Nutrient removal and bio-energy production from Netley-Libau Marsh at Lake Winnipeg through annual biomass harvesting

The primary goal of this research study was to evaluate the concept of combining bio-power production and nutrient removal by yearly biomass harvesting during ice-covered periods at Netley-Libau Marsh on Lake Winnipeg. Depending on the extent of vegetation within the marsh on any given year, removal rates range from 1.026 to 1.368 kt (3.1–4.2% of total Red River loading to Lake Winnipeg) of total nitrogen and 188–227 t (3.8–4.7% of total loading) of total phosphorus by harvesting 60% of the marsh area and 75% of the emergent parts of the vegetation. The effective management of water levels within the marsh was critical for vegetation growth and diversity. Suggestions on biomass harvesting and utilization methods were provided and a number of technologies were examined for the conversion of the harvested biomass to energy. The power produced in these systems ranged from 1.75 to 4.71 MW and, for some of the technologies, usable cogeneration heat was produced as a potential added value. CO₂ emission credits of 55.07 kt y⁻¹ can be expected with possible additional GHG credits for methane and NO_x displacement.     

Ni1−xCux alloy-based anodes for low-temperature solid oxide fuel cells with biomass-produced gas as fuel

Ni–Cu alloy-based anodes, Ni_1−xCu_x (x = 0, 0.05, 0.2, 0.3)–Ce_0.8Sm_0.2O_1.9 (SDC), were developed for direct utilization of biomass-produced gas in low-temperature solid oxide fuel cells (LT-SOFCs) with thin film Ce_0.9Gd_0.1O_1.95 electrolytes. The alloys were formed by in situ reduction of Ni_1−xCu_xO_y composites synthesized using a glycine-nitrate technique. The electrolyte films were fabricated with a co-pressing and co-firing technique. Electrochemical performance of the Ni_1−xCu_x–SDC anode supported cells was investigated at 600 °C when humidified (3% H₂O) biomass-produced gas (BPG) was used as the fuel and stationary air as the oxidant. With Ni–Cu alloys as anodes, carbon deposition was substantially suppressed and electrochemical performance of the cells was sustained for much longer periods of time. For example, the power export of a Ni–SDC supported cell was only 50% of the initial value (200 mW cm⁻² at 0.5 V) after 20 min, while Ni_0.8Cu_0.2–SDC supported cells could maintain 90% of the initial power density (250 mW cm⁻² at 0.5 V) over a period of 10 h. The improved performance of the Ni–Cu alloy-based anodes is worth considering in developing SOFCs fueled directly with dilute hydrocarbons such as gases derived from biomass.     

National and regional generation of municipal residue biomass and the future potential for waste-to-energy implementation

Municipal residue biomass (MRB) in the municipal solid waste (MSW) stream is a potential year-round bioenergy feedstock. A method is developed to estimate the amount of residue biomass generated by the end-user at the scale of a country using a throughput approach. Given the trade balance of food and forestry products, the amount of MRB generated is calculated by estimating product lifetimes, discard rates, rates of access to MSW collection services, and biomass recovery rates. A wet tonne of MRB could be converted into about 8 GJ of energy and 640 kg of carbon dioxide (CO₂) emissions, or buried in a landfill where it would decompose into 1800 kg of CO₂ equivalent (in terms of global warming potential) methane (CH₄) and CO₂ emissions. It is estimated that approximately 1.5 Gt y^?1 of MRB are currently collected worldwide. The energy content of this biomass is approximately 12 EJ, but only a fraction is currently utilized. An integrated assessment model is used to project future MRB generation and its utilization for energy, with and without a hypothetical climate policy to stabilize atmospheric CO₂ concentrations. Given an anticipated price for biomass energy (and carbon under a policy scenario), by the end of the century, it is projected that nearly 60% of global MRB would be converted to about 8 EJ y^?1 of energy in a reference scenario, and nearly all of global MRB would be converted into 16 EJ y^?1 of energy by the end of the century under a climate policy scenario.     

