首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献,搜索用时 265 毫秒
1.
采用超声挤出制备了聚丙烯/纳米碳酸钙(PPCA s)复合材料,考察了加入纳米碳酸钙前后的结构演变和结晶行为的变化。结果表明,超声辐照能促进n-C aCO3粒子在聚合物基体中的分散,使其分散尺寸减小,分布更均匀。由于纳米粒子的成核效应,PPAC s的结晶温度和结晶度都有所提高,施加超声使结晶温度又有所提高,使结晶度相对于未施加超声辐照的纳米复合材料的低。  相似文献   

2.
考察了熔融挤出后施加的牵伸比和增容剂对聚丙烯 (PP)/热致液晶聚合物(TLCP) 原位复合材料中TLCP分散相形貌的影响。结果表明,复合材料中的TLCP相随着牵伸比的增大逐渐形成良好的微纤结构,TLCP微纤的长径比随牵伸比增大而增大;当体系中加入增容剂PP-g-MAH后,体系中TLCP在较小的牵伸速率下即可形成长径比很大的微纤结构。将上述所得原位复合材料与玻纤在 200℃(低于TLCP熔融温度) 下熔融挤出制得玻纤和液晶聚合物微纤混杂增强的材料。实验证明,在此加工温度下液晶聚合物形态得到较好保持,注射样品中不存在原位复合材料中典型的"皮-芯"形貌。同时,增容剂PP-g-MAH还明显改善了玻纤与基体之间的界面粘结。  相似文献   

3.
对具有良好液晶聚合物微纤结构的聚丙烯/热致液晶聚合物/玻璃纤维 (PP/TLCP/GF) 混杂复合材料,使用静态拉伸和动态力学分析 (DMA) 的方法研究了材料的力学性能。拉伸实验结果表明,混杂复合材料的拉伸强度和模量随着PP和TLCP挤出后的牵伸速率增大而上升,并且含有增容剂PP-g-MAH的体系,力学性能更优异。DMA测试结果表明,混杂复合材料的动态模量E'随着体系中玻纤的含量增加而增大;当体系中加入增容剂后,复合材料的刚性得到进一步提高。但无论是否使用了增容剂PP-g-MAH,当体系中玻纤含量高于20%后,模量随玻纤含量增大的趋势变缓。当体系中增强相的含量增加,以及加入增容剂使增强相与基体的界面粘结得到改善后,PP基体的损耗因子 (tanδ) 峰值都有一定的减小。  相似文献   

4.
本文将超声分散后的改性碳酸钙晶须分散液加入天然胶乳,对其进行补强,制得绿色环保高性能的改性碳酸钙晶须/天然胶乳医用复合材料。系统研究了该医用复合材料的力学性能、抗菌性能及热稳定性能。结果表明,使用硬脂酸改性后的碳酸钙晶须与天然胶乳基体材料有极佳的相容性。医用复合材料的力学性能、抗菌性能及热稳定性能均比纯胶有所提高。当改性碳酸钙晶须用量为4%时,医用复合材料的各项性能达到最佳。  相似文献   

5.
采用竹纤维与聚烯烃为主要原料,并辅以少量改性与加工助剂,通过同向平行双螺杆挤出造粒线,制备高填充竹塑复合材料颗粒,用于注塑成型包装盒盒坯。研究竹纤维填充量、润滑剂与填料对复合材料加工性能的影响,聚烯烃树脂与填料对成型周期的影响,以及树脂基体、模具温度对包装盒盒坯翘曲变形的影响。研究结果表明:随着竹纤维含量的增加,复合材料的熔融指数快速下降,竹纤维质量分数超过50%后下降速度减缓;润滑剂可以提高复合材料的熔融指数,且内外润滑平衡的复合润滑剂最稳定;滑石粉较碳酸钙更有利于改善复合材料的流动性。聚丙烯比聚乙烯基体复合材料的注塑冷却时间短,滑石粉在缩短冷却时间方面优于碳酸钙。竹塑包装盒盒坯的翘曲变形量随着混合树脂基体中聚丙烯含量的增加而减少,随着模具温度的变化出现波动,最佳模具温度为50℃左右。  相似文献   

