Rapidly mixed combustion of hydrogen/oxygen diluted by N2 and CO2 in a tubular flame combustor

In this study hydrogen flames have been attempted in a rapidly mixed tubular flame combustor for the first time, in which fuel and oxidizer are individually and tangentially injected into a cylindrical combustor to avoid flame flash back. Three different cases were designed to examine the effects of fuel and oxidizer feeding method, diluent property, oxygen content and equivalence ratio on the characteristics of hydrogen flame, including the flame structure, lean extinction limit, flame stability and temperature. The results show that by enhancing mixing rate through feeding system, the range of equivalence ratio for steady tubular flame can be much expanded for the N₂ diluted mixture, however, at the oxygen content of 0.21 (hydrogen/air) the steady tubular flame is achieved only up to equivalence ratio of 0.5; by decreasing oxygen content, the lean extinction limit slightly increases, and the upper limit for steady tubular flame establishment increases significantly, resulting in an expanded tubular flame range. For CO₂ diluted mixture, the stoichiometric combustion has been achieved within oxygen content of 0.1 and 0.25, for which the burned gas temperature is uniformly distributed inside the flame front; as oxygen content is below 0.21, a steady tubular flame can be obtained from the lean to rich limits; and the lean extinction limit increases from 0.17 to 0.4 as oxygen content decreases from 0.21 to 0.1, resulting in a shrunk tubular flame range. Laminar burning velocity, temperature and Damköhler number are calculated to examine the differences between N₂ and CO₂ diluted combustion as well as the requirement for hydrogen-fueled tubular flame establishment.     

Numerical study on the extinction dynamics of partially premixed meso-scale methane-air jet flames with hydrogen addition

In this paper, a model of partially premixed jet flames that sustained above a meso-scale short tube was established for an individual flame port of domestic gas stoves. The effects of hydrogen addition (volume ratio β = 0%, 10%, 20%, 30%) on the extinction dynamics of CH₄-air jet flames were numerically investigated. It is found that flame oscillation occurs once (β = 10% and 20%) or twice (β = 30%) in the extinction process. Moreover, the larger of β, the longer the extinction process can sustain. Analysis was performed in terms of both chemical effect and thermal effect. As to the chemical effect, in the first place, the reaction rate decreases as the inlet velocity is reduced. As a result, the consumption rate of O₂ will be less than the supply rate from the incoming mixture, which makes the O₂ concentration in the flame center increase. On the other hand, the amount of H radicals increases with the increase of β, and when the O₂ content at the flame center reaches a “critical point”, the key elementary reaction “H + O₂ ? O + OH” will be enhanced and consequently the total reaction rate will also be intensified. After that, the consumption rate of O₂ will be larger than the supply rate due to the reduced flow rate of incoming mixture. The total heat release rate will decrease sharply and extinction occurs. As regards the thermal effect, it is revealed that heat recirculation effect (indirect preheating effect) lags behind the variation of the reaction zone (i.e., flame), thus, it has a negligible impact on flame oscillation. In contrast, the preheating temperature in the vicinity of flame front (named as “direct preheating effect”) exhibits a similar variation tendency with the total heat release rate of the flame. And the larger of β, the more remarkable of the direct preheating effect can be. In summary, due to the chemical effect and thermal effect caused by hydrogen addition, the flame can survive for a longer time with fluctuation during the extinction process.     

Experimental and numerical investigation on combustion characteristics of premixed hydrogen/air flame in a micro-combustor with a bluff body

Combustion characteristics of lean hydrogen/air mixture in a planar micro-channel with a bluff body were investigated experimentally and numerically. Effects of the inlet velocity and equivalence ratio on the blow-off limit, combustion efficiency and exhaust gas temperature were examined. The results show that the blow-off limit is greatly extended as compared with that of the micro-combustor without a bluff body. Moreover, the blow-off limit increases as the equivalence ratio is increased from 0.4 to 0.6. Furthermore, with the increase of inlet velocity, the flame front is prolonged and becomes narrower, and the high temperature segment of outer wall shifts downstream. In addition, the combustion efficiency and exhaust gas temperature increase first and then decrease with the increase of the inlet velocity. Finally, comparatively high combustion efficiency can be maintained over the whole combustible velocity range at a moderate equivalence ratio.     

