空心微珠表面化学镀Ni-P合金及其吸波性能研究

采用化学镀法在平均粒径2 μm的空心微珠表面包覆了均匀完整的Ni-P非晶合金镀层,并对该材料进行了电磁性能和吸波性能测试.测试结果表明:空心微珠包覆Ni-P非晶合金镀层后矫顽力达到343.08Oe,属于电磁损耗型材料;以包覆后的空心微珠粉体为吸收荆制备吸波涂层,当涂层厚度为3 mm时,在4.32GHz达到最强吸收-20.81 dB,当涂层厚度为1.5 mm时,在8.56～10.08 GHz内出现了小于-10 dB的较宽吸收.     

脲醛树脂包覆对片状羰基铁粉电磁吸波性能的影响

目的 提高片状羰基铁粉（FCI）的吸波性能。方法 采用原位聚合法制备脲醛树脂（UF）包覆片状羰基铁粉核壳复合粒子。通过透射电子显微镜（TEM）和X射线衍射仪（XRD）分别对试验前后样品的微观形貌和物相组分进行表征。采用矢量网络分析仪对处理前后片状羰基铁粉在0.5～18 GHz频率范围内的电磁参数进行测试,基于传输线理论对其反射损耗曲线进行拟合分析。结果 微观形貌及X射线衍射谱结果表明,成功合成了脲醛树脂包覆片状羰基铁粉复合粒子（FCI@UF）。对测得的电磁参数进行分析,与原始片状羰基铁粉相比,包覆后铁粉介电常数和磁导率的实部、虚部均呈下降趋势,电磁波衰减能力减弱,与空气的阻抗匹配能力增强。反射损耗曲线图中,包覆后铁粉能有效吸收频带变宽（以反射损耗小于-10dB的带宽作为有效吸收频带）,由3.15 GHz变为4.38 GHz,在13.84 GHz时有最小反射损耗（-20.64 dB）,最小反射损耗向高频移动,最小值降低率达41.38%。结论 使用脲醛树脂对片状羰基铁粉进行包覆,制备了综合吸波性能更具优势的FCI@UF复合粒子,有效提高了片状羰基铁粉的吸波性能。     

Y-Fe-Cr合金的微波吸收性能

采用电弧熔炼法与高能球磨相结合的方法制备Y-Fe-Cr合金微粉,将制得的合金微粉放在真空石英管中在850℃下退火2h,采用XRD和SEM对合金粉的相结构及颗粒形貌进行分析,最后利用矢量网络分析仪对合金粉末的吸波性能进行分析;并以Y11Fe86Cr3为例研究热处理对Y-Fe-Cr合金微粉吸波性能的影响。结果表明:在吸波涂层厚度(d)为1.5mm的条件下,YxFe97-xCr3(x=7,9,11,13,摩尔分数,%)合金微粉都具有较好的宽频特性,在低频端,Y9Fe88Cr3的吸波性能优于其他合金的吸波性能,在7～18GHz频率范围内,Y7Fe90Cr3、Y11Fe86Cr3和Y13Fe84Cr3的反射率均小于-6dB;在d为1.8mm的条件下,在吸收峰附近,热处理后合金的反射率较热处理前的反射率得到明显改善,热处理前合金的吸收峰值为-10.5dB左右,而热处理后合金的吸收峰值达到-13.8dB左右,而且小于-10dB的带宽达到5GHz;在偏离吸收峰处,热处理不但达不到改善合金吸波性能的目的,甚至使合金的吸波性能变差。     

随机分布Fe纳米线复合材料的吸波性能

在具有纳米级孔洞的多孔氧化铝模板上,用电沉积方法制备出α-Fe纳米线有序阵列组装膜.用10%NaOH将纳米线溶液解离,并使之与树脂混合均匀,制成随机分布Fe纳米线/绝缘体复合吸波材料,并对其吸波性能进行了研究.研究结果表明:随铁纳米线体积分数的提高,随机分布的Fe纳米线/绝缘体复合吸波材料的电磁参数也随之增大;用测试电磁参数计算了不同厚度的反射率,体积分数为25%随机分布的铁纳米线/绝缘体的复合吸波材料最佳吸收厚度为1.14 mm;在9.7 GHz时,反射率达-45 dB,小于-5 dB时,反射率带宽达到9 GHz;随铁纳米线/绝缘体的复合吸波材料厚度的增加,吸收峰位向低频移动;随铁纳米线体积分数的增加,其吸收率明显增大,同时最佳吸收厚度也减小.     

