共查询到18条相似文献,搜索用时 875 毫秒
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超高分子量聚乙烯纤维与环氧树脂的粘接性能很差,给高性能轻型复合材料的研制带来困难。本文采用低温等离子体对纤维表面进行处理。结果表明,处理后的纤维表面能提高,使环氧树脂能良好地浸润纤维,纤维与环氧树脂间粘接强度可提高5-8倍。粘接性能改善的原因是:由表面引入的多种含氧基团所形成的化学键力,由表面刻蚀坑产生的机械嵌合力。 相似文献
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本文采用低温等离子体对超高分子量聚乙烯纤维进行表面处理,以改善其与环氧树脂的粘接性能,为进一步研制高性能轻型复合材料提供科学依据。实验结果表明处理后的纤维表面能大大提高,使环氧树脂能良好地浸润纤维;纤维与环氧树脂间粘接强度可提高近5—10倍。本文进一步分析了粘接性能改善的原因,并对粘接强度做出贡献的各种作用进行了综合的定量分析。 相似文献
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为提高芳纶纤维与复合材料基体间的界面强度,首先,使用LiCl乙醇溶液处理芳纶纤维一定时间;然后,对LiCl处理芳纶纤维表面的化学组成、微观形貌、单丝拉伸强度及芳纶纤维/环氧树脂复合材料的界面性能等进行了测试分析。结果表明:使用LiCl乙醇溶液处理芳纶纤维后,芳纶纤维表面的含氮官能团含量增加;处理后,芳纶纤维表面有刻蚀出的沟槽,表面粗糙度增大,进而改善了芳纶纤维与环氧树脂基体的界面粘接性能,使芳纶纤维/环氧树脂复合材料的层间剪切强度由处理前的21.75 MPa提升到37.98 MPa;最佳处理时间为3~4h,而处理时间过长会导致芳纶纤维的单丝拉伸强度及复合材料的层间剪切强度下降。所得结论证实使用LiCl处理芳纶纤维是一种有效的表面改性方法。 相似文献
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采取不同浓度的磷酸水溶液对芳纶纤维进行表面处理, 并对不同处理条件下芳纶纤维的单丝强度、表面性质及其环氧树脂复合材料的界面性能进行了分析和测试。结果表明: 20 wt %磷酸溶液处理的芳纶纤维, 纤维表面含氧官能团含量最高; 继续提高磷酸溶液的浓度, 含氧官能团含量下降, 纤维表面趋于平整, 单丝强度上升。用20 wt %磷酸溶液处理芳纶纤维, 纤维/ 环氧树脂基复合材料的层间剪切强度达到62 MPa , 界面剪切强度提高18 % , 是一种简单有效的表面处理方法。纤维表面粗糙度和纤维表面含氧官能团的数量是影响芳纶纤维/ 环氧树脂复合材料界面结合性能的关键因素。 相似文献
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针对芳纶纤维与树脂基体界面性能差及纤维原纤化的问题,采用超临界二氧化碳分散环氧树脂对芳纶纤维进行表面改性,研究超临界二氧化碳处理对芳纶纤维结构及性能的影响。结果表明超临界二氧化碳改性处理能够提高环氧树脂对芳纶纤维的浸润效果,利用超临界二氧化碳分散环氧树脂对芳纶纤维进行处理,可以在一定程度上提高芳纶纤维的性能并改善芳纶增强树脂基复合材料的界面性能。超临界二氧化碳处理能够提高芳纶纤维表面粗糙度及比表面积,且芳纶纤维性能不受影响。 相似文献
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PBO作为增强纤维存在与环氧树脂基体界面粘结性能差的问题.通过在聚合过程中添加少量5-磺酸钠-间苯二甲酸部分替代对苯二甲酸与4,6-二氨基间苯二酚盐酸盐进行共聚,合成了大分子链上含有离子基团的SPBO共聚物,并制得SPBO初生纤维.通过接触角测试和XPS研究了纤维的表面性能,通过微脱粘实验和SEM评价了纤维与环氧树脂基体的界面粘结性能.结果表明: 与PBO纤维相比,SPBO纤维表面浸润性能提高,表面含氮、氧量均增加,与环氧树脂的界面剪切强度从8.2MPa提高到10.1Mpa,提高了23%. 相似文献
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离子基团对PBO 纤维的表面性能及其界面粘结性能的影响 总被引:4,自引:3,他引:4
PBO作为增强纤维存在与环氧树脂基体界面粘结性能差的问题。通过在聚合过程中添加少量5-磺酸钠-间苯二甲酸部分替代对苯二甲酸与4,6-二氨基间苯二酚盐酸盐进行共聚,合成了大分子链上含有离子基团的SPBO共聚物,并制得SPBO初生纤维。通过接触角测试和XPS研究了纤维的表面性能,通过微脱粘实验和SEM评价了纤维与环氧树脂基体的界面粘结性能。结果表明:与PBO纤维相比,SPBO纤维表面浸润性能提高,表面含氮、氧量均增加,与环氧树脂的界面剪切强度从8.2MPa提高到10.1MPa,提高了23%。 相似文献
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The poor adhesion of ultra-high-molecular-weight polyethylene (UHMW-PE) fibres to epoxy resin (due to characteristics of their surface structure) makes it difficult to develop light composite materials with good mechanical properties. In our experiments a low-temperature plasma was applied to treat the surfaces of the fibres. The results showed that the surface energy of the treated fibres was increased greatly so that the fibres could be wetted very well by resin, which was an essential prerequisite in improving the adhesion of the fibre/epoxy resin systems; and the results also showed that the pull-out adhesion strength of the treated fibres to resin was increased significantly by about 10 times. This paper discusses the mechanism of the improvement of the adhesion. Two reasons for improvement are that: varieties of polaroxygen-containing groups are produced in the non-polar surface layer, forming chemical bonds; and plasma-etched pits spread all over the surface of the fibres into which the resin penetrates to form a mechanical interlock between fibre and resin. A synthetic analysis and discussion of these two factors and of non-polar interactions influencing the adhesion is given, and a preliminary relationship between them is presented. 相似文献
