Mg-2Zn-0.5Y镁合金半固态等温处理过程中的微观组织演变

本文研究了挤压Mg-2Zn-0.5Y合金在半固态等温处理过程中的微观组织演变规律。结果表明：挤压态的Mg-2Zn-0.5Y合金包含α-Mg,I相和W相三种物相,并且平均晶粒尺寸为7μm。在温度为793K的半固态等温热处理过程中,晶粒不断长大,直到保温时间达到4min时才出现液相。随着等温处理温度和时间的增加,α-Mg固相颗粒不断长大,并且逐步被液相分离;同时,出现在晶界的液相与颗粒内部的液滴都在不断地增多。研究还发现,当固相率较高的时候,晶粒间的合并机制与固相颗粒再熔化机制同时起主导作用;然而当固相率较低的时候,Ostwald熟化机制是主要的粗化机制,同时也可以观察到晶粒间的合并。     

Mg-2Zn-0.5Y镁合金半固态等温处理过程中的微观组织演变（英文）

研究了挤压Mg-2Zn-0.5Y(at%)合金在半固态等温处理过程中的微观组织演变规律。结果表明:挤压态的Mg-2Zn-0.5Y合金包含α-Mg,Mg3-Zn6-Y1(I-Phase)和Mg3-Zn3-Y2(W-phase)3种物相,并且α-Mg的平均晶粒尺寸为7μm。在温度为793 K的半固态等温热处理过程中,晶粒不断长大,直到保温时间达到4.0 min时才出现液相。随着等温处理温度和时间的增加,α-Mg固相颗粒不断长大,并且逐步被液相分离;同时,出现在晶界的液相与颗粒内部的液滴都在不断地增多。研究还发现,当固相率较高时,晶粒间的合并机制与固相颗粒再熔化机制同时起主导作用;然而当固相率较低时,Ostwald熟化机制是主要的粗化机制,同时也可以观察到晶粒间的合并。     

半固态处理工艺参数对挤压AZ91镁合金微观组织的影响

研究了半固态等温处理温度和时间对挤压AZ91镁合金微观组织演变的影响。挤压AZ91镁合金的微观组织为流线带状组织,由分布于其间的细小再结晶α-Mg等轴晶组成。在半固态温度区间进行等温处理时,合金内的低熔点相及溶质元素富集区优先开始熔化,然后沿着晶界渗透,形成液相包围固相晶粒的半固态组织。随着等温温度的升高,固相晶粒熔化分离的速度加快。在等温温度为560℃时,随着等温时间的延长,液相不断增加,固相晶粒分离并不断趋于圆整。等温处理20 min后,合金达到了固/液平衡状态,Ostwald熟化机制开始明显,晶粒长大成为主要机制。挤压AZ91镁合金较佳的等温处理工艺为等温温度560℃,等温时间20~30 min。     

Mg-7Zn-0.3Mn-xCu镁合金半固态组织演变

本文研究了Cu含量、重熔温度及等温时间对Mg-7Zn-0.3Mn镁合金半固态组织演变的影响。结果表明:Mg-7Zn-0.3Mn-1Cu合金的铸态组织由白色α-Mg基体和黑色共晶组织(α-Mg+Mg_4Zn_7+MgZn_2+CuMnZn)组成。在等温热处理过程中,Cu有加速非枝晶颗粒分离和球化的作用,且Cu含量(质量分数)为1.0%时效果最佳;Mg-7Zn-0.3Mn-1Cu镁合金通过适当提高保温温度或延长保温时间,能够得到细小且分布均匀的球状颗粒。然而当保温温度超过585℃或保温时间超过20 min时,半固态颗粒则会粗化长大。这种粗化长大现象是在合并长大机制与Ostwald熟化机制共同作用下产生的。在整个等温热处理过程中,半固态组织演变主要经历了初始粗化、组织分离、球化和最后粗化四个阶段。Mg-7Zn-0.3Mn-1Cu镁合金的最佳等温热处理工艺参数为保温温度585℃和保温时间20 min,其非枝晶颗粒的平均尺寸、形状因子和固相率分别为38.85μm、1.39和53.38%。     

