共查询到19条相似文献,搜索用时 93 毫秒
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借助扫描电镜观察球铁中夹杂物并对其进行能谱分析,结合热力学计算结果研究了球铁中钛元素的热力学、动力学行为和含Ti夹杂物的组成、形貌、尺寸及分布状态.结果表明:在1 373~1 873 K,球铁中能够形成TiC、TiN、TiS、TiO2、Ti2O3和Ti3O5夹杂物,其中氧化物最易形成,其次为硫化物、氮化物和碳化物;球铁中存在TiC单相夹杂物,Ti-La-Ce-Mg-C-N-S稀土复相夹杂物和Ti-Mg-Si-C-N、 Ti-V-Si-C等复相夹杂物,夹杂物以多边形为主,尺寸在1~3 μm,分布在珠光体与铁索体基体中,少量夹杂物分布在晶界处.在钛与稀土元素的中和反应和含钛氧化物与碳的还原反应共同作用下,球铁中能形成大量富集稀土元素的含Ti复相夹杂物. 相似文献
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《铸造技术》2019,(10)
对大直径球墨铸铁型材中夹杂物的分布、尺寸、成分进行了研究。结果表明,主要的夹杂物聚集在型材中心线上方3/4R附近,多数呈丝状分布,且尺寸较大。SEM结果表明,几乎所有的丝状、块状及散落状的夹杂物都分布在铁素体中,且周围通常有退化石墨存在。颗粒状夹杂物则在铁素体和珠光体中都有分布。EDS和EPMA结果说明,由于RE-Mg球化剂与铁液中其他元素反应而导致的镁不足是促成多数夹杂物(尤其是丝状、块状和散落状夹杂物)形成的主要原因。夹杂物和退化石墨的存在对型材的力学性能不利。因此,选用合适的球化处理工艺及参数对防止夹杂物产生、保证大直径型材的组织与性能有重要的意义。 相似文献
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本文研究了气体保护条件下,常规熔铸的Mg-Gd-Y-Zr合金中夹杂物的形貌、分布及形成原因,并通过计算分析了夹杂物的沉降行为.结果表明,Mg-Gd-Y-Zr合金中有MgO或Y的氧化物为主的球状、簇状、不规则状、线状的复合夹杂物和含熔剂夹杂物,夹杂物的平均尺寸为12.7μm,平均体积分数为0.26%.夹杂物出现的频率随其尺寸增大而急剧减小,尺寸在20μm以下的夹杂物占夹杂物总体积接近85%,尺寸在45μm以下的夹杂物占96%.计算结果表明,夹杂物沉降速率与其尺寸和密度相关;夹杂物密度增大,可使镁合金中夹杂物的最大尺寸减小,计算得到的合金中最大夹杂物的尺寸与实验结果基本一致. 相似文献
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对大型汽轮机转子密集型缺陷进行解剖分析,通过低倍、高倍及能谱等研究手段,发现钙铝酸盐夹杂物和镁铝尖晶石夹杂物是造成锻件超声检测缺陷超标的原因。钙铝酸盐夹杂物来自于保护渣,镁铝尖晶石夹杂物来源于钢包炉衬耐火材料。 相似文献
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围绕车轴钢EA1N质量问题,对典型缺陷进行了剖切和磨制,采用SEM-EDS对其进行了能谱分析。研究发现缺陷的类型是以O、Al等元素为主,同时含有少量的Ca、Ti,偶尔出现含有Mg元素的夹杂类缺陷,由能谱分析可知,夹杂物是引起车轴钢EA1N出现缺陷的重要原因。在冶炼过程中,铝氧反应在钢液中形成大量的Al2O3夹杂物,在精炼渣、含镁耐火材料等因素的作用下,钢液中[Mg]、[Ca]等元素含量升高,Al2O3会转变为含有多种物相的复合夹杂物,未能上浮去除而滞留在钢中的夹杂物很容易在随后的轧制和热处理过程中产生危害,引发裂纹等缺陷,直接导致性能下降。本研究为进一步探究夹杂物与车轴钢缺陷的相关性提供了依据。 相似文献
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在Gleeble-3500热模拟试验机上,利用模拟轧制和卷取方法研究了不同S含量Ti-IF钢热轧成品第二相粒子的析出行为。试验结果表明,Ti-IF钢的析出物类型随着S含量的增加出现明显变化,当S质量分数为140×10-6时,大尺寸析出物中出现TiS单独析出情况,同时随着钢中S含量的增加,大尺寸析出物(200 nm以上)逐渐增多,主要析出物类型为TiS和Ti4C2S2;而小尺寸析出物(20 nm以下)逐渐减少,主要析出物类型为TiC。结合钢种的热力学分析可知,当S含量增加时,基体内固溶的C原子,首先满足Ti4C2S2形成的需要,其次再以TiC的形式析出,可见S元素对固定间隙C原子有明显作用,由此提出钢种设计时S元素含量按下限设定的理论。 相似文献
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L. M. Kuznetsov S. I. Stepanov V. A. Strizhak V. V. Kiselev O. A. Khomenko 《Metal Science and Heat Treatment》1988,30(2):126-129
Conclusion Inclusions of TiS during cutting of dispersion-hardening alloys initiates main crack generation ahead of the cutting edge and it is a solid structural lubricant which provides formation of a reduced level of residual stresses in the machined article.Translated from Metallovedenie i Termicheskaya Obrabotka Metallov, No. 2, pp. 32–34, February, 1988. 相似文献
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微米级钽粉(Ta)在生物医疗增材制造和其它制造领域具有广阔的应用前景。采用射频热等离子体对不规则钽粉进行球化处理以改善其流动性,对等离子体球化处理前后的钽粉进行了表征,并分析了球化过程中卫星粉的形成过程与机制。结果表明,经等离子体球化后的钽粉具有较为理想的球形度和光滑的表面,其霍尔流动性和表观密度分别从13.6 s·(50 g)-1提高到6.73 s·(50 g)-1和6.83 g·cm-3提升至9.06 g·cm-3,钽粉的球化率和球形度分别可约达95.2%和0.92;球化过程中卫星粉的形成主要是因液滴的碰撞所致,且随着送粉速度的增加,液滴碰撞概率增大,液滴的凝并使球形颗粒的粒径增大。 相似文献
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G. Wranglen 《Corrosion Science》1974,14(5):331-349
