共查询到18条相似文献,搜索用时 62 毫秒
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DAVIES H A 《金属学报(英文版)》1992,5(10):292-299
Studies were made of the effect of mechanical pulverization on relaxation,crystallizationand brittle-ductile transition of the anneal-embrittled Fe_(75)Si_(10)B_(15) metallic glass rib-bon.Results show that the Curie temperature,T_C,decreases and the total enthalpy ofrelaxation increases gradually with variation of pulverized time.DSC traces reveal anextra exothermic peak,T_X_1,and a distinct glass transition endothermic peak,T_g_1,withincreasing pulverized time,T_C,T_X_1,and T_g_1 decrease simultaneously,and the exother-mic peak area corresponding to T_X_1 increases gradually.The surface slip-steps of flakyparticles and their corresponding shear are produced by pulverizing the pre-embrittledamorphous glass.The lost ductility of the glass may restore during annealing. 相似文献
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NING Yuantao LI Yongnian Kunming Institute of Precious Metals China Ning Yuantao Professor Institute of Precious Metals Kunming Yunnan China 《金属学报(英文版)》1990,3(7):43-48
The influence of rare-earth elements,La,Ce,Pr,Nd,Sm,Eu,Gd,Dy,Ho,Er and Yb onthe thermal stability of PdSi_(16.5) glass was studied systematically by means of DSC.Allrare-earth elements,especially heavy ones,increase obviously the thermal stabilityparameters,including T_θ(T_g ,T_x ,T_g),T_(rg) and ΔE etc.The crystallization temperaturesT_(p1) and T_(p2) increase linearly with the lanthanide constriction increasing,but Eu shows ananomalous influence:Pd-Si-Eu metallic glass possesses the highest thermal stability and thelowest concentration limit of glass forming among Pd-Si-R glasses. 相似文献
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LI Hui Institute of Metal Research Academia Sinica Shenyang ChinaLIU Xiang Northeast Institute of Technology Shenyang ChinaGUO Jianting HU Zhuangqi Institute of Metal Research Academia Sinica Shenyang China Associate Professor Institute of Metall Research Academia Sinica Shenyang China 《金属学报(英文版)》1989,2(4):256-261
By means of nonstoichiometry,rapid solidification and adequate boron addition,the tensilestrength and bending resistance of Ni_3Al has been improved.When adding 0.52 to 1.37 at.-%B into Ni_3Al,which has the beneficial effect on the ductility.If boron addition is too high,there are coarse Ni_(23)B_6 particles and NiB_(12) phases found at the grain boundaries.Boronmodification in Ni_3Al promotes the ordering in the region near grain boundaries.The grainboundary of boron free Ni_3Al is a large angle one,but turns into a small angle grain bound-ary with sub-grains of dislocation characteristics when the boron content in Ni_3Al reaches1.37 at.-%. 相似文献
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在直到300℃的范围内考查了 Fe_8Ni_(27)Co_(43)Si_8B_(14)金属玻璃的磁导率弛豫。估计了弛豫过程的激活能谱。证实了时效引起的磁导率衰减是可逆的结构重排过程。观察到磁导率衰减中的 cross-over 效应。定量地估计了较低温度下的磁稳定性。 相似文献
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A series of poly(phenylenevinylene) (PPV)/titanium oxide (TiO2) nanocomposites with different contents of TiO2 nanoparticles were prepared from mixtures of PPV
precursor and titanium butoxide ethanol solution in a sol-gel process. TEM images
showed the formation of the connected network of TiO2 nanoparticles with a higher
content of TiO2, which resulted in the titanium butoxide hydrolyzed to form Ti organic
compound. Meanwhile, the conjugation of PPV polymer chains can be interrupted by
the TiO2 network structure. The PL spectra revealed that the emitted light of the
PPV/TiO2 nanocomposites blue shifted without fine structure and the PL intensity
enhanced when the TiO2 network formed. In the lifetime spectroscopy of positron
annihilation, the structural properties of the PPV dominated the character of the
nanocomposites, in which the formation of the o-Ps was presented in free volume pf
