火焰喷焊对碳钢疲劳寿命的影响

对三种不同基材状态的45~3钢经表面火焰喷焊Ni60后的疲劳性能及腐蚀疲劳性能变化的研究,表明强度高的调质态基材喷焊后的疲劳极限下降7%,而正火态和轧态基材喷焊后疲劳极限提高14%。当有3.5%NaCl腐蚀介质存在时,不管基材强度高或低,表面喷焊都使材料的腐蚀疲劳强度(10~7寿命)提高30%以上。文中通过断口金相分析阐明喷焊后基材表面组织结构变化及其对疲劳裂纹形成及扩展的影响,讨论了Ni60喷焊层在腐蚀疲劳过程的行为,为喷焊工艺在工业中的应用提供了依据。     

Corrosion fatigue behavior of a steel with sprayed coatings

This paper describes the corrosion fatigue behavior and fracture mechanisms of a steel with different sprayed coatings. Rotating bending fatigue tests were conducted in 3% NaCl solution using specimens of a medium carbon steel with sprayed coatings of a ceramic (Cr₂O₃), a cermet (WC-12%Co) and two metals (Ni-11 % P and Al-2% Zn). The corrosion fatigue process was basically the same for ceramic, cermet, and Ni-11 % P sprayed specimens. That is, the corrosive media could be supplied from the specimen surface to the substrate through cracks initiated during fatigue cycling and/or pores in the coatings, and thus corrosion pits were generated followed by subsequent crack initiation and growth in the substrate. The corrosion fatigue strength of ceramic sprayed specimens was slightly improved compared to that of the substrate steel because the under-coating (Ni-5%A1) could impede the penetration of the corrosive media although the ceramic coating had a poor resistance to cracking under cyclic loading. Cermet sprayed specimens also exhibited improved corrosion fatigue strength because of the high resistance to cracking and the low volume fraction of pores of the coating. In Ni-11 % Psprayed specimens, cracks were initiated in the coating even at low stress levels; thus the corrosion fatigue strength was the same as that of the substrate. Anodic dissolution took place in Al-2 % Zn coating because the coating was electrochemically poor, and thus the substrate was cathodically protected. Therefore, the corrosion fatigue strength of Al-2 % Zn sprayed specimens was enhanced to as high as the fatigue strength of the substrate in room air. Based on the experimental results, a dual-layer coating consisting of WC-12%Co and Al-2%Zn was fatigue tested. The coating was effective at low stress levels and exhibited long life under conditions where corrosion fatigue strength was critical.     

植入铸造不锈钢髋关节断裂失效事例分析

利用ＳＥＭ对实际使用时断裂的髋关节的断口和表面进行了分析，认为此关节的断裂为以弯曲应力为主的腐蚀疲劳断裂。疲劳裂纹首先在表面的腐蚀点孕育产生，应力和腐蚀的共同作用使得裂纹得以扩展断裂。     

The effects of gas nitriding on fatigue behavior in titanium and titanium alloys

Fatigue behavior has been studied on gas-nitrided smooth specimens of commercial pure titanium, an alpha/beta Ti-6Al-4V alloy, and a beta Ti-15Mo-5Zr-3Al alloy under rotating bending, and the obtained results were compared with the fatigue behavior of annealed or untreated specimens. It was found that the role of the nitrided layer on fatigue behavior depended on the strength of the materials. Fatigue strength was increased by nitriding in pure titanium, while it was decreased in the Ti-6Al-4V and Ti-15Mo-5Zr-3Al alloys. Based on detailed observations of fatigue crack initiation, growth, and fracture surfaces, the improvement and the reduction in fatigue strength by nitriding in pure titanium and both alloys were primarily attributed to enhanced crack initiation resistance and to premature crack initiation of the nitrided layer, respectively.     

Electrochemical Behavior of Novel Superelastic Biomedical Alloys in Simulated Physiological Media Under Cyclic Load

The aim of the present work was to study corrosion and electrochemical behavior of Ti-22Nb-6Ta and Ti-22Nb-6Zr (at.%) superelastic alloys under conditions which imitate the performance mode of target devices (bone implants), i.e., under cyclic load in simulated physiological solutions. Open circuit potential (OCP) measurements were carried out on wire specimens in Hank’s solution and artificial saliva at 37 °C with various strain values up to 1.5%. It is shown that at clinically relevant strain values (about 0.2%) the alloys exhibit OCP growth indicating their high stability and resistance to corrosion fatigue under these cycling conditions. At much higher strains (about 1%), fatigue crack initiation and propagation take place, however, the corresponding OCP variation indicates that the fracture process is significantly restrained by reversible martensitic transformation during cycling.     

