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烧结工艺对Ti(C,N)基金属陶瓷性能的影响 总被引:1,自引:0,他引:1
采用粉末冶金法制备Ti(C,N)基金属陶瓷,利用金相图像分析系统和扫描电镜观察陶瓷表面孔洞和微观组织形貌,分析了热处理和烧结气氛工艺对不同碳氮比的Ti(C,N)基金属陶瓷性能的影响.结果表明:真空烧结后的热处理工艺可使Ti(C,N)基金属陶瓷的横向断裂强度提高10%以上,硬度也有不同程度的提高,其中Ti(C0.5 N0.5)基金属陶瓷适合采用低压工艺处理,Ti(C0.7 N0.3)基金属陶瓷适合采用热等静压工艺处理.氮气气氛烧结中,Ti(C0.5 N0.5)基金属陶瓷在氮分压值为2kPa时的横向断裂强度达到最大值,而硬度变化不明显,这可归因于合适的氮分压阻碍了金属陶瓷内氮化物的分解,提高了材料的致密度,细化了晶粒组织. 相似文献
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采用粉末冶金法制备了超细晶Ti( C, N)基金属陶瓷和纳米改性Ti( C, N)基金属陶瓷试样和刀具。研究了陶瓷相粉末粒度对Ti( C, N)基金属陶瓷显微组织、力学性能及其刀具耐磨损性能的影响。结果表明,超细晶Ti( C, N)基金属陶瓷和纳米改性Ti( C, N)基金属陶瓷的硬质相均具有黑芯/灰壳和白芯/灰壳两种显微结构。超细晶Ti( C, N)基金属陶瓷中白芯/灰壳结构硬质相晶粒较多,而纳米改性Ti( C, N)基金属陶瓷中硬质相晶粒主要为黑芯/灰壳结构。与超细晶Ti( C, N)基金属陶瓷相比,纳米改性Ti( C, N)基金属陶瓷具有较高的抗弯强度和断裂韧度以及较低的硬度和孔隙度。纳米改性Ti( C, N)基金属陶瓷刀具具有较长的使用寿命,约为超细晶Ti( C, N)基金属陶瓷刀具使用寿命的2.3倍。 相似文献
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采用自制的多元复式碳氮化物陶瓷粉末 ((Ti,W,Ta) (C,N) p)制备 (Ti,W,Ta) (C,N) p/Ti(C,N)基金属陶瓷。研究了 (Ti,W,Ta) (C,N) p 粉末的组织结构特征及其加入对金属陶瓷的组织及性能的影响。结果表明 ,多元复式碳氮化物粉末的晶格常数与元素的固溶度有很好的对应关系 ,调整粉末中元素的固溶度可控制粉末的晶格常数 ,进而控制材料的性能。 Ti(C,N)基金属陶瓷中 (Ti,W,Ta) (C,N) p 粉末的加入 ,有利于重金属元素 W和 Ta向粘结相中扩散 ,从而降低了硬质相在粘结相中的溶解度 ,阻碍了晶粒长大。(Ti,W,Ta) (C,N) p/Ti(C,N)基金属陶瓷各项性能指标优于 Ti(C,N)基金属陶瓷和国外对应的金属陶瓷牌号 CT5 2 5的产品。强化机制主要表现为细晶强化与固溶强化。 相似文献
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对国内外近年来有关Ti(C,N)基金属陶瓷材料的显微结构与性能的研究成果进行了总结。首先,介绍了Ti(C,N)基金属陶瓷材料的发展史;Ti(C,N)基金属陶瓷的显微结构、力学性能,以及显微结构与其性能的关系等。其次,列举并比较了不同的烧结方法所制备的Ti(C,N)基金属陶瓷材料的力学性能;结果表明:微波烧结和放电等离子烧结技术在较低的温度就可以成功烧结高硬度、高抗弯强度与断裂韧性高的产品,但实际生产中,这类技术还没有广泛被应用,应用最广的是真空烧结方法。最后介绍了Ti(C,N)基金属陶瓷材料的今后的研究趋势。 相似文献
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《硬质合金》2019,(2):109-115
采用高温碳管炉制备了平均粒度约为1.2μm的(Ti,La)(C,N)复式碳氮化物粉末,并将其应用于(Ti,La)(C,N)基金属陶瓷的制备。研究稀土La元素的固溶含量对(Ti,La)(C,N)基金属陶瓷的组织结构和性能的影响,同时对比了La_2 O_3的直接加入对Ti(C,N)基金属陶瓷组织结构和性能的影响。通过X衍射和扫描电镜对两组金属陶瓷进行研究分析,结果表明:La含量相同时,相比于直接添加La_2 O_3的Ti(C,N)基金属陶瓷,(Ti,La)(C,N)基金属陶瓷各项性能指标均有提高,其抗弯强度提高了约20%,硬度也稍有提升,且当(Ti,La)(C,N)中La元素固溶0.25%时,物理和力学性能最佳;(Ti,La)(C,N)基金属陶瓷强化机制主要表现为固溶强化。 相似文献
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Effect of Mo and Mo2 C on the microstructure and properties of Ti(C,N)-based cermets was investigated in this article. The results have indicated that the weight percentage of Mo from 5 to 10 can reduce Ti(C,N) grain diameter and thickness of the rim, and Ti(C,N) grain can be wetted by Ni-Cu-Mo liquid so as to get small contiguity of Ti(C,N) grain. In that way, the transverse rupture strength of Ti(C,N)-based cermets has reached 1800-1900 MPa; the fracture toughness has been due to 16-18 MPa.m1/2. But 15 wt pct Mo was not more effective on Ti(C,N)-based cermets, because the thickness of the rim becomes larger. In the circumstance of Mo2 C, 5 wt pct Mo2 C was good for microstructure and properties of Ti(C,N)-based cermets, but 11 wt pct Mo2C has resulted in larger contiguity of Ti(C,N) grain and big Ti(C,N) grain diameter so as to reduce transverse rupture strength and fracture toughness. So that, the effect of Mo on Ti(C,N)-based cermets is better than Mo2C. 相似文献
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金属陶瓷材料及其在切削刀具上的应用 总被引:3,自引:0,他引:3
黄国权 《组合机床与自动化加工技术》2003,(5):37-38
文章论述了TiC基、Ti(C,N)基金属陶瓷的性能及其特点;作为刀具材料,金属陶瓷比硬质合金具有更多的优异性能,说明金属陶瓷作为刀具材料应用的范围。 相似文献
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YING Xiayu XIONG Ji GUO Zhixing CHEN Jianzhong XIONG Sujian YANG Mei FAN Hongyuan 《稀有金属(英文版)》2011,30(6):583-588
In this paper, Ti(C,N)-based nano cermets were prepared by nano particles, and the effect of VC addition on the microstructure
and properties of Ti(C,N)-based nano cermets was investigated. The results showed that there existed black-core grayish-rim
