CCD探测技术,研制了一种可用于现场测量水中石油类污染物质的荧光光谱测量仪器。鉴于现场环境的特殊性,设计了水中自动取样预处理系统,可以实现真正意义上的实时分析,方便了现场操作。通过现场实验和性能测试,证实了其可行性,可以对水中石油类污染物质进行现场测量,从而进行污染物质的定性识别与定量分析,为水中污染物质监测提供了新的技术手段。     

紫外辐射计的波长定标及不确定度分析

限于常规汞灯谱线法波长定标的局限性,构建了紫外辐射计波长定标装置,研究了紫外辐射计波长定标的物理过程和测量链,并对紫外辐射计中臭氧十二个吸收波长进行了光谱定标,通过对定标影响量的分析和计算,得到定标影响量的测量不确定度和波长定标合成标准不确定度,其中波长定标合成标准不确定度为0.026nm,同时通过光学CAD分析和实验验证紫外辐射计的光谱带宽可以达到1.0nm.应用自行构建的紫外波长定标装置较好地完成了紫外辐射计臭氧吸收谱线的定标工作,满足了臭氧反演所需的波长精度要求和光谱带宽要求.     

Changes in spectral shape of tissue optical properties in conjunction with laser-induced thermotherapy

We measured the optical properties on samples of rat liver tissue before and after laser-induced thermotherapy performed in vivo with Nd:YAG laser irradiation. This made it possible to monitor not only the influence of coagulation on the scattering properties but also the influence of damages to vessels and heat-induced damage to blood on the absorption properties. An experimental integrating-sphere arrangement was modified to allow the determination of the g factor and the absorption and scattering coefficients versus the wavelength in the 600-1050-nm spectral region, with the use of a spectrometer and a CCD camera. The results show a relative decrease in the g factor of on average 21 ? 7% over the entire spectral range following thermotherapy, and a corresponding relative increase in the scattering and absorption coefficients of 23 ? 8% and 200 ? 100%, respectively. An increase of on average 200 ? 80% was consequently found for the reduced scattering coefficient. The cause of these changes in terms of the Mie-equivalent average radius of tissue scatterers as well as of the distribution and biochemistry of tissue absorbers was analyzed, utilizing the information yielded by the g factor and the spectral shapes of the reduced scattering and absorption coefficients. These results were correlated with the alterations in the ultrastructure found in the histological evaluation. The average radius of tissue scattering centers, determined by using either the g factors calculated on the basis of Mie theory or the spectral shape of reduced scattering coefficients calculated on the Mie theory, was estimated to be 21-32% lower in treated than in untreated liver samples. The Mie-equivalent average radii of scattering centers in untreated liver tissue deduced by the two methods corresponded well and were found to be 0.31 and 0.29 mum, respectively, yielding particle sizes in the same range as the size of a mitochondrion.     

Partitioning in situ total spectral absorption by use of moored spectral absorption-attenuation meters

High-temporal-resolution spectral absorption data were acquired by use of one bottom-mounted (~68-m) and three moored spectral absorption and attenuation meters (ac-9 meters at 14, 37, and 52 m) on the Middle Atlantic Bight continental shelf during the fall 1996 period of the Coastal Mixing and Optics experiment. We employed a previously published spectral absorption model with the data to partition total absorption into absorption by water, phytoplankton, detritus, and gelbstoff (dissolved matter). We validated the model by comparing its results against coincident in vivo absorption coefficients derived from discrete bottle samples. Correlations between modeled and in vivo spectra range from 0.873 to 0.998. We optimized these correlations to determine the model parameters. These parameters could not be determined solely from the moored ac-9 results. Therefore a separate set of absorption measurements (from discrete bottle samples) was necessary to permit values for the model parameters to be determined. Model results allow us to separate particulate and dissolved components of absorption and to examine the temporal variability and the vertical distributions and concentrations of each component, given the total absorption in the water column.     