Pits are initiated at sulphide inclusions (usually MnS) in both carbon steels and stainless steels. In carbon steels, the attack starts in the matrix close to the sulphide inclusion which is more noble than the matrix. Some sulphides, termed “active”, initiate attack more easily than others, termed “inactive”. Active and inactive sulphides in carbon steels may be distinguished by a so-called micro-corrosion test (MCT). In stainless steels, the attack starts in the sulphide inclusion proper, which is less noble than the surrounding oxide film, and then spreads to the active metal below the sulphide inclusions. The propagation of a pit is, in principle, the same in both types of steel and depends upon the formation of a concentration cell in which the pit solution has a higher salt content, a higher acid content and a lower oxygen content than the surrounding bulk of the solution. The detrimental effect of S upon the corrosion properties of steels is counteracted by metals which form sulphides less soluble than FeS. These sparingly soluble sulphides may either be present in the steel (examples: TiS, CrS and VS) or form during the corrosion process (examples: the sulphides of W, Mo, Ni, Co, Zn, Cd, Sn, Pb, Cu, Ag, Bi and Hg). Of the latter metals, Cu is of particular importance. 相似文献
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Hidemasa Takana Juyong Jang Junji Igawa Tomoki Nakajima Oleg P. Solonenko Hideya Nishiyama 《Journal of Thermal Spray Technology》2011,20(3):432-439
For the further improvement of in-flight alumina spheroidization process with a low-power direct-current radiofrequency (DC-RF)
hybrid plasma flow system, the effect of a small amount of helium gas mixture in argon main gas and also the effect of increasing
DC nozzle diameter on powder spheroidization ratio have been experimentally clarified with correlating helium gas mixture
percentage, plasma enthalpy, powder in-flight velocity, and temperature. The alumina spheroidization ratio increases by helium
gas mixture as a result of enhancement of plasma enthalpy. The highest spheroidization ratio is obtained by 4% mixture of
helium in central gas with enlarging nozzle diameter from 3 to 4 mm, even under the constant low input electric power given
to a DC-RF hybrid plasma flow system. 相似文献
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对Ti-6Al-4V合金表面进行辉光离子渗硫处理后的显微组织、摩擦学特性进行了研究.结果表明:合金经离子渗硫处理后,渗层主要由TiS2、TiS、TiS3、Ti2S等硫化物组成;对处理前后试样的摩擦学性能研究显示,渗硫后试样在干摩擦纯滑动的情况下表现出良好的减摩性能,并对减摩机理进行了探讨. 相似文献
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An investigation on subcritical spheroidization anneal of the cold-rolled 50CrV4 steel at 720?°C has been carried out. During spheroidization anneal, the lamellar cementite was gradually broken down and changed to spherical shape. With prolonging of soaking time, the amount of lamellar cementite decreases gradually, and that of the spheroidized cementite particle increases gradually. The relationship of the spheroidization ratio versus soaking time for the steel can be described by a typically sigmoid curve. Additionally, the cold rolling deformation accelerates the breakup of lamellar cementite and the formation of spheroidal cementite particles during spheroidization anneal of the steel. The more severe the deformation is, the more rapidly the spheroidization occurs. From the results of tensile and hardness test, the yield strength, ultimate tensile strength, and hardness decrease and the percentage elongation to failure increases rapidly during the first 2?h of spheroidization. Between 2 and 8 h, the yield strength, ultimate tensile strength, hardness nearly keep a constant, which are independent of the soaking time, whereas the percentage elongation to failure firstly increases and then decreases with prolonging of soaking time. 相似文献