AZ91镁合金的SIMA法半固态组织特征

研究了挤压态AZ91镁合金的SIMA法半固态组织演变.结果表明:挤压合金为以α-Mg再结晶等轴晶为主相,与极少量细粒状成串分布于α-Mg基体上的Mg17Al12颗粒组成的两相组织,基体中存在大量的大角度亚晶及高密度的位错缠结.在二次加热过程中,原子扩散通道多,晶界液化及颗粒球化所需的加热温度低,等温时间短.565℃等温5min,即可获得固相率为57%,颗粒平均直径为58 μm、形状圆整、分布均匀的半固态组织.等温5 min后,半固态颗粒发生长大,其长大机制为Ostwald熟化.     

流变挤压铸造Mg-6Zn-3RE-1.4Y镁合金的组织

采用超声振动制备了Mg-6Zn-3RE-1.4Y新型镁合金的半固态浆料,并对半固态浆料进行直接挤压铸造。研究了流变挤压铸造Mg-6Zn-3RE-1.4Y镁合金的组织和相组成。结果表明,Mg-6Zn-3RE-1.4Y合金流变挤压铸件组织中存在两种细小圆整但尺寸差异较大的α1-Mg和α2-Mg晶粒,α1-Mg平均晶粒尺寸和形状系数分别为22μm和0.74,α2-Mg为浆料中剩余液相形成的以球形为主的细小晶粒。合金的相组成主要为α-Mg基体、α-Zr以及沿晶界分布的Mg12Ce、Mg12La以及I-Mg3Zn6Y相。     

等温热处理对Mg-7Zn-0.3V合金半固态组织演变的影响

通过半固态等温热处理,研究保温温度和保温时间对Mg-7Zn-0.3V镁合金把固态组织演变的影响。结果表明:保温温度和保温时间对Mg-7Zn-0.3V非枝晶组织的演变有重要的影响。提高保温温度或是延长保温时间,可以使Mg-7Zn-0.3V中的非枝晶组织转变为更加细小且分布均匀的球状颗粒。当保温温度过高或是保温时间过长时,半固态颗粒会出现合并和长大,其主要的演变机制与Ostwald熟化规律相符合。Mg-7Zn-0.3V合金的最佳等温热处理工艺是:保温温度605℃,保温时间40 min,非枝晶颗粒的平均尺寸为48.5μm,形状因子为1.26。     

AZ80镁合金半固态等温处理过程中的组织演变

对挤压态AZ80镁合金进行了不同时间的等温处理,观察分析了半固态微观组织的演变规律与晶内液池的形成过程。结果表明:在等温过程中,组织演变过程主要表现为晶粒合并粗化、晶界局部液相出现和液相区扩大、α-Mg晶粒球化转变、熟化与合并长大几个阶段。挤压AZ80镁合金半固态等温处理过程中α-Mg晶粒内液池出现机制以α-Mg晶内溶质元素富集处发生局部优先熔化为主。     

AZ80镁合金半固态组织的等温演化研究

对半连续铸造和热挤压态AZ80镁合金进行半固态等温处理,研究了其微观组织的演变规律和α-Mg晶粒尺寸及形状系数与工艺参数的定量关系。结果表明,相同参数条件下,挤压AZ80镁合金经半固态等温处理后,α-Mg晶粒更圆整,晶粒尺寸分布更均匀;其α-Mg晶内液相出现机制以溶质元素富集和高能储备导致晶内局部优先熔化为主;而半连续铸造AZ80镁合金半固态等温处理过程中,α-Mg晶内液相出现机制以枝晶臂合并导致液相进入晶内为主。挤压AZ80镁合金经不同参数的半固态等温处理后,α-Mg晶粒尺寸均符合高斯分布;其较佳的半固态处理工艺参数为570℃保温20min,此时固、液相的相对分布更均匀,α-Mg晶粒平均形状系数为0.86,且多集中于高系数区。     