Buoyancy effects on hydrogen diffusion flames confined in a small tube

In this work, buoyancy effects on hydrogen jet flames confined in a small tube without air co-flow were numerically investigated. The results show that the extinction limit of fuel velocity under buoyant condition is much lower than that without buoyancy. Moreover, hydrogen flames under buoyant condition attatch the nozzle exit for all fuel velocities investigated; however, the flames without buoyancy surround the lower wall at low fuel velocity. In addition, combustion is nearly complete in the presence of buoyancy, whereas the combustion efficiency under non-buoyant condition is below 45%. Furthermore, flame temperature under buoyant condition is much higher compared to the counterpart under non-buoyant condition at low and moderate fuel velocities. Analysis reveals that in the case without buoyancy, the negative gauge pressure in the annular space is unable to entrain sufficient air from the ambient. Hence, hydrogen has to diffuse downwards to sustain the flame and complete combustion is unrealizable.     

Formation and O2/CO2 combustion characteristics of real-environment coal char in high-temperature oxy-fuel conditions

Oxygen-fuel combustion is a promising technology for CO₂ emission reduction. The high-temperature entrained flow reactor and high-temperature drop tube furnace were used to analyses the formation and O₂/CO₂ combustion characteristics of real-environment coal char in high-temperature oxy-fuel conditions. It proposed “inflection point standard” of high-temperature flame method for the preparation of real-environmental oxy-fuel coal char according to the flame method. The results show that the ratios of C=O/C-O and C=O/C_ar increase in the coal char compared with the raw coals. The trend of C=O/C_ar in oxy-fuel condition is opposite to that in the inert atmosphere, due to the effect of high-concentration CO₂. To achieve the burnout rate similar to air combustion for coal char, with the increase of coal rank, the O₂ concentration should be enhanced. The optimal O₂ concentration for the oxy-fuel combustion of JC anthracite is 30%, while that of other low-rank coals could be lower than 30%. The combustion characteristic of JC anthracite is with the highest sensitivity to temperature and O₂ concentration.     

Numerical study on premixed hydrogen/air combustion characteristics in micro–combustor with slits on both sides of the bluff body

An approach to improve premixed hydrogen/air combustion in micro combustor is numerically studied in this paper. The micro–combustor with slits on both sides of the bluff body shows better combustion efficiency and uniformity of temperature distribution. The effects of the controllable flow ratio (γ) and the angle of bluff body (θ) on combustion characteristics are investigated by using a two–dimensional model with the H₂/O₂ reaction mechanism. The results show that the increase of controllable flow ratio and angle of bluff body can improve combustion efficiency and decrease velocity extinction limit. However, at higher θ, increasing γ do not play an important role in improving combustion efficiency. In addition, at higher inlet velocity, combustion efficiency do not increase dramatically with the increase of θ. Moreover, at high inlet velocity, a special phenomenon of temperature ‘waist’ is observed in the micro–combustor with slits on both sides of the bluff body, which has a huge impact on combustion characteristics. Therefore, controllable flow ratio and angle of bluff body should be reasonably chosen to improve combustion characteristics.     

Effect of hydrogen enrichment and electric field on lean CH4/air flame propagation at elevated pressure

Electric assisted combustion for hydrogen enriched hydrocarbons may even extend the lean burn limit and provide the further improvement on combustion stability. This study investigates the effect of hydrogen enrichment and DC electric field on lean CH₄/air flame propagation. Electric field inside the chamber was generated by mesh and needle electrodes. Effect of hydrogen enrichment on the ion mole fraction in the flame was discussed based on reaction mechanism included neutral and ion reactions. The flame propagation images, flame displacement speed were used to evaluate the combined influences of hydrogen enrichment and electric field on propagating flame. Results showed that the hydrogen addition would increase positive ions mole fraction and the peak value is mainly determined by H₃O⁺. This would be due to that CH increases with hydrogen fraction, which is the main species in the initial reaction for the ion reactions. Electric field effect about flame propagation was suppressed with hydrogen addition due to the competition between the increment in ion mole fraction and the decrement in flame time. Electric assisted combustion is more evident at leaner conditions and elevated pressure. The ratio of ionic wind velocity to flow velocity may be the determined factor to predict the electric field effect about propagating flame. The tendency based on this ratio is in accordance with the experimental results for various hydrogen fraction and equivalence ratio at elevated pressure.     