Estimation of the inherent optical properties of natural waters from the irradiance attenuation coefficient and reflectance in the presence of Raman scattering

By means of radiative transfer simulations we developed a model for estimating the absorption a, the scattering b, and the backscattering b(b) coefficients in the upper ocean from irradiance reflectance just beneath the sea surface, R(0-), and the average attenuation coefficient for downwelling irradiance, 1, between the surface and the first attenuation depth. The model accounts for Raman scattering by water, and it does not require any assumption about the spectral shapes of a, b, and b(b). The best estimations are obtained for a and b(b) in the blue and green spectral regions, where errors of a few percent to <10% are expected over a broad range of chlorophyll concentration in water. The model is useful for satellite ocean color applications because the model input, R(0-) and 1, can be retrieved from remote sensing and the model output, a and b(b), is the major determinant of remote-sensing reflectance.     

Multispectral diffuse optical tomography with absorption and scattering spectral constraints

We present a new method to simultaneously reconstruct the images of oxyhemoglobin, deoxyhemoglobin, and water concentrations, as well as the volume fraction images of the scattering particles using continuous wave multispectral diffuse optical tomography with the absorption and scattering spectral prior constraints. In this method, the nonlinear relationship between the reduced scattering coefficient and the volume fraction and the size of the particles is linearized, allowing direct reconstruction of the volume fraction of scattering particles in tissues. The method is validated by a series of numerical simulations, phantom experiments, and in vivo clinical experiments. The initial clinical results indicate that the volume fraction of scattering particles in a malignant tumor is higher than that in a benign tumor.     

Frequency-domain method for measuring spectral properties in multiple-scattering media: methemoglobin absorption spectrum in a tissuelike phantom

We have measured the optical absorption and scattering coefficient spectra of a multiple-scattering medium (i.e., a biological tissue-simulating phantom comprising a lipid colloid) containing methemoglobin by using frequency-domain techniques. The methemoglobin absorption spectrum determined in the multiple-scattering medium is in excellent agreement with a corrected methemoglobin absorption spectrum obtained from a steady-state spectrophotometer measurement of the optical density of a minimally scattering medium. The determination of the corrected methemoglobin absorption spectrum takes into account the scattering from impurities in the methemoglobin solution containing no lipid colloid. Frequency-domain techniques allow for the separation of the absorbing from the scattering properties of multiple-scattering media, and these techniques thus provide an absolute measurement of the optical absorption spectra of the methemoglobin/lipid colloid suspension. One accurately determines the absolute methemoglob in absorption spectrum in the frequency domain by extracting the scattering and absorption coefficients from the phase shift Φ and average light intensity DC (or Φ and the amplitude of the light-intensity oscillations AC) data with relationships provided by diffusion theory, but one determines it less accurately by using the Φ and modulation M (M ≡ AC/DC) data and the diffusion theory relationships. In addition to the greater uncertainty in the absorption and scattering coefficients extracted from the Φ and M data, the optical parameters extracted from the Φ and M data exhibit systematically inaccurate behavior that cannot be explained by random noise in the system. Possible reasons for the systematically lower accuracy of the methemoglobin absorption spectrum obtained from Φ and M data are discussed.     

Numerical evaluation of the possibilities of remote laser sensing of fish schools

The operation of an airborne lidar intended for the detection of fish schools is numerically simulated by the Monte Carlo method. The calculations are performed for schools located at small depths in order to study the regularities in the shaping of the lidar return accurately. Three models of the phase function of scattering of laser radiation in sea water are used. The signals reflected from surface waters that contain a school of fish are determined as a function of the lidar parameters, light scattering and absorption coefficients in the water, stratification of light scattering layers, and fish-school depth. The results obtained can be used for interpreting the signals of the fish-detection lidar.     

