高性能稀土镁合金的研究及其应用

综述了稀土高强高韧镁合金、稀土耐蚀镁合金和稀土耐热镁合金的研究进展及其应用。利用微合金化、多元合金化技术,研发低成本、高性能稀土镁中间合金和稀土镁合金是镁合金技术的发展方向。     

稀土Sm在耐热镁合金中的应用

概述了镁合金的耐热性能及合金化设计依据,介绍了稀土元素Sm在耐热镁合金中的应用,探讨了Sm对镁合金耐热性能的影响,展望了耐热镁合金的发展方向,旨在为耐热镁合金的开发提供思路和依据。     

Ca在耐热镁合金中的应用

概述了镁合金的耐热性能及合金化设计依据,介绍了碱土元素Ca在耐热镁合金中的应用,展望了含Ca耐热镁合金的发展方向。     

Sn在耐热镁合金中的应用

概述了Sn合金化在镁合金中的强化机理,介绍了合金元素Sn在耐热镁合金中的应用,展望了含Sn耐热镁合金的发展方向.     

含Sm耐热镁合金的研究进展

概述了镁合金的耐热性能及合金化设计依据,介绍了铈族元素Sm在耐热镁合金中的最新研究进展,探讨了新型含Sm镁合金的组织和性能,指出含Sm镁合金在生产应用中存在的主要问题和今后的研究方向。     

耐热镁合金的研究进展

综述了耐热镁合金的研究进展和应用现状,重点介绍了Si、Ca、Sr、Bi、Sb、RE等合金化元素对镁合金抗高温蠕变性能的作用及影响,指出了开发耐热镁合金应注意的问题.     

耐热镁合金摩擦磨损性能的研究

以Ce微合金化的耐热镁合金为研究对象,研究了载荷、转速和滑行距离对耐热镁合金摩擦行为的影响。结果表明,随着载荷增加,摩擦系数减小,磨损率增大;转速和滑动距离对耐热镁合金的摩擦学性能影响较小;在25、150和200℃下,磨损率变化趋势相近,且摩擦系数和磨损率在200℃时比25℃的低。     

Bi合金化在耐热镁合金中的应用

介绍了合金元素Bi的特性(在镁中的溶解度高,可实现沉淀强化)及其在镁合金中的作用(细化组织,改善高温性能),综述了Bi合金化在耐热镁合金中的应用研究进展,在此基础上,指出了含Bi耐热镁合金存在的问题和发展的方向.     

耐热铸造镁合金的研究现状及其发展趋势

耐热铸造镁合金在航空航天以及汽车工业等领域得到了广泛应用。本文主要介绍了Mg-Al系、Mg-Zn系和Mg—RE系耐热铸造镁合金的研究现状；对新型高性能耐热镁合金的发展趋势提出了一些见解，指出，合金化方法作为解决镁合金高温性能不足的最有效的手段之一，应该进一步通过优化合金元素组合，进行有效的合金设计，解决铸造镁合金在耐高温、抗蠕变等方面存在的问题。     

汽车用耐热稀土镁合金的研究进展

综述了添加稀土元素的Mg-Al,Mg-Zn和Mg-RE系三大耐热镁合金系的强化途径、机制和提高耐腐蚀性能的研究进展。目前,得到应用的稀土镁合金中稀土含量相对较高,容易引起铸造性能降低和成本升高,难以工业化生产。因此,探索微合金化元素对稀土镁合金的作用,制备含有碱土金属的耐热镁合金也是未来趋势之一。     

耐热铸造镁合金的研究应用进展

介绍了耐热镁合金的蠕变特点及其强化方法。分析了Mg—AI系、Mg—Zn来和Mg—RE系合金耐热性能改善的组织结构因素。探讨了现有耐热镁合金存在的问题和新型耐热镁合金研究开发的方向。     

耐热镁合金及其开发思路

简述了耐热镁合金的特点和概况,介绍了舍金化耐热镁合金、镁基复合材料和快速凝固镁合金3大领域,重点分析了开发新型耐热镁合金的思路、方法与需要注意的问题,并提出了一些建议,为进一步拓宽镁合金在汽车、航天航空、3C产品等领域的应用提供理论依据。     

Effect of heat treatment on interfacial and mechanical properties of A6022/A7075/A6022 roll-bonded multi-layer Al alloy sheets

