共查询到20条相似文献,搜索用时 281 毫秒
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辊式涂布两辊间隙施涂过程的数值计算分析 总被引:1,自引:1,他引:0
目的系统地计算涂层厚度与两辊间隙、涂布辊速度以及胶黏剂的流体稠度和流动指数等影响因子的关系。方法在分析该复杂流动机理的基础上,利用CFD软件对具有非牛顿流体特性胶黏剂的两辊间隙施涂过程进行二维数值模拟。结果在五辊无溶剂涂布工程中,两辊间隙增大,最终涂布厚度也明显增大;增大涂布辊转速,涂布厚度也将减小;胶黏剂的流体稠度越大,最终传递到基材上的涂层厚度减小。结论两辊间隙的大小对涂层厚度的影响最大,胶黏剂的流体稠度、流动指数也对涂层厚度有较大的影响。 相似文献
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Pengwei Wang Jiajia Zhou Bojie Xu Cong Lu Qing'an Meng Huan Liu 《Advanced materials (Deerfield Beach, Fla.)》2020,32(45):2003453
The Plateau–Rayleigh instability (PRI) is a well-known phenomenon where a liquid column always breaks up into droplets to achieve the minimization of surface energy. It normally leads to the non-uniformity of a liquid film, which, however, is unfavorable for the fluid coating process. So far, strategies to overcome this instability rely on either the surfactants, UV/high-temp curing treatments, or specific chemical reactions, which suffer from both limited liquid composition and complicated experimental conditions. Natural mulberry silk, a typical composite fiber, is produced by silkworms through a similar fluidic coating process, but exhibits a remarkably uniform and smooth surface. Drawing inspiration, it is revealed that the unique dual parallel fibers are capable of overcoming the PRI during the fluid coating process. Such anti-PRI ability is attributable to the changes in the Laplace pressure difference caused by the alternative asymmetry of the liquid film, as has been demonstrated by both a force analysis on the irregular liquid film and theoretical simulation according to the stability of the liquid on parallel fibers in the fluid coating process. The strategy is applicable for preparing various smooth functional coatings on fibers, which offers new perspectives for fluid coating and microfluidic technologies. 相似文献
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在钛及钛合金表面生成羟基磷灰石(HA)来制备生物材料是医学应用中亟待解决的问题。利用微弧氧化工艺在Ti合金表面制备了HA膜,研究了膜层在模拟体液中浸泡前后的形貌、相结构、Ca与P原子分数比,并分析了膜层在模拟体液中的降解和沉淀机制以及浸泡后的耐磨性。结果表明:膜层在模拟体液中随浸泡时间延长而逐渐变厚;浸泡20d后膜层中... 相似文献
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Hu Kai Yang Xianjin Cai Yanli Cui Zhenduo Wei Qiang 《Frontiers of Materials Science in China》2007,1(3):229-236
A hydroxyapatite (HA)/collagen (COL) composite coating on NiTi shape memory alloy (SMA) was prepared by eletrochemical deposition
(ELD) in modified simulated body fluid (MSBF). To draw comparisons of physical characteristics and bioactivity of the composite
coating, the HA/COL composite coating was also prepared by chemically biomimetic growth (BG) and the ELD coating was re-soaked
in MSBF again for further biomimetic growth (called EBG method in this paper). It was indicated that the c-axis of HA crystals
was oriented parallel to the longitudinal direction of the COL fibril in BG and EBG coating, which could not found in ELD
coating. The EBG method could induce a denser, thicker and better crystallized HA/COL coating. The cell culture test indicated
that the BG coating presented better cell biocompatibility. 相似文献
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A simple analysis of the fluid dynamics of the optical fiber coating process is used to predict the resulting coating thickness as a function of draw velocity, coating cup pressure, and resin viscosity for a cylindrical coating die. The effects of surface tension forces and viscous heating are assessed. The analysis is compared to experimental data and found to give good predictions. 相似文献
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Sharma S Soni VP Bellare JR 《Journal of materials science. Materials in medicine》2009,20(Z1):S93-100
