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1.
Microbiologically influenced corrosion (MIC) is a big threat to the strength and safety of many metallic materials used in different environments throughout the world. The metabolites and bioactivity of the microorganisms cause severe deterioration on the metals. In this study, MIC of pure titanium (Ti) was studied in the presence of a highly corrosive aerobic marine bacterium Pseudomonas aeruginosa. The results obtained from electrochemical test showed that Ti was corrosion resistant in the abiotic culture medium after 14 d, while the increased corrosion current density (icorr) obtained from polarization curves and the decreased charge transfer resistance (Rct) from electrochemical impedance spectroscopy (EIS) indicated the accelerated corrosion of Ti caused by P. aeruginosa biofilm. For further confirmation of the above results, the surface of Ti was investigated using scanning electron microscopy (SEM), confocal laser scanning microscopy (CLSM) and X-ray photoelectron spectroscopy (XPS). According to the XPS results, TiO2 was formed in both abiotic and biotic conditions, while unstable oxide Ti2O3 was detected in the presence of P. aeruginosa, leading to the defects in the passive film and localized corrosion. Pitting corrosion was investigated with the help of CLSM, and the largest pit depth found on Ti surface immersed in P. aeruginosa was 1.2 μm. Ti was not immune to MIC caused by P. aeruginosa.  相似文献   

2.
The microbially influenced corrosion of stainless steel (SS) by marine bacterium Vibrio natriegens (V. natriegens) was investigated using surface analysis (atomic force microscopy (AFM), scanning electron microscopy (SEM), and energy dispersive X-ray analysis (EDXA)) and electrochemical techniques (the open circuit potential, electrochemical impedance spectroscopy (EIS), and potentiodynamic polarization curves ). AFM images corroborated the results from the EIS models which show biofilm attachment and subsequent detachment over time. The SEM images revealed the occurrence of micro-pitting corrosion underneath the biofilms on the metal surface after the biofilm removal. The presence of carbon, oxygen, phosphor and sulfur obtained from EDXA proved the formation of biofilm. The electrochemical results showed that the corrosion of SS was accelerated in the presence of V. natriegens based on the decrease in the resistance of the charge transfer resistance (Rct) obtained from EIS and the increase in corrosion current densities obtained from potentiodynamic polarization curves.  相似文献   

3.
Electrochemical techniques (electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization curves) and surface analysis (scanning electron microscopy (SEM)) were carried out to determine the possible mechanism of the microbially influenced corrosion of 303 stainless steel (303 SS) by marine bacterium Vibrio natriegens (V. natriegens). In order to clarify the mechanism, 303 SS coupons were immersed in four different mediums. EIS results were interpreted with different equivalent circuits to model the physicoelectric characteristics of the electrode/biofilm/solution interface. The results showed that N2-fixation actually promoted the corrosion of 303 SS; however, the influence of the produced NH3 was negligible. It can be speculated that the electron transfer and/or the nitrogenase catalyzing the process may influence the corrosion.  相似文献   

4.
Electrochemical corrosion behaviours of the untreated and the carburized of Ti-46.5Al (mol %) alloy were investigated. X-ray diffractometry (XRD) and scanning electron microscopy (SEM) were applied to characterize the carburized layer. Potentiodynamic polarization curve, electrochemical impedance spectroscopy (EIS) and SEM morphology of the corroded surface were used to evaluate corrosion resistance of both carburized and untreated TiAl alloy in 1 mol/L HCl. The outer layer of the carburized TiAl alloy is a continuous Ti2AlC scale. Polarization curve and electrochemical impedance spectroscopy (EIS) of the carburized TiAl alloy present a nobler corrosion potential, a more positive pitting potential and a higher polarization resistance, respectively, compared with the untreated sample. After anodic corrosion or immersion corrosion, a deposited layer can be observed on the surface of the carburized titanium aluminide alloy. By contrast, pitting and crevasse corrosion occur on the surface of the untreated TiAl alloy after anodic corrosion and some corrosion products and slight corrosion appear on the surface of the untreated TiAl alloy after immersion corrosion.  相似文献   

5.
Hydroxyapatite (HA) coating with nanoparticles like nanorice is fabricated on chemically pretreated titanium (Ti) surface, through an electrochemical deposition approach, for biomaterial applications. The Ti surface was chemically patterned with anatase TiO2 nanofibers. These nanofibers were prepared by in situ oxidation of Ti foils in a concentrated solution of H2O2 and NaOH, followed by proton exchange and calcinations. Afterward, TiO2 nanofibers on Ti substrate were coated with HA nanoparticles like nanorice. The obtained samples were annealed at high temperature to produce inter diffusion between TiO2 and HA layers. The resultant layers were characterized by Scanning Electron Microscopy (SEM), Transmission Electron Microscopy (TEM), X-ray Photoelectron Spectroscopy (XPS), X-ray Diffraction (XRD), Infrared Spectroscopy (FTIR), corrosion tests in SBF solution, and Electron Probe Micro Analysis (EPMA). It was found that only Ti from the titanium substrate diffuses into the HA coating and a good corrosion resistance in simulated body fluid was obtained.  相似文献   

