共查询到19条相似文献,搜索用时 140 毫秒
1.
本文通过组织观察、硬度测试和理论计算,研究了Al-14Cu-7Ce合金中片状Al8CeCu4相的高温球化行为。随着退火温度的升高,Al8CeCu4相的球化速度加快。采用通用速率公式计算出Al8CeCu4相的球化过程控制元素为Ce;微观组织观察表明,Al8CeCu4相球化过程包括Gibbs-Thompson 效应作用下片状相分解成棒状相,以及棒状相通过Rayleigh毛细管扰动机制分解成球状相。 相似文献
2.
研究了Al-4.0Cu-0.45Mg-0.4Ag-0.25Er合金铸态晶界相的组成及其生长规律.结果表明:稀土Er在合金中主要以Al8Cu4Er相的形式存在,Mg和Ag固溶于α-Al.合金铸态组织由α-Al固溶体、Al8Cu4Er相和Al2Cu相组成.Al8Cu4Er相和Al2Cu相共生于α-Al固溶体晶界,形成离异型共晶组织.凝固过程中,Al8Cu4Er相优先依附于先共晶相α-Al形核,并且分别以枝晶生长和平面生长这2种方式有选择的进行生长,形成α-Al、Al8Cu4Er相和Al2Cu相的三元共晶组织. 相似文献
3.
采用金相显微镜、差示扫描量热仪、扫描电镜及其能谱仪研究了Al-5.4Zn-2.0Mg-0.3Mn-0.25Cu-0.1Zr和Al-5.4Zn-2.0Mg-0.3Mn-0.35Cu-0.1Zr-0.25Sc两种合金的铸态及均匀化态显微组织演变与成分分布.结果表明:铸态组织以典型的枝晶结构存在,由过饱和的α-Al固溶体和α-Al+η-MgZn2的非平衡共晶相组成;铸态合金在470℃保温24 h,非平衡共晶相消失,合金枝晶偏析消除.确定合金铸锭的理想均匀化工艺参数为470℃×24 h. 相似文献
4.
采用金相显微镜(OM)及能谱仪(EDS),研究了Al-0.9Mg-0.9Si-0.6Cu-0.6Mn合金的铸态及其均匀化后的组织,并对合金的铸态组织及均匀化退火过程中相的演化进行了分析.结果表明:合金的铸态组织中存在大量的网状化合物和球状析出物,分别是α-Al+Ai(MnFe)3Si2的共品体和富铜相.均匀化退火过程中,随均匀化退火温度的升高,网状结构α-Al+Al(MnFe)3Si2的共晶体逐渐变成球状细小颗粒Al(MnFe)3Si2相,材料的微观组织得到改善.经560℃×6 h退火,均匀化过程基本完成,品粒未发生明显的粗化. 相似文献
5.
本文采用硬度测试、扫描电镜、图像分析和物理建模,研究了Al-14Cu-7Ce合金中Al8CeCu4相的Ostwald熟化行为。研究结果表明,Al8CeCu4相的熟化过程受控于Ce元素在Al中的体扩散,其动力学满足体积修正的Lifshits-Slyozov-Wagner理论;基于通用速率公式,计算了Ce元素在Al中的体扩散系数以及Al8CeCu4与Al基体的界面能。 相似文献
6.
采用金相显微镜(OM)及扫描电子显微镜(SEM),研究了Al-0.44Mg—1.15Si-0.32Cu-0.11Fe-0.11Cr-0.07Mn合金的铸态、均匀化组织,并对合金在凝固过程及均匀化退火后形成的相进行了分析。结果表明:合金的铸态组织中主要存在α—Al、Mg2Si、Si、β-Al5FeSi、α-Al(MnCr)FeSi、CuAl2和Al5Cu2Mg8Si6(Q)等相。均匀化退火后,Mg2Si、CuAl2和Q相消失,Si相聚集分布在晶界处。同时针状的β-Al5FeSi转变为颗粒状α-Al(MnCr)FeSi相,材料的组织得到改善。 相似文献
7.
