AZ91镁合金的形变热处理

用金相显微镜、扫描电镜等分析手段及力学性能测试,研究了形变热处理对AZ91合金组织及力学性能的影响。结果表明,AZ91镁合金拉伸变形主要是以孪生的方式进行。拉伸变形后的合金经时效处理时,β-Mg17Al12首先在孪晶内及孪晶界处弥散析出,随着时效时间的延长,析出物的量不断增加。当孪晶内析出物的量达到一定值时,在晶界处出现了非连续的片层状β-Mg17Al12相,晶内也出现了少量的连续析出的β-Mg17Al12相。未发生变形的AZ91镁合金时效处理时,β-Mg17Al12相仅在晶界处以非连续的方式呈片层状形式析出。AZ91镁合金变形试样经时效处理后,其室温抗拉强度均高于经过相同工艺时效处理后的未变形试样,且当时效时间为12 h时达到最大值。     

AZ61镁合金的差热分析及凝固组织观察

通过差热分析并结合金相组织观察的方法研究了AZ61镁合金相变温度点和凝固组织的特征,并对凝固组织演变机理做了理论分析。结果表明:AZ61镁合金固液转变温度在587.10~608.43℃之间,共晶转变温度在413℃左右;AZ61镁合金在凝固过程中首先析出α-Mg树枝晶,α-Mg树枝晶间富Al的残余液体发生共晶转变,形成α-Mg+β-Mg17Al12共晶组织。共晶组织中的α-Mg相往往依附初晶α-Mg形核生长,并将β-Mg17Al12相推向α-Mg枝晶的晶界,形成离异共晶组织。     

固溶处理对AZ80镁合金显微组织的影响

采用光学显微镜(OM)、X射线衍射(XRD)、扫描电镜(SEM)研究了固溶工艺对AZ80镁合金时效处理后显微组织的影响.研究发现,不同固溶工艺获得的组织对200 ℃时效处理后β-Mg17Al12相的析出方式、数量及形貌有较大的影响.时效处理4 h后,析出方式以不连续析出为主,固溶不彻底的合金时效析出相较多;时效时间延长至12 h时,固溶彻底的合金其析出方式以晶内的连续析出为主,连续析出相阻止了晶界处不连续析出相的形核与长大,而固溶不彻底的合金其析出方式仍然以不连续析出为主,部分析出相向α-Mg晶粒内生长.     

时效时间对锻造AZ80镁合金腐蚀性能影响(英文)

通过浸泡实验、析氢实验、SEM和极化曲线测试研究在170°C下不同时效时间对锻造AZ80镁合金腐蚀性能的影响。结果表明:在时效初期阶段,锻造AZ80镁合金腐蚀速率随着时效时间的延长而急剧降低,而时效时间超过20 h后腐蚀速率又缓慢上升。当时效时间小于20 h时,β-Mg17Al12含量随时效时间的延长不断增加,锻造AZ80镁合金腐蚀速率降低;时效39 h后,β相长大,基体中铝含量降低,导致随着时效时间的延长合金腐蚀速率上升。当β-Mg17Al12相含量较低时,试样容易产生点蚀,试样表面呈多孔蜂窝状;反之,当β-Mg17Al12相含量较高时,试样腐蚀较均匀。     

喷射成形Mg-9Al-xZn合金的微观组织演变

利用喷射成形技术制备AZ91、AZ92和AZ93镁合金沉积柱坯,并对其微观组织演变进行观察.结果表明:铸态普通凝固AZ91合金的晶粒粗大,脆性β-Mg17Al12相连续分布成网状结构;而喷射成形AZ91、AZ92和AZ93合金的组织均匀,晶粒被充分细化,β-Mg17Al12相的网状结构被打破;喷射沉积快速凝固条件下高的冷却速率促进了过饱和α-Mg固溶体组织的形成,使得偏析相减少,形态改善;Zn含量的增加降低了Al在Mg中的溶解极限,促进了β-Mg17Al12相在晶界的析出及α-Mg+β-Mg17Al12离异共晶组织的形成;Zn元素的偏析倾向为激活成分过冷区内的形核质点提供了驱动力,从而阻碍了晶粒长大.     

磁场频率对AZ91合金焊接接头直接时效的组织和性能的影响

对AZ91镁合金板进行钨极氩弧焊（TIG）,并在焊接过程中施加了不同频率纵向交流磁场,焊后对焊接接头直接进行了时效处理,并和焊后固溶时效处理方式进行了对比。结果表明：随着磁场频率的增加,AZ91镁合金焊接接头经直接时效处理后,焊缝中的β-Mg17Al12相由连续状析出形态变成非连续状析出,其组织形态与焊后固溶时效相比,β-Mg17Al12相较粗大且数量减少;并随着磁场频率增加,直接时效后的焊接接头析出β-Mg17Al12相先变得均匀细小后又变得粗大,其接头的力学性能先变好后变差,而焊接接头的抗电化学腐蚀性先减小后增大。与固溶时效相比,直接时效后接头的力学性能较差,但耐腐蚀性能更好。     

AZ80镁合金热变形中第二相析出机理研究

对AZ80镁合金进行了等温平面压缩试验,利用扫描电子显微镜观察分析了不同温度变形后AZ80合金组织,主要研究AZ80镁合金在热压缩变形过程中其组织中第二相β-Mg17Al12的析出形态及其形成机理.结果表明,在200、250、300和350℃变形时,合金中的β-Mg17Al12相经直接变形破碎呈条状分布,变形温度越高,流线特征越明显;在400℃变形时,AZ80合金为单相α组织.但在变形后的水冷过程中,合金内部析出了块状的β-Mg17Al12相,经高倍观察为细小紧密的层片状组织.     