structure as well as gray-core grayish-rim structure in VC-doped Ti(C,N)-based nano cermets. With the increase of VC addition,
the number of gray cores increased, the lattice parameter of Ti(C,N) phase increased, the grain size decreased, the hardness
and fracture toughness of Ti(C,N)-based nano cermets were enhanced, and nearly full densification could be achieved. However,
excessive addition of VC to 1 wt% resulted in slight decrease in hardness and fracture toughness. Some deep dimples were found
in the fracture surface of cermets with VC addition, which corresponded to ductile fracture. 相似文献
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第二相碳化物对Ti(C,N)基金属陶瓷组织和性能的影响 总被引:4,自引:2,他引:2
简要介绍了Ti(C,N)基金属陶瓷的基本结构,重点阐述了第二相碳化物对Ti(C,N)基金属陶瓷的组织结构和力学性能的影响。 相似文献
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Ti(C,N)_w/Ti(C,N)基金属陶瓷的组织与力学性能研究 总被引:1,自引:0,他引:1
采用Ti(C,N)晶须和颗粒复合粉末(Ti(C,N)w+Ti(C,N)p)制备Ti(C,N)w/Ti(C,N)基金属陶瓷。研究了复合粉末对金属陶瓷组织及性能的影响。结果表明,Ti(C,N)w的加入,金属陶瓷的各项力学性能都得到了提高。组织表现为环形相结构特征,与Ti(C,N)基金属陶瓷相比,双层环形相结构所占比例增大,且尺寸加厚。烧结组织中Ti(C,N)w的长径比大于临界长径比,在强化金属陶瓷方面起着重要的作用。环形相使Ti(C,N)w与基体界面结合紧密,增韧机制主要表现为裂纹桥联和裂纹偏转,拔出效应不明显。 相似文献
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Owing to the denitrification behavior of Ti(C,N)-based cermets during the sintering process, nitrogen atmosphere sintering is essential for the fabrication of high-quality products. Disclosing the roles of the sintering atmosphere on the microstructure and properties of cermet is of significance. Herein, Ti(C,N)-based cermets were fabricated under six types of sintering atmosphere. Effects of sintering atmosphere on the microstructure, coercive force (Hc), specific saturation magnetization (Ms (%)), and mechanical properties of cermets were investigated. More rimless Ti(C,N) grains with increased fraction of black cores were formed with increasing the nitrogen partial pressure. Three types of gradient structure of cermets were confirmed caused by the different nitrogen activity at the liquid sintering state. Vacuum sintering induced the formation of thicker rims on smaller Ti(C,N) cores at the surface due to the low nitrogen potential, while fcc solid solutions rich in N was formed in nitrogen atmosphere. Vacuum sintered cermets showed the lowest Hc and Ms. (%) of 3.66 KA/m and 2.13%, owing to the denitrification process. High-quality Ti(C,N)-based cermets were achieved via the solid-state nitrogen atmosphere sintering, benefiting from the optimized core-rim structure, i.e. moderate thickness of rims and certain amount of black Ti(C,N) cores. 相似文献
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The present work investigated the effects of secondary carbides (Mo2C\WC\TaC\NbC) on the erosion-corrosion behavior of Ti(C,N)-based cermets. The results indicate that the erosion-corrosion resistance of Ti(C,N)-based cermets is enhanced in the order of NbC, TaC, WC and Mo2C addition. The contribution of erosion to the erosion-corrosion of Ti(C,N)-based cermets is much more significant than that of corrosion, and it increases with the decreased mechanical properties. The synergistic effect plays a dominant role in the degradation of Ti(C,N)-based cermets in erosion-corrosion conditions. There are two modes to ceramic phase degradation in erosion conditions: large ceramic grains are prone to deterioration through crack initiation and propagation → grain fracture → fragment removal; finer ceramic grains trend to be pulled out after the deterioration of binder and interface. The binder loss is determined by the corrosion resistance of binder, the erosion resistance of binder and the erosion resistance of ceramic phase. 相似文献