测试了Al-14Cu-7Ce(质量百分数)铸造铝合金在室温至450℃内的高温短时拉伸性能,并采用扫描电镜分析不同温度下试样断口形貌和断裂行为.试验结果表明:温度低于200℃时,强度缓慢下降,且200℃下抗拉强度达到343.4 MPa;在200~450℃,强度迅速下降,但450℃下其抗拉强度仍能达到142.5MPa,表明合金具有良好的耐热能力.随着变形温度的升高,合金逐渐由脆性断裂转变为韧性断裂,在250℃下合金表现出混合断裂特征.此外,裂纹萌生都由Al8CeCu4相引发,在应力作用下形成裂纹源,并从Al8CeCu4相内部扩展导致开裂,之后裂纹扩展至基体并与前方裂纹相互连接,最终导致试样发生断裂. 相似文献
8.
采用光学显微镜(OM)、扫描电镜(SEM)、电子探针(EPMA)、波谱分析(WDS)、X射线衍射(XRD)以及差示扫描量热仪(DSC)等技术对Al-Zn-Mg-Cu-Zr-0.12Ce合金铸态组织及均匀化退火过程中的组织演变进行研究。结果表明:该合金铸态组织存在严重的枝晶偏析,主要由α(Al)基体、α(Al)+Mg(Zn,Al,Cu)_2非平衡共晶组织以及少量的θ(Al_2Cu)相、Al_8Cu_4Ce相、Al_7Cu_2Fe相构成;均匀化退火过程中,大量层片状共晶组织溶入基体,同时转变生成Al_2Cu Mg相;合金的过烧温度为474.87℃;合金的最佳单级均匀化退火工艺为465℃、40 h,这与均匀化动力学方程测算结果接近;合金经(435℃,8 h)+(470℃,32 h)双级均匀化退火处理后,回溶效果更好,主要残留相为难溶的Al_2CuMg相,少量含Fe杂质相以及Al_8Cu_4Ce相。 相似文献
9.
采用光学显微镜、扫描电镜、能谱分析、X射线衍射分析和差示扫描量热分析研究了Al-9.1Zn-1.9Mg-1.6Cu合金铸态与均匀化态显微组织及相组成演化规律。试验结果表明,该合金铸态组织中存在大量的非平衡低熔点共晶相,其初始熔化温度为475℃;合金铸态组织相组成包括α-Al、η-MgZn2及少量的Al7Cu2Fe相;在460℃以上均匀化后,该合金处于α-Al单相区,组织中非平衡低熔点共晶相均能固溶于基体内;465℃×24h是该合金适宜的均匀化处理工艺。 相似文献
10.
通过X射线衍射(XRD)、扫描电镜(SEM)、能谱(EDS)和金相(OM)分析,研究了Al-0.8Mg-1.0S-0.8Cu-0.3Mn-0.5Fe-0.15Zr合金的铸态组织,探讨了合金在均匀化退火前后析出相变化。结果表明:电磁搅拌铸锭的晶粒多呈等轴晶、析出相主要为Al2FeSi、Al9Fe0.84Mn2.16Si及Al4Cu2Mg8Si7,以及极少量的Mg2Si相和β-Si,但未观察到Al3Zr相。均匀化退火后,第二相质点分布均匀,Mg2Si相、Al4Cu2Mg8Si7相溶解消失,Mn元素替代了部分Fe元素,使(AlFeMnSi)相增多,针状β-Al2FeSi相转变为颗粒状α-Fe1.7Al4Si相,出现了Al3Zr相。 相似文献
11.
制备了Mg-5Li-3Al-2Zn-xCe(x=0-2.5;质量分数,%)铸态合金,并将所得合金分别于300°C和370°C进行均匀化和固溶处理;研究固溶处理后合金显微组织和拉伸性能的变化。结果表明,合金中加入Ce后出现Al2Ce/Al3Ce析出相,此时合金主要由α-Mg、Al2Ce、Al3Ce和AlLi相组成;固溶处理后合金中AlLi和Al-Ce析出相数量减少。析出相的数量与形态对合金的力学性能十分重要,含有1.0%Ce的合金获得了优良的拉伸性能。固溶处理后Mg-5Li-3Al-2Zn-0.5Ce合金的强度和伸长率都得到了大幅度的提高,这是因为合金在固溶处理后由于基体中的溶质原子增加而获得良好的固溶强化作用。 相似文献
12.