FeCuNbSiB非晶带材/环氧树脂复合材料界面设计及其吸波性能（英文）

针对FeCuNbSiB非晶带材与环氧树脂基体不浸润的难题,通过表面化学改性,在FeCuNbSiB非晶带材两面分别生成一层厚度5～10μm、相结构为Cu_(0.75)Fe_(2.25)O_4和Fe_3O_4的界面层。结果表明:界面层与带材结合强度高,与环氧树脂浸润性好;以FeCuNbSiB非晶带材为增强材料,同时按FSS网络设计的FeCuNbSiB非晶带材/环氧树脂铺层在13～18 GHz频带出现R=-5～-10 dB的吸收峰。增加铺层数,吸收峰值不变,但吸收峰频带往低频率方向移动。利用此特性可以修正其它复合材料的雷达波吸波特性,拓宽吸收频带,增加吸波性能。     

环氧基复合吸波涂层的制备与性能研究

目的 制备综合吸波性能良好的复合吸波涂层。方法 选择炭黑和羰基铁粉进行机械混合,作为吸波剂加入到环氧树脂中进行吸波材料制备,利用扫描电子显微镜对炭黑和羰基铁粉分别进行微观形貌的观察。利用矢量网络分析仪在2～18 GHz内测试其电磁性能,研究炭黑和羰基铁粉含量及涂层厚度对吸波性能的影响规律。结果 通过观察微观形貌发现,炭黑颗粒较小,出现团聚和粘附性现象,羰基铁粉颗粒呈球状,表面光滑,分散性好。复合后的材料混合较均匀,羰基铁粉分散在基体中,与炭黑团配合能够提高材料的吸波性能。纯炭黑的吸波频带较窄,纯羰基铁粉的频带主要集中在中高频段,而复合后的吸波频段较宽,有着良好的吸波性能。炭黑质量分数为4%,羰基铁粉质量分数为250%,厚度为2 mm时,吸波涂层在9～18 GHz的微波吸收率超过90%,且反射损耗峰值达到近–45 dB。结论 炭黑和羰基铁粉复合后,吸波材料的吸波频带更宽,效果更好,解决了单一吸波剂涂层存在的吸波频带窄和集中于高频段的问题。通过调节涂层厚度,可以使材料在相对应的波段获得更好的吸波性能,从而得到更广泛的应用。     

羰基铁/NiLa_(0.02)Fe_(1.98)O_4双层宽频吸波体的构建及实现

根据电磁波传输线理论和阻抗匹配原理,设计羰基铁(CIP)/NiLa_(0.02)Fe_(1.98)O_4双层复合吸波材料,并以环氧树脂为基体制备相应的性能优异的吸波涂层。使用XDR和SEM对粉末和涂层的结构进行表征。通过同轴法测定CIP和NiLa_(0.02)Fe_(1.98)O_4的电磁参数,借助MATLAB软件,计算面层与底层不同厚度和不同次序条件下的反射率。结果表明:Ni La_(0.02)Fe_(1.98)O_4作为面层,CIP作为底层时可以极大地拓展涂层的吸收带宽和减小反射率峰值。以NiLa_(0.02)Fe_(1.98)O_4为面层,CIP为底层,厚度分别为1.5和0.6 mm时,涂层的吸波效果最好,反射率峰值为-38.2 dB,小于-10 dB频宽为13.4 GHz。制备的涂层中吸波剂总体分散良好,无明显缺陷。通过实验值和理论值的比较,验证优化结果的准确性,实现在较小厚度和较宽频带下,吸波涂层有较强吸收的要求。     

热喷涂纳米β-SiC/LBS涂层的吸波性能

应用喷雾造粒技术对纳米β-SiC/LBS复合吸波粉末进行团聚造粒,采用超音速火焰喷涂工艺制备高温纳米复合吸波涂层,并对复合涂层性能进行研究.结果表明,颗粒状β-SiC弥散在半熔融状态的LBS中形成涂层.涂层与基体的结合强度为8.46 MPa,拉伸过程中,涂层从内部撕裂,并表现为脆性断裂.与普通陶瓷吸波涂层相比,复合涂层的吸波性能得到扩展;随着涂层厚度的增加,复合涂层对电磁波的衰减能力将从高频向低频移动.受到涂层抗拉强度的限制,复合涂层的厚度应该小于1 mm.纳米β-SiC含量(质量分数)为46%时,复合涂层的电磁波反射率系数达到-13 dB;当在涂层厚度相同而微波频率大于14 GHz时,复合涂层的电磁波反射率系数均小于-10 dB.数值模拟结果表明,当β-SiC质量含量为46%时,复合涂层的吸波性能最佳.     