Part I: Experimental studies on a pulverised fuel stove

This paper is concerned with development of a pulverised fuel stove with improved conversion efficiency and minimal emissions at near constant power level without the use of external power. The design originates from a cylindrical sawdust stove with a central porthole being lit from the bottom. Such a stove will have a flame in port with enhanced sooting tendency. For similar configuration, stable premixed combustion behaviour of the combustible gases from the port of the fuel block (known as the gasification mode) has been achieved by use of air supply through a thin slot at the bottom, for at least 30 min of stove operation. In order to ensure stable combustion of the gases at exit, a metal device is used. In an attempt to extend gasification duration, studies are conducted in single port configuration having air entry from the bottom with a horizontal baffle to control the flow rate. This configuration worked in gasification mode for about 20 min but there have been problems of flame extinction. To overcome these drawbacks multi-port design with vertical air entry is employed with success.The stove has exhibited conversion efficiency in excess of 37% due to well focused nature of flame at exit. CO emission factors are about 12 g (kg fuel)⁻¹, a performance superior to conventional biomass stoves (∼45 g kg⁻¹). NO_x emission factors are about 1 g kg⁻¹ fuel which falls in the range of reported data for NO_x. Studies with different pulverised leafy fuels have indicated these fuels have lower volatile release rates and therefore exhibit lower power level operation for a given port configuration compared to sawdust fuel.     

Competition for the biomass resource: Greenhouse impacts and implications for renewable energy incentive schemes

In Australia, the Mandatory Renewable Energy Target (MRET) scheme, which targets a 9.5 TWh per annum increase in renewable electricity generation by 2010, is stimulating interest in bioenergy. Development of bioenergy projects may cause competition for biomass resources. For example, sawmill residues are an attractive feedstock for bioenergy, but are also utilised for particleboard manufacture. This study compares the greenhouse gas (GHG) mitigation impacts of alternative scenarios where sawmill residues are used either for generation of electricity or for manufacture of particleboard. The study considers a theoretical particleboard plant processing 100 kt feedstock of dry sawmill residues per annum. If the sawmill residues are used instead for bioenergy, and the particleboard plant utilises fresh plantation biomass, 205 kt CO₂eq emissions are displaced. However, GHG emissions for particleboard manufacture increase by about 38 kt CO₂eq, equivalent to 19% of the fossil fuel emissions displaced, due to the higher fossil fuel requirements to harvest, transport, chip and dry the green biomass. Also, plantation carbon stock declines by 147 kt CO₂eq per year until a new equilibrium is reached after 30 years. This result is influenced particularly by the fossil fuel displaced, the relative efficiency of the fossil fuel and bioenergy plants, the moisture content of the sawmill residues, and the efficiency of the dryer in the particleboard plant.Under MRET, calculation of Renewable Energy Certificates is based solely on the quantity of power generated. This study illustrates that indirect consequences can reduce the GHG mitigation benefits of a bioenergy project. Increased emissions off-site, and loss of forest carbon stock, should be considered in calculating the net GHG mitigation benefit, and this should determine the credit earned by a bioenergy project.     

Feasibility assessment of poplar bioenergy systems in the Southern Europe

A detailed reliability assessment of bioenergy production systems based on poplar cultivation was made. The aim of this assessment was to demonstrate the Economic feasibility of implementing poplar biomass production for power generation in Spain. The assessment considers the following chain of energy generation: cultivation and harvesting, and transportation and electricity generation in biomass power plants (10, 25 and 50 MW). Twelve scenarios were analysed in accordance with the following: two harvesting methods (high density packed stems and chip production in the field), two crop distributions around the power plant and three power plant sizes. The results show that the cost of biomass delivered at power plant ranges from 18.65 to 23.96 € Mg^?1 dry basis. According to power plant size, net profits range from 3 to 22 million € per yr.Sensibility analyses applied to capital cost at the power plant and to biomass production in the field demonstrate that they do not affect the feasibility of these systems. Reliability is improved if benefits through selling CO₂ emission credits are taken into account.This study clears up the Economic uncertainty of poplar biomass energy systems that already has been accepted as environmentally friendlier and as offering better energetic performance.     

Performance of simulated flexible integrated gasification polygeneration facilities,Part B: Economic evaluation.