Multi-layered Al alloy sheets can exhibit unique properties by the combination of properties of component materials. A poor corrosion resistance of high strength Al alloys can be complemented by having a protective surface with corrosion resistant Al alloys. Here, a special care should be taken regarding the heat treatment of multi-layered Al alloy sheets because dissimilar Al alloys may exhibit unexpected interfacial reactions upon heat treatment. In the present study, A6022/A7075/A6022 sheets were fabricated by a cold roll-bonding process, and the effect of the heat treatment on the microstructure and mechanical properties was examined. The solution treatment gave rise to the diffusion of Zn, Mg, Cu and Si elements across the core/clad interface. In particular, the pronounced diffusion of Zn, which is a major alloying element (for solid-solution strengthening) of the A7075 core, resulted in a gradual hardness change across the core/clad interface. Mg2Si precipitates and the precipitate free zone were also formed near the interface after the heat treatment. The heat-treated sheet showed high strengths and reasonable elongation without apparent deformation misfit or interfacial delamination during the tensile deformation. The high strength of the sheet was mainly due to the T4 and T6 heat treatment of the A7075 core.     

Microstructure Control and High Temperature Properties of Al-Mn-Based AlloysEI北大核心CSCD

The process of production and working environment of heat exchangers call for materials with good elevated temperature properties. However, the previous investigations were mainly focused on their room temperature properties. The relationship between microalloying and high temperature properties, especially creep properties of Al-Mn-based alloys are barely discussed. In order to improve the industrial applications of Al-Mn-based alloys, the effect of Mg, Ni and Zr additions and annealing process on the microstructure and high temperature properties of Al-Mn-based alloys were studied in this work. The investigated alloys were treated in two ways, first one is cold-rolling and heat treatment at 873 K for 10 min, and the second one is cold-rolling, heat treatment at 623 K for 1 h and 873 K for 10 min. The results indicate that annealing process has remarkable effect on the grain shape, fine equiaxed crystal grains are obtained in the former, while stable elongated grains are obtained for precipitation precedes recrystallization at 623 K in the latter. With Mg addition, more AlMnSi phase precipitated during annealing. The addition of Zr and Ni increases the type and amount of heat resistant compounds, precipitate Al3Zr and AlMnSiNi, which are beneficial to improving high temperature properties of Al-Mn alloy. Al-Mn-0.3Mg-0.2Ni alloy has the best elevated temperature properties, and the tensile strength of it is 102 MPa (50 MPa higher than Al-Mn alloy) at 523 K. And the steady-creep rate is strongly decreased to 3.93x10(-8) s(-1), two orders of magnitude smaller than Al-Mn alloy at the temperature of 523 K under the stress of 40 MPa. With dispersoids complicated or increased, the movement of dislocations are pinned strongly, which are contribute to improving the creep properties of Al-Mn alloy for the creep is mainly controlled by dislocation climb.     

基于人工神经网络与遗传算法的Al-Mg-Si系合金抗拉强度预测模型

为了研究Al-Mg-Si系合金热处理制度和合金成分对力学性能的影响规律,采用人工神经网络（artificial neural network, ANN）和遗传算法（genetic algorithm, GA）相结合的方法,构建了Al-Mg-Si系合金强度预测模型（ANN-GA模型）。通过单因素和双因素分析,研究了合金元素含量和热处理工艺参数对铝合金抗拉强度的影响规律。结果表明,随着Si含量的增加,铝合金的抗拉强度呈现先降低后升高的趋势;随着Mg含量的增加、Cu含量的增加或者Fe含量的减少,铝合金的抗拉强度整体上呈现升高的趋势。双因素分析更能反映输入参数对铝合金抗拉强度的影响。Mg/Si比、Mg+Si总量和时效时间对Al-Mg-Si系合金力学性能的影响显著。铝合金的硬度随时间的变化趋势与ANN-GA模型的计算结果一致,峰值时效时间为29 h,相对误差为11.86%。     

Effect of Zr Addition on the Grain Refinement Mechanism of Mg-Gd-Er AlloysEI北大核心CSCD