铁镍磁性合金粉的电磁与吸波性能研究

针对传统吸波材料在雷达波S波段的吸波性能较差,以多种铁镍磁性合金粉为吸波剂,硅橡胶为基体,制备不同组分的吸波材料.采用HP8722ET矢量网络分析仪对吸波材料的电磁与吸波性能进行了研究.结果表明:吸波材料的最小反射率为-19.5 dB,其对应的峰值频率为2.5 GHz,有效带宽(小于-8 dB)为1.9 GHz;吸波材料在S波段表现出优异的吸波性,具有良好的应用前景.     

基于双磁介质层复合的超材料低频吸波体研究

本研究将磁性吸波涂层融入至超材料的结构设计中,得到了一种新型低频复合超材料吸波体,吸波体由环形电阻膜、双层磁性吸波涂层和金属背板组成。采用CST仿真软件计算了超材料吸波体的吸收性能,研究了吸波体各个结构参数对吸收性能的影响。仿真结果表明,设计的超材料吸波体厚度为2.5 mm时,在1.9和4 GHz处存在2个吸收峰,在1.59～6.59GHz频率范围内反射损耗低于-8dB,吸收带宽达到5GHz。通过吸波体电磁场分布对吸波机理进行了讨论。结果表明,吸波体低频吸收带宽的增加是由于表面的电阻膜图案改变了超材料吸波体的电场分布和磁场分布,促进了磁介质层的损耗。最后制备了吸波体样品并进行了反射率测试,实物测试结果与仿真结果基本一致,说明设计制备的吸波体具有优异的低频吸波性能,吸波带宽相比磁性吸波涂层大幅提高。     

新型的治疗阿尔茨海默氏症药物(1-二甲基磷酰基-2,2,2-三氯)-乙基-1-醇烟酸醋对体外神经细胞的作用

目的: 观察本实验室合成的一种治疗阿尔茨海默氏症(AD)的药物(1-二甲基磷酰基-2, 2, 2 -三氯)-乙基^-1-醇烟酸醋(NMF),对体外培养的皮层神经细胞活性的影响以及对海人藻酸(KA)所致的神经损伤的保护作用。方法: 采用体外培养皮层神经元的方法,解剖分离 15 d胚胎小鼠皮层神经细胞, 接种于 96孔板,48 h 后加药并培养 72 h,以 MIT 法 观察 NMF 对小鼠皮层神经细胞活性的影响;同时将接种于 24 孔板的细胞预先给予 NMF,d 3 时加或不加KA处理后,以台盼蓝染色鉴别并计数死、活细胞,可得出细胞的存活率。结果: NMF 明显促进胎鼠皮层神经元活性,其中 NMF1、0. 1、10nmol·L^-1促进神经元活性增殖率分别高达 34.7%、37.4%、36. 7%, NMF 明显促进正常胎鼠皮层神经元存活卒,与对照组比较,10nmol·L^-1 NMF 对皮层神经元的存活率分别提高 39.3%、73.5%。 NMF能显著 对抗 KA 所致的神经元损伤,与 KA 损伤组相比, NMF0.1、10、10nmol·L^-1对损伤皮层神经元的保护率分别为 77.30%、80.10%、84.15%。结论: NMF 明 显促进胎鼠皮层神经元的洁性、提高正常皮层神经元,的存活卒,并能有效地保护KA所致的神经元损伤,提示 NMF 是一种很有潜力的治疗 AD 的药物。     

Three-Dimensional Growth of Coherent Ferrite in Austenite: A Molecular Dynamics Study

Coherent second phase often exhibits anisotropic morphology with specifi c orientations with respect to both the second and the matrix phases. As a key feature of microstructure, the morphology of the coherent particles is essential for understanding the second-phase strengthening eff ect in various industrial alloys. This letter reports anisotropic growth of coherent ferrite from austenite matrix in pure iron based on molecular dynamics simulation. We found that the ferrite grain tends to grow into an elongated plate-like shape, independent of its initial confi guration. The fi nal shape of the ferrite is closely related to the misfi t between the two phases, with the longest direction and the broad facet of the plate being, respectively, consistent with the best matching direction and the best matching plane calculated via the Burgers vector content(BVC) method. The strain energy calculation in the framework of Eshelby's inclusion theory verifi es that the simulated orientation of the coherent ferrite is energetically favorable. It is anticipated that the BVC method will be applicable in analysis of anisotropic growth and morphology of coherent second phase in other phase transformation systems.     