Effect of the composition of the hot product stream in the quasi-steady extinction of strained premixed flames

The extinction of premixed CH₄/O₂/N₂ flames counterflowing against a jet of combustion products in chemical equilibrium was investigated numerically using detailed chemistry and transport mechanisms. Such a problem is of relevance to combustion systems with non-homogeneous air/fuel mixtures or recirculation of the burnt gases. Contrary to similar studies that were focused on heat loss/gain, depending on the degree of non-adiabaticity of the system, the emphasis here was on the yet unexplored role of the composition of counterflowing burnt gases in the extinction of lean-to-stoichiometric premixed flames. For a given temperature of the counterflowing products of combustion, it was found that the decrease of heat release with increase in strain rate could be either monotonic or non-monotonic, depending on the equivalence ratio φ_b of the flame feeding the hot combustion product stream. Two distinct extinction modes were observed: an abrupt one, when the hot counterflowing stream consists of either inert gas or equilibrium products of a stoichiometric premixed flame, and a smooth extinction, when there is an excess of oxidizing species in the combustion product stream. In the latter case four burning regimes can be distinguished as the strain rate is progressively increased while the heat release decreases smoothly: an adiabatic propagating flame regime, a non-adiabatic propagating flame regime, the so-called partially-extinguished flame regime, in which the location of the peak of heat release crosses the stagnation plane, and a frozen flow regime. The flame structure was analyzed in detail in the different burning regimes. Abrupt extinction was attributed to the quenching of the oxidation layer with the entire H-OH-O radical pool being comparably reduced. Under conditions of smooth extinction, the behavior is different and the concentration of the H radical decreases the most with increasing strain rate, whereas OH and O remain comparatively abundant in the oxidation layer. As the profile of the heat release rate thickens, the oxidation layer is quenched and the attack of the fuel relies more heavily on the OH radicals.     

Influence of controllable slit width and angle of controllable flow on hydrogen/air premixed combustion characteristics in micro combustor with both sides–slitted bluff body

To improve the combustion stability of micro combustor, both sides-slitted bluff body is applied to the micro combustor. The H₂/O₂ reaction mechanism is used to study the influence of controllable slit width (d) and angle of controllable flow (β) on combustion characteristics of the micro-combustor. The result shows that the reduction of d can significantly improve the combustion efficiency. Under the same controllable flow ratio (γ), the reduction of d can effectively expand the recirculation region. However, the blow-off limit will be reduced if d is too large or too small. With the same γ, the recirculation region and low-velocity zone expand when β decreases, which can entrain more high-temperature gas and increase the residence time of fuel in the low-velocity zone, thus improving the combustion efficiency. The residence time of fuel in the combustor will be reduced when β is too large or small, resulting in lower combustion efficiency and blow-off limit. Therefore, it is significant to choose the parameter of d and β.     

Effect of hydrogen percentage and air jet Reynolds number on fuel lean flame stability of LPG-fired inverse diffusion flame with hydrogen enrichment

The flame type studied in this paper is a circumferential-fuel – jet inverse diffusion flame, and the fuel is liquefied petroleum gas enriched with hydrogen gas. Fuel lean flame stability limit regarding to the volumetric percentage of hydrogen and the air jet Reynolds number was investigated. There were three flame stable-related limits examined: local extinction limit, restore limit, and complete extinction limit. Global Energy Consumption Rate of fuel, fuel jet velocity, and overall equivalence ratio of the air/fuel mixture at the three stable-related limits were presented. Experimental results indicate that with hydrogen addition, the inverse diffusion flame can sustain burning with a lower global energy than without it. The most significant stabilization effect was obtained with 30% hydrogen addition for complete extinction limit and 30%–90% for local extinction limit. The corresponding fuel jet velocity at complete extinction limit also decreases with hydrogen addition. However, fuel jet velocities at local extinction limit and restore limit increase significantly, when hydrogen percentage is larger than 70%. Air jet Reynolds number does not show notable influence on Global Energy Consumption Rate or fuel jet velocity at the three stability limits. In addition, overall equivalence ratio, which is an important parameter of inverse diffusion flame combustion dropping dramatically with air jet Reynolds number when it is less than 2000.     

The effect of the blockage ratio on the blow-off limit of a hydrogen/air flame in a planar micro-combustor with a bluff body

We recently developed a micro-combustor with a bluff body, which has a demonstrated 3- to 5-time extension in the blow-off limit. In the present work, the dimension effect of the bluff body on the blow-off limit (indicated by the blockage ratio, ζ) was investigated with a