退火温度对激光熔覆AlFeCrCoNiTi高熵合金涂层组织与性能的影响

采用激光熔覆法制备AlFeCrCoNiTi高熵合金涂层,研究涂层经600、800和1200℃退火处理后的组织和性能。结果表明:快速凝固抑制了该合金涂层金属间化合物的析出,涂层组织为树枝晶结构,主要由体心立方固溶体(BCC)构成,具有较高的硬度,其平均显微硬度为698HV;经不同温度退火后,涂层组织长大不明显,硬度没有明显下降,相结构和硬度的高温稳定性好;Fe、Al在枝晶中富集,而Cr、Co、Ni、Ti在枝晶间富集;随着退火温度升高,偏析程度加剧。     

奥氏体不锈钢表面激光熔覆锆涂层的组织及硬度

为了提高常用奥氏体不锈钢的表面性能,延长其服役寿命,拓宽其使用价值,采用激光熔覆技术在一种典型奥氏体不锈钢表面制备了锆涂层,借助金相显微镜、XRD、ECC、EDS对熔覆涂层的微观组织进行了表征,利用维氏硬度测试仪对熔覆涂层和基体的硬度进行了测试。结果表明,锆涂层与基体具有良好的冶金结合,其中涂层晶粒主要呈树枝晶形貌,基体晶粒主要呈含退火孪晶的等轴晶形貌。激光熔覆涂层中Zr、Si元素主要富集在枝晶内,Fe、Cr元素主要富集在枝晶间,Ni、Mn元素分布较均匀。涂层区的硬度(约743.2 HV0.1)相较于基体区(230.5 HV0.1)有了显著提升,约为基体的3.2倍。这可能与涂层部分形成的枝晶结构的微观组织和其中的元素偏聚有关,此外第二相强化也不可忽视。     

退火对激光熔覆CoCrFeNiB_(0.5)高熵合金涂层组织与电化学性能的影响

采用激光熔覆在45钢基体上制备了CoCrFeNiB_(0.5)高熵合金涂层,研究了不同退火温度(700、900、1100℃)对涂层组织及性能的影响。结果表明,涂层激光熔覆态相组成主要为fcc相+少量bcc相,显微组织主要为枝晶组织;退火后,相组成转变为fcc+bcc+M_xB的混合相结构;700℃退火后,枝晶略有粗化,更高温度退火使枝晶断开,枝晶组织逐渐消失;1100℃退火后出现明显的颗粒化、球化相组织;激光熔覆涂层显微硬度较高,最高达到603 HV;700、900℃退火后,由于第二相析出强化,涂层显微硬度略有提高,但1100℃退火后涂层显微硬度下降;CoCrFeNiB_(0.5)涂层具有较高的腐蚀电位与较低的腐蚀电流密度,耐腐蚀性能明显优于45钢;1100℃退火后,3.5%NaCl溶液中腐蚀电流密度比45钢基体低3个数量级,具有较好的耐腐蚀性能。     

激光熔覆等离子喷涂Al2O3陶瓷涂层组织结构研究

研究了45钢表面激光熔覆等离子喷涂Al2O3陶瓷涂层的组织结构、显微硬度及滑动磨损特性.结果表明,等离子喷涂Al2O3涂层的组织呈层片状,层间为机械结合,涂层由α-Al2O3, ZrO2和少量γ-Al2O3组成;激光熔覆Al2O3陶瓷涂层组织为细小枝状晶,由α-Al2O3及少量ZrO2组成.激光熔覆Al2O3涂层的显微硬度较高,滑动磨损时耐磨性明显优于等离子Al2O3喷涂层.     

