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1.
用标准单辊甩带技术在大气环境下制备Fe73.5Si13.5-x Gex B9Cu1Nb3(x=3,6)非晶条带,分别在470℃、510℃、550℃和590℃对非晶条带进行真空等温退火1 h后,在非晶基体中形成了纳米晶相。用X射线衍射(XRD),透射电镜(TEM)和差示扫描量热法(DSC)测量研究了快淬态和热处理后样品的结构和结晶动力学。基于差热分析的数据,使用Kissinger,Ozawa和AugisBennett模型计算了非晶条带的结晶激活能,利用Johnson-Mehl-Avrami(JMA)方程计算了非晶条带初始结晶的局域Avrami因子n。局域Avrami因子n随晶化体积分数α的显著变化说明,非晶条带非等温初始结晶的机理在不同的晶化阶段是不同的。晶化初期的机理是扩散控制的三维形核和晶粒生长的整体晶化,形核速率逐渐减小;晶化中后期为一维形核和生长的表面晶化过程,形核速率近似为零。基于XRD和TEM测量结果,分别在510℃、550℃和590℃真空等温退火1 h后,在Fe73.5Si13.5-x Gex B9Cu1Nb3(x=3,6)非晶条带中析出的α-Fe(Si,Ge)相的平均晶粒尺寸D小于15 nm。  相似文献   

2.
利用标准的单辊甩带技术在大气环境下制备了Fe73.5Si13.5B9Cu1Nb3-xVx(x=1,2)非晶条带。利用非等温DSC测量研究了非晶条带的初始结晶动力学行为。采用Kissinger方法计算了非晶条带的初始结晶激活能,其数值分别是302kJ/mol(x=1)和364kJ/mol(x=2)。Avrami因子n的计算结果分别为2.35(x=1)和1.61(x=2),Avrami因子的计算结果表明,非晶条带非等温初始结晶的机理为扩散控制的低维生长,且其形核率不断降低。在793、823和853K下分别对非晶条带进行真空等温退火1h,从而在非晶基体中形成纳米晶相。XRD分析结果表明,823和853K下真空等温退火1h后,x=1和2非晶条带中析出的α-Fe(Si)相的平均晶粒尺寸分别为12.8、14.0、13.3和14.2nm。  相似文献   

3.
研究了460~640℃等温退火后纳米晶(FexCo1-x)73.5Cu1Nb3Si13.5B9(x=0.5,1)合金的初始磁导率麒随温度变化。与双相纳米晶Fe73.5Nb3Si13.5B9合金相比,(Fe0.5Co0.5)73.5Cu1Nb3Si13.5B9合金室温下的磁导率降低,但晶化相和非晶相居里温度明显升高,并显著提高了合金在高温下的软磁性能。初步探讨了改善纳米晶合金高温磁性的机理。  相似文献   

4.
研究了(Fe50Co50)73.5Cu1Nb3Si13.5B9合金晶化过程中的微观结构及形成纳米晶后的合金软磁性能,发现在FINEMET合金基础上,用Co置换1/2含量Fe形成的(Fe50Co50)73.5Cu1Nb3Si13.5B9非晶合金具有相对较高居里温度Tc≈450℃,460℃退火处理后(Fe50Co50)73.5Cu1Nb3Si13.5B9合金形成均匀纳米晶组织,晶粒度约为20nm.  相似文献   

5.
研究了460~580℃等温退火(30min)后纳米晶(Fe0.5 Co0.5)73.5 Cu1Mo3Si13.5B9合金高温软磁性能.结果表明,在Fe73.5Cu1Mo3Si13.5B9纳米晶合金中用Co取代部分Fe仍可形成双相纳米晶结构,并且可显著提高合金的高温特性.与Fe73.5Cu1Mo3Si13.5B9纳米晶软磁合金相比,其室温μi略有下降,但表征高温磁稳定性的居里温度明显提高,同时磁导率在高温下衰减变缓,从而拓宽了纳米晶软磁材料的高温使用范围.文中初步探讨了用Co取代部分Fe后使高温特性得到改善的机理.  相似文献   

6.
研究了Fe71.5Cu1Nb3Si13.5B9V2非晶带材经不同退火工艺处理后的压磁特性,并对不同成分带材的压磁特性进行了对比分析。研究表明,在测试频率f=1 kHz、压应力σ≤0.2 MPa条件下,Fe71.5Cu1Nb3Si13.5B9V2非晶带材闭合回路的电感值随压应力的增大而增大,带材具有良好的压磁稳定性,当退火温度为550℃时,带材的压磁特性稳定性最好,电感值与加载时间、SI(%)与压应力均具有良好的线性关系;热处理工艺对Fe71.5Cu1Nb3Si13.5B9V2带材的压磁性能具有显著影响,退火工艺为300℃×30 min时SI(%)达到最大值0.183;带材的压磁效应与其成分有关,相同测试条件下,Fe73.5Cu1Nb3Si13.5B9带材具有最大的压磁效应,Fe78Si9B13带材次之,Fe71.5Cu1Nb3Si13.5B9V2带材压磁效应最小。  相似文献   

