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目的获得电沉积Ni-Cr泡沫合金的最佳工艺参数。方法采用正交实验法研究镀液成分等工艺参数对镀层沉积速率、厚度以及合金中Cr含量的影响,并利用扫描电子显微镜等测试手段对镀层横截面厚度等镀层指标进行了考察。结果阴极电流密度为28 A/dm2,镀液pH值为2.0,镀液温度为25℃,CrCl3·6H2O的质量浓度为125 g/L,配位剂与Cr3+摩尔比为1.8时,电沉积60 min能够获得表面光亮平整的Ni-Cr合金镀层,镀层厚度为24.09μm,沉积速率为0.4198 mg/(cm2·min),镀层中Cr的质量分数为14.76%。结论镀液温度在25~40℃范围内,对Ni-Cr合金镀层厚度、沉积速率的影响最大;镀液中CrC13·6H2O浓度、配位剂与Cr3+的摩尔比两个因素,对合金镀层中Cr含量的影响较大。 相似文献
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采用复合电沉积法在T91钢表面制备Ni/CrAl镀层,研究了CrAl微粒在镀层中的含量与搅拌强度、镀液pH值、电流密度及温度的关系,确定最佳工艺参数为:电流密度2.5~4.5 A/dm2,pH值4~4.5,温度30℃.采用该工艺制备了较高CrAl含量的复合镀层,并对工艺参数影响复合电沉积的机理进行了简单探讨. 相似文献
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采用电沉积技术制备几种电沉积式锌电极,考察镀液中KOH浓度和沉积电流密度对所制得镀锌层的微观形貌与性能的影响规律.结果表明镀锌层的枝晶随着KOH浓度(250~400 g/L)的增加而变得粗大,且其析氢量、腐蚀电位和腐蚀电流密度均呈现先减小而后增加的趋势;随着电流密度(25~100 mA/cm2)的增长,镀锌层由块状结晶向枝晶转变,相应地电极反应活性随之增大,而耐蚀性则随之变差,并发现沉积电流密度为75 mA/cm2时,锌电极的综合性能最好,以200 mA/g充放电循环10周次,其放电容量仍可达504 mA-h/g.解释了主要工艺参数对结晶形态及电极性能影响的原因,并说明适当的KOH浓度和沉积电流密度有利于提高电极的综合性能. 相似文献
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锂离子电池用负极集流体铜箔材料目前主要采用电沉积法制备。为制备良好的电解铜箔,采用不同电镀工艺参数,在基于三乙醇胺(TEA)和乙二胺四乙酸二钠(EDTA.2Na)双络合体系的CuSO4/H2SO4溶液中进行镀铜工艺研究。通过线性扫描、循环伏安、SEM和XRD手段对镀液性质、镀层微观形貌和结构进行测定和表征,并进行镀层质量重复性实验。结果表明:选择含P 0.1%的磷铜作为阳极,采取机械搅拌镀液的方式,在CuSO4.5H2O为300 g/L、H2SO4为90 g/L、Cl-为40~80 mg/L、TEA为3.5 g/L和EDTA.2Na为5 g/L中适量添加剂P的镀液中,以电流密度为490 mA/cm2,镀液温度为40~60℃,施镀5~10 min能得到良好镀层;添加剂明显降低循环伏安阴极峰电流,Cu2+的还原速度减慢;添加剂提高镀层表面的结晶细化程度,使晶体颗粒变小,致密性提高,镀层质量变好,整平作用明显,Cu镀层呈现(111)晶面择优取向;镀速可达19.4 mg/min,镀层质量有很好的重现性。 相似文献
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C.J. Sun H.R. Geng Y.S. Shen X.Y. Teng Z.X. Yang 《金属学报(英文版)》2007,20(3):181-186
The rheology feature of Sb, Bi melt and alloys was studied using coaxial cylinder high-temperature viscometer. The results showed that the curve of torsion-rotational speed for Sb melt presents a linear relation in all measured temperature ranges, whereas for the Bi melt, the curve presents obvious non-Newtonian feature within the low temperature range and at relative high shear stress. The rheology feature of Sb80Bi20 and Sb20Bi80 alloy melts was well correlated with that of Sb and Bi, respectively. It is considered that the rheology behavior of Sb melt plays a crucial role in Sb80Bi20 alloy and that of Bi melt plays a crucial role in Sb20Bi80 alloy. 相似文献
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Peng Liu Zhao-Kuang Chu Yong Yuan Dao-Hong Wang Chuan-Yong Cui Gui-Chen Hou Yi-Zhou Zhou Xiao-Feng Sun 《金属学报(英文版)》2019,32(4):517-525
The effect of heat treatment on the microstructures and mechanical properties of a newly developed austenitic heat resistant steel(named as T8 alloy) for ultra-supercritical applications have been studied. Results show that the main phases in the alloy after solution treatment are γ and primary MX. Subsequent aging treatment causes the precipitation of M_(23)C_6 carbides along the grain boundaries and a small number of nanoscale MX inside the grains. In addition, with increasing the aging temperature and time, the morphology of M_(23)C_6 carbides changes from semi-continuous chain to continuous network.Compared with a commercial HR3C alloy, T8 alloy has comparable tensile strength, but higher stress rupture strength. The dominant cracking mechanism of the alloy during tensile test at room temperature is transgranular, while at high temperature, intergranular cracking becomes the main cracking mode, which may be caused by the precipitation of continuous M_(23)C_6 carbides along the grain boundaries. Typical intergranular cracking is the dominant cracking mode of the alloy at all stress rupture tests. 相似文献