6.
纳米粒子改性环氧树脂及其复合材料力学性能研究   总被引:6,自引:0,他引:6  
通过机械共混法制备了Al2O3纳米粒子改性环氧树脂基体,研究了纳米粒子含量对改性树脂基体力学性能的影响,并采用紧凑拉伸实验研究了纳米粒子改性环氧树脂的断裂韧性。利用改性树脂制备了玻璃纤维增强复合材料,研究了改性复合材料的力学性能与纳米粒子含量之间的关系。结果表明:纳米粒子的加入明显改善了环氧树脂基体的断裂韧性并且有助于提高树脂与纤维之间的界面粘接强度,因而使改性复合材料的层间性能明显提高而其他力学性能基本不变。  相似文献   

7.
TiC与TiC-WC的添加对FeAl/Al2O3复合材料力学性能的影响   总被引:2,自引:0,他引:2  
在FeAl/Al2O3复合材料基体中分别加入TiC或TiC-WC固溶体可显著提高其抗弯强度。当添加20%TiC和20%TiC-WC固溶体时,复合材料的抗弯强度分别达到1028.46MPa和1328.72MPa,但其断裂韧性分别降低约40%和30%。当TiC-WC固溶体加入量为5%时,可同时提高复合材料的抗弯强度和断裂韧性。  相似文献   

8.
采用扫描电镜(SEM)、动态力学分析(DMA)、力学性能测试、动态流变分析等手段研究了基体极性和相容剂对磷酸盐玻璃(TFP)/聚丙烯(PP)复合体系相容性的影响。结果表明,当基体用聚丙烯接枝马来酸酐(PP-MAH)替换非极性的聚丙烯(PP)时,磷酸盐玻璃(TFP)粒子在基体中的分散尺寸由10μm减小为2μm,分散相对复合材料的复数黏度(η*)的影响更为明显;加入相容剂后,体系的黏度进一步增大,且基体的玻璃化转变温度向高温方向移动了5℃,复合材料的断裂伸长率近似线性增长。  相似文献   

9.
TiC颗粒增韧MoSi2基复合材料的力学性能   总被引:10,自引:0,他引:10  
通过湿法混合和热压法制备了不同体积百分比的TiCp-MoSi2复合材料,研究了TiC颗粒对MoSi2基体材料显微结构和力学性能的影响。实验结果表明,在MoSi2基体中加入TiC颗粒,细化了基体的晶粒,改善了其力学性能。与纯MoSi2相比,含40vol% TiC颗粒的复合材料的室温抗弯强度提高了65%,含20vol%TiCp的复合材料的室温断裂韧性提高了53%,而且TiC颗粒的加入大大提高了MoSi2的高温承载能力,随TiC颗粒含量的增加,复合材料的高温抗弯强度大为增加。  相似文献   

10.
采用差示扫描量热仪研究了增容剂和稀土β成核剂对聚丙烯/硫酸钙晶须复合材料非等温结晶动力学及熔融行为的影响。动力学分析表明,莫志深方法能很好地描述聚丙烯非等温结晶动力学,达到相同的结晶度,复合材料所需要的冷却速率要小于纯基体。结晶形态和熔融行为均依赖于复合材料的组成和降温冷却速率。硫酸钙晶须具有一定的β成核作用,聚丙烯接枝马来酸酐(PP-g-MAH)的加入不利于β晶型的生成。  相似文献   

11.
A single three point bend specimen compliance method for determining JIC of high strength high fracture toughness steels is presented and a formula for calculatinff J-integral is proposed as follows.It is simple and valid for high strength high fracture toughness steels. The values of JIC and KIC measured by this method are in good agreement with those measured by standard test method.  相似文献   