A systematic study on how Cu content affects the microstructure and mechanical properties of rheo-diecasting Al-6Zn-2Mg-xCu alloys during solution treatment and ageing heat treatment was conducted. The swirled enthalpy equilibrium device (SEED) was adopted to prepare the semi-solid slurry of Al-6Zn-2Mg-xCu alloys. The microstructure development and mechanical properties were studied using optical microscopy (OM), scanning electron microscopy (SEM), X-ray diffraction (XRD), differential scanning calorimetry (DSC), as well as hardness and tensile testing. The grain boundary and shape factor were calculated using image processing software (Image-Pro Plus 6.0). Results show that the alloys are composed of typical globular primary α-Al grains, eutectic phases, and smaller secondary α-Al grains. After solution and ageing heat treatment, the eutectic phases are dissolved into Al matrix when the Cu content is lower than 1.5wt.%, while some eutectic phases transform into Al2CuMg (S) phases and remain at grain boundaries when Cu content reaches 2wt.%. T6 heat treatment significantly enhances the mechanical properties of rheo-diecasting Al-6Zn-2Mg-xCu alloys. When Cu concentration is 0.5wt.%–1.5wt.%, the ultimate tensile strength, yield strength and elongation of T6 treated alloys rise to around 500 MPa, 420 MPa, and 18%, respectively. 相似文献
13.
采用热分析、光学显微镜技术、扫描电镜技术、聚焦离子束和能量色散谱分析方法研究Ce对Al-Si-Cu合金中α(Al)-Al2Cu共晶形貌的影响。结果表明,在枝晶、硅和AlSiFeMn之间较小空间内形成了α(Al)-Al2Cu共晶。Al2Cu为非层状的不规则共晶组织。Al2Cu在经Ce改性的合金中更加致密。部分Ce溶解于Al2Cu中,这是粗晶Al2Cu形成的原因。与基体Al-Si-Cu合金相比,Ce的加入能使α(Al)-Al2Cu共晶合金的显微硬度提高约10%。 相似文献
14.
对自行研制的易切削Zn-10Al-1.0Cu-0.1Bi-0.1Sn变形合金铸态样品进行均匀化热处理,并采用力学性能测试、扫描电镜分析、钻削试验等手段,研究了热处理对该合金显微组织与力学性能和切削性能的影响。结果表明,试验合金铸态组织中存在较严重的枝晶偏析及非平衡共晶组织,经均匀化退火后,枝晶偏析和非平衡β+η共晶组织基本消除,组织分布更加均匀;其中经360℃保温12 h炉冷热处理后合金的抗拉强度降低,伸长率升高53.94%,塑性明显提高,有利于后续的热塑性加工;均匀化热处理对合金的切削性能影响不大。 相似文献
15.
Heat treatment has important influence on the microstructure and mechanical properties of Al-Si alloys. The most common used heat treatment method for these alloys is solution treatment followed by age-hardening. This paper investigates the microstructural evolution of a direct chill (DC) cast Al-15.5Si-4Cu-1Mg-1Ni-0.5Cr alloy after solution treated at 500, 510, 520 and 530℃, respectively for different times. The major phases observed in the as-cast alloy are α-aluminum dendrite, primary Si particle, eutectic Si, Al7Cu4Ni, Al5Cu2Mg8Si6, Al15(Cr, Fe, Ni, Cu)4Si2 and Al2Cu. The Al2Cu phase dissolves completely after being solution treated for 2 h at 500℃, while the eutectic Si, Al5Cu2Mg8Si6 and Al15(Cr, Fe, Ni, Cu)4Si2 phases are insoluble. In addition, the Al7Cu4Ni phase is substituted by the Al3CuNi phase. The α-aluminum dendrite network disappears when the solution temperature is increased to 530℃. Incipient melting of the Al2Cu-rich eutectic mixture occurrs at 520℃, and melting of the Al5Cu2Mg8Si6 and Al3CuNi phases is observed at a solution temperature of 530℃. The void formation of the structure and deterioration of the mechanical properties are found in samples solution treated at 530℃. 相似文献
16.
