Heat extraction methods from salinity-gradient solar ponds and introduction of a novel system of heat extraction for improved efficiency

Heat has generally been successfully extracted from the lower convective zone (LCZ) of solar ponds by two main methods. In the first, hot brine from the LCZ is circulated through an external heat exchanger, as tested and demonstrated in El Paso and elsewhere. In the second method, a heat transfer fluid circulates in a closed cycle through an in-pond heat exchanger, as used in the Pyramid Hill solar pond, in Victoria, Australia. Based on the experiences at the El Paso and Pyramid Hill solar ponds, the technical specifications, material selection, stability control, clarity maintenance, salt management and operating strategies are presented. A novel method of extracting heat from a solar pond is to draw the heat from the gradient layer. This method is analysed theoretically and results of an experimental investigation at Bundoora East, RMIT, are presented. An in-pond heat exchanger made of polyethylene pipe has been used to extract heat for over 2 months. Results indicate that heat extraction from the gradient layer increases the overall energy efficiency of the solar pond by up to 55%, compared with conventional method of heat extraction solely from the LCZ. The experimental results are compared with the theoretical analysis. A close agreement has been found. From this small-scale experimental study, convection currents were found to be localised only and the density profiles were unaffected. An experimental study using an external heat exchanger for brine extraction and re-injection at different levels within the gradient layer still needs to be conducted to determine the effect of the heat extraction from the non-convective zone (NCZ) on the stability of the salinity gradient (both vertically and horizontally) and an economic analysis needs to be conducted to determine the economic gains from increased thermal efficiency.     

Brine clarity maintenance in salinity-gradient solar ponds

Brine transparency is an important part of the maintenance of a salinity-gradient solar pond as it affects the amount of solar radiation reaching the storage zone and hence has an influence on the thermal performance. There is a wide range of factors that can hinder the transmission of light in a solar pond. Algal and microbial growths are the most common problems encountered in working solar ponds and control of their densities is essential to maintain transparency. Two different chemical treatment methods for algae growth prevention are described in this paper: chlorine and a novel chemical product – copper ethylamine complex. The latter method has never been implemented previously in a working pond. This paper discusses the theory of the algae control methods used and presents the experimental results of the chemical treatments. The results showed that Cupricide is more effective than chlorine and is therefore the recommended chemical for algae control in solar ponds; it improves the water transparency especially in the upper convective zone and lower convective zone with all measurement values less than 1 NTU. Chlorine was found to be more corrosive than Cupricide due to the acidic effect it has on the pH. The preliminary cost analysis showed that granular chlorine is the cheapest chemical. A more detailed financial analysis is nevertheless required to refine these costs.     

A one-dimensional numerical study of the salt diffusion in a salinity-gradient solar pond

A one-dimensional transient mathematical model is used for the study of the salt diffusion and stability of the density gradient in a solar pond. A finite difference method with a diffusion coefficient dependent on both temperature and salt concentration is used to solve the salt diffusion equation. On the basis of simple considerations we analyze the influence of the salinity-gradient thickness on the useful energy which can be withdrawn from the bottom layer of the solar pond. Finally some considerations on the effect of the velocity of injected brine in rising solar ponds are presented, making use of the Rayleigh analysis of the small perturbations in order to study the stability of the system.     

The effect of thermodiffusion on the stability of a salinity gradient solar pond

A one-dimensional mathematical model is used for the study of the NaCl diffusion in a salinity-gradient solar pond. The model takes into account the effect of the thermodiffusion, or Soret effect, and also the possibility of injection of concentrated brine at the bottom of the salinity-gradient zone of the solar pond. The model results show that the thermodiffusion moves in the same direction of the molecular diffusion process, thus contributing to destabilize the salinity-gradient layer. This effect can be a significant contribution to the salt diffusion (over 10%), when the temperature gradient and salt concentration are high, like at the bottom of the salinity-gradient zone.     