6.
The electrochemical behaviour of two commercial titanium alloys Ti-6Al-4 V (ASTM F136) and Ti-13Nb-13Zr (ASTM F1713) was investigated in Ringer physiological solution at two pH values (5.5 and 7.0). The corrosion properties were examined by using electrochemical techniques: Potentiodynamic anodic polarization, cyclic polarization and electrochemical impedance spectroscopy (EIS). The electrochemical corrosion properties of both alloys at different conditions were measured in terms of corrosion potential (E corr), corrosion current density (i corr) and passivation current density (i pass). Equivalent electrical circuits were used to modulate EIS data, in order to characterize alloys surface and better understanding the pH effect on the interface alloy/solution.  相似文献   

7.
In this paper, corrosion resistance of the Mg–4.0Zn–0.2Ca alloy was modified by micro-arc oxidation (MAO) process. The microstructure and phase constituents of MAO layer were characterized by SEM, XRD and X-ray photoelectron spectroscopy (XPS). The corrosion resistance of MAO treated Mg–4.0Zn–0.2Ca alloy in the simulated body fluid were characterized by potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) techniques. The microstructure results indicated that a kind of ceramic film was composed by MgO and MgF2 was formed on the surface of Mg–4.0Zn–0.2Ca alloy after MAO treatment. The electrochemical test reveals that the corrosion resistance of MAO treated samples increase 1 order of magnitude. The mechanical intensity test showed that the MAO treated samples has suitable mechanical properties.  相似文献   

8.
A pre-treatment system consisting of a nanostructured titania interlayer loaded with an inhibitor and a hybrid silicate film deposited on the TiO2 layer is shown to provide protection against active corrosion of mild steel. A nanostructured TiO2 interlayer was prepared on the mild steel surface via controllable hydrolysis of titanium alkoxide. To further improve this pre-treatment, the hybrid silicate film was synthesized from tetraethylorthosilicate and 3-glycidoxypropyltrimethoxysilane precursors. The morphology and structure of the titania interlayer and hybrid silicate film were characterized with atomic force microscopy, scanning electron microscopy and energy dispersive X-ray spectroscopy techniques. The corrosion performance of the coatings was examined using electrochemical techniques, including potentiodynamic scanning and electrochemical impedance spectroscopy. The TiO2 nanostructure calcinated/inhibitor/hybrid silicate system shows enhanced corrosion performance, as confirmed by impedance and polarization measurements.  相似文献   

9.
Corrosion inhibition effect of rhodanine-N-acetic acid (R-NA) on mild steel (MS) corrosion in 0.1 M HCl solution was investigated. For this purpose, potentiodynamic polarization, electrochemical impedance spectroscopy (EIS), linear polarization resistance (LPR) as well as hydrogen gas evolution (VH2t) and the change of open circuit potential as a function of immersion time (Eocp − t) were used. The MS surfaces exposed to 0.1 M HCl solution in the absence and presence of inhibitor were examined by scanning electron microscopy (SEM). The thermodynamic parameters of adsorption were calculated and discussed. In order to gain more information about the adsorption mechanism, the EIS technique was used to evaluate the potential of zero charge (PZC) and a mechanism of adsorption process was proposed. It was found that, R-NA is a good corrosion inhibitor for the MS corrosion in 0.1 M HCl solution. The inhibition efficiency increased with increasing inhibitor concentration and reached 98% at 1.0 × 10−2 M R-NA. The high inhibition efficiency was related to adsorption of R-NA on steel surface. Surface SEM images showed a good surface coverage of inhibitor on the metal surface.  相似文献   

10.
Microbiologically influenced corrosion (MIC) by microbes capable of iron reduction (iron reducing bacteria (IRB)) on API 5L ×52 carbon steel coupons was investigated. A wild type of IRB was isolated and cultivated from a water sample collected from a sour oil well located in Louisiana, USA. 16S rRNA gene sequence analysis indicated that the mixed bacterial consortium contained two phylotypes close to members of the Proteobacteria (Shewanella oneidensis sp.) and Firmicutes (Brevibacillus sp.). The corrosion behavior of carbon steel coupons exposed to different media, with and without these microbes, was characterized by open circuit potential (OCP), electrochemical impedance spectroscopy (EIS) and polarization resistance (Rp), and a corrosion mechanism has been proposed. The biofilm and pit morphology that developed with time were characterized using field emission scanning electron microscopy (FESEM). Interestingly, surface morphology and electrochemical evaluations confirmed that IRB metabolic activities and resulting biofilms inhibit the corrosion process. The maximum corrosion rate in the biotic system was 4 mpy, while it was 20 mpy in the abiotic solution. Minor isolated pits were revealed in the biotic system, whereas extensive general pitting was found in the abiotic system. Elemental analysis and corrosion product structures were characterized by energy-dispersive X-ray spectroscopy (EDS) and X-ray diffraction (XRD). XRD confirmed the formation of a significant amount of iron oxide compounds that include iron, Hematite (Fe2O3), Magnetite (Fe3O4) and iron (II) hydroxide Fe(OH)2 on the steel surface exposed to a biotic system.  相似文献   

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