This paper investigates the economics of integrated gasification polygeneration (IG-PG) facilities and assesses under which market conditions flexible facilities outperform static facilities. In this study, the facilities use Eucalyptus wood pellets (EP), torrefied wood pellets (TOPS) and Illinois #6 coal as feedstock to produce electricity, FT-liquids, methanol and urea. All facilities incorporate CCS. The findings show production costs from static IG-PG facilities ranging between 12 and 21 €/GJ using coal, 19–33 €/GJ using TOPS and 22–38 €/GJ using EP, which is above the average market prices. IG-PG facilities can become competitive if capital costs drop by 10%–27% for coal based facilities. Biomass based facilities will need lower biomass pellet prices or higher CO₂ credit prices. Biomass becomes competitive with coal at a CO₂ credit price of 50–55 €/t CO₂. Variations in feedstock, CO₂ credit and electricity prices can be offset by operating a feedstock flexible IG-PG facility, which can switch between coal and TOPS, thereby altering its electricity production. The additional investment is around 0.5% of the capital costs of a dedicated coal based IG-PG facility. At 30 €/t CO₂, TOPS will be the preferred feedstock for 95% of the time at a feedstock price of 5.7 €/GJ. At these conditions, FT-liquids (gasoline/diesel) can be produced for 15.8 €/GJ (116 $/bbl). Historic records show price variations between 5.7 and 7.3 €/GJ for biomass pellet, 1.0–5.6 €/GJ for coal and 0–32 €/t CO₂. Within these price ranges, coal is generally the preferred feedstock, but occasionally biomass is preferred. Lower biomass prices will increase the frequency of switching feedstock preference from coal to biomass, raising the desire for flexibility. Of the three investigated chemicals, an IG-PG facility producing FT-liquids benefits the most from flexibility. Our study suggests that if the uncertainty in commodity prices is high, a small additional investment can make flexible IG-PG facilities attractive.     

A techno-economic evaluation of the effects of centralized cellulosic ethanol and co-products refinery options with sugarcane mill clustering

This work compares the calculated techno-economic performance for thermochemical and biochemical conversion of sugarcane residues, considering future conversion plants adjacent to sugarcane mills in Brazil. Process models developed by the National Renewable Energy Laboratory were adapted to reflect the Brazilian feedstock composition and used to estimate the cost and performance of these two conversion technologies. Models assumed that surplus bagasse from the mill would be used as the feedstock for conversion, while cane trash collected from the field would be used as supplementary fuel at the mill. The integration of the conversion technology to the mill enabled an additional ethanol production of 0.033 m³ per tonne of cane for the biochemical process and 0.025 m³ t^?1 of cane plus 0.004 m³ t^?1 of cane of higher alcohols for the thermochemical process. For both cases, electricity is an important co-product for the biorefinery, but especially for biochemical conversion, with surpluses of about 50 kWh t^?1 of cane. The economic performance of the two technologies is quite similar in terms of the minimum ethanol selling price (MESP), at 318 $ m^?3 (United States 2007 dollars) for biochemical conversion and 329 $ m^?3 for thermochemical conversion.     

Evaluating the impact of three incentive programs on the economics of cofiring willow biomass with coal in New York State

Plantations of fast-growing willow shrubs are being promoted as a source quality biomass feedstock for bioenergy and bioproducts in New York State (NY). In the near-term, cofiring of the feedstock—in combination with other woody biomass—with coal in existing utility power boilers is considered to be the most promising conversion method for energy generation. Despite the clear technological viability and associated environmental benefits, cofiring of willow has not been widely adopted. The relatively high production cost of the willow feedstock, which is over twice that of coal, is the primary reason for this lack of interest. Taxes that account for some of the social costs of using coal and/or incentives that appropriate value for some of the social benefits of using willow are essential for eliminating most or the entire current price differential. This paper presents an integrated analysis of the economics of power generation from cofiring willow biomass feedstock with coal, from the perspective of the grower, aggregator and the power plant. Emphasis is placed on analyzing the relative impact of a green premium price, a closed-loop biomass tax credit, and payments to growers under the proposed Conservation Reserve Program (CRP) harvesting exemption policy. The CRP payments reduced the delivered cost of willow by 36–35%, to $1.90 GJ⁻¹ and $1.70 GJ⁻¹, under current and increased yield conditions, respectively. These prices are still high, relative to coal. Other incentives are required to ensure commercial viability. The required levels of green premium price (0.4–1.0 cents kWh⁻¹) and biomass tax credit (0.75–2.4 cents kWh⁻¹) vary depending on whether the incentives were being applied by themselves or in combination, and whether current yield or potential increased yields were being considered. In the near term, cofiring willow biomass and coal can be an economically viable option for power generation in NY if the expected overall beneficial effects associated with the production and use of the biomass is accounted for.     