MADSTRESS: a linear approach for evaluating scattering and absorption coefficients of samples measured using time-resolved spectroscopy in reflection

Time-resolved spectroscopy is a powerful technique permitting the separation of the scattering properties from the chemical absorption properties of a sample. The reduced scattering coefficient and the absorption coefficient are usually obtained by fitting diffusion or Monte Carlo models to the measured data using numerical optimization techniques. However, these methods do not take the spectral dimension of the data into account during the evaluation procedure, but evaluate each wavelength separately. A procedure involving multivariate methods may seem more appealing for people used to handling conventional near-infrared data. In this study we present a new method for processing TRS spectra in order to compute the absorption and reduced scattering coefficients. This approach, MADSTRESS, is based on linear regression and a two-dimensional (2D) interpolation procedure. The method has allowed us to calculate absorption and scattering coefficients of apples and fructose powder. The accuracy of the method was good enough to provide the identification of fructose absorption peaks in apple absorption spectra and the construction of a calibration model predicting the sugar content of apples.     

Uniqueness in remote sensing of the inherent optical properties of ocean water

We examine the problem of uniqueness in the relationship between the remote-sensing reflectance (Rrs) and the inherent optical properties (IOPs) of ocean water. The results point to the fact that diffuse reflectance of plane irradiance from ocean water is inherently ambiguous. Furthermore, in the 400 < lambda < 750 nm region of the spectrum, Rrs(lambda) also suffers from ambiguity caused by the similarity in wavelength dependence of the coefficients of absorption by particulate matter and of absorption by colored dissolved organic matter. The absorption coefficients have overlapping exponential responses, which lead to the fact that more than one combination of IOPs can produce nearly the same Rrs spectrum. This ambiguity in absorption parameters demands that we identify the regions of the Rrs spectrum where we can isolate the effects that are due only to scattering by particulates and to absorption by pure water. The results indicate that the spectral shape of the absorption coefficient of phytoplankton, a(ph)(lambda), cannot be derived from a multiparameter fit to Rrs(lambda). However, the magnitude and the spectral dependence of the absorption coefficient can be estimated from the difference between the measured Rrs(lambda) and the best fit to Rrs(lambda) in terms of IOPs that exclude a(ph)(lambda).     

2008年夏季广州大气消光系数与细粒子的关系

为了解夏季广州大气中细粒子消光特性,利用浊度仪、黑碳仪和自动气象站获得散射系数μsp、吸收系数μap以及气象要素等观测数据,并利用采样器采集大气悬浮颗粒物PM2.5和PM1.0样品获取其质量浓度。结果表明,散射系数μsp、吸收系数μap和大气消光系数(μext=μsp+μap)的平均值分别为(226±111)、(53±20)、(280±125)Mm-1;大气悬浮颗粒PM2.5和PM1.0的质量浓度分别为(53.7±23.2)、(46.1±21.3)μg/m3;消光系数μext与PM2.5和PM1.0的相关性系数分别达到0.96和0.93;PM2.5和PM1.0的平均质量浓度消光效率分别为到5.2、5.5 m2/g,表明大气中小粒径的粒子对消光系数的影响更为明显。     

Spectral radiative properties of a living human body

Spectral radiative properties of the human body were studied experimentally in the region from the ultraviolet to the far-infrared to know the thermal response of the human body exposed to solar radiation and infrared radiation. The measuring equipment for reflectance and transmittance of a semitransparent scattering medium was developed and measurement on a living human skin was performed in vivo. The measured parts are forearm, cheek, dorsum hand, hip, and hair. The values obtained by the present study are much different from those of previous in vitro measurements. Fairly large values for hemispherical reflectances are observed in the visible and near-infrared regions but very small values for hemispherical reflectances are observed in the infrared region, below 0.05. By applying the four-flux treatment of radiative transfer, the absorption coefficient and scattering coefficient in the human skin are determined. The scattering coefficient is large in the visible region but negligible in the infrared region. The absorption coefficient is very close to that of water and large in the infrared region.