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1.
以超高分子量聚乙烯纤维(UHMWPE)-碳纤维(CF)三维混杂编织体为增强体,环氧树脂(ER)为基体,通过树脂传递模塑(RTM)工艺制备了三维编织混杂复合材料,研究了其摩擦磨损性能了,并采用混合正压力模型对摩擦系数进行了预测。结果表明,在纤维总体积含量一定的情况下,随着CF体积含量的增加,复合材料的摩擦系数增大,而其比磨损率降低。UH3D/ER复合材料的磨损机制以粘着磨损为主,CF3D/ER复合材料则以磨粒磨损为主,混杂复合材料的磨损机制主要取决于CF与UHMWPE纤维的相对含量 ,通过调节UHMWPE纤维和CF的体积比例可实现对复合材料摩擦磨损性能的有效调控。采用的计算模型可较好地预测UH3D/ER的摩擦系数。  相似文献   

2.
聚合物基复合材料的湿扩散参数研究   总被引:4,自引:1,他引:3       下载免费PDF全文
通过系统地研究几种国产复合材料的吸湿行为,获得了描述湿气在其中扩散的基本参数,如平衡湿含量Mm,Mm与相对湿度φ关系中的常数a和b,沿板材厚度方向上的一维湿扩散系数Dx以及Dx与温度关系中的常数ΔE(湿扩散活化能)和D0等。  相似文献   

3.
分别采用溶液交联和蒸汽交联法制备了CL/Gel复合材料,溶液交联CL/Gel复合材料的溶胀行为可用二次速率方程描述,但不满足Fick定律;蒸汽交联CL/Gel复合材料的溶胀既不能用二次速率方程表达,也不满足Fick定律,其溶胀度低于前者。虽然溶液交联CS/Gel复合材料的溶胀与溶液交联CL/Gel复合材料遵循同样的规律,但CS/Gel复合材料的平衡溶胀度W和溶胀速率K均小于相应的CL/Gel复合材料。结果表明,纤维形式和含量对C/Gel生物复合材料的溶胀性能有较大的影响,笔者对其影响机制进行了初步探讨。  相似文献   

4.
热模压辅助先驱体浸渍裂解制备Cf/SiC复合材料研究   总被引:6,自引:2,他引:4       下载免费PDF全文
以聚碳硅烷为先驱体,采用热模压辅助先驱体浸渍裂解工艺制备3D-B Cf/SiC复合材料,研究了热模压辅助对3D-B Cf/SiC复合材料致密度和力学性能的影响。结果表明:先驱体浸渍裂解制备陶瓷基复合材料第一次浸渍后引入高温热模压工艺可以改善材料微观结构,显著提高材料的致密度和力学性能。其中1600℃,10MPa,1h下热模压辅助先驱体浸渍裂解6次制备的3D-B Cf/SiC复合材料的密度为1.79g/cm3,弯曲强度高达672MPa,断裂韧性达18.9MPa·m1/2,剪切强度接近50MPa,且具有较好的抗热震性和高温抗氧化性。  相似文献   

5.
热膨胀是影响复合材料性能和使用寿命的主要因素之一。为研究具有低/负热膨胀的复合材料,本文以碳纤维粉、ZrW2O8颗粒和环氧树脂为原料,采用模压法制备了Cf-ZrW2O8/9621环氧树脂基复合材料,研究了碳纤维粉和ZrW2O8颗粒含量对复合材料热膨胀行为的影响规律,并分析了不同温度区间内Cf-ZrW2O8/9621环氧树脂基复合材料热膨胀的变化规律。研究结果表明:在30~200 ℃范围内,当ZrW2O8颗粒含量不变时,随着碳纤维粉含量的增加复合材料的平均热膨胀系数逐渐降低,其中碳纤维粉含量增加到12%时,复合材料的平均热膨胀系数最低,为29.9×10-6/℃,降低了约60%;当碳纤维粉含量不变时,ZrW2O8颗粒含量逐渐增加到12%时,复合材料的平均热膨胀系数呈现先减小后增加的趋势,当ZrW2O8颗粒含量为9%时,复合材料的热膨胀系数最低,为40.8×10-6/℃,降低了约28%。在30~200 ℃范围内,Cf-ZrW2O8/9621复合材料在热膨胀过程中,温度升高后试样长度的变化量dL与试样原始长度L0的比值出现增加、减小和增加3个阶段。碳纤维粉和ZrW2O8颗粒均能够降低复合材料的热膨胀系数,但碳纤维粉降低复合材料热膨胀的效果比ZrW2O8颗粒更好些。  相似文献   