Experimental study of natural brine solar ponds in Tibet

A salinity gradient solar pond (SGSP) is a simple and effective way of capturing and storing solar energy. The Qinghai-Tibet Plateau has very good solar energy resources and very rich salt lake brine resources. It lacks energy for its mineral processes and is therefore an ideal location for the development and operation of solar ponds. In China, solar ponds have been widely applied for aquaculture, in the production of Glauber’s salt and in the production of lithium carbonate from salt lake. As part of an experimental study, a SGSP using the natural brine of Zabuye salt lake in the Tibet plateau has been constructed. The pond has an area of 2500 m² and is 1.9 m deep. The solar pond started operation in spring when the ambient temperature was very low and has operated steadily for 105 days, with the LCZ temperature varying between 20 and 40 °C. During the experimental study, the lower convective zone (LCZ) of the pond reached a maximum temperature of 39.1 °C. The results show that solar ponds can be operated successfully at the Qinghai-Tibet plateau and can be applied to the production of minerals.     

Turbidity study of solar ponds utilizing seawater as salt source

A series of experiments were conducted to study the turbidity reduction in solar ponds utilizing seawater as salt source. The experiment on the turbidity reduction efficiency with chemicals indicates that alum (KAl(SO₄)₂·12H₂O) has a better turbidity control property because of its strongly flocculating and also well depressing the growing of algae and bacteria in the seawater. In comparison with bittern and seawater, our experiment shows that the residual brine after desalination can keep limpidity for a long time even without any chemical in it. Experiments were also conducted on the diffusion of turbidity and salinity, which show that the turbidity did not diffuse upwards in the solution. In the experiment on subsidence of soil in the bittern and saline with the same salinity, it was found that soil subsided quite quickly in the pure saline water, but very slowly in the bittern. In this paper we also proposed an economical method to protect the solar pond from the damage of rain. Finally, thermal performance of a solar pond was simulated in the conditions of different turbidities using a thermal diffusion model.     

Effect of water turbidity on thermal performance of a salt-gradient solar pond

The effect of water turbidity on the thermal performance of a salt-gradient solar pond is studied using a one-dimensional theoretical model. The theoretical model uses an empirical correlation that includes the effect of water turbidity on solar radiation penetration in water. The correlation is based on a uniform turbidity distribution in water; however, the correlation is extended to include a non-uniform turbidity distribution with respect to depth of water. The results indicate that water clarity plays a significant role on thermal performance for salt gradient solar ponds.     

Effects of porous media on thermal and salt diffusion of solar pond

Laboratory and field experiments were carried out along with numerical simulations in this paper to study the effects of porous media on thermal and salt diffusion of the solar ponds. From our laboratory experiments simulating heat transfer inside a solar pond, it is shown that the addition of porous media to the bottom of a solar pond could help enhance its heat insulation effect. The experiment on salt diffusion indicates that the upward diffusion of the salt is slowed down when the porous media are added, which helps maintain the salt gradient. Our field experiments on two small-scaled solar ponds indicate that when porous media are added, the temperature in the lower convective zone (LCZ) of the solar pond is increased. It is also found that the increase in turbidity is repressed by porous media during the replenishment of the salt to the LCZ. Thermal diffusivities and conductivities of brine layers with porous media such as pebble and slag were also respectively measured in this paper based on the unsteady heat conducting principles of a semi-infinite body. These measured thermal properties were then used in our numerical simulations on the effect of porous media on thermal performance of a solar pond. Our simulation results show that brine layer with porous media plays more positive role in heat insulation effect when thermal conductivity of the ground is big. On the other hand, when the ground has a very small thermal conductivity, the performance of solar pond might be deteriorated and total heat storage quantity of solar pond might be reduced by brine layer with porous media.     

Performance investigation of a salt gradient solar pond coupled with desalination facility near the Dead Sea

Solar ponds provide the most convenient and least expensive option for heat storage for daily and seasonal cycles. This is particularly important for a desalination facility, if steady and constant water production is required. If, in addition to high storage capacity, other favorable conditions exist, the salt gradient solar ponds (SGSPs) are expected to be able to carry the entire load of a large-scale flash desalination plants without dependence upon supplementary sources. This paper presents a performance investigation of a SGSP coupled with desalination plant under Jordanian climatic conditions. This is particularly convenient in the Dead Sea region characterized by high solar radiation intensities, high ambient temperature most of the year, and by the availability of high concentration brine. It was found that a 3000 m² solar pond installed near the Dead Sea is able to provide an annual average production rate of 4.3 L min⁻¹ distilled water compared with 3.3 L min⁻¹ that would be produced by El Paso solar pond, which has the same surface area. Based on this study, solar ponds appear to be a feasible and an appropriate technology for water desalination near the Dead Sea in Jordan.     