等温热处理对Mg-Gd-Zn-Zr合金半固态组织的影响

选择稍高于共晶反应温度作为等温热处理温度,对铸态Mg-15Gd-2Zn-0.6Zr合金进行等温热处理,获得了半固态球化组织。研究了热处理温度和保温时间对半固态组织的影响,探讨了半固态组织演变机制及适用于低温等温热处理的半固态Mg-Gd-Zn-Zr合金成分设计。结果表明,液相组织具有低的温度敏感性,其组织演变主要机制为α-Mg表面熔化和α-Mg动态再析出,而固相颗粒球化机制为:α-Mg树枝晶→枝晶臂粗化→枝晶臂合并、不规则多边形化→球化。     

新型的治疗阿尔茨海默氏症药物(1-二甲基磷酰基-2,2,2-三氯)-乙基-1-醇烟酸醋对体外神经细胞的作用

目的: 观察本实验室合成的一种治疗阿尔茨海默氏症(AD)的药物(1-二甲基磷酰基-2, 2, 2 -三氯)-乙基^-1-醇烟酸醋(NMF),对体外培养的皮层神经细胞活性的影响以及对海人藻酸(KA)所致的神经损伤的保护作用。方法: 采用体外培养皮层神经元的方法,解剖分离 15 d胚胎小鼠皮层神经细胞, 接种于 96孔板,48 h 后加药并培养 72 h,以 MIT 法 观察 NMF 对小鼠皮层神经细胞活性的影响;同时将接种于 24 孔板的细胞预先给予 NMF,d 3 时加或不加KA处理后,以台盼蓝染色鉴别并计数死、活细胞,可得出细胞的存活率。结果: NMF 明显促进胎鼠皮层神经元活性,其中 NMF1、0. 1、10nmol·L^-1促进神经元活性增殖率分别高达 34.7%、37.4%、36. 7%, NMF 明显促进正常胎鼠皮层神经元存活卒,与对照组比较,10nmol·L^-1 NMF 对皮层神经元的存活率分别提高 39.3%、73.5%。 NMF能显著 对抗 KA 所致的神经元损伤,与 KA 损伤组相比, NMF0.1、10、10nmol·L^-1对损伤皮层神经元的保护率分别为 77.30%、80.10%、84.15%。结论: NMF 明 显促进胎鼠皮层神经元的洁性、提高正常皮层神经元,的存活卒,并能有效地保护KA所致的神经元损伤,提示 NMF 是一种很有潜力的治疗 AD 的药物。     

Three-Dimensional Growth of Coherent Ferrite in Austenite: A Molecular Dynamics Study

Coherent second phase often exhibits anisotropic morphology with specifi c orientations with respect to both the second and the matrix phases. As a key feature of microstructure, the morphology of the coherent particles is essential for understanding the second-phase strengthening eff ect in various industrial alloys. This letter reports anisotropic growth of coherent ferrite from austenite matrix in pure iron based on molecular dynamics simulation. We found that the ferrite grain tends to grow into an elongated plate-like shape, independent of its initial confi guration. The fi nal shape of the ferrite is closely related to the misfi t between the two phases, with the longest direction and the broad facet of the plate being, respectively, consistent with the best matching direction and the best matching plane calculated via the Burgers vector content(BVC) method. The strain energy calculation in the framework of Eshelby's inclusion theory verifi es that the simulated orientation of the coherent ferrite is energetically favorable. It is anticipated that the BVC method will be applicable in analysis of anisotropic growth and morphology of coherent second phase in other phase transformation systems.     