6.
将累托石(REC)有机化处理后通过熔融插层复合法制备了REC/热塑性聚氨酯弹性体(TPUR)纳米复合材料,并用傅立叶变换红外光谱仪(FTIR),X-射线和扫描电镜(SEM)等进行了表征。研究结果表明:十二烷基芳基季铵盐(C12)对REC的处理效果及在TPUR中的分散性优于十六烷基季铵盐(C16)和联苯胺(BZD);少量有机化处理REC(分别记作C12-REC,C16-REC和BZD-REC)加入TPUR就可使复合材料的力学性能大幅度提高,其中C12-REC/TPUR的拉伸和撕裂强度在2 wt% C12-REC含量时分别由38.87 MPa和92.8 kN/m提高到57.93 MPa和123.37 kN/m ,增幅分别达49 %和33 %;初步考察了有机化处理条件对力学性能的影响,结果发现:用处理2h的REC制备的纳米复合材料性能最佳。  相似文献   

7.
实验测量了TiC 烧结体的高温塑性变形行为, 讨论了掺入Cr3C2 对TiC 高温塑性变形的影响, 结合TiC/Ni3A l 梯度材料的循环热冲击特性得出: TiC/Ni3A l 梯度材料有效热导率随循环次数增加呈下降趋势与TiC 的塑性变形行为密切相关, TiC 表面的纵向裂纹是由巨大的径向压应力引起的。  相似文献   

8.
湿热环境对抽油杆CF/VE拉挤复合材料的影响   总被引:7,自引:0,他引:7       下载免费PDF全文
研究了95℃蒸馏水环境中油田抽油杆用碳纤维/乙烯基酯树脂(CF/VE)拉挤复合材料的吸湿特性,以及材料的力学性能和动态热机械性能的变化,并观察了湿热老化前后该复合材料的表面和断口形貌。结果表明,CF/VE拉挤复合材料的吸湿行为符合菲克第二定律,材料的平衡含湿量Mm约为1.046%,水分在复合材料中的扩散系数约为2.233×10-6 mm2/s;复合材料的性能下降趋势与吸湿率的增加趋势相对应,浸泡1176 h后,弯曲强度和层间剪切强度的最终保留率分别约为49%和54%;DMTA及SEM结果表明,湿热环境导致该复合材料发生基体溶胀、塑化和界面脱粘,引起基体和界面形貌的变化,但未发生化学老化。  相似文献   

9.
利用挤压铸造法制备了Al2O3f+Cf/ZL109短纤维混杂金属基复合材料,并探讨了Al2O3纤维对该混杂复合材料干滑动摩擦磨损行为的影响。结果表明:混杂复合材料的摩擦系数以及从轻微磨损到急剧磨损转变的临界载荷均随着Al2O3体积分数的增加不断增大。在轻微磨损阶段,复合材料的主要磨损机制为犁沟磨损和层离,且Al2O3体积分数为12%时混杂复合材料的磨损率最低。发生严重磨损时,基体和复合材料的磨损机制均为严重的粘着磨损。  相似文献   

10.
以聚碳硅烷(PCS)/二乙烯基苯(DVB)为先驱体,经8个周期的反复真空浸渍-交联-裂解处理制备出三维编织碳纤维增强碳化硅(3D-B Cf/SiC)复合材料,考察了裂解工艺对材料结构与性能的影响。结果表明:提高裂解升温速率可以提高材料密度,形成较理想的界面结合,从而提高材料的力学性能。裂解温度对材料性能也有较大的影响,Cf/SiC复合材料在第6个周期采用1600℃ 裂解可以弱化纤维与基体之间的界面,提高材料致密度,材料的力学性能也得到较大改善。裂解升温速率为15℃/min,第6个周期采用1600℃裂解制备的Cf/SiC材料性能较好,弯曲强度达到556.7 MPa。  相似文献   