7.
张湘义  张雄关等 《功能材料》1995,26(2):161-163,167
用XRD测定了退火Fe73.5Cu1M3Si13.5B9(M=Nb,Mo)合金中晶化相--α-Fe(Si)和非晶相的结构,讨论了添加元素M=Nb,Mo对Fe73.5Cu1m3Si13.5B9合金起始磁导率影响的原因,结果表明,添加Nb的Fe73.5Cu1Nb3Si13.5B9合金其α-Fe(Si)的尺寸小,Si含量高,且非晶相的铁磁性强,从而获得了较高的起始磁导率。  相似文献   

8.
主要研究掺杂了不同含量稀土La后的铁基非晶带材Fe73.5Cu1Nb3Si13.5B9非晶带材组织结构与软磁性能.结果表明,随着稀土La掺杂含量的增加,Fe73.5Cu1Nb3Si13.5B9非晶带材的Fe-Si相的析出温度下降,而Fe-B相的析出温度则升高,一方面,非晶的热稳定性下降,另一方面,有利于控制Fe73.5...  相似文献   

9.
杜康  朱正吼  周佳  付远  乔宝英 《功能材料》2013,(17):2468-2472
通过对Fe基非晶合金带材连续施加压力,测试其附近闭合回路电感变化,研究了Fe基非晶合金带材的电感式压磁效应。结果表明,通过测试Fe基非晶合金带材附近闭合回路电感变化可用来测试和表征Fe基非晶合金带材的压磁性能;在f=1kHz时,Fe基非晶合金带材压磁性能稳定性好,随着压力的增大带材压磁性能升高,在同一压力情况下,Fe73.5Cu1Nb3Si13.5B9带材压磁性能优于Fe78Si9B13带材;在f=100kHz时,Fe73.5Cu1Nb3Si13.5B9带材压磁性能稳定性优于Fe78Si9B13带材,并且Fe73.5Cu1Nb3-Si13.5B9带材在f=1kHz、压应力为0.69MPa时具有最佳的压磁性能;在压应力<0.1MPa条件下,随着压应力增大,线圈电感值Ls有一个剧增的上升趋势,铁基非晶带材压磁性能对微小应力更加敏感。  相似文献   

10.
热处理对FeCuNbSiB/丁基橡胶复合材料电磁屏蔽性能的影响   总被引:1,自引:0,他引:1  
研究了热处理工艺对Fe73.5Cu1Nb3Si13.5B9非晶粉体/丁基橡胶复合材料电磁屏蔽性能的影响。结果表明,Fe73.5Cu1Nb3Si13.5B9粉体在非晶态时经过350℃×1h的退火处理后,其复合材料的屏蔽性能达到最佳。粉体经550℃×2h晶化处理后,屏蔽性能得到进一步改善,在1000~6000MHz频段内,其|SE|值比经350℃×1h退火处理后的高出2~3dB;复合材料的后续热处理对屏蔽性能影响较大,特别是粉体处于非晶态时,后续热处理对屏蔽性能改善的幅度最大,当f1000MHz时,与未后续热处理的材料相比,经过180℃×6h后续热处理试样的|SE|上升3dB以上。  相似文献   

11.
In this paper, we present a new method for inserting several triangulated surfaces into an existing tetrahedral mesh generated by the meccano method. The result is a conformal mesh where each inserted surface is approximated by a set of faces of the final tetrahedral mesh. First, the tetrahedral mesh is refined around the inserted surfaces to capture their geometric features. Second, each immersed surface is approximated by a set of faces from the tetrahedral mesh. Third, following a novel approach, the nodes of the approximated surfaces are mapped to the corresponding immersed surface. Fourth, we untangle and smooth the mesh by optimizing a regularized shape distortion measure for tetrahedral elements in which we move all the nodes of the mesh, restricting the movement of the edge and surface nodes along the corresponding entity they belong to. The refining process allows approximating the immersed surface for any initial meccano tetrahedral mesh. Moreover, the proposed projection method avoids computational expensive geometric projections. Finally, the applied simultaneous untangling and smoothing process delivers a high‐quality mesh and ensures that the immersed surfaces are interpolated. Several examples are presented to assess the properties of the proposed method.  相似文献   