浊度和池底反射率对太阳池热性能的影响

提出了同时考虑浊度和池底漫反射的太阳池辐射透射模型和热效率模型,计算分析了浊度和池底反射 率对太阳池热性能的综合影响。模拟计算表明,浊度一定时,热性能总是随着池底反射率的增大而降低。计算 还表明,存在一个临界池底反射率,当池底反射率小于临界值时,浊度的增大导致太阳池热性能的下降;当池 底反射率超过临界值时,一定范围内浊度的增加反而有利于太阳池热性能的提高;当池底反射率在临界值附近 时,浊度的变化对太阳池热性能的影响很小。通过模拟计算得出了典型情况下的临界池底反射率,在太阳池的 实际研究和设计中可供参考。     

苦卤太阳池池水的太阳辐射透射率与浊度的实验研究

在较大浊度范围内进行了太阳辐射透射率实验。实验表明浊度对太阳能在水中的辐射透射影响很大,浊度为8.1ntu的苦卤在水下50cm太阳辐射透射率仅为0.08。进行了苦卤的降浊处理和降浊后苦卤中浮游藻类的再滋生实验。实验表明絮凝降浊对苦卤中藻类的生长有一定的抑制作用,但经过一段时间可能会突然迅速滋生蔓延,并使太阳池内的浊度大幅增加。进行了苦卤太阳池水浊度的研究实验,发现苦卤水中的浊度并不向上层扩散,故不必对底层的苦卤进行降浊处理;发现尘土落入纯盐水中可较快沉降,而在苦卤中沉降速度很慢,很难自然澄清。     

Development of the gel pond technology

A review of the development of the gel pond technology is presented. First, the emergence and growth of solar pond technology since the 1950's is described. The inherent problems encountered with the conventional salt gradient ponds are discussed, leading to the concept of the solar gel pond in which the salt gradient layer in the former is replaced by a transparent polymer gel. The major work in the first phase dealt with the experimental development of a polymer gel which met certain selection criteria. The criteria considered included transmissivity, stability of physical and chemical properties, high viscosity and other physical and optical properties. The gradual development of the polymer gel through an alternating process of testing and elimination and evaluation of relevant properties of the gel has been described. Modeling and optimization studies of the solar gel pond have been presented. Bansal and Kaushik's model for a salt gradient pond has been modified for a solar gel pond, and the results of the simulation are presented in a graphical form to serve as a quick reference for estimation of pond surface area, depth and flow rate for heat extraction depending on the extreme temperature required in the storage zone and the required heat load. Then, a cost-benefit economic analysis compares the economics of a solar gel pond with a conventional salt gradient pond. The construction of an experimental gel pond (18 m²) at The University of New Mexico is described, and the results of the study are summarized. Information on commercial scale ponds at Chamberino, New Mexico (110 m²), and in Albuquerque, New Mexico (400 m²), is provided. The review of the technology demonstrates the immense potential of the gel pond as a source of alternate energy for the years ahead.     

Solar ponds in alkaline lake and oil well regions

Solar ponds are probably the simplest technology available for the useful conversion of solar energy. The basic technology is proven. Solar ponds have been shown to be technically feasible and economically viable for many applications, particularly for thermal use. The electrical conversion and use of solar energy via solar ponds is still questionable, in general, for economic viability. By putting the untapped sources together in the South Plains region, it looks promising economically both for thermal and electrical conversions and applications. There are a number of alkaline lake basins randomly scattered in the South Plains region of the U.S.A. In that area, there are thousands of crude oil producing wells that produce brine in abundance. The selection of suitable alkaline lake basins as a solar pond site and as depository sites of brine from oil wells and the using of this brine and salty water from alkaline lakes makes the solar pond economically viable for both thermal and electrical demands in the area.     