Rheology Feature of Simple Metal Melt

The rheology feature of Sb, Bi melt and alloys was studied using coaxial cylinder high-temperature viscometer. The results showed that the curve of torsion-rotational speed for Sb melt presents a linear relation in all measured temperature ranges, whereas for the Bi melt, the curve presents obvious non-Newtonian feature within the low temperature range and at relative high shear stress. The rheology feature of Sb80Bi20 and Sb20Bi80 alloy melts was well correlated with that of Sb and Bi, respectively. It is considered that the rheology behavior of Sb melt plays a crucial role in Sb80Bi20 alloy and that of Bi melt plays a crucial role in Sb20Bi80 alloy.     

Effect of Short-Time Aging on the Pitting Corrosion Behavior of a Novel Lean Duplex Stainless Steel 2002

The effect of short-time aging in the temperature range between 400 and 1000 °C on the pitting corrosion behavior and mechanical property of a novel lean duplex stainless steel(LDSS) 2002 was investigated through the potentiostatic critical pitting temperature(CPT) tests and the Charpy impact tests. Both the pitting corrosion resistance and the toughness of aged specimens degraded due to the precipitation of detrimental secondary phases and the most significant reduction of CPT and impact energy emerged at 650 °C concurrently. The CPT of LDSS 2002 specimen aged at 650 °C decreased by 28 °C, and the impact energy dropped from 69 to 29 J/cm~2 compared with the solution-annealed sample. Transmission electron microscopy characterization showed that the main precipitates in LDSS 2002 were Cr_2N and M_(23)C_6 along the ferrite–austenite grain boundaries.     

INTRODUCTION TO PATENTS

The invention provides a method of making a mold which can reduce SOx generation rate while preventing decrease in hardening rate in the case of using sulfuric acid for a hardener composition. The method has a mixture step in which fire-resistant particles, a hardener composition and a binder composition are mixed to obtain a composition for a mold. The hardener composition contains sulfuric acid. In the mixture step, sodium carbonate is added. A molar ratio of the sulfuric acid to the sodium carbonate is 0.5 or more and 4.0 or less.     

China Foundry Week 2014

China Foundry Week, hosted by the Foundry Institution of Chinese Mechanical Engineering Society （FICMES） each year, is a large academic event in China. It is one of the ten high-impact activities sponsored by the Chinese Mechanical Engineering Society.     

17th Conference of Hydrodynamic and Electromechanical Control Engineering Call for papers

正1.Contents In order to promote the academic exchanges and technical communication of the research in the field of fluid power transmission and control,fluid control engineering specialized committee of the Chinese Society of Theoretical and Applied Mechanics will hold the 17th Conference of Hydrodynamic and Electromechanical Control Engineering on July 27-29,2014 in Tibet,Lhasa city.     

Information for Contributors

正The Transactions of Nonferrous Metals Society of China,founded in 1991 and sponsored by The Nonferrous Metals Society of China,is published monthly now and mainly contains reports of original research which reflect the new progresses in the field of nonferrous metals science and technology,including mineral processing,extraction metallurgy,metallic materials and heat treatments,metal working,physical metallurgy,powder metallurgy,with the emphasis     

Preface

<正>We are pleased to present this Special Issue of Transactions of Nonferrous Metals Society of China containing selected papers from the First Asian Conference on Aluminum Alloys(ACAA-2013),held in Beijing,China,13–17 October 2013.This conference has been initiated,with approval of     

Information for Contributors

The Transactions of Nonferrous Metals Society of China, founded in 1991 and sponsored by The Nonferrous Metals Society of China, is published monthly now and mainly contains reports of original research which reflect the new progresses in the field of nonferrous metals science and technology, including mineral processing, extraction metallurgy, metallic materials and heat treatments, metal working, physical metallurgy, powder metallurgy, with the emphasis on fundamental science. It is the unique preeminent publication in English for scientists, engineers, under/post-graduates on the field of nonferrous metals industry. This journal is covered by many famous abstract/index systems and databases such as SCI Expanded, Ei Compendex Plus, 1NSPEC, CA, METADEX, AJ and JICST.