激光熔覆AlCrCoFeNiMoTi0.75Si0.25高熵合金涂层刀具的性能

利用激光熔覆技术制备了AlCrCoFeNiMoTi0.75Si0.25高熵合金涂层刀具,研究了激光快速凝固和经过1 000℃退火处理的AlCrCoFeNiMoTi0.75Si0.25高熵合金涂层微观组织和硬度、摩擦磨损性能,并比较了普通高速钢及高熵合金涂层刀具的切削加工性能。结果表明:激光熔覆AlCrCoFeNiMoTi0.75Si0.25高熵合金涂层的主要相结构为bcc相,涂层具有较好的高温稳定性。激光熔覆高熵合金涂层刀具表面硬度高,摩擦因数小,断屑效果好,被加工材料表面光洁度高。     

重熔及退火对316L不锈钢激光熔覆层残余应力的影响

选用316L不锈钢粉末在Q235钢板上进行激光熔覆,并对熔覆试样进行了激光重熔和退火处理。利用盲孔法对熔覆层及基体的残余应力进行测试,采用光学显微镜、维氏硬度计对熔覆层进行微观组织观察和硬度测试。结果表明,激光重熔后熔覆层组织结构未发生显著改变;熔覆层经600 ℃退火2 h后晶粒有轻微长大,经800 ℃退火2 h后发生再结晶,枝状晶数量减少。经过激光重熔和退火工艺后,显微硬度仍维持较高值。激光重熔最多能使残余应力降低55.9%,而合理的退火处理工艺能使残余应力降低70%以上, 800 ℃退火2 h时残余应力的改善效果最显著,残余应力降低了83.8%。     

Al/Si比例对TC4合金表面激光熔覆Ti-Al-Si涂层组织与摩擦性能的影响

以不同Al/Si比例的Ti-Al-Si复合粉末为原料,采用激光熔覆技术在TC4合金表面制备Ti-Al-Si涂层,研究了Al/Si比例对涂层物相、微观组织、显微硬度及摩擦磨损性能的影响。结果表明,单道熔覆的涂层中没有发现明显的裂纹及气孔,涂层与基体之间呈现良好的冶金结合。不同Al/Si比例涂层中组织均以熔断的枝晶为主,枝晶的成分主要为α-Ti,增强相为板条状的Ti₅Si₃及Ti₇Al₅Si₁₂,枝晶间主要是TiAl、Ti₃Al、TiAl₃金属间化合物。Si元素含量越高,涂层中原位生成的增强相的含量越多,涂层的显微硬度也比较高,最高可达1194 HV0.1,约为基体的4.1倍,但增强相过多会使涂层的脆性增加,耐磨性降低。Al元素含量较多时,组织细化效果明显,增强相对硬度和耐磨性能的影响比晶粒细化的作用更强。     

退火对激光熔覆制备FeCrNiCoMn高熵合金涂层组织与性能的影响

采用气雾化法制备了FeCrNiCoMn合金粉末,并在45钢基体上激光熔覆制备出了FeCrNiCoMn高熵合金涂层。分别采用SEM、EDS、XRD对粉末、涂层的微观形貌及相结构进行了分析,并测试了涂层的硬度。对涂层在300℃、550℃、700℃时退火4 h,研究涂层的抗高温软化性。结果表明:气雾化制备的合金粉末具有较好的球形度,FeCrNiCoMn涂层由单一的FCC相构成,组织为椭球状的枝晶与枝晶间形貌;不同温度退火后的涂层保持FCC相不变;在550℃以下退火,涂层组织无变化,但在700℃退火后,涂层组织变化明显;退火前后涂层的硬度无明显变化。     

激光熔覆MoSi2粉末涂层的组织结构和性能

用XRD、SEM、EDAX和显微硬度仪研究了 4 5钢基体激光熔覆MoSi2 粉末涂层的组织结构和硬度。结果表明 ,由于基体的稀释作用 ,涂层的相组成为FeMoSi、Fe2 Si和少量的Mo5Si3 。涂层组织呈现典型的细小枝晶组织特征 ,枝晶为FeMoSi领先相 ,枝晶间为FeMoSi和Fe2 Si两相共晶 ,组织中无孔隙和裂纹等缺陷。Mo、Si、Fe线扫描成分分析表明 ,这些元素都分布在涂层 基体界面处 ,且缓慢过渡 ,基体与涂层发生互扩散 ,为冶金结合。涂层硬度可达 84 5HV0 5 ,基体硬度为 180HV0 5 ,涂层硬度比基体高 3 7倍。从涂层到基体硬度逐渐降低 ,过渡区比较缓和。     