S135钻杆钢预腐蚀后的弯曲疲劳性能

目的：考察有机盐钻井液对S135钻杆材料腐蚀及疲劳性能的影响。方法首先利用高温高压釜模拟有机盐钻井液井筒的工况环境,对疲劳试样进行预腐蚀,通过点蚀仪测定试样表面的腐蚀状况;然后利用旋转弯曲疲劳试验机在不同弯曲应力条件下对预腐蚀试样和未腐蚀试样的疲劳性能进行测试,算得不同存活率下的疲劳强度,并绘制不同存活率下的S-N曲线。用体视显微镜和扫描电镜观察预腐蚀试样和未腐蚀试样的疲劳断口形貌,进而得出S135钻杆材料表面腐蚀对其疲劳寿命的影响程度和影响机制。结果经过腐蚀的试样表面有较多腐蚀坑,腐蚀坑深度在0.4~0.7 mm之间。未腐蚀试样的疲劳强度为553 MPa,其疲劳断口只观察到单个疲劳裂纹源;腐蚀试样的疲劳强度为409 MPa,其疲劳断口观察到多个疲劳裂纹源。 S135钻杆材料腐蚀疲劳开裂敏感性指数为26%。结论经过高温高压有机盐钻井液环境腐蚀后,试样表面点蚀严重,腐蚀坑底部存在应力集中并导致裂纹源的形成,多个裂纹源的同时生长加快了裂纹的扩展,最终降低S135钻杆钢的疲劳强度。     

外加电位对奥氏体不锈钢应力腐蚀与腐蚀疲劳交互作用的影响SCIEI

本文研究了0Cr18Ni9Ti奥氏体不锈钢在42%沸腾MgCl_2中,在低频,高平均应力循环载荷下的环境敏感断裂行为,研究了应力腐蚀疲劳与应力腐蚀在裂纹扩展规律及断口形貌上的差别与联系。从断裂特征上分析了应力腐蚀与腐蚀疲劳的交互作用,并着重研究了外加极化电位对这种交互作用的影响。     

EFFECT OF POTENTIAL ON INTERACTION BETWEEN STRESS CORROSION CRACKING AND CORROSION FATIGUE OF AUSTENITIC STAINLESS STEEL IN BOILING 42% MgCl_2 SOLUTION

The environment-sensitive fracture behaviour of 0Cr18Ni9Ti austenitic stainless steel inboiling 42% MgCl_2 under the specific load of low frequency and high mean stress was inves-tigated from the relations and differences of crack growth rates and fractographs betweenstress corrosion fatigue and stress corrosion cracking.The interaction between stress corro-sion cracking and corrosion fatigue was also studied from fracture characteristics with empha-sis on the effects of applied potential on the interaction.     

Untersuchungen zum SwRK-Verhalten des unlegierten Stahles Ck 45 in chloridionenhaltigen wäßrigen Medien

Corrosion fatigue behaviour of steel Ck 45 in aqueous solutions containing chloride ions The fatigue behaviour of carbon steel Ck 45 (comparable to AISI 1045x) is investigated for cyclic tension and rotating bending load with a frequency of 25 Hz. The fatigue limits under cyclic tension load in air are 410 N/mm² for smooth specimens and 290 N/mm² for notched specimens. For rotating bending load a value of 200 N/mm² is found for smooth specimen. The fatigue limits for N = 10⁷ in two different environments (0.3% and 3% NaCl-solution) reach only 37–57% of the according values in air. Cathodic protection of smooth specimens causes an improvement to 95% of the air fatigue limit. The evaluation of the free corrosion potential for all corrosion fatigue tests and the appearence of fracture show typical attributes of corrosion fatigue in the active state.     

Verbesserung des Schwingungsrißkorrosionsverhaltens von Stahlproben durch Beschichtung

Improvement of the corrosion fatigue behavior of steels by paint-coating Paint-coatings have been used extensively to prevent corrosion of steel. In order to investigate the influence of an anticorrosive paint on the corrosion fatigue strength of steel, specimens of SAE 4135 in a quenched and tempered state, and in salt bath nitrocarburized state, on the one hand, and specimens of the steel SAE 5115 in a salt bath carburized state, on the other hand, were subjected to comparative rotating bending fatigue tests in inert media and in aqueous 5 pct NaCl. The results demonstrate that the 5 pct NaCl environment is reducing fatigue life drastically, but the painting treatment, however, was found to improve significantly the corrosion fatigue life. Regarding the beneficial effect of the painting treatment on the corrosion fatigue behavior, a superiority of the nitrocarburized variant in contrast to the other variants was ascertained.