Field testing on nonsalt solar ponds

A new type of nonsalt solar pond was investigated by field testing. The roof of the solar pond was formed using a transparent double film. Three kinds of tests were carried out under the following conditions: (1) insulating pellets were packed between the layers of the transparent double film of the roof at sunset; (2) the water surface of the pond was insulated using only the two transparent films; (3) the water surface of the pond was covered by the double film with the top surface blackened on which solar energy can be collected, while pond water was circulated using a solar cell powered submerged water pump. The warm water stored in the solar pond by the above methods was utilized as a heat source for a gas engine powered heat pump used to heat a greenhouse. In this report, the results of the field tests on the above solar ponds and greenhouse heating system are discussed. Also the utility of a combination plant using a solar pond and underground borehole storage system is evaluated.Important conclusions on performance are as follows: (1) collection efficiencies of these solar ponds become 9–54% corresponding to the weather conditions and pond temperatures; (2) maximum temperature of the pond water under weather conditions at Osaka is about 80°C; (3) the solar pond can be effectively utilized for heating a greenhouse; (4) the combination plant using the solar pond and the underground storage layer can store heat of 1119 MJ m⁻² yr⁻¹.     

Examining potential benefits of combining a chimney with a salinity gradient solar pond for production of power in salt affected areas

The concept of combining a salinity gradient solar pond with a chimney to produce power in salt affected areas is examined. Firstly the causes of salinity in salt affected areas of northern Victoria, Australia are discussed. Existing salinity mitigation schemes are introduced and the integration of solar ponds with those schemes is discussed. Later it is shown how a solar pond can be combined with a chimney incorporating an air turbine for the production of power. Following the introduction of this concept the preliminary design is presented for a demonstration power plant incorporating a solar pond of area 6 hectares and depth 3 m with a 200 m tall chimney of 10 m diameter. The performance, including output power and efficiency of the proposed plant operating in northern Victoria is analysed and the results are discussed. The paper also discusses the overall advantages of using a solar pond with a chimney for production of power including the use of the large thermal mass of a solar pond as a practical and efficient method of storing collected solar energy.     

Solar ponds using ammonium salts

Ammonium salts have good potential for use in salt gradient solar ponds. The environmental problems associated with NaCl are eliminated by incorporating the salt discharge from the solar pond into the fertilizer cycle of an agricultural system. Thermophysical and optical properties of several ammonium salts are sufficiently close to those of NaCl to suggest that the thermal efficiency of solar ponds using ammonium salts should be equivalent to that of a NaCl pond. Ammonia outgassing is minimal, and algae growth is curtailed by precipitating soluble phosphates. Because fertilizer is purchased for the agricultural system, the cost of salt for the solar pond is determined by the real interest for holding the fertilizer in inventory. These economics make feasible several desirable maintenance schedules for the solar pond.     

Dependence of ground heat loss upon solar pond size and perimeter insulation calculated and experimental results

Ground heat losses from solar ponds are modelled numerically for various perimeter insulation strategies and several solar pond sizes. The numerical simulations are steady state calculations of heat loss from a circular or square pond to a heat sink at the outer boundaries of an earth volume that surrounds the pond on the bottom and sides. Simulation results indicate that insulation on top of the ground around the pond perimeter is rather ineffective in reducing heat loss, and that uninsulated sloping side walls are slightly more effective than insulated vertical side walls, except for very small ponds. The numerical results are used to derive coefficients for a semi-empirical equation describing ground heat loss as a function of pond area, pond perimeter and insulation strategy. Experimental results for ground heat loss and energy balance in the 400 m² solar pond at the Ohio State University are reported. Analysis of this data, along with data on solar energy input, heat gain by the pond, heat loss through the gradient zone, and heat extraction from the pond yields a good energy balance. Numerical simulation of ground heat loss from this pond shows good agreement with the results obtained from pond measurements. Loss turns out to be large because of unexpectedly high values of earth thermal conductivity in the region.     