11.
对比研究了环氧5228A树脂及碳纤维/环氧5228A树脂复合材料层合板在3种湿热环境(水煮、70℃水浸,70℃85%相对湿度)下的湿热性能,考察了湿热条件对复合材料层间剪切性能的影响规律,并从吸湿特性、物理化学特性、树脂力学性能、湿应力等方面分析了不同湿热环境下复合材料性能衰减的机制。研究表明,碳纤维/高温固化环氧树脂复合材料层间剪切性能主要是由吸湿率决定,相同吸湿率不同湿热条件下性能的下降幅度基本相同;3种湿热条件下该树脂及其复合材料未发生化学反应、微裂纹等不可逆变化,复合材料层合板湿热老化机制主要是吸入水分后基体增塑和树脂、纤维湿应变不一致导致的湿应力对复合材料性能的负面作用。  相似文献   

12.
通过对碳纤维环氧复合材料试样进行不同湿热环境下的拉伸和压缩实验,分析其吸湿特性、拉压力学性能、破坏后断口形貌以及动态力学性能,探讨湿热对该复合材料的拉伸和压缩性能的影响。结果表明:碳纤维环氧复合材料的吸湿过程满足Fick定律,饱和吸湿率约为0.86%。吸湿后材料表面变得光滑,有少量纤维拔出和树脂破坏发生,但吸湿后没有发生化学反应和新物质生成。吸湿后在130℃下,复合材料的拉伸性能保持率为96%,而压缩性能保持率仅为69%。吸湿后玻璃化转变温度比干态时下降了33℃。  相似文献   

13.
In this work, the effect of moisture absorption on the mechanical properties of particulate composite materials is studied. Moisture absorption constitutes a main parameter affecting the thermomechanical behaviour of composites, since it causes plasticization of the polymer matrix with a concurrent swelling. In the present work, the influence of water absorption on the flexural properties of particle-reinforced composites was thoroughly investigated. It was found that during the process of moisture absorption there exists a variation of the flexural properties closely related to the degradation of the mechanical behaviour of the composite, as well as the percentage amount of moisture absorbed. Experiments were carried out with composite made of epoxy resin reinforced with low-content iron particles. The variation of ultimate stress, breaking strain, deflection, elastic modulus and Poisson ratio due to water absorption was examined.  相似文献   

14.
This paper reports the fabrication and the characterization of glass/epoxy, carbon/epoxy and hybrid laminated composites used in the reinforcement and/or the repair of aeronautic structures. These composites were manufactured by the hand lay-up process. Their physical, thermal and mechanical behaviors are discussed in terms of moisture absorption, thermal stability, tensile strength, elastic modulus, flexural strength, flexural modulus and abrasive wear resistance. The impact of hygrothermal aging on the mechanical properties of each composite group has been also investigated.The main results indicated that after water immersion, all composites showed significant moisture absorption especially for glass/epoxy composite. Thermogravimetric analysis showed that the hybrid composite presented the best thermal stability behavior while the glass/epoxy composite the bad behavior. The mechanical properties of the carbon/epoxy composites, in the bulk material, were considerably higher than those of the glass/epoxy; the hybrid structure presented intermediate mechanical properties. The same trend was also observed in terms of wear properties. Finally, a deleterious effect on the strength of all composites due to hygrothermal exposure was established. However, carbon/epoxy composites seem to be less susceptible to aging damage after 90 days at 90 °C.  相似文献   

15.
The aim of this work is to investigate the long term effects of moisture on the interface between a carbon fibre and an epoxy matrix. High modulus carbon fibres were used to prepare single fibre model composites based on an epoxy resin. The samples were immersed in the seawater and demineralised water and their moisture uptake behaviour was monitored. The equilibrium moisture content and diffusion coefficients for the samples were determined. DSC has been used to analyse the moisture effects on glass transition temperature and thermal stability of the pure epoxy specimens. These results showed a reduction in the glass transition temperature (Tg) after moisture absorption. Tensile tests were also carried out for the epoxy specimens and a general decrease in the mechanical properties of the epoxy matrix was observed. Raman spectroscopy was used to observe the effects of moisture on the axial strain of the carbon fibre within the composite and stress transfer at the interface as a function of exposure time. The results show that the decrease in the mechanical and interfacial properties of the model composites under the seawater immersion is more significant than under demineralised water immersion.  相似文献   