Ce element was introduced to modify Al-2%Fe (mass fraction) binary alloy. The microstructures, crystallization behavior, electrical/thermal conductivities and mechanical properties of these alloys were systematically investigated. The results indicated that the appropriate Ce addition decreased the recalescence temperature and growth temperature of Al-Fe eutectic structure, improved the morphology and distribution of Fe-containing phase, and simultaneously increased the conductivity and mechanical properties. The annealed treatment improved the thermal conductivity of these alloys due to the decreasing concentration of point defects. Rolling process further broke up the coarser Fe-containing phases into finer particles and made the secondary phases uniformly distributed in the α(Al) matrix. After subsequent annealing treatment and rolling deformation, the thermal conductivity, ultimate tensile strength and hardness of the Al-2%Fe-0.3%Ce (mass fraction) alloy reached 226 W/(m·K), (182±1.4) MPa and HBW (49.5±1.7), respectively. 相似文献
17.
研究了添加Ce与P+Sr复合变质对Al-21Si-1.5Cu-0.5Mg-2.5Fe合金显微组织与性能的影响。结果表明:添加1.5%Ce使粗大针状铁相消失,形成富Ce富Fe的鱼骨状相;P+Sr复合变质可使初晶硅平均尺寸由70 mm细化到20mm,共晶硅平均截线长降到2.1 mm,合金室温抗拉强度比未变质前提高21.5%,与P+Sr+Ce复合变质的Al-21Si-1.5 Cu-1.5Ni-2.5Fe-0.5Mg合金相当。 相似文献
18.
In this paper, the microstructural evolution and mechanical properties of squeeze cast Al-Cu alloys with different amounts of Cu and Fe after T7 heat treatment were investigated using various methods, including optical microstructure (OM), scanning electron microscopy (SEM), transmission electron microscopy (TEM), electron probe micro-analyzer (EPMA), and tensile testing. Results show that better comprehensive mechanical properties of squeeze cast Al-Cu alloys can be achieved by designing the Fe and Cu contents. These results can be attibuted to an increase in precipitate particles in the α(Al) matrix and the formation of nano-sized iron-rich intermetallics (IRIs). Ultimate tensile strength (UTS), yield strength (YS), and elongation (EL) of the Al-6.5Cu-0.6Mn-1.0Fe alloy were as high as 314 MPa, 293 MPa, and 6 %, respectively. These values were close to those of Al-Si alloys with high Fe content (1.0 %) under applied pressure, and this indicates the high potential for developing recycled squeeze cast Al-Cu cast alloys. 相似文献
19.
为进一步提高Mg-Al-RE基合金的力学性能,采用高压压铸技术制备Mg-3.0Al-1.8Ce-0.3Y-0.2Mn合金,并研究其微观组织、金属间相的热稳定性和合金的力学性能。结果表明:合金由细小的初生α-Mg枝晶和枝晶间的共晶组成。共晶中存在两种金属间相,即Al11(Ce,Y)3和Al2(Ce,Y),其中Al11(Ce,Y)3是主要增强相。研究还表明,Al11(Ce,Y)3的热稳定性是有条件限制的,在200°C时效800h,它基本保持稳定,而在450°C时效800h,绝大部分的Al11(Ce,Y)3发生相分解,转变为Al2(Ce,Y)。添加Ce和Y后,合金强度在室温和200°C下得到明显的提高。合金性能的提高主要归因于Al11(Ce,Y)3的形成对枝晶间区域的增强作用、晶粒细化的影响以及由Y原子造成的固溶强化。 相似文献
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