激光熔覆Ni-Si金属硅化物复合材料涂层显微组织与耐蚀性

以Ni,Si,Cr元素粉末为原料 ,利用激光熔覆技术在A3钢表面制得了Ni Si金属硅化物复合材料涂层。分析了该涂层的显微组织 ,采用测定阳极极化曲线的方法评价了该涂层在 0 .5mol/LH2 SO4 及 3 .5 %NaCl水溶液中的耐蚀性能。结果表明 :激光熔覆Ni Si金属硅化物复合材料涂层组织由Ni2 Si初生胞状树枝晶及枝晶间少量FeNi/Ni31Si12 共晶组成 ,涂层表面平整、组织细小、与基体间为完全冶金结合 ;涂层组织显微硬度在HV80 0～ 95 0之间且沿层深分布均匀 ;由于涂层组织组成相Ni2 Si和Ni31Si12 等本身均具有很好的耐蚀性并具有快速凝固细小均匀的显微组织 ,激光熔覆Ni Si金属硅化物复合材料涂层在 0 .5mol/LH2 SO4 及 3.5 %NaCl水溶液中均表现出优良的耐蚀性能。激光熔覆Ni Si金属硅化物复合材料涂层可望成为一种很有发展前景的耐蚀涂层新材料。     

新型的治疗阿尔茨海默氏症药物(1-二甲基磷酰基-2,2,2-三氯)-乙基-1-醇烟酸醋对体外神经细胞的作用

目的: 观察本实验室合成的一种治疗阿尔茨海默氏症(AD)的药物(1-二甲基磷酰基-2, 2, 2 -三氯)-乙基^-1-醇烟酸醋(NMF),对体外培养的皮层神经细胞活性的影响以及对海人藻酸(KA)所致的神经损伤的保护作用。方法: 采用体外培养皮层神经元的方法,解剖分离 15 d胚胎小鼠皮层神经细胞, 接种于 96孔板,48 h 后加药并培养 72 h,以 MIT 法 观察 NMF 对小鼠皮层神经细胞活性的影响;同时将接种于 24 孔板的细胞预先给予 NMF,d 3 时加或不加KA处理后,以台盼蓝染色鉴别并计数死、活细胞,可得出细胞的存活率。结果: NMF 明显促进胎鼠皮层神经元活性,其中 NMF1、0. 1、10nmol·L^-1促进神经元活性增殖率分别高达 34.7%、37.4%、36. 7%, NMF 明显促进正常胎鼠皮层神经元存活卒,与对照组比较,10nmol·L^-1 NMF 对皮层神经元的存活率分别提高 39.3%、73.5%。 NMF能显著 对抗 KA 所致的神经元损伤,与 KA 损伤组相比, NMF0.1、10、10nmol·L^-1对损伤皮层神经元的保护率分别为 77.30%、80.10%、84.15%。结论: NMF 明 显促进胎鼠皮层神经元的洁性、提高正常皮层神经元,的存活卒,并能有效地保护KA所致的神经元损伤,提示 NMF 是一种很有潜力的治疗 AD 的药物。     

Three-Dimensional Growth of Coherent Ferrite in Austenite: A Molecular Dynamics Study

Coherent second phase often exhibits anisotropic morphology with specifi c orientations with respect to both the second and the matrix phases. As a key feature of microstructure, the morphology of the coherent particles is essential for understanding the second-phase strengthening eff ect in various industrial alloys. This letter reports anisotropic growth of coherent ferrite from austenite matrix in pure iron based on molecular dynamics simulation. We found that the ferrite grain tends to grow into an elongated plate-like shape, independent of its initial confi guration. The fi nal shape of the ferrite is closely related to the misfi t between the two phases, with the longest direction and the broad facet of the plate being, respectively, consistent with the best matching direction and the best matching plane calculated via the Burgers vector content(BVC) method. The strain energy calculation in the framework of Eshelby's inclusion theory verifi es that the simulated orientation of the coherent ferrite is energetically favorable. It is anticipated that the BVC method will be applicable in analysis of anisotropic growth and morphology of coherent second phase in other phase transformation systems.     