Frequently metal implants undergo detachment from the host tissue due to inadequate biocompatibility and poor osteointegration. In view of this, bioactive porous apatite-wollastonite/chitosan nanocomposite coating was prepared using electrophoretic deposition (EPD) technique in the present work. The effect of coating duration and current density on surface characteristics of the nanocomposite coating was assessed using optical microscope and scanning electron microscope. EPD led to the formation of thick and homogeneous coating. Adhesion of the composite coating on titanium substrate was evaluated using tape test and bioactivity of the coatings was studied by immersing in simulated body fluid (SBF). The coating with higher current density and longer coating duration was found to be suitable with improved adhesion and bioactivity for intended metal implants. 相似文献
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铝合金表面铈锰化学转化 总被引:1,自引:0,他引:1
以硝酸铈和高锰酸钾为主盐,在6063铝合金表面制备了Ce-Mn化学转化膜。研究了室温下成膜时间、转化液pH值、硝酸铈和高锰酸钾浓度对Ce—Mn转化膜电化学性能的影响,获得了最佳成膜工艺:7g/LCe(NO3)3,2g/LKMnO4,时间9min,pH值2.3。采用极化曲线考察了所得转化膜的耐蚀性,并通过扫描电镜和能谱仪分析了膜的表面微观形貌和组成。结果表明:Ce.Mn转化膜比6063铝合金具有更低的腐蚀电流密度和更大的极化电阻,表现出良好的耐腐蚀性能;Ce-Mn转化膜主要成分是铝、镁、铈、锰和氧。 相似文献
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Smriti Sharma Vivek P. Soni Jayesh R. Bellare 《Journal of materials science. Materials in medicine》2009,20(1):93
Frequently metal implants undergo detachment from the host tissue due to inadequate biocompatibility and poor osteointegration. In view of this, bioactive porous apatite-wollastonite/chitosan nanocomposite coating was prepared using electrophoretic deposition (EPD) technique in the present work. The effect of coating duration and current density on surface characteristics of the nanocomposite coating was assessed using optical microscope and scanning electron microscope. EPD led to the formation of thick and homogeneous coating. Adhesion of the composite coating on titanium substrate was evaluated using tape test and bioactivity of the coatings was studied by immersing in simulated body fluid (SBF). The coating with higher current density and longer coating duration was found to be suitable with improved adhesion and bioactivity for intended metal implants. 相似文献
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G. Perfetti D.E.C. van der Meer W.J. Wildeboer G.M.H. Meesters 《Advanced Powder Technology》2012,23(1):64-70
The purpose of the present study is to obtain better understanding of the influence of the coating thickness, h, coating formulation, Tg, and fluid bed temperature, Tbed, variables on the resistance to attrition of the coated sodium benzoate reference particles. Three reference coating materials (Tg = 50 – 125 – 150 °C) have been sprayed by using top spray fluid bed coater. Per each coating formulation three different coating levels (h = 1% – 5% – 9% w/w) have been obtained. The coating processes were performed at three different fluid bed temperatures (Tbed = 40 – 55 – 70 °C). The experiments have been designed according to the response surface methodology (RSM). Both single effects and interactions between single effects on the resistance to attrition (response variable) calculated by means of repeated impact tester were evaluated. From statistical analysis, the coating quantity appears to have a predominant effect on the resistance to attrition of the coated particle in these studied ranges of variables. This relationship is linear and positive, which means that an increasing quantity leads to more resistance to attrition. The interaction coating thickness – coating formulation, the interaction between the fluid bed temperature and the coating formulation and the coating formulation as well as the interaction costing thickness – fluid bed temperature were found to be very significant. On the contrary, no direct effect of the fluid bed temperature on the resistance to attrition is detected. 相似文献
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大气喷涂法制备的镁黄长石涂层是一种具有优良生物活性的新型骨科移植体涂层材料, 但其结晶度较低, 影响涂层的化学稳定性。本研究采用真空等离子喷涂法在钛合金表面制备了高结晶度的镁黄长石涂层。与大气喷涂镁黄长石涂层相比, 真空喷涂镁黄长石涂层具有更高的磷灰石矿化能力, 在SBF中浸泡6 d后表面即沉积了一层类骨磷灰石层, 浸泡14 d后表面沉积的磷灰石层的厚度约为大气涂层的4倍。真空喷涂镁黄长石涂层的离子释放明显低于大气涂层, 显示出更高的化学稳定性。骨髓间充质干细胞在真空和大气喷涂镁黄长石涂层表面粘附和铺展良好, 在两种涂层表面的增殖速度均明显高于HA涂层。本研究表明真空等离子喷涂的镁黄长石陶瓷涂层因其显著提高的生物活性及化学稳定性, 可能更适合用作人工关节涂层材料。 相似文献