Experimental and numerical investigations of mixing in raceway ponds for algae cultivation

The current high interest in the algae sector is leading to the development of several demo/commercial scale projects, either for the food market or bioenergy production. Raceway Ponds (RWPs) are a widely used technology for algae mass cultivation. RWPs were developed long time ago, and thus capital and operating costs are well assessed. Nevertheless, room still exists to further reduce operational costs. A possible route towards energy optimization and therefore operational cost reduction can be identified through a better understanding of the mixing phenomena.The focus of the present work is that vertical mixing, defined as the cyclical movement of the algal cells between surface and bottom layers of the culture, cannot be completely determined by considering only turbulence, and therefore it is not represented by the Re number.A 3D Computational Fluid Dynamic (CFD) analysis of a conventional RWP was carried out based on a multi-phase “Volume of Fluid” model, in order to investigate the flow field of the culture in the pond. The CFD results were compared with experimental measures on a 20 m² pilot RWP. Once agreement among CFD and experimental results was shown, a statistical evaluation of the trajectories calculated for algae particles in the flow was carried out. The aim of this statistical evaluation was to define the level of vertical mixing in different sections of the pond.The model proposed was then used to scale-up the results to a demo/pre-commercial size RWP (500 m²). The standard deviation of the actual trajectory was calculated with respect to the undisturbed trajectory for each section modeled.The results of the simulation showed that a limited mixing is to be expected in RWPs. In the long straight parts of the pond vertical mixing is poor and algae tend to settle to the bottom. Only in the bends the vortexes produced by flow separation move part of the culture from the bottom to the top and vice-versa. This result does not fit with the practice, typically observed in large scale ponds, of reducing vortexes around the bends by placing baffles. The method described can be applied to different pond designs operated at different culture velocities.     

Microalgal biomass production and carbon dioxide sequestration from an integrated ethanol biorefinery in Iowa: A technical appraisal and economic feasibility evaluation

Microalgae present some advantageous qualities for reducing carbon dioxide (CO₂) emissions from ethanol biorefineries. As photosynthetic organisms, microalgae utilize sunlight and CO₂ to generate biomass. By integrating large-scale microalgal cultivation with ethanol biorefineries, CO₂ sequestration can be coupled with the growth of algae, which can then be used as feedstock for biodiesel production. In this case study, a 50-mgy ethanol biorefinery in Iowa was evaluated as a candidate for this process. Theoretical projections for the amount of land needed to grow algae in raceway ponds and the oil yields of this operation were based on the amount of CO₂ from the ethanol plant. A practical algal productivity of 20 g m⁻² d⁻¹ would require over 2,000 acres of ponds for complete CO₂ abatement, but with an aggressive productivity of 40–60 g m⁻² d⁻¹, a significant portion of the CO₂ could be consumed using less than 1,000 acres. Due to the cold temperatures in Iowa, a greenhouse covering and a method to recover waste heat from the biorefinery were devised. While an algal strain, such as Chlorella vulgaris, would be able to withstand some temperature fluctuations, it was concluded that this process is limited by the amount of available heat, which could maintain only 41 acres at 73 °F. Additional heating requirements result in a cost of 10–40 USD per gallon of algal oil, which is prohibitively expensive for biodiesel production, but could be profitable with the incorporation of high-value algal coproducts.     

Comparative performance evaluation of fertiliser solar pond under simulated conditions

An experimental test rig for solar pond simulation was developed to study the chosen fertiliser salt, Muriate of Potash (MOP) for use in a solar pond under simulated conditions with provisions to vary the heating input and maintain a particular lower convective zone temperature. The performance, in terms of temperature and density profiles, was studied for MOP and was compared with that of sodium chloride and saltless solar ponds for different heating regimes and lower convective zone temperatures. The formation of three zones viz., upper convective zone, nonconvective zone, and lower convective zone was distinct at all heating combinations for both MOP and sodium chloride salts under simulated conditions. The temperature and density gradients were not affected significantly by intermittent no-heating spells of the solar ponds. Maintaining lower convective zone temperature of 70 °C and above led to the initiation of minor internal convective zone under simulated conditions. The temperature decay of lower convective zone (LCZ) was at lesser rate for different LCZ temperatures associated with both the heating regimes, for a MOP pond over a 24 h period of cessation of heating as compared to sodium chloride and saltless ponds.