Effect of Short-Time Aging on the Pitting Corrosion Behavior of a Novel Lean Duplex Stainless Steel 2002

The effect of short-time aging in the temperature range between 400 and 1000 °C on the pitting corrosion behavior and mechanical property of a novel lean duplex stainless steel(LDSS) 2002 was investigated through the potentiostatic critical pitting temperature(CPT) tests and the Charpy impact tests. Both the pitting corrosion resistance and the toughness of aged specimens degraded due to the precipitation of detrimental secondary phases and the most significant reduction of CPT and impact energy emerged at 650 °C concurrently. The CPT of LDSS 2002 specimen aged at 650 °C decreased by 28 °C, and the impact energy dropped from 69 to 29 J/cm~2 compared with the solution-annealed sample. Transmission electron microscopy characterization showed that the main precipitates in LDSS 2002 were Cr_2N and M_(23)C_6 along the ferrite–austenite grain boundaries.     

INTRODUCTION TO PATENTS

The invention provides a method of making a mold which can reduce SOx generation rate while preventing decrease in hardening rate in the case of using sulfuric acid for a hardener composition. The method has a mixture step in which fire-resistant particles, a hardener composition and a binder composition are mixed to obtain a composition for a mold. The hardener composition contains sulfuric acid. In the mixture step, sodium carbonate is added. A molar ratio of the sulfuric acid to the sodium carbonate is 0.5 or more and 4.0 or less.     

China Foundry Week 2014

China Foundry Week, hosted by the Foundry Institution of Chinese Mechanical Engineering Society （FICMES） each year, is a large academic event in China. It is one of the ten high-impact activities sponsored by the Chinese Mechanical Engineering Society.     

17th Conference of Hydrodynamic and Electromechanical Control Engineering Call for papers

正1.Contents In order to promote the academic exchanges and technical communication of the research in the field of fluid power transmission and control,fluid control engineering specialized committee of the Chinese Society of Theoretical and Applied Mechanics will hold the 17th Conference of Hydrodynamic and Electromechanical Control Engineering on July 27-29,2014 in Tibet,Lhasa city.     

Information for Contributors

正The Transactions of Nonferrous Metals Society of China,founded in 1991 and sponsored by The Nonferrous Metals Society of China,is published monthly now and mainly contains reports of original research which reflect the new progresses in the field of nonferrous metals science and technology,including mineral processing,extraction metallurgy,metallic materials and heat treatments,metal working,physical metallurgy,powder metallurgy,with the emphasis     

Preface

<正>We are pleased to present this Special Issue of Transactions of Nonferrous Metals Society of China containing selected papers from the First Asian Conference on Aluminum Alloys(ACAA-2013),held in Beijing,China,13–17 October 2013.This conference has been initiated,with approval of     

Information for Contributors

The Transactions of Nonferrous Metals Society of China, founded in 1991 and sponsored by The Nonferrous Metals Society of China, is published monthly now and mainly contains reports of original research which reflect the new progresses in the field of nonferrous metals science and technology, including mineral processing, extraction metallurgy, metallic materials and heat treatments, metal working, physical metallurgy, powder metallurgy, with the emphasis on fundamental science. It is the unique preeminent publication in English for scientists, engineers, under/post-graduates on the field of nonferrous metals industry. This journal is covered by many famous abstract/index systems and databases such as SCI Expanded, Ei Compendex Plus, 1NSPEC, CA, METADEX, AJ and JICST.     

Rheology Feature of Simple Metal Melt

The rheology feature of Sb, Bi melt and alloys was studied using coaxial cylinder high-temperature viscometer. The results showed that the curve of torsion-rotational speed for Sb melt presents a linear relation in all measured temperature ranges, whereas for the Bi melt, the curve presents obvious non-Newtonian feature within the low temperature range and at relative high shear stress. The rheology feature of Sb80Bi20 and Sb20Bi80 alloy melts was well correlated with that of Sb and Bi, respectively. It is considered that the rheology behavior of Sb melt plays a crucial role in Sb80Bi20 alloy and that of Bi melt plays a crucial role in Sb20Bi80 alloy.