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1.
采用反应烧结方法,利用TiO2,Al和B粉末间的放热反应在较低的温度下制备Al2O3-TiB2复相陶瓷和原位生长Al2O3和TiB2弥散粒子增强Al复合材料Al2O3-TiB2复相陶瓷是密度ρ~0.8的多孔体,由尺寸约10μm的生长单元构成晶粒,在陶瓷中还含有少量的Al3Ti.Al基复合材料中原位形成的Al2O3和TiB2粒子尺寸小于2μm,在基体中呈现均匀分布,没有发现Al3Ti生成.这种原位Al基复合材料具有优于SiCw/Al复合材料的强度.  相似文献   

2.
本文研究了原位生成的TiC/TiB2/MoSi2三相复合材料的一种新的显微结构及其对力学性能的影响,结果表明,当热压金属Ti,B4C和MoSi2的混合粉末时,在MoSi2的基体内生成由TiC和TiB2组成的空心粒子。  相似文献   

3.
TiO2—Al—B系反应烧结制备的复相陶瓷和原位Al基复合材料   总被引:2,自引:0,他引:2  
采用反应烧结方法,利用TiO2,Al和B粉末间的放热反应的较低的温度下制备Al2O3-TiB2复相陶瓷和原位生长Al2O3和TiB2弥散粒子增强Al复合,Al2O3-TiB2复相陶瓷是密度ρ-0.8的多孔体,由尺寸小于2μm,在基体中呈现均匀分布,没有发现Al3Ti生成,这种原位Al基复合材料具有优于SiCw/Al复合材料的强度。  相似文献   

4.
运用XD工艺制备了颗粒增强TiAl基复合材料。增强颗粒均匀分布于TiAl基体中并细化TiAl合金。通过在TiB_2/TiAl、TiC/TiAl复合材料中加入适量的Si,颗粒增强TiAl基复合材料的室温延性得到了改善。  相似文献   

5.
碳化硅材料具有许多优良的性能,采用原位合成碳化硅基复合材料已经成为当前研究的一大热点。本文对近年来采取原位合成TiB2来增强增韧碳化硅基复合材料作了简要综述。  相似文献   

6.
本文研究了原位生成的TiC/TiB2/MoSi2三相复合材料的一种新的显微结构及其对力学性能的影响,结果表明,当热压金属Ti,B4C和MoSi2的混合粉末时,在MoSi2的基体内生成由TiC和TiB2组成的空心粒子.其中的TiC和TiB2粒子均为纳米粒子.具有此新显微结构的复合材料,强度达到480MPa,断裂韧性为5.2MPa·m1/2,较单相MoSi2材料的力学性能有大幅度提高.  相似文献   

7.
颗粒类型对颗粒增强铝基复合材料性能的影响   总被引:1,自引:0,他引:1  
本文对粉末冶金法制备的SiC和TiC颗粒增强铝基复合材料进行了研究。试验表明,在颗粒含量相同、尺寸相当的条件下,TiC增强Al基复合材料的强度和模量均低于SiC增强Al基复合材料,但其屈强比却明显高于SiC增强Al基复合材料。高温长时间等温处理对TiC颗粒增强纯Al复合材料的强度没有明显的影响。  相似文献   

8.
原位反应制备的颗粒增强钛基复合材料中增强颗粒与基体的相容性好,复合材料高温性能稳定,成为制备高性能颗粒增强钛基复合材料的首选途径.目前,粉末冶金法、熔铸法、放热弥散法、燃烧合成法和机械合金化法都已用于原位反应制备颗粒增强钛基复合材料.综述了这些制备方法的原理、特点以及制备出的复合材料的组织和性能,指出了原位反应制备颗粒增强钛基复合材料今后的发展方向.  相似文献   

9.
XD法原位自生ZL201/TiB2P复合材料显微组织及力学性能   总被引:3,自引:0,他引:3  
采用XD工艺在Ti-Al-B体系中原位自生制备了亚微米级TiB2颗粒增强铝基复合材料。并借助TEM,SEM等分析测试手段研究了该材料的显微组织和常温力学性能,结果表明,TiB2颗粒尺寸在0.1 ̄0.4μm,力学性能大幅度提高。  相似文献   

10.
原位合成TiC颗粒增强铁基复合材料的微观结构研究   总被引:15,自引:0,他引:15  
采用不同化学成分基体制备了原位合成TiC颗粒增强铁基复合材料,并以透射电镜为手段对其微观结构进行了分析研究,结果表明,TiC增强相周围基体组织与基体含碳量有关,基体中较高的含碳量有助于抑制Fe2Ti相的形成,在含钼基体中TiC增强相与基体之间存在一富钼的包覆层,进一步改善了基体对碳化钛的润湿性,有利于增强体在基体中的均匀分布。  相似文献   

