磁流变弹性体剪切式动态力学性能测试

磁流变弹性体（MRE）是磁流变材料中新的一员,研究磁流变弹性体材料,其动态力学性能的探究是研究的重要组成部分,建立一套磁流变弹性体动态力学性能测试系统是需亟待解决的问题。设计了一种磁流变弹性体剪切式动态力学性能测试装置,由电磁振动台提供稳定的正弦激励,通过可调间距的钕铁硼永磁体产生可变的磁场,利用安装在测试系统中的力与加速度传感器,获取磁流变弹性体在往复剪切运动中的剪切力与加速度信号,其中加速度信号经两次数值积分获得位移数据,通过力与位移数据建立磁流变弹性体在动态剪切模式下的应力-应变关系,结合粘弹性材料理论模型,得到磁流变弹性体在剪切模式下的磁控动态力学性能参数。为研制高性能的磁流变弹性体提供了评价体系。     

硅橡胶基磁流变弹性体的研制

磁流变弹性体是一种新型的智能材料,它的力学性能可以受磁场控制,在需要变刚度的器件等方面有着广泛的应用前景.本文总结了一些制备高性能磁流变弹性体的基本方法,尝试采用不同的组份制备了以硅橡胶为基体的高性能磁流变弹性体.并使用改进的动态机械分析仪来测试分析所制样品的磁致剪切储能模量和损耗因子等性能.结果表明,所制备的磁流变弹性体在600mT磁感应强度下的剪切储能模量相对变化可达到501%.     

磁流变弹性体的制备及力学性能研究

研究和设计了不同的制备磁路用于制备磁流变弹性体材料,结果表明使用线圈加磁装置可产生可调的磁场,而使用永磁铁加磁时,有导磁装置产生的磁场明显大于直接用永磁铁加磁,并且磁力线几乎无扩散,很好地运用了磁能量.并根据单自由度原理搭建了磁流变弹性体的力学性能测试平台,通过理论分析和推导,得到了磁流变弹性体在不同磁感应强度下的刚度与损耗因子等力学性能参数的计算方法,为高性能磁流变弹性体的制备及准确的力学性能测试提供了技术参考.     

硅橡胶基磁流变弹性体制备及动态剪切性能研究

磁流变弹性体是一种新型的智能复合材料，其动态力学性能受磁场控制，可以应用于变刚度或避免共振的智能器件。在原有制备磁流变弹性体的基础上尝试采用不同的组份配比制备了以双组份室温硫化硅橡胶为基体的高性能磁流变弹性体。在0-700mT磁感应强度范围内，使用动态信号测试分析仪来测试分析所制样品的磁致动态频响函数。结果表明，在70...     

磁流变弹性体压缩模式动态力学性能测试

磁流变弹性体是一种新型的磁流变材料,已被成功地应用于变刚度器件设计中。为了评价磁流变弹性体材料性能,迫切需要建立一套磁流变弹性体性能测试系统。利用电磁振动台的线性扫频功能,采用激光位移传感器同步获取测试系统在不同磁感应强度下测试系统的激励与响应信号,通过系统的运动力学模型和相关理论计算,实现压缩模式下的磁流变弹性体刚度与阻尼性能的测试。该测试系统的建立为研制高性能的磁流变弹性体提供了动态压缩模式下的评价手段。     

硅橡胶基磁流变弹性体制备及动态剪切性能研究

磁流变弹性体是一种新型的智能复合材料,其动态力学性能受磁场控制,可以应用于变刚度或避免共振的智能器件。在原有制备磁流变弹性体的基础上尝试采用不同的组份配比制备了以双组份室温硫化硅橡胶为基体的高性能磁流变弹性体。在0～700mT磁感应强度范围内,使用动态信号测试分析仪来测试分析所制样品的磁致动态频响函数。结果表明,在700mT磁感应强度下及羰基铁粉质量分数为75%时,所制备的磁流变弹性体的共振频率相对变化率可达到30%,具有较好的频率可控特性,同时,其动态剪切模量最大相对变化率可以达到67%,达到了磁场控制剪切模量的目的。     

基于分数阶导数的磁流变弹性体参数模型

磁流变弹性体宏观力学行为是基体粘弹性和磁致模量变化的综合反映,建立能够准确模拟其力学特性的参数模型是设计磁流变弹性体装置所必需的。因此,该文利用建立粘弹性材料参数模型的VFD(粘弹性分数阶导数)元件及弹簧元件与表述磁致效应的非线性弹簧元件,建立了磁流变弹性体的磁致粘弹性参数模型,分析了频率、磁场强度和分数阶数对该模型动态性能的影响,结果表明该模型能够反映磁流变弹性体磁致效应对其力学性能的影响,且该模型仅需少量参数就能在较宽频率范围内更好地模拟真实的试验性能。     

