共查询到20条相似文献,搜索用时 62 毫秒
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几年前,声化学(Sonochemistry)这一术语很多人还是陌生的。由于超声在化学合成,金属有机化学,化学结构的解释,聚合物科学等领域中有了大量成果,引起了人们对声化学这门新学科的重视。 事实上,声化学已有相当长的历史,50年代就有研究论文发表。那时大多是研究声波对水的分解作用。在沉寂了20年之后,声化学复兴了,出于探索新技术与新材料的动机,得到了更加广泛深入的研究。 从根本上讲,化学乃是能量与物质的一种互作用。传统的能量形式是热学的、光学的或是离子辐射的。声能则是另一种独特的形式。声波与化学分子并不直接发生互作用。超声在… 相似文献
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研究了频率为20 kHz的超声作用在圆柱形料腔中出现声流现象时超声空化效应的空间分布特性。结合大振幅声源条件下的声辐射力,对声场内的声流现象进行了仿真分析,获取了不同超声功率和液位高度下的声流速度场分布,初步探究了声流条件下空化气泡的运动分布规律。采用超声空化效应的声致化学发光实验,对比研究了有、无声流条件时超声空化效应的空间分布特性。结果表明:功放电流高于80 mA(电功率为17.6 W)时,超声场可形成稳定的声致流动现象且可有效提高其声能辐射效率,大大增加了空化效应的作用区域,进而提高了声化学反应效率;声流条件下料腔内超声空化效应的分布区域与超声功率(振幅)、料腔液位高度相关,功放电流从40 mA(电功率为8.8 W)增加至120 mA(电功率为26.4 W)时,空化面积占比提高了100.86%,液位高度为60 mm时的空化面积占比较50 mm和70 mm时分别提高了13.11%和73.91%,提高超声功率及选择合理的料腔液位高度,可有效提高空化气泡扩散距离,增大空化分布面积;对于固定形状及尺寸料腔中的声场,声流速度达到一定阈值时,会出现空化效应增强,空化效应增强区域位于大于声流速... 相似文献
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工业规模液体内的声处理应用越来越多地得到国内外声学工作者的关注。一般认为,液体内声处理的机理是声空化,因此要扩大声处理的规模,应把研究的重点放在声空化的优化,而不是一味提高声能输入。而对声空化优化的前提则需要找到简单易行、生产上可用的空化测量方法。回顾了声空化检测、测量方法,分析比较后认为:实时谱分析方法更适用于大规模液体声处理的空化测量,需加大力度深入研究。 相似文献
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This paper reports on an electrochemical technique for the detection of oxidizing radical species, produced as the result of cavitation induced by ultrasound. A study of two example reactions is reported: the Weissler reaction and the Fricke reaction. In both cases, redox-active materials trap oxidative radicals. Electrochemical detection within a flow cell system is then used to sense redox-active products of the reactions between a chosen trapping agent and radicals produced within an ultrasonically irradiated aqueous solution. A demonstration of the sensitivity of electrochemical detection of radical products is presented. An equivalent dose of the ultrasonic reactor is reported. 相似文献
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《Materials Letters》2006,60(25-26):3038-3040
Ag2Se nanocrystals were rapidly synthesized by the sonochemical reaction between Ag ions and Se powders in diluted ammonia water. By using different complexing agents (NH3, citric acid or KSCN) in the reaction system, Ag2Se nano-spheres with different sizes were obtained. X-ray diffraction patterns showed that the samples obtained was orthorhombic β-Ag2Se. The morphology was characterized by scanning electron microscopy (SEM). This mild method may be extended to prepare other chalcogenides nanocrystalline at room temperature. 相似文献
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Homogeneous distribution of semicrystalline ceria in polymethylmethacrylate has been reported. The ceria has been prepared by sonochemical method, in situ. The as-prepared composite was characterized by XRD, TEM, DSC and TGA methods. An average size of the ceria is found to be 5 nm by XRD and TEM measurements. The photonic band gap has been measured as 3.55 eV, which is in well agreement with the ceria crystals, indicating absence of a quantum size effect. 相似文献
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我国的建筑隔声分级评价体系和绿色建筑的隔声性能评价方法都未能体现建筑构件空气声隔声单值量的测量不确定度,从而造成测量与评价的困难。根据ISO 12999-1所规定的隔声单值量不确定度评定方法计算30个构件的隔声单值量不确定度,并结合GB/T 50121规定的分级评价体系进行分析。结果表明在普通频率范围内,对于三种不同频谱修正的全正相关不确定度皆随计权隔声量的增加而加大,而在扩展低频范围时,这种斜率的差异会更明显,这是因为建筑构件在低频范围较弱的隔声性能会极大影响其不确定度;若构件在低频范围和高频范围分别受阻尼控制作用和吻合作用而产生"低谷",则低谷越大,其隔声单值量不确定度越大;采用隔声单值量的测量不确定度后,方能较好地利用隔声单值量进行建筑隔声分级评价以及绿色建筑隔声性能评价。 相似文献
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Synthesis of uniform nano-structured lead oxide by sonochemical method and its application as cathode and anode of lead-acid batteries 总被引:1,自引:0,他引:1
This paper discusses the results of a research aimed at investigating the synthesis of nano-structured lead oxide through reaction of lead nitrate solution and sodium carbonate solution by the sonochemical method. At the first, lead carbonate was obtained in a synthesized solution and then, after filtration, it was calcinated at the temperature of 320 °C so that nano-structured lead oxide can be produced. The effects of different parameters on particle size and morphology of final lead oxide powder were optimized by a “one at a time” method. The prepared lead oxide powder was characterized by scanning electron microscopy (SEM), transmission electron spectroscopy (TEM) and X-ray diffraction (XRD). Under optimum conditions, uniformed and homogeneous nano-structured lead oxide powder with more spongy morphology and particle size of 20-40 nm was obtained. The synthesized lead oxide, as anode and cathode of lead-acid batteries, showed an excellent discharge capacity (140 mA h/g). 相似文献