12.
Fracture Mechanic Analysis of Toughness Behaviour of Filled Thermoplastics For determination of toughness properties of filled thermoplastics the instrumented Charpy impact test has been used. The interpretation of impact load-deflection curves has been carried out with modern concepts of fracture mechanics. The change of toughness with increasing filler volume can be described for particle filled composites with the help of the J-integral in a suitable mode. The influence of filler volume, filler dimension and matrix type on critical J-integral and COD on the initiation of instable crack growth was tested. With the help of a micromechanical model to describe failure processes taking account of energy dissipative processes it is possible to calculate fracture mechanical behaviour of filled thermoplastics.  相似文献   

13.
The Effective Fracture Toughness in Hydraulic Fracturing   总被引:1,自引:0,他引:1  
This paper examines the effective fracture toughness approach which is used in hydraulic fracturing in order to explain the high net-pressures that are often observed in field operations. The effective fracture toughness is calculated using a fully deterministic elasto-plastic hydraulic fracturing model. Rock is modelled by Mohr–Coulomb flow theory of plasticity for cohesive-frictional dilatant material. Fluid flow is modelled by lubrication theory. A cohesive crack model which takes into account the softening behaviour of rocks is employed as the propagation criterion. The fully coupled model is solved numerically by the finite element method and the effective fracture toughness is calculated using the path independent J-integral. The results show that plastic yielding near the tip of a propagating fracture provides an effective shielding, resulting in an increase in the rock effective fracture toughness by more than an order of magnitude. It is demonstrated that an elastic model based on the concept of effective fracture toughness matches the results of plasticity quite well. The effective fracture toughness increases with formation yielding, which is influenced by the deviator of the in-situ stresses, the rock strength, the elastic modulus and the pumping parameters. Tables of effective fracture toughness for a representative set of physical parameters are presented. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

14.
In this paper unreinforced and long-glass-fibre-reinforced PA66/PP blends with different glass-fibre sizing were studied with respect to their fracture toughness determined by the typical Kc method. The fracture surfaces of these blends were studied by scanning electron microscopy in order to characterize the failure mechanisms. For the unreinforced blends a decrease in fracture toughness was observed when 25 wt% of polyamide (PA) was added to the polypropylene (PP) matrix, compared with the plain PP and PA matrices. On the other hand an increase in fracture toughness was observed when 25 wt% of PP was added to the PA matrix. This was explained by the differences in thermal expansion of PP and PA. The fracture toughness of the long-glass-fibre (LGF) composites were not affected by the glass-fibre sizing up to a PA/PP ratio of 50/50. After the phase inversion from a continuous PP to a continuous PA phase in the matrix (between PA/PP ratios of 50/50 and 75/25) the PA glass-fibre sized composite showed higher fracture toughness than the PP sized. This was explained by the change of the fibre-related failure mechanism from frequent fibre pull-out to fibre fracture. In addition the matrix affected the fracture toughness of the PA/PP75/25 blend with PA glass-fibre sizing in a positive way, resulting in the highest fracture toughness observed in this study.  相似文献   

15.
测定混凝土应变软化曲线的J积分法   总被引:2,自引:0,他引:2  
本文提供用普通材料试验机对含有不同初始裂缝深度混凝土劈裂试件进行断裂试验的结果。试验得到了稳定的荷载位移全过程曲线。求得了断裂韧度JIC、δC、断裂能GF;并由J积分法推导出了混凝土材料的拉应变软化曲线。  相似文献   

16.
选取三点弯曲试样、采用J积分方法评价了GH690合金从室温到623K的断裂韧性,考察了不同温度下合金的断裂行为。结果表明,GH690合金的断裂韧性随着温度的升高而降低。由于室温层错能较低,合金变形可以通过孪生协调进行,而形变孪晶诱导裂纹扩展转向,延长了裂纹的扩展路径,使合金表现为较高的断裂韧性;随着温度的升高,合金的层错能增加,形变孪晶生成的机率降低,裂纹扩展转向减少,导致合金的断裂韧性随之降低。  相似文献   