磁流变弹性体的动态压缩性能

制备了聚氨酯基磁流变弹性体,并构建了一种压缩性能的实验装置,对磁流变弹性体的动态压缩性能进行了系统的研究.采用激振的方法,建立了磁流变弹性体的动态力学性能的理论模型,提出了磁流变效应的计算方法.分别研究了预压缩、激励振幅、激励频率、外加磁场对磁流变效应的影响.结果表明,磁流变弹性体的磁流变效应随着外加磁场、激励振幅的增...     

磁流变弹性体的厚度对其力学性能的影响

磁流变弹性体在变刚度变阻尼的隔振或吸振系统中具有广阔的应用前景,材料厚度是影响结构优化和减振效果的重要因素。为了研究材料厚度对磁流变弹性体力学性能影响,制备了同一组分不同厚度的4种试样,采用流变仪对磁流变弹性体在不同磁场、应变、频率下的动态力学性能进行表征。通过对测试结果的处理与分析,得到了磁流变弹性体材料厚度与力学性能之间的变化关系,为磁流变弹性体装置的优化设计提供依据。     

温度对磁流变弹性体力学性能的影响分析

温度影响磁流变弹性体硅橡胶或天然橡胶基体的剪切模量与损耗因数,进而影响磁流变弹性体的减振性能。研究温度对磁流变弹性体力学性能的影响,首先通过ANSYS Workbench仿真分析磁流变弹性体减振器工作时温度随工作时间变化过程,发现磁流变弹性体减振器中励磁线圈随着时间增加,温度逐渐上升,导致磁流变弹性体升温幅度测试磁流变弹性体试样在不同剪切应变与激励频率条件下的力学性能随温度变化过程。结果表明,温度对磁流变弹性体的剪切模量与损耗因数影响较大,在50 Hz、2.5%剪切应变的条件下,试样的剪切模量由25°C时的0.42 MPa降低到65°C时的0.36 MPa,损耗因数由0.307降低到0.204,降幅为33.55%,在不同温度下,磁致性能随温度变化相对较小。基于MATLAB动力学仿真,表明无外加磁场条件下磁流变弹性体减振器系统传递率由25°C时的5.065升高到65°C时的6.705,增幅为32.38%。     

柱状和层状结构磁流变弹性体剪切模量的数值计算

从颗粒间的磁相互作用能出发,计算了磁流变弹性体的磁致剪切模量.考虑了链内颗粒和相邻链中颗粒的影响,修正了磁流变弹性体的磁偶极子模型.构建了体心立方结构和简单立方结构计算模型,分别考虑了柱和层状聚集结构的大小以及其间距,对含柱状结构和层状结构的磁流变弹性体的力学性能进行了计算.计算结果表明,单层模型的磁流变弹性体磁致剪切模量比单链模型的预报值高约48%.在提高磁流变弹性体的磁致剪切模量方面,层状结构优于柱状结构.     

Dynamic mechanical behavior of nickel-based superalloy metal rubber

The work describes the manufacturing and dynamic characterization of nickel wire-based metal rubber (MR) solids. The storage modulus and the loss factor of the nickel MR samples are measured over a frequency range between 0.1 Hz and 200 Hz, and at different levels of dynamic force and strain using a dynamic mechanical analyzer (DMA) technique. A sensitivity analysis about the effect of different static and dynamic testing parameters is initially carried out to identify suitable testing protocols for this metal porous material. DMA testing is then carried out over three different batches of samples (5 specimens each) with variable relative densities to identify the correlation between storage modulus and loss factors with frequency and dynamic force and strain levels. The results are discussed using a mechanical theoretical model relating the mechanical properties of MR solids to the contact states of the wire composing the microstructure. A comparison with analogous results obtained from cyclic tests at 1 Hz from a conventional tensile machine is also performed. The results from this benchmark highlight the necessity to use dynamic-based testing protocols to efficiently implement nickel-based metal rubber for vibration damping and energy absorption designs and applications.     