In recent years, Zr is widely used as an important additive element in magnesium alloys containing rare earth (RE), to improve the mechanical properties of Mg-RE alloys such as strength, ductility, creep resistance and corrosion resistance property. Heterogeneous nucleation mechanism and peritectic reaction mechanism are recognized as the main grain refining mechanisms. Whereas, during the solidification process, the melt wetting angle and nucleation energy are important factors which influence the nucleation. In this work, the effect of Zr on the solidification microstructure of the Mg-Gd-Er alloy was analyzed by using OM and EBSD; the undercooling of alloy melts was tested by using DSC; and the Mg/Zr interface relationship and interfacial energy were investigated by using HRTEM. Moreover, the effects of Zr on the wetting angle and nucleation activation energy of the Mg-11Gd-2Er and Mg-11Gd-2Er-0.4Zr alloys were investigated; the refinement mechanism of Zr on the alloys was discussed. The results indicates that the addition of Zr element can significantly refine the grain, and the grain size decreased from 1000 mm to 50 mu m. Compared with the Zr-free alloy, the nucleation wetting angle of the present alloy melt decreased from 18.3 degrees to 11.1 degrees, and the activation energy of nucleation decreased by 44.4%. The (1010) plane of Mg was completely coherent with the (1100) plane of Zr, reducing the interfacial energy between the (1010) Mg and the (1100) Zr. The grain refinement of Mg-Gd-Er alloy was ascribed to the decrease of melt wetting angle and the fully coherent interface relationship between Mg and Zr.     

Microalloying Effect of Sn on Phase Transformation During Heat Treatment in Mg–Y–Zn–Zr Alloys

The microstructure and mechanical properties of the as-cast and heat-treated Mg-4.6 Y-2.5 Zn-0.6 Zr-x Sn(x = 0, 0.2 and0.5 wt%) alloys were investigated in this work. The results showed that the eutectics have been refined with 0.2% Sn addition and it has no effect on the phase category of the alloys. However, Sn3 Y5 phase was found in 0.5% Sn-added alloy.After heat treatment at 520 °C, the transformation of the long-period stacking ordered(LPSO) phase takes place in the Mg-Y-Zn-Zr alloy, but the transition is not completed in the alloys containing Sn. In addition, during the heat treatment, the mechanical properties of Sn-free alloys are significantly improved, and the strength of alloys containing Sn does not change much. Through observation and analysis of the microstructure and mechanical properties, it is found that Sn addition hinders the process of a0-Mg ? a-Mg ? 14 H and the process is the key to the transition of 18 H-LPSO to 14 H-LPSO.     

磁热处理对La-Mg-Ni-Cu合金相结构与电化学性能的影响

考察了La0.67Mg0.33Ni2.5Cu0.5合金分别在铸态、热处理后及磁热处理后3种状态下的相结构及其电化学性能.并通过XRD分析合金物相组成及SEM观察合金组织形貌,研究了Cu部分取代Ni以及有无外加磁场下热处理对合金相结构与电化学性能的作用规律.结果表明,La0.67Mg0.33Ni2.5Cu0.5铸态合金经过50次循环后,放电容量保持率从64.40%提高到72.44%;经磁热处理的La0.67Mg0.33Ni2.5Cu0.5合金最大放电容量为328.2 mAh/g,较常规热处理合金的容量提高了31.51%, 50次循环后的容量保持率为75.89%.其放电平台更为宽广且平坦;极限电流显著增大,氢在合金体相中的扩散速度加快.     

La0．67Mg0．33Ni2．5Co0．5贮氢合金的制备和MH电极性能研究

采用高频感应熔炼方法制备了PuNi3型La0.67Mg0.33Ni2.5Co0.5合金;用X射线衍射分析和电化学方法研究了添加不同Mg含量以补偿Mg元素烧损时合金的组织结构和电化学性能。X射线衍射分析(XRD)表明,铸态合金由．PuNi3型主相和少量的CaCu5型第二相组成,铸态合金经1223K和10h退火处理后,CaCu5型第二相可明显减少,其中Mg增加10％时得到纯度较高的PuNi3型组织。电化学测试表明,增加适当Mg含量和进行退火热处理能明显提高和改善合金电极容量、循环稳定性和大电流放电性能。与AB5型和。482型Laves相贮氢合金比较,PuNi3型La0.67Mg0.33Ni2.5Co0.5贮氢合金具有电极容量高及优良的大电流放电性能。