17.
Polypropylene/wood flour composites with different fibre content were prepared. The effect of composition and the incorporation of maleinated polypropylene on the materials tensile and fracture and failure behaviour was investigated. Reliable fracture toughness data that will be useful for structural applications were obtained. In unmodified composites an increase in Young´s modulus was found with the addition of wood flour to PP, whereas tensile strength, strain at break and fracture toughness were observed to decrease as fibre content increased. The presence of MAPP was beneficial to tensile strength and ductility and had no significant effect on fracture toughness, as a result of enhanced fibre dispersion within the matrix and improved interfacial adhesion. Although reduced ductility and toughness were observed for the composites respect to the matrix, in the case of modified composites, environmentally friendly stiffer materials were obtained with cost saving without sacrificing strength.  相似文献   

18.
为了拓展聚丙烯材料的应用,在对CaCO3粉体进行表面偶联处理后,混入聚丙烯中,制成聚丙烯/CaCO3复合材料。通过透射电镜、X射线衍射仪、偏光显微镜、电子万能试验机等仪器设备研究了样品的显微组织及其力学性能。结果表明:CaCO3粉体有异相成核剂的作用,使球晶尺寸变小,结晶度有所提高,在聚丙烯基体中产生明显的增强增韧效果。经改性后的聚丙烯/CaCO3复合材料显微组织得到改善,力学性能有所提高。  相似文献   

19.
As a composite material, cortical bone accumulates fatigue microdamage through the repetitive loading of everyday activity (e.g. walking). The accumulation of fatigue microdamage is thought to contribute to the occurrence of fragility fractures in older people. Therefore it is beneficial to understand the relationship between microcrack accumulation and the fracture resistance of cortical bone. Twenty longitudinally orientated compact tension fracture specimens were machined from a single bovine femur, ten specimens were assigned to both the control and fatigue damaged groups. The damaged group underwent a fatigue loading protocol to induce microdamage which was assessed via fluorescent microscopy. Following fatigue loading, non-linear fracture resistance tests were undertaken on both the control and damaged groups using the J-integral method. The interaction of the crack path with the fatigue induced damage and inherent toughening mechanisms were then observed using fluorescent microscopy. The results of this study show that fatigue induced damage reduces the initiation toughness of cortical bone and the growth toughness within the damage zone by three distinct mechanisms of fatigue–fracture interaction. Further analysis of the J-integral fracture resistance showed both the elastic and plastic component were reduced in the damaged group. For the elastic component this was attributed to a decreased number of ligament bridges in the crack wake while for the plastic component this was attributed to the presence of pre-existing fatigue microcracks preventing energy absorption by the formation of new microcracks.  相似文献   

20.
通过30个尺寸为100mm×100mm×515mm的聚丙烯纤维水泥稳定碎石和普通水泥稳定碎石三点弯曲试件断裂试验,探讨了聚丙烯纤维对水泥稳定碎石断裂韧度(KIC)、断裂能(GF)、临界裂缝嘴张开位移(CMODC)、临界裂缝尖端张开位移(CTODC)、极限裂缝嘴张开位移(CMODmax)和极限裂缝尖端张开位移(CTODmax)的影响。试验结果表明:聚丙烯纤维的掺入可增大水泥稳定碎石的断裂韧度、断裂能、临界裂缝嘴张开位移、极限裂缝嘴张开位移、临界裂缝尖端张开位移和极限裂缝尖端张开位移;随着聚丙烯纤维体积掺量的增加,断裂韧度、临界裂缝嘴张开位移和临界裂缝尖端位移的变化无明显规律,但断裂能、极限裂缝嘴张开位移和极限裂缝尖端位移基本上呈线性增加的。  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号