16.
为研究玻璃纤维(GF)/环氧树脂复合材料湿热老化机制,首先,利用称重法、动态热机械分析仪(DMA)、SEM和矢量网络介电分析仪研究了湿热老化对GF/环氧树脂608(EP608)复合材料性能的影响;然后,分析了复合材料的吸湿率、力学性能、介电性能与老化时间的关系,并对其老化机制进行了探讨。结果表明:随老化时间延长,GF/EP608复合材料的力学性能和介电性能均有不同程度的下降;湿热老化对GF/EP608复合材料吸湿率的影响符合Fickian扩散定律;树脂基体的塑化、水解和基体-纤维界面的破坏是造成GF/EP608复合材料力学性能和介电性能下降的主要因素。所得结论可为GF增强环氧树脂基复合材料的应用提供科学依据。  相似文献   

17.
The aim of the present study is to investigate and compare the mechanical and thermal properties of raw jute and banana fiber reinforced epoxy hybrid composites. To improve the mechanical properties, jute fiber was hybridized with banana fiber. The jute and banana fibers were prepared with various weight ratios (100/0, 75/25, 50/50, 25/75 and 0/100) and then incorporated into the epoxy matrix by moulding technique to form composites. The tensile, flexural, impact, thermal and water absorption tests were carried out using hybrid composite samples. This study shows that addition of banana fiber in jute/epoxy composites of up to 50% by weight results in increasing the mechanical and thermal properties and decreasing the moisture absorption property. Morphological analysis was carried out to observe fracture behavior and fiber pull-out of the samples using scanning electron microscope.  相似文献   

18.
采用复合处理工艺对三维混杂超高分子量聚乙烯纤维/碳纤维编织体进行表面处理, 通过RTM工艺制备了环氧树脂基混杂复合材料(UHMWPE/CF/ER), 并研究了其力学性能及混杂效应。结果表明, 在纤维总体积分数一定的情况下, 随着超高分子量聚乙烯纤维/碳纤维混杂比的减小, 复合材料的弯曲强度、 弯曲模量及压缩强度增大, 而其纵向剪切强度及冲击韧性降低。三维编织混杂复合材料的断裂机制由混杂纤维的混杂比及其性质决定, 通过调节混杂比可实现对复合材料力学性能的有效调控。  相似文献   

19.
采用实验和有限元方法,研究了三维编织碳纤维/环氧树脂复合材料在低温场(20、0、-50、-100℃)中横向压缩性质温度效应。研究结果表明:温度对碳纤维/环氧树脂横向压缩模量、屈服应力及切向模量均有不同程度影响。三维编织碳纤维/环氧树脂复合材料横向压缩后,试样表面形貌受温度影响显著。低温场中,表面鳞纹现象减弱,且纱线-树脂间界面出现开裂。温度降低导致碳纤维/环氧树脂内部产生热应力。热应力对碳纤维/环氧树脂力学性能影响有限,不是温度效应的主导因素。基体性质随温度变化是三维编织碳纤维/环氧树脂复合材料横向压缩性质温度效应的主要机制。  相似文献   

20.
自行开发了一种高刚度环氧树脂(5182树脂),研究了5182树脂的增刚机制、耐热性能和力学性能。结果表明,原位生成的酰亚胺刚性链段及增加的多交联位点提高了5182树脂交联网络的刚性,其玻璃化转变温度达228℃,拉伸模量达到4 375 MPa。采用高刚度5182树脂制备了国产BHM3和东丽M40J高模碳纤维增强高刚度环氧树脂复合材料,考察了高模碳纤维/高刚度环氧树脂单丝复合材料的界面黏结性能和断面微观形貌,并评价了高模碳纤维/高刚度环氧树脂单向复合材料的宏观力学性能。结果表明,由于树脂模量的提高及界面破坏区域由碳纤维表面转移到环氧树脂区,高模碳纤维/高刚度环氧树脂复合材料的界面剪切强度最高达106.8 MPa,宏观力学性能优异,尤其弯曲性能和层间剪切强度大幅提高。  相似文献   

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