Char oxidation study of sugar cane bagasse,cotton stalk and Pakistani coal under 1% and 3% oxygen concentrations

Chars of Sugar cane bagasse (1 & 2), Cotton stalk and low rank Pakistani coal have been studied by TGA under low oxidative environments with O₂ concentrations of 1% and 3%. The maximum reactivity of the chars was found to be greater by a factor of 2 under 3% oxygen compared to 1% O₂ conditions. Overall conversion levels at 3% O₂ for Sugar cane bagasse-2 increased from 63% to 100%, Sugar cane bagasse-1; 54% to 97%, Cotton stalk; 45% to 100% and Pakistani coal; 63% to 90% in comparison to 1% O₂. The maximum average rate of weight loss was found in Region III compared to Region I and II supported by CO/CO₂ FTIR Chemigram analysis. On the other hand, % conversion was maximum in Region II under 1% and 3% O₂ concentration. Overall average rates of weight losses were dependant on O₂ concentration and temperature ranges, however for all the regions % conversion and average weight loss were twice in 3% compared to 1% O₂ concentration. Biomass chars were found to be more reactive than the coal studied here during each region of the oxidation process. Evaluated apparent energy of activations for biomass chars was found within range of 41.2–105.8 kJ mole^?1 under 1%, 46.9–125.6 kJ mole^?1 under 3% compared to coal; 70.3–183.9 kJ mole^?1 under 1% and 83.1–167.4 kJ mole^?1 in 3% O₂ concentration for order of reaction (n) varying between 0.5 ≤ n ≤ 2. From the tests carried under O₂ levels of 1% and 3%, it is possible to give the following sequence to the apparent activation energies under any of the fixed value of n, obtained for the biomasses and coal; Pakistani coal > Cotton stalk > Sugar cane bagasse-2 > Sugar cane bagasse-1.     

Combustion of spent mushroom compost and coal tailing pellets in a fluidised-bed

Previous investigations found that fluidised-bed combustion of spent mushroom compost–coal tailing pellets was preferred for these high ash content fuels. This paper considers the combustion tests carried out on these wastes in a laboratory-scale fluidised-bed, where parameters, including the pellet feedrate, primary/fluidising air flowrate and bed depth, were investigated. Based on the minimum air ratio of 2.5 required to achieve high combustion efficiencies of around 97%, the optimum operating conditions for the combustor employed were a pellet feedrate of 3.25 kg/h (180 kg/m²h) and a total air flowrate of 650 kg/m²h. A lower sand bed depth of 0.22 m was also deemed beneficial, as deeper beds resulted in slugging and noticeable reductions in combustion efficiency. Acid gas emissions (NO_x, SO_x and HCl) were found in limited concentrations, as species remained primarily as inorganic compounds in the flyash. Some N₂O is thought to have formed, as fluidised-bed combustors are particularly prone to this. The alkali index of the ash suggests probable fouling/slagging in the system. For industrial-scale combustion of these wastes, the combustion efficiency could be improved by the presence of secondary air jets to aid turbulent mixing.     

A novel polygeneration system integrating the acetylene production process and fuel cell

This paper presents a novel polygeneration system that integrates the acetylene process and the use of fuel cells. The system produces acetylene and power by a process of the partial oxidation/combustion (POC) of natural gas process, a water–gas shift reactor, a fuel cell and a waste heat boiler auxiliary system to recover the exhaust heat and gas from the fuel cell. Based on 584.3 kg/h of natural gas feedstock, a POC reactor temperature of 1773 K, an absorber pressure of 1.013 MPa and a degasser pressure of 0.103 MPa, the simulation results show that the new system achieved acetylene production of 1.9 MW, net electricity production of 1.7 MW, power generation efficiency of 26.8% and exergy efficiency of 43.4%, which was 20.2% higher than the traditional acetylene production process. The new system's exergy analysis and the flow rate of the products were investigated, and the results revealed that the energy conversion and systematic integration mechanism demonstrated the improvement of natural gas energy conversion efficiency.     

Effect of titanium substitution in layered LiNiO2 cathode material prepared by molten-salt synthesis

LiNi_1−xTi_xO₂ (0 ≤ x ≤ 0.1) compounds have been synthesized by a direct molten-salt method that uses a eutectic mixture of LiNO₃ and LiOH salts. According to X-ray diffraction analysis, these materials have a well-developed layered structure (R3-m) and are an isostructure of LiNiO₂. The LiNi_1−xTi_xO₂ (0 ≤ x ≤ 0.1) compounds have average particle sizes of 1–5 μm depending on the amount of Ti salt. Charge–discharge tests show that a LiNi_1−xTi_xO₂ (0 ≤ x ≤ 0.1) cathode prepared at 700 °C has an initial discharge capacity as high as 171 mA h g⁻¹ and excellent capacity retention in the range 4.3–2.8 V at a current density of 0.2 mA cm⁻².     