磁流变弹性体的研究现状及工程应用

磁流变弹性体是一种新型磁流变材料,其特点是流变性能可控可逆、响应时间非常短,而且稳定性好、结构设计简单,因而在智能化减振降噪、电磁传感器和主动控制等领域具有广阔的应用前景。系统介绍了国内外磁流变弹性体的研究现状,包括磁流变弹性体的力学模型、磁致力学性能及影响因素和工程应用,并提出了今后应深入研究的几个问题。     

光纤Bragg光栅用于高频应变测试的研究

提出了一种传感部分采用光纤Bragg光栅(Fiber Bragg grating,FBG)传感器的高频应变测试新方法.设计并构建了基于非平衡马赫-曾德(Mach-Zehnder)干涉仪的高频解调系统.完整的测试系统由FBG传感器、高频应变产生装置和解调系统三部分组成.所产生的应变信号的频率可以通过专门的实验装置来控制,这是一种广泛用于测试材料机械性能的变形分离式霍布金逊压杆(Split Hopkinson Pressure Bar,SHPB)实验装置,应变持续的时间根据与撞击弹性等径的冲锤长度计算.借助高频振动信号研究了测试系统可测信号的频率范围.给出了振动和冲击实验结果,并进行了讨论.所设计的系统可以实时测试动态应变的幅值,实验结果表明,该系统对频率为8kHz以下的信号具有好的响应.     

The stability of polysiloxanes incorporating nano-scale physical property modifiers

Abstract

Reported here is the synthesis and subsequent characterization of the physical and chemical properties of novel polysiloxane elastomers modified with a series of polyhedraloligomericsilsequioxane (POSS) molecular silicas. The physical properties of the formulated nanocomposite systems have been characterized with a combination of dynamic mechanical analysis (DMA), broadband dielectric spectroscopy (BDS) and confocal Raman microscopy. The results of the physical property characterization demonstrate that the incorporation of low levels (1–4% by wt.) of POSS particles into the polysiloxane network leads to significant improvements in the mechanical properties of the elastomer and significantly alters the motional chain dynamics of the system as a whole. The results of studies performed to assess the long-term stability of these novel nanocomposite systems have demonstrated that POSS physical property modifiers can significantly alter the thermal stability of polysiloxane elastomers. Physically dispersed POSS has also been shown in some cases to be both mobile and disruptive within the polysiloxane networks, agglomerating into domains on a micron scale and migrating to the surface of the elastomers. This work demonstrates both the potential of POSS nanoparticles as physical property modifiers and describes the effects of POSS on the physical and chemical stability of polysiloxane systems.     

Furan-Based Bionanocomposites Reinforced with a Hybrid System of Carbon Nanofillers

Bionanocomposites based on poly(trimethylene 2,5-furandicarboxylate)-block-poly(tetramethylene oxide) (PTF-b-F-PTMO) with various contents of carbon nanofibers, graphene nanoplatelets and a hybrid system of these nanoparticles are synthesized via in situ polymerization. The dispersion of nanoparticles in the nanocomposites is determined using a scanning electron microscope and optical microscopy images. The thermal properties are studied employing differential scanning calorimetry, dynamic mechanical thermal analysis, and thermogravimetric analysis. The melt viscosity of the synthesized materials is determined using rheological measurements. Mechanical properties, along with the thermal and electrical conductivity, are also analyzed. The synthesized polymer nanocomposites are processed using injection molding and they display mechanical properties of elastomers during mechanical testing, which indicates that the obtained materials are, in fact, thermoplastic elastomers (TPE). Compared to a neat matrix (PTF-b-F-PTMO 50/50), the incorporation of nanoparticles causes an increase in the value of the degree of crystallinity and the value of the tensile modulus values (E) of the nanocomposites. Such reinforced bionanocomposites are especially interesting from an applicative point of view. They can be used as components of fuel systems, bumpers, or cupholders.     

Ionomeric modification of metallocene-based polyolefinic elastomers with varied pendant chain length and its influence on physico-mechanical properties

A new class of ionomer was developed through sulfonation of the metallocene-based poly(ethylene–octene) elastomer, followed by its neutralization with zinc acetate. Ionomeric products were characterized through Fourier transform infrared (FT-IR) spectroscopy, small angle X-ray scattering (SAXS), and transmission electron microscopy (TEM) studies. The effect of pendant chain length on the ionomeric modification was also studied through the variation of the comonomer. The impact of these ionomeric modifications on various physico-mechanical properties was thoroughly investigated by using differential scanning calorimetry, mechanical, dynamic mechanical, and thermogravimetric analysis. The resultant properties were correlated with structures of the modified elastomers. Ionomerisation of the base elastomers causes a significant improvement in the stress–strain, as well as the thermal properties compared to the corresponding pristine elastomer. Anjan Biswas is on leave from Government College of Engineering and Leather Technology, LB Block, Sector III, Saltlake City, Kolkata-700098, India.