12.
13.
A flow calorimeter for enthalpy increment measurements on condensed gases is presented. A better knowledge of the properties of the liquefied natural gas is needed, and therefore a liquid loop has been designed for our flow calorimeter. The fluid loop in the calorimeter is designed in order to avoid the two-phase region, since two phases would give compositional disturbances in the measurements. The avoidance of the two-phase region is made possible by increasing the pressure of the test fluid after the measurement section, then heating the fluid at super-critical pressure past the critical point. Finally, the fluid is throttled to the low-pressure gas state at the inlet condition of the compressor that circulates the fluid. To perform the pressure increase, a new cryogenic pump has been designed. To evaluate the new equipment, measurements were taken on liquid ethane over the temperature range 146–256 K at pressure between 0.9 and 5.1 MPa.  相似文献   

14.
A four-ball tester was used to evaluate the anti-wear performance of three kinds of organomolybdemun compounds in the engine oils, i. e., molybdenum dialkyldithiophosphate (MoDDP), molybdenum dialkyldithiocarbamate ( MoDTC), and sulphur and phosphorus freeorganomolybdeum (Molybdate). The results indicate that a low concentration of MoDDP doesn' t improve the anti-wear properties of the commercial engine oils, but a high concentration of MoDDP can obviously improve the anti-wear properties and the load-carrying capacity of the engine oils. MoDTC doesn' t improve the antiwear properties of the engine oils, but worsens the anti-wear properties of the oils. Signifi can timprove ment of frictional and wear characteristics is obtained with Molybdate added in the commercial engine oils and the formulated oils.  相似文献   

15.
Standards are the basis for production enterprises to organize production, ex-factory inspection, trade (delivery) and technical exchanges, product certification, quality arbitration and supervision.……  相似文献   

16.
On November 30, 2007, the China Association for Standardization (CAS) held a press conference at Beijing Diaoyutai State Guest House. Leaders from the China Household Electric Appliance Research Institute, the China Household Electric Appliance Association, and the China Consumers' Association attended and made speeches.……  相似文献   

17.
In the present study a high‐boron high speed steel (HSS) roll material was designed. Many expensive alloy elements have been substituted by cheap boron alloy, and high‐boron high speed steel roll has been manufactured by centrifugal casting method. The microstructures, mechanical properties and wear resistance of centrifugal casting high‐boron high speed steel roll have been investigated by optical microscopy (OM), scanning electron microscopy (SEM), and X‐ray diffraction (XRD) analysis, hardness test, impact test and wear test. The results indicated that the solidification microstructures of high‐boron high speed steel roll consisted of M2(B,C), (W,Mo)2(B,C), M3(B,C), M23(B,C)6 type borocarbides and martensite, a small amount of retained austenite. Borocarbides were continuously distributed over the grain boundary. After quenching from 1050 °C, local broken network appeared in partial borocarbides, and fine secondary borocarbide precipitated from the matrix. After tempering from 525 °C, the amount of precipitated borocarbide increased significantly. After heat treatment, the hardness of high‐boron high speed steel roll excelled 60 HRC, and its impact toughness excelled 8.0 J/cm2. The single groove steel rolling amount of high‐boron high speed steel rolls increases by 500% than that of bainite cast iron roll, when the rolls are used in K1 mill housing of bar mill.  相似文献   

18.
We associate a variety of innovations with the term "Industry 4.0". The pioneer of many 4.0 modifications forms the basisfor the trend towards the integrated di...  相似文献   

19.
The definition of the thixotropy is a decrease in viscosity with time in shear and a subsequent recovery of viscosity after the shear deformation is removed.We ...  相似文献   

20.
Several researches have been reported about the characteristic of β-Ga2O3 nanowires which was synthesized on nickel oxide particle. But indeed, recent researches about synthesis of β-Ga2O3 nanowires on oxide-assisted transition metal are limited to nickel or cobalt oxide catalyst. In this work, Gallium oxide (β-Ga2O3 ) nanowires were synthesized by a simple thermal evaporation method from gallium powder in the range of 700 - 1000℃ using the iron, nickel, copper, cobalt and zinc oxide as a catalyst, respectively. The β-Ga2O3 nanowires with single crystalline without defects were successfully synthesized at the reaction temperature of 850, 900 and 950℃ in all the catalysts. But optimum experimental condition in synthesis of nanowires varied with the kind of catalyst. As increasing synthesis temperature,the morphology of gallium oxide nanowires changed from nanowires to nanorods, and its diameter increased. From these results, we could be proposed that the growth mechanism of β-Ga2O3 nanowires was changed with synthesis temperature of nanowires. Microstructure and morphology of Synthesized nanowire was characterized by HR-TEM, FE-SEM, EDX and XRD.  相似文献   

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