polymer, when the content of TiO2 was below 10%. Further increasing the content
of TiO2 相似文献
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STRUCTURE AND GLASS FORMING ABILITY(GFA)OF AMORPHOUS ALLOYS 总被引:1,自引:0,他引:1
LU Ke State Key Laboratory for RSA Institute of Metal Research Academia Sinica Shenyang China 《金属学报(英文版)》1992,5(10):245-254
A new microstructure model is developed for amorphous alloys,so called Cluster medel,in which the amorphous phase is thought of composing of randomly distributed orderedclusters of different sizes.Thermodynamic calculation on this model deduces a parameterdescribing the glass forming ability of metallic alloys:α_c=(1-2.08/Φ_m)T_g/T_m,whereT_g is gass transition temperature,T_m is the melting temperature,and Φ_m is entralpychange of melting.It is believed that easy glass forming alloy systems have larger valuesof a_c.This new criterion of GFA not only provides the theoretical background for severalGFA criteria in the literature cited,but also can predict the GFA of many alloy systemsmore reasonably and accurately. 相似文献
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应用等离子体浸没离子注入装置对纯Ti表面进行氟离子注入, 通过SEM和XPS分析研究材料的表面形貌和化学组成. 将MG-63成骨细胞接种于氟离子注入前、后的 Ti样品表面, 采用激光共聚焦显微镜观察材料表面对成骨样细胞MG-63 I型胶原形成的影响; 逆转录聚合酶链反应检测I型胶原mRNA的表达; 蛋白印迹法检测I型胶原蛋白的表达. 结果表明, 氟离子注入后Ti样品表面新出现TiF3; 且MG-63细胞在其表面分别培养6, 24和48 h后, I型胶原的形成和表达均明显高于纯Ti表面. 含氟表面改性层可提高Ti材料的生物相容性. 相似文献
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Cu films with thickness of 630-1300nm were deposited on glass substrates without heating by DC magnetron sputtering in pure Ar gas. Ar pressure was controlled to 0.5, 1.0 and 1.5Pa respectively. The target voltage was fixed at 500V but the target current increased from 200 to 1150mA with Ar pressure increasing. X-ray diffrac-tion, scanning electron microscopy and atomic force microscopy were used to observe the structural characterization of the films. The resistivity of the films was measured using four-point probe technique. At all the Ar pressures, the Cu films have mixture crystalline orientations of [111], [200] and [220] in the direction of the film growth. The film deposited at lower pressure shows more [111] orientation while that deposited at higher pressure has more [220] orientation. The amount of larger grains in the film prepared at 0.5Pa Ar pressure is slightly less than that prepared at 1.0Pa and 1.5Pa Ar pressures. The resistivities of the films prepared at three different Ar pressures re 相似文献
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退火变脆Fe75Si10B15金属玻璃的脆韧性转变 总被引:1,自引:0,他引:1
研究了机械研磨对退火变脆Fe_(75)Si_(10)B_(15)金属玻璃的弛豫过程,晶化行为及脆韧性转变的影响。发现退火变脆的Fe_(75)Si_(10)B_(15)金属玻璃,经不同时间机械研磨,Curie温度T_C逐渐回落,总的弛像焓ΔH_?逐渐回升。在DSC曲线上观察到明显的玻璃转变温度T_(g_1)和一个附加的宽放热峰T_(x_1),随着研磨时间的增加,T_(x_1),T_(x_1),T_C同步降低,与T_(x_1)对应的放热面积ΔH_(x_1)逐渐增大,并在片状粒子表面形成切变带以及与其对应的剪切带,玻璃在退火过程中失掉的韧性逐渐得到恢复。 相似文献
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HEATCAPACITIESOFFe_(40)Ni_(40)B_(20)GLASSYALLOYMEASUREDBYENTHALPYMETHOD¥JIANGQing;ZHAOMing;LIJianchen(JilinUniversityofTechnol?.. 相似文献
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LU Jian WANG Jingtang DING Bingzhe Institute of Metal Research Academia Sinica Shenyang China 《金属学报(英文版)》1989,2(12):392-396
The thermal expansion along the longitudinal and transverse directions for amorphousFe_(78)B_(13)Si_9 alloy prepared under various preparing conditions were investigated.The thermalexpansion anisotropy appears in all specimens.The expansion along the longitudinal directionis less than that along the transverse direction.The cooling rate,the melt temperature beforejet casting and the cycling temperature affect the thermal expansion coefficients andanisotropy.The amisotropy of thermal expansion originates from the orientation of atomicinteraction force,the atomic oscillatory frequency and short range order structure or thedirectional arrangement of defects in the alloy. 相似文献
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