非平衡凝固AZ91D镁合金热稳定性及力学性能

采用铜模喷铸技术制备出AZ91D镁合金非平衡凝固试样,并对其热稳定性进行了研究。采用光学显微镜、扫描电镜、能谱分析仪及维氏显微硬度计对不同温度热处理镁合金的晶粒形貌、溶质含量及显微硬度变化进行对比研究。实验结果表明,当热处理温度200℃,保温时间240 min时,晶粒形貌未发生明显变化,但由于时效效应的存在,导致过饱和α-Mg固溶体中沉淀相析出,Al元素溶质含量有所下降,合金显微硬度略有升高。相同保温时间条件下,随热处理温度升高,β-Mg17Al12共晶相体积分数不断降低,固溶到基体中导致Al元素含量增加。与此同时,初生α-Mg相晶界逐渐清晰并发生明显的晶粒长大现象,合金显微硬度呈整体下降趋势。     

热处理对汽车用AZ91镁合金微观组织和力学性能的影响

研究了汽车用AZ91镁合金挤压后固溶时效处理对其微观组织和力学性能的影响。结果表明:AZ91镁合金的微观组织主要由基体α-Mg和约20.6wt%的β-Mg17Al12相组成,晶粒平均尺寸约为22μm。固溶处理后合金发生再结晶,β相完全回溶到α-Mg基体,约有15.6wt%的二次β相在时效过程中析出。AZ91镁合金在410℃固溶8 h后拉伸强度略微增大,而固溶处理16 h后拉伸强度降低。合金随后在200℃时效8~16 h的过程中析出细小二次β相,增加了晶内位错运动和晶界滑动阻力,使合金的拉伸强度逐渐增大。时效24 h后因细小二次β相的粗化而使合金力学性能降低。挤压态AZ91镁合金较优的固溶时效工艺为:410℃×8 h,空冷+200℃×16 h,空冷。     

热处理对细晶AZ91D镁合金组织和性能的影响

采用MEF-3金相显微镜、JSM-6700F扫描电镜、EMPA-1600电子探针以及WDW-100D型电子万能实验机等,对经Al-Ti-B细化处理的AZ91D镁合金铸态组织及固溶-时效态的显微组织和力学性能进行了观察和分析。结果表明：分布在铸态AZ91D镁合金晶界的网状β-Mg17Al12相在T4热处理过程中逐渐溶解,使得合金的硬度下降,而抗拉强度升高;T6热处理后,合金组织中出现不连续析出与连续析出的β-Mg17Al12相,使得抗拉强度和硬度明显提高;不同的热处理使合金的断口发生明显变化。     

新型的治疗阿尔茨海默氏症药物(1-二甲基磷酰基-2,2,2-三氯)-乙基-1-醇烟酸醋对体外神经细胞的作用

目的: 观察本实验室合成的一种治疗阿尔茨海默氏症(AD)的药物(1-二甲基磷酰基-2, 2, 2 -三氯)-乙基^-1-醇烟酸醋(NMF),对体外培养的皮层神经细胞活性的影响以及对海人藻酸(KA)所致的神经损伤的保护作用。方法: 采用体外培养皮层神经元的方法,解剖分离 15 d胚胎小鼠皮层神经细胞, 接种于 96孔板,48 h 后加药并培养 72 h,以 MIT 法 观察 NMF 对小鼠皮层神经细胞活性的影响;同时将接种于 24 孔板的细胞预先给予 NMF,d 3 时加或不加KA处理后,以台盼蓝染色鉴别并计数死、活细胞,可得出细胞的存活率。结果: NMF 明显促进胎鼠皮层神经元活性,其中 NMF1、0. 1、10nmol·L^-1促进神经元活性增殖率分别高达 34.7%、37.4%、36. 7%, NMF 明显促进正常胎鼠皮层神经元存活卒,与对照组比较,10nmol·L^-1 NMF 对皮层神经元的存活率分别提高 39.3%、73.5%。 NMF能显著 对抗 KA 所致的神经元损伤,与 KA 损伤组相比, NMF0.1、10、10nmol·L^-1对损伤皮层神经元的保护率分别为 77.30%、80.10%、84.15%。结论: NMF 明 显促进胎鼠皮层神经元的洁性、提高正常皮层神经元,的存活卒,并能有效地保护KA所致的神经元损伤,提示 NMF 是一种很有潜力的治疗 AD 的药物。     