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《中国铸造》2014,(6):540-541
Organized by Suppliers China Co., Ltd and co-organized by the National Technical Committee 54 on Foundry of Standardization Administration of China, the 15th Global Foundry Sourcing Conference 2014 (hereinafter referred to as FSC 2014) was successfully held on Sep. 23rd in Grand Regency Hotel, Qingdao. More than 500 delegates from home and abroad attended this conference, including over 130 purchasers from 20 countries and 380 domestic and foreign suppliers. 相似文献
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LASER CLADDED TiCN COATINGS ON THE SURFACE OF TITANIUM 总被引:3,自引:0,他引:3
Y.L. Yang D. Zhang and H.S. Kou College of Science Northeastern University Shenyang China C.S. Liu College of Material Metallurgy Northeastern University Shenyang China 《金属学报(英文版)》2007,20(3):210-216
Laser cladded coatings of TiCN were produced on the surface of titanium. To obtain the optimal techniques, several conditions were tested by varying the laser scanning rate. The choice of shielding gas was also studied. The cladded coatings were then evaluated from the surface mechanics point of view based on their microhardness. The microstructure of some interesting samples was investigated by optical micrographs (OM). The results showed that under the condition of fixed pulse frequency and pulse width, the laser scanning rate and the shielding gas are the main factors influencing the components of coatings. TiCN coatings were decompounded and oxidized during the cladding process in the condition of no shielding gas of N2. X-ray diffraction results indicated that the composite coatings composed of TiCN, TiC, Ti2N, and TiO2 were produced using appropriate techniques. The results indicated that the best condition in terms of the surface microhardness is obtained when the scanning rate is 1.5mm / s, the pulse frequency is 15Hz, the pulse width is 3.0ms, and N2 is chosen as the shielding gas. The microhardness of the composite coatings is about 1331kg · mm - 2, which is about 4 times that of the substrate. The optical micrographs indicated that the cladding zone is made up of TiCN, TiO2, and some interdendritic Ti, but the diffusion zone mainly consists of the dendrites phase, and the cladded depth is about 80m, which is more than 2 times that of the laser nitrided sample. There were no microcracks or air bubbles in the cladded sample, which was cladded using the above optimal techniques. 相似文献
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X80 pipeline steel plates were friction stir welded(FSW) under air, water, liquid CO_2 + water, and liquid CO_2 cooling conditions, producing defect-free welds. The microstructural evolution and mechanical properties of these FSW joints were studied. Coarse granular bainite was observed in the nugget zone(NZ) under air cooling, and lath bainite and lath martensite increased signifi cantly as the cooling medium temperature reduced. In particular, under the liquid CO_2 cooling condition, a dual phase structure of lath martensite and fi ne ferrite appeared in the NZ. Compared to the case under air cooling, a strong shear texture was identifi ed in the NZs under other rapid cooling conditions, because the partial deformation at elevated temperature was retained through higher cooling rates. Under liquid CO_2 cooling, the highest transverse tensile strength and elongation of the joint reached 92% and 82% of those of the basal metal(BM), respectively, due to the weak tempering softening. A maximum impact energy of up to 93% of that of the BM was obtained in the NZ under liquid CO_2 cooling, which was attributed to the operation of the dual phase of lath martensite and fi ne ferrite. 相似文献