11.
铸态(TiB+TiC)/Ti复合材料组织和性能的研究   总被引:10,自引:1,他引:9       下载免费PDF全文
利用钛与碳化硼及石墨之间的自蔓燃高温合成反应,经非自耗电弧熔炼工艺制备了TiB晶须和TiC粒子混杂增强的钛基复合材料。借助扫描电镜和透射电镜观察了复合材料的微观结构,结果表明:原位合成增强体均匀地分布在基体合金中,TiB增强体以晶须状生长,而TiC增强体以树枝状、等轴状生长。原位合成增强体与基体合金的界面非常干净,不存在界面反应产物,但TiC粒子周围的基体合金中存在高密度的位错。原位合成增强体的加入提高了复合材料的力学性能,合金化元素铝的加入不仅固溶强化了钛基体合金,同时使增强体长得更为细小,也有利于改善复合材料的性能。  相似文献   

12.
利用钛与碳化硼及石墨之间的自蔓延高温合成反应经普通的熔铸工艺原位合成制备了不同摩尔比值TiB和TiC增强的钛基复合材料。测定了原位合成钛基复合材料的高温力学性能。结果表明:由于增强体的原位合成,复合材料的高温拉伸性能与基体合金比较有了明显的提高。高温拉伸断裂与温度有关,温度较低时,增强体断裂是材料失效的主要原因;而随着温度的提高,增强体与基体合金界面脱粘成为材料失效的主要原因。高温拉伸时裂纹容易在短纤维状增强体TiB的端面处形核与长大从而使增强体与基体合金脱粘导致材料失效,因此加入石墨形成更多的TiC粒子有利于提高复合材料的高温力学性能。  相似文献   

13.
利用激光熔化沉积工艺制备了TiB+TiC增强相体积分数分别为9%、11%、22%及57%的4种(TiB+TiC)/TA15原位钛基复合材料。随增强相含量提高,TiB形态由片层状向棱柱状转化,TiC形态由不规则颗粒状向枝晶状转化,钛基复合材料硬度及弹性模量均显著提高而塑性明显下降。增强相体积分数约为9%的复合材料表现出较好的综合力学性能,增强相体积分数大于11%后复合材料的抗拉强度急剧降低。与激光熔化沉积态TA15钛合金相比,TiB+TiC增强相体积分数约为9%的复合材料抗拉强度(1040 MPa)及屈服强度(935 MPa)均提高约12%。  相似文献   

14.
通过在激光熔覆沉积过程中向熔池内送入一定比例纯Ti粉和B4C颗粒,直接制备出钛基复合材料,分析了所制备材料的微观组织、相组成及性能。结果表明,在激光熔覆沉积过程中,Ti粉和B4C颗粒发生原位反应,生成与基体界面结合良好的TiC和TiB增强相,TiC为短棒状或颗粒状,TiB为短纤维状,复合材料中同时有大量未完全反应的B4C颗粒存在,所制备钛基复合材料的抗拉强度、硬度较激光熔覆沉积的纯钛有较大幅度的提高。  相似文献   

15.
In the present work, (TiBw+ TiCp)/Ti6242 composites were fabricated via common casting and hot-forging technology utilizing the SHS reaction between titanium and B4C. The XRD technique was used to identify the phases of composites. The microstructures were characterized by means of OM and TEM. Results from DSC and analysis of phase diagram determine solidification paths of in situsynthesized Ti6242 composites as following stages: -Ti primary phase, monovariant binary eutectic -Ti + TiB, invariant ternary eutectic -Ti + TiB + TiC and phase transformation from -Ti to -Ti. In situsynthesized reinforcements are distributed uniformly in titanium matrix alloy. Reinforcement TiB grows in whisker shape whereas TiC grows in globular or near-globular shape. TiB whiskers were made to align the hot-forging direction after hot-forging. The interfaces between reinforcements and Ti matrix alloy are very clean. There is no any interfacial reaction. Moreover, the mechanical properties improved with the addition of TiB whiskers and TiC particles although some reduction in ductility was observed. Fractographic analysis indicated that the composites failed in tension due to reinforcements cracking. The improvements in the composite properties were rationalized using simple micromechanics principles. The strengthening mechanisms are attributed to the following factors: undertaking load of TiB whiskers and TiC particles, high-density dislocations and refinement of titanium matrix alloy's grain size.  相似文献   