Three-Dimensional Growth of Coherent Ferrite in Austenite: A Molecular Dynamics Study

Coherent second phase often exhibits anisotropic morphology with specifi c orientations with respect to both the second and the matrix phases. As a key feature of microstructure, the morphology of the coherent particles is essential for understanding the second-phase strengthening eff ect in various industrial alloys. This letter reports anisotropic growth of coherent ferrite from austenite matrix in pure iron based on molecular dynamics simulation. We found that the ferrite grain tends to grow into an elongated plate-like shape, independent of its initial confi guration. The fi nal shape of the ferrite is closely related to the misfi t between the two phases, with the longest direction and the broad facet of the plate being, respectively, consistent with the best matching direction and the best matching plane calculated via the Burgers vector content(BVC) method. The strain energy calculation in the framework of Eshelby's inclusion theory verifi es that the simulated orientation of the coherent ferrite is energetically favorable. It is anticipated that the BVC method will be applicable in analysis of anisotropic growth and morphology of coherent second phase in other phase transformation systems.     

Rheology Feature of Simple Metal Melt

The rheology feature of Sb, Bi melt and alloys was studied using coaxial cylinder high-temperature viscometer. The results showed that the curve of torsion-rotational speed for Sb melt presents a linear relation in all measured temperature ranges, whereas for the Bi melt, the curve presents obvious non-Newtonian feature within the low temperature range and at relative high shear stress. The rheology feature of Sb80Bi20 and Sb20Bi80 alloy melts was well correlated with that of Sb and Bi, respectively. It is considered that the rheology behavior of Sb melt plays a crucial role in Sb80Bi20 alloy and that of Bi melt plays a crucial role in Sb20Bi80 alloy.     

Effect of Short-Time Aging on the Pitting Corrosion Behavior of a Novel Lean Duplex Stainless Steel 2002

The effect of short-time aging in the temperature range between 400 and 1000 °C on the pitting corrosion behavior and mechanical property of a novel lean duplex stainless steel(LDSS) 2002 was investigated through the potentiostatic critical pitting temperature(CPT) tests and the Charpy impact tests. Both the pitting corrosion resistance and the toughness of aged specimens degraded due to the precipitation of detrimental secondary phases and the most significant reduction of CPT and impact energy emerged at 650 °C concurrently. The CPT of LDSS 2002 specimen aged at 650 °C decreased by 28 °C, and the impact energy dropped from 69 to 29 J/cm~2 compared with the solution-annealed sample. Transmission electron microscopy characterization showed that the main precipitates in LDSS 2002 were Cr_2N and M_(23)C_6 along the ferrite–austenite grain boundaries.     

INTRODUCTION TO PATENTS

The invention provides a method of making a mold which can reduce SOx generation rate while preventing decrease in hardening rate in the case of using sulfuric acid for a hardener composition. The method has a mixture step in which fire-resistant particles, a hardener composition and a binder composition are mixed to obtain a composition for a mold. The hardener composition contains sulfuric acid. In the mixture step, sodium carbonate is added. A molar ratio of the sulfuric acid to the sodium carbonate is 0.5 or more and 4.0 or less.     

China Foundry Week 2014

China Foundry Week, hosted by the Foundry Institution of Chinese Mechanical Engineering Society （FICMES） each year, is a large academic event in China. It is one of the ten high-impact activities sponsored by the Chinese Mechanical Engineering Society.     

17th Conference of Hydrodynamic and Electromechanical Control Engineering Call for papers

正1.Contents In order to promote the academic exchanges and technical communication of the research in the field of fluid power transmission and control,fluid control engineering specialized committee of the Chinese Society of Theoretical and Applied Mechanics will hold the 17th Conference of Hydrodynamic and Electromechanical Control Engineering on July 27-29,2014 in Tibet,Lhasa city.     

Information for Contributors

正The Transactions of Nonferrous Metals Society of China,founded in 1991 and sponsored by The Nonferrous Metals Society of China,is published monthly now and mainly contains reports of original research which reflect the new progresses in the field of nonferrous metals science and technology,including mineral processing,extraction metallurgy,metallic materials and heat treatments,metal working,physical metallurgy,powder metallurgy,with the emphasis     

Preface

<正>We are pleased to present this Special Issue of Transactions of Nonferrous Metals Society of China containing selected papers from the First Asian Conference on Aluminum Alloys(ACAA-2013),held in Beijing,China,13–17 October 2013.This conference has been initiated,with approval of     

Information for Contributors

The Transactions of Nonferrous Metals Society of China, founded in 1991 and sponsored by The Nonferrous Metals Society of China, is published monthly now and mainly contains reports of original research which reflect the new progresses in the field of nonferrous metals science and technology, including mineral processing, extraction metallurgy, metallic materials and heat treatments, metal working, physical metallurgy, powder metallurgy, with the emphasis on fundamental science. It is the unique preeminent publication in English for scientists, engineers, under/post-graduates on the field of nonferrous metals industry. This journal is covered by many famous abstract/index systems and databases such as SCI Expanded, Ei Compendex Plus, 1NSPEC, CA, METADEX, AJ and JICST.