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A series of mechanical tests have been performed on composites consisting of high-strength carbon fibres in an amine-cured epoxy resin. A comparison has been made between composites containing untreated, commercially treated (electrochemically), and plasma treated fibres. While both treatments improve interfacial adhesion, the manner in which the composite fails is totally different. In composites that contain electrochemically treated fibres failure is, in most cases, matrix dominated, whereas interfacial failure always occurs in samples made from plasma-treated fibres. This behaviour can be explained in terms of the nature of the fibre surface after each type of treatment. 相似文献
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《Materials Science & Technology》2013,29(10):814-826
AbstractA detailed examination has been undertaken of the influence of surface treatment on the adhesion of polyethylene fibres to epoxy resin. The pull-out adhesion has been determined for untreated, chromic acid treated, and plasma etched monofilaments with different draw ratios and thermal annealing treatments. In a few cases, additional chemical treatments were applied to plasma treated fibres before the pull-out test. The polyethylene surface energy also has been determined by measurement of contact angle. The results, taken together, suggest that the adhesion depends on three factors: (i) the wettability (or physicochemical interactions), which is affected by the extent and nature of the surface treatment as well as the fibre draw ratio; (ii) the surface roughness, after plasma etching only, where a honeycomb structure of pits permits mechanical keying between the fibre and the resin (this structure has been examined by scanning electron microscopy); and (iii) the number of chemical bonds per unit area between the fibre and the resin. It is concluded that these three factors can be regarded as additive and that optimum results are obtained when their respective pull-out strengths reach their maximum values, ~2, ~3, and ~1·7 MN m?2.MST/640 相似文献
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为改善芳纶纤维增强树脂基复合材料中界面粘结强度,本研究用Mctowo.Takayanagi——化学处理法,对芳纶1414纤维进行表面处理.并依据红外光谱分析(IR),元素分析(E.A.),XPS能谱分析等近似估价芳纶1414纤维表面导入约88mol%接技率的E-51环氧化合物.用单纤维拉拔实验法直接测定芳纶1414纤维/环氧树脂基体体系的界面剪切强度.实验结果表明,芳纶1414纤维经表面环氧接技化处理后,可较明显地提高界面剪切强度而对纤维拉伸强度的降低较小.树脂基体性能对界面剪切强度的影响较显著.通过电子显微镜(SEM)观察被拔出纤维及树脂孔穴的破坏形貌,解析界面破坏机理. 相似文献
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通过橡胶分子链在玻璃纤维表面的接枝,在玻璃纤维毡增强聚丙烯复合体系中引入了界面柔性层,研究了柔性层的种类及厚度对复合体系界面结合及力学性能的影响,结果表明,采用容易与玻璃纤维表面形成化学键等牢固结合与基体树脂有一定相容性的橡胶分子链作为界面柔性层,可以获得高强度,高抗冲的玻璃纤维毡增强聚丙烯复合材料,柔性层的厚度对复合体系的力学性能有很大的影响,超过一定的厚度后,随着柔性层的增厚,玻璃纤维增强聚丙烯复合材料的力学性能呈下降的趋势。 相似文献
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The ultra high modulus polyethylene (UHMPE) fiber was treated with argon plasma in order to improve the interfacial adhesion of UHMPE fiber/vinylester composites. Argon plasma treatment of the UHMPE fiber introduces micro-pittings and roughness onto the UHMPE fiber surface. These micro-pittings and surface roughness increase the interfacial adhesion of the UHMPE fiber/vinylester composites through the mechanical interlocking between the UHMPE fiber and vinylester resin. Argon plasma treatment also changes the UHMPE fiber surface into chemically more inert state in comparison with the control UHMPE fiber surface. These chemical changes decrease the efficiency of the mechanical interlocking as the inert surface makes the wetting of the UHMPE fiber by the vinylester resin difficult. In this study, the mechanical interlocking through the micro-pittings is known to play a key role in improving the interfacial adhesion of UHMPE fiber/vinylester composites by the argon plasma treatment. However, the complete wetting of the UHMPE fiber by the vinylester resin is known to be an important requirement for the effective mechanical interlocking between the UHMPE fiber and vinylester resin. 相似文献