16.
结合Ti-B-Al体系的热力学及Ti-B相图,提出了可制备薄壁、复杂形状原位自生钛基复合材料构件的SMIF工艺.采用XRD、SEM和TEM等手段研究用该工艺制备的复合材料的相组成和显微组织.结果表明,钛基复合材料中生成了TiB增强相,且在基体中分布均匀,呈短纤维状;并且Al的加入使得TiB相具有较高的长径比,最高可达110.TiB增强相/基体界面清洁、无污染.受熔模精铸陶瓷型壳的激冷作用,钛基复合材料铸锭表层中TiB相垂直于铸锭的表面分布.与基体合金相比较,钛基复合材料的力学性能有了很大程度的提高.  相似文献   

17.
The main purpose of this study is an in-situ synthesis of (TiB+TiC) hybrid titanium matrix composites (TMCs) by vacuum induction melting method and to verify its mechanical properties.The melting route was adopted to synthesize the commercial pure titanium (cp Ti) and granular boron carbide (B-4C).The reinforcements,the fraction of 10 vol.pct,were formed by adding 1.88 wt pct B-4C to cp Ti.After in-situ synthesis of TMCs,electron probe micro-analysis elemental mapping was carried out to confirm the distribution and shape of reinforcements.The cone-on-disk type sliding wear test was also done for the identification of TMCs.It is concluded that (TiB+TiC) hybrid TMCs can be in-situ synthesized and has better wear properties than H13.  相似文献   

18.
The initial oxidation behavior of titanium matrix composites (TMCs) was studied in a temperature range 550 to 650C in a flow of purified oxygen at atmospheric pressure using thermogravimetry. The oxidation kinetics very initially follows approximately a linear rate law and then a parabolic rate law. The oxidation rate decreases gradually as the oxidation proceeds. The initial in situ oxidation was investigated by high-temperature optical microscopy in air. The oxide layer was examined by X-ray diffraction and scanning electron microscopy combined with an energy dispersive X-ray spectroscopy unit. It was found that the reaction products are predominantly rutile. The reinforcements of TiB and TiC can result in a decrease in the overall oxidation rate at 550, 600, and 650C. This is attributed to the interface cohesion and the clean interfacial microstructure between reinforcements and the titanium matrix alloy, which is strong enough such that the reinforcements can act as barriers to solid-state diffusion.  相似文献   

19.
《Composites Part B》2013,44(8):3334-3337
Ti–5Al–5Mo–5V–1Fe–1Cr Ti alloy and Ti–5Al–5Mo–5V–1Fe–1Cr Ti matrix composites containing different weight fractions of trace TiB and TiC are fabricated via in situ synthesis method. The as-cast ingots are subjected to thermo-mechanical processing and heat treatment. The Widmannstatten structure is obtained after the heat treatment. The microstructure length scales of the materials are identified. The identification indicates that 0.4 wt.% TiB and 0.1 wt.% TiC can reduce the average size of the β grains by more than 50%. Whereas the extent of the microstructure refinement gradually decreases while increasing the weight fraction of the trace reinforcements. The influences of weight fraction and morphology of the trace TiB and TiC on microstructure refinement are researched in this work. Moreover, the tensile properties of the heat-treated materials are examined. It is revealed that Hall–Petch mechanism plays an identically important role in improving the mechanical properties of the composites comparing with the load bearing and dispersion strengthening of the trace reinforcements.  相似文献   

20.
Ti–5Al–5Mo–5V–1Fe–1Cr Ti alloy and Ti–5Al–5Mo–5V–1Fe–1Cr Ti matrix composites containing different weight fractions of trace TiB and TiC are fabricated via in situ synthesis method. The as-cast ingots are subjected to thermo-mechanical processing and heat treatment. The Widmannstatten structure is obtained after the heat treatment. The microstructure length scales of the materials are identified. The identification indicates that 0.4 wt.% TiB and 0.1 wt.% TiC can reduce the average size of the β grains by more than 50%. Whereas the extent of the microstructure refinement gradually decreases while increasing the weight fraction of the trace reinforcements. The influences of weight fraction and morphology of the trace TiB and TiC on microstructure refinement are researched in this work. Moreover, the tensile properties of the heat-treated materials are examined. It is revealed that Hall–Petch mechanism plays an identically important role in improving the mechanical properties of the composites comparing with the load bearing and dispersion strengthening of the trace reinforcements.  相似文献   

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