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《中国铸造》2014,(3):215-217
China Securities News reported on March 21, 2014: Guangdong Hongtu Wuhan Die Casting Co., Ltd. (Wuhan Hongtu), a wholly owned subsidiary of Guangdong Hongtu Technology (Holdings) Co., Ltd., held a groundbreaking ceremony recently. With the registered capital of 50 million Yuan, Wuhan Hongtu has a total land area of 100,000 square meters and a plant construction area of 72,000 square meters. It is expected to have a production capacity of about 30,000 tonnes of aluminum castings annually after it is put into production. 相似文献
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M.E Li G. C. Yang 《金属学报(英文版)》2007,20(4):258-264
Two new classes of growth morphologies, called doublons and seaweed, were simulated using a phase-field method. The evolution of doublon and seaweed morphologies was obtained in directional solidification. The influence of orientation and velocity on the growth morphology was investigated. It was indicated that doublons preferred growing with its crystallographic axis aligned with the heat flow direction. Seaweed, on the other hand, could be obtained by tilting the crystalline axis to 45°. Stable doublons could only exist in a range of velocity regime. Beyond this regime the patterns formed would be unstable. The simulation results agreed with the reported experimental results qualitatively. 相似文献
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Z.C. Guo X.Y. Zhu R.D. Xu 《金属学报(英文版)》2007,20(2):111-116
The effects of pulse frequency f and duty cycle r on the deposition rate, composition, morphology, and hardness of pulse electrodeposited RE (rare earth)-Ni-W-P-SiC composite coatings have been studied. The results indicate that pulse current can improve the deposition rate of RE-Ni-W-P-SiC composite coatings; W, P, and SiC contents in the coating decrease with the increase of pulse frequency and reach the lowest value at f = 33Hz, whereas the RE content in the composite coatings increases with the increase of pulse frequency. SiC content decreases with the increase of duty cycle, W content reaches the lowest value, and P content reaches the highest value at r = 0.4; pulse current and RE can lead to smaller size of the crystalline grains; however, the effects of different pulse frequency and duty cycle on the morphologies of RE-Ni-W-P-SiC composite coatings are not obvious. The hardness of RE-Ni-W-P-SiC composite coatings is the highest when the duty cycle is at 0.6 and 0.8 and pulse frequency is at 50Hz. At the same pulse frequency, the hardness of RE-Ni-W-P-SiC composite coatings at r= 0.8 is higher than that at r= 0.6. 相似文献
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Y.G. Cao S.F. Xue K. Tanaka 《金属学报(英文版)》2007,20(1):40-48
To investigate the causes that led to the formation of cracks in materials, a novel method that only considered the fracture surfaces for determining the fracture toughness parameters of J-integral for plain strain was proposed The principle of the fracture-surface topography analysis (FRASTA) was used. In FRASTA, the fracture surfaces were scanned by laser microscope and the elevation data was recorded for analysis. The relationship between J-integral and fracture surface average profile for plain strain was deduced. It was also verified that the J-integral determined by the novel method and by the compliance method matches each other well. 相似文献