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在纯钛基体表面通过电泳沉积的方法制得壳聚糖/羟基磷灰石(CS/HA)复合涂层, 然后将复合涂层烧结形成多孔HA涂层。采用SEM对多孔HA涂层的形貌进行观察, XRD分析涂层的物相组成, 粘结拉伸实验测定涂层与基体的结合强度, 1.5倍人体模拟体液(1.5SBF)浸泡测定涂层的生物活性。结果表明: 当悬浮液中CS与HA质量比为1∶1时, 制得的CS/HA复合涂层经过700℃烧结处理, 涂层中CS热分解致孔形成多孔HA涂层, 孔径在10~25 μm, 涂层与基体的结合强度可达19.5 MPa; 在1.5SBF中浸泡5天后, 多孔HA涂层表面完全碳磷灰石化, 呈现较好的生物活性。 相似文献
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Understanding the interaction of bioactive coatings with aqueous media is essential for development of systems possessing
rapid osteointegration and durability. An in vitro study of a commercial, plasma sprayed hydroxyapatite coating has been undertaken. The coating behaviour when test coupons
were immersed in water, simulated body fluid and foetal calf serum has been examined. The principal aim was to characterise,
in detail, any structural changes to the coatings and, in particular, examine features of any new layers formed.
The amorphous phase of the coating showed preferential dissolution in all media. The rate of dissolution was greatest in water
and the process was initially retarded in the foetal calf serum. A nanocrystallite apatite layer was shown to precipitate
on the coatings in all media although this was significantly enhanced in simulated body fluid. The features of this layer
(e.g., lattice parameters, crystallite size etc.) were quantified by adopting a novel approach to the X-ray diffraction data
analysis.
The results are discussed in the context of similar studies and implications for in vivo behaviour. 相似文献
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The evolution of a temperature gradient at the free surface of a coating solution during the spin coating process is examined. Solvent evaporation causes localized cooling at the top that can result in thermocapillary instability within the coating solution, and thereby driving convective flows that may result in non-uniform coatings. We examine the evolution of these temperature gradients by using a one dimensional finite difference model that simultaneously describes the thinning behavior (both by flow and by evaporation) and the temperature evolution within the solution. The entire system is initially isothermal but is subject to evaporation-driven cooling at the free surface of the gradually thinning fluid. The model is then used to determine the magnitude of the thermocapillary effects during the spin coating process. As test systems we simulate the spin coating of several pure alcohol solutions having different volatilities and therefore different evaporative-cooling powers. As the fluid thins, we calculate the instantaneous Marangoni (Mn) number, which signifies the magnitude of thermocapillary-driven convection. We compare these Mn values against their relevant threshold values, determined from prior reports in the literature, in order to deduce the magnitude of the instabilities they represent. If the Mn value is super-critical, then the instability that it represents will be sufficient for the onset of convection cells within a stagnant fluid layer of corresponding thickness. Because the radial outflow is fully laminar under normal conditions, super-critical Mn values imply that similar instabilities would arise within a spinning solution. Super-critical Mn values were observed under numerous conditions suggesting that thermocapillary instability may be responsible for striation features that develop in coatings made by spin coating. Trends related to spin-speed, solvent volatility, and initial solution thickness are discussed with the goal of improving the flatness of coatings that are made by this process. 相似文献
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采用超声空蚀与电化学测试相结合的方法,对AC-HVAF热喷涂非晶金属和金属陶瓷两种涂层在水力压裂液中的空蚀及交互作用规律进行了研究,分析了耐蚀性和硬度在空蚀时的主导作用,确定了空蚀机理。结果表明,压裂液中KCl恶化了涂层的腐蚀性能,进而影响了空蚀行为。涂层在压裂液中的抗空蚀性能是耐蚀性与硬度结合的双变量函数。空化的力学破坏对高硬度涂层的空蚀过程有显著影响,硬度相对较高的金属陶瓷防护涂层的抗空蚀性能优异。压裂工况下,AC-HVAF涂层空蚀损伤是由于气泡溃灭垂直冲击孔隙或缺陷区域,硬相直接被剥离表面。降低孔隙和提高粘结相结合强度有助于提高涂层在压裂液中的抗空蚀性能。 相似文献