Self-propagating room temperature synthesis of nanopowders for solid oxide fuel cells (SOFC)

Ceria based solid solutions are promising ceramic electrolytes for SOFC which will be able to function at intermediate temperatures. In accordance with common trends to decrease the production and operating costs of new generation of SOFC materials the reaction based on metathetical pathway is described, whereby solid solution powders of rare earth doped ceria in the nanoscale range were obtained at room temperature. By simple hand mixing of reactants the reaction was enhanced, propagating afterwards by itself. Nanometric ceria powders doped with Y or Nd, as well as co doped with both cations were synthesized. Composition of Ce_1 − xMe_xO_2 − y ranged from x = 0–0.25. The reaction course is described in detail and the properties of the obtained powders are presented.     

Metal oxyfluorides TiOF2 and NbO2F as anodes for Li-ion batteries

Lithium insertion and extraction in to/from the oxyfluorides TiOF₂ and NbO₂F is investigated by galvanostatic cycling, cyclic voltammetry and impedance spectroscopy in cells using Li-metal as a counter electrode at ambient temperature. The host compounds are prepared by low-temperature reaction and characterized by powder X-ray diffraction (XRD), Rietveld refinement and Brunauer, Emmett and Teller (BET) surface area. Crystal structure destruction occurs during the first-discharge reaction with Li at voltages below 0.8–0.9 V for Li_xTiOF₂ as shown by ex situ XRD and at ≤1.4 V for Li_xNbO₂F to form amorphous composites, ‘Li_xTi/NbO_y–LiF’. Galvanostatic discharge–charge cycling of ‘Li_xTiO_y’ in the range 0.005–3.0 V at a current density of 65 mA g⁻¹ gives a capacity of 400 (±5) mAh g⁻¹ during 5–100 cycles with no noticeable capacity fading. This value corresponds to 1.52 mol of recycleable Li/Ti. The coulombic efficiency (η) is >98%. Results on ‘Li_xNbO_y’ show good reversibility of the electrode and a η >98% is achieved only after 10 cycles (range 0.005–3.0 V and at 30 mA g⁻¹) and a capacity of 180 (±5) mAh g⁻¹ (0.97 mol of Li/Nb) was stable up to 40 cycles. In both ‘Li_xTiO_y’ and ‘Li_xNbO_y’, the average discharge and charge voltages are 1.2–1.4 and 1.7–1.8 V, respectively. The impedance spectral data measured during the first cycle and after selected numbers of cycles are fitted to an equivalent circuit and the roles played by the relevant parameters as a function of cycle number are discussed.     

Computed NOx emission characteristics of opposed-jet syngas diffusion flames

This paper reported a numerical study on the NO_x emission characteristics of opposed-jet syngas diffusion flames. A narrowband radiation model was coupled to the OPPDIF program, which used detailed chemical kinetics and thermal and transport properties to enable the study of 1-D counterflow syngas diffusion flames with flame radiation. The effects of syngas composition, pressure and dilution gases on the NO_x emission of H₂/CO synthetic mixture flames were examined. The analyses of detailed flame structures, chemical kinetics, and nitrogen reaction pathways indicate NO_x are formed through Zeldovich (or thermal), NNH and N₂O routes both in the hydrogen-lean and hydrogen-rich syngas flames at normal pressure. Zeldovich route is the main NO formation route. Therefore, the hydrogen-rich syngas flames produce more NO due to higher flame temperatures compared to that for hydrogen-lean syngas flames. Although NNH and N₂O routes also are the primary NO formation paths, a large amount of N₂ will be reformed from NNH and N₂O species. For hydrogen-rich syngas flames, the NO formation from NNH and N₂O routes are lesser, where NO can be dissipated through the reactions of NH + NO → N₂ + OH and NH + NO → N₂O + H more actively. At a rather low pressure (0.01 atm), NNH-intermediate route is the only formation path of NO. Increasing pressure then enhances NO formation reactions, especially through Zeldovich mechanisms. However, at higher pressures (5–10 atm), NO is then converted back to N₂ through reversed N₂O route for hydrogen-lean syngas flames, and through NNH as well for hydrogen-rich syngas flames. In addition, the dilution effects from CO₂, H₂O, and N₂ on NO emissions for H₂/CO syngas flames were studied. The hydrogen-lean syngas flames with H₂O dilution have the lowest NO production rate among them, due to a reduced reaction rate of NNH + O → NH + NO. But for hydrogen-rich syngas flames with CO₂ dilution, the flame temperatures decrease significantly, which leads to a reduction of NO formation from Zeldovich route.     