Effect of Short-Time Aging on the Pitting Corrosion Behavior of a Novel Lean Duplex Stainless Steel 2002

The effect of short-time aging in the temperature range between 400 and 1000 °C on the pitting corrosion behavior and mechanical property of a novel lean duplex stainless steel(LDSS) 2002 was investigated through the potentiostatic critical pitting temperature(CPT) tests and the Charpy impact tests. Both the pitting corrosion resistance and the toughness of aged specimens degraded due to the precipitation of detrimental secondary phases and the most significant reduction of CPT and impact energy emerged at 650 °C concurrently. The CPT of LDSS 2002 specimen aged at 650 °C decreased by 28 °C, and the impact energy dropped from 69 to 29 J/cm~2 compared with the solution-annealed sample. Transmission electron microscopy characterization showed that the main precipitates in LDSS 2002 were Cr_2N and M_(23)C_6 along the ferrite–austenite grain boundaries.     

INTRODUCTION TO PATENTS

The invention provides a method of making a mold which can reduce SOx generation rate while preventing decrease in hardening rate in the case of using sulfuric acid for a hardener composition. The method has a mixture step in which fire-resistant particles, a hardener composition and a binder composition are mixed to obtain a composition for a mold. The hardener composition contains sulfuric acid. In the mixture step, sodium carbonate is added. A molar ratio of the sulfuric acid to the sodium carbonate is 0.5 or more and 4.0 or less.     

China Foundry Week 2014

China Foundry Week, hosted by the Foundry Institution of Chinese Mechanical Engineering Society （FICMES） each year, is a large academic event in China. It is one of the ten high-impact activities sponsored by the Chinese Mechanical Engineering Society.     

17th Conference of Hydrodynamic and Electromechanical Control Engineering Call for papers

正1.Contents In order to promote the academic exchanges and technical communication of the research in the field of fluid power transmission and control,fluid control engineering specialized committee of the Chinese Society of Theoretical and Applied Mechanics will hold the 17th Conference of Hydrodynamic and Electromechanical Control Engineering on July 27-29,2014 in Tibet,Lhasa city.     

Information for Contributors

正The Transactions of Nonferrous Metals Society of China,founded in 1991 and sponsored by The Nonferrous Metals Society of China,is published monthly now and mainly contains reports of original research which reflect the new progresses in the field of nonferrous metals science and technology,including mineral processing,extraction metallurgy,metallic materials and heat treatments,metal working,physical metallurgy,powder metallurgy,with the emphasis     

Preface

<正>We are pleased to present this Special Issue of Transactions of Nonferrous Metals Society of China containing selected papers from the First Asian Conference on Aluminum Alloys(ACAA-2013),held in Beijing,China,13–17 October 2013.This conference has been initiated,with approval of     

Information for Contributors

The Transactions of Nonferrous Metals Society of China, founded in 1991 and sponsored by The Nonferrous Metals Society of China, is published monthly now and mainly contains reports of original research which reflect the new progresses in the field of nonferrous metals science and technology, including mineral processing, extraction metallurgy, metallic materials and heat treatments, metal working, physical metallurgy, powder metallurgy, with the emphasis on fundamental science. It is the unique preeminent publication in English for scientists, engineers, under/post-graduates on the field of nonferrous metals industry. This journal is covered by many famous abstract/index systems and databases such as SCI Expanded, Ei Compendex Plus, 1NSPEC, CA, METADEX, AJ and JICST.     

Formulas of Tension of Continuous Rolling Process

The development of computer controlled continuous rolling process calls for a mathematical expression that can express the inequality condition of "constant flow". Tension is the link of the continuous rolling process. From the condition of dynamic equilibrium, a differential equation of tension is given out. On the basis of the physical rules established from the industrial practice and experimental studies, the law of volume constancy, the linear relation of forward slip and tension, the state equation of continuous rolling, the formula of dynamic tension, and the formula of static tension have been obtained. These formulae reflect the functional relations between tensions, thickness, roll velocity, and time in the continuous rolling process. It is implied that the continuous rolling process is a gradually steady, controllable, and measurable dynamic system. An assumption of predicting the thickness of a steel plate using these tension formulae is also put forward.