Biodiesel production from palm oil via heterogeneous transesterification

This paper presents the study of the transesterification of palm oil via heterogeneous process using montmorillonite KSF as heterogeneous catalyst. This study was carried out using a design of experiment (DOE), specifically response surface methodology (RSM) based on four-variable central composite design (CCD) with α (alpha) = 2. The transesterification process variables were reaction temperature, x₁ (50–190 °C), reaction period, x₂ (60–300 min), methanol/oil ratio, x₃ (4–12 mol mol^?1) and amount of catalyst, x₄ (1–5 wt%). It was found that the yield of palm oil fatty acid methyl esters (FAME) could reach up to 79.6% using the following reaction conditions: reaction temperature of 190 °C, reaction period at 180 min, ratio of methanol/oil at 8:1 mol mol^?1 and amount of catalyst at 3%.     

Synthesis and electrochemical properties of Mo-doped Li[Ni1/3Mn1/3Co1/3]O2 cathode materials for Li-ion battery

The layered Li[Ni_(1−x)/3Mn_(1−x)/3Co_(1−x)/3Mo_x]O₂ cathode materials (x = 0, 0.005, 0.01, and 0.02) were prepared by a solid-state pyrolysis method (700, 800, 850, and 900 °C). Its structure and electrochemical properties were characterized by XRD, SEM, XPS, cyclic voltammetry, and charge/discharge tests. It can be learned that the doped sample of x = 0.01 calcined at 800 °C shows the highest first discharge capacity of 221.6 mAh g⁻¹ at a current density of 20 mA g⁻¹ in the voltage range of 2.3–4.6 V, and the Mo-doped samples exhibit higher discharge capacity and better cycle-ability than the undoped one at room temperature.     

Calculation of bright roof-tops for solar PV applications in Dhaka Megacity,Bangladesh

Bangladesh has already been known as the country of power crisis. Although the country's electricity generation capacity is 4275 MW, around 3000–3500 MW of electricity can be generated against the demand of more than 5000 MW. The country's power is being generated mostly with conventional fuel (82% indigenous natural gas, 9% imported oil, 5% coal) and renewable sources (4% hydropower and solar). But recently a remarkable decline of the indigenous gas takes place, which rapidly aggravates electricity generation. Dhaka, the capital as well as prime city of the country with its nearly 14 million populations faces the worst situation due to the shortfall of electricity. Around 1000–1200 MW of electricity is supplied to Dhaka Megacity, while the existing demand is nearly 2000 MW. As a result frequent load shedding takes place and most of the service sectors in the city are interrupted, which has recently created immense dissatisfaction among the city-dwellers. Given the city's power crisis and geophysical situations, applications of either stand-alone or grid connected PV systems would be very effective and pragmatic for power supplement. The conservative calculation of bright roof-tops from the Quickbird Scene 2006 of Dhaka city indicates that the city offers 10.554 km² of bright roof-tops within the Dhaka City Corporation (DCC) ward area (134.282 km²). The application of stand-alone PV systems with 75 Wp solar modules can generate nearly 1000 MW of electrical power, which can substantially meet the city's power demand.     

Effect of the Sm content on the structure and electrochemical properties of La1.3 − xSmxCaMg0.7Ni9 (x = 0–0.3) hydrogen storage alloys

La_1.3 − xSm_xCaMg_0.7Ni₉ (x = 0–0.3) hydrogen storage alloys were prepared by inductive melting and the effect of the Sm content on the structure and electrochemical properties was investigated in the paper. The Sm substitution for La in La_1.3 − xSm_xCaMg_0.7Ni₉ (x = 0–0.3) alloys does not change the main phase structure (the rhombohedral PuNi₃-type structure), but leads to a shrinkage of unit cell and a decrease of hydrogen storage capacity. With the increase of the Sm content in the alloys, the maximum discharge capacity of electrode decreases from 400.2 (x = 0) to 346.6 mAh g⁻¹ (x = 0.3), but the high-rate dischargeability and cycling stability is improved. After 100 cycles, the capacity retention rate increases from 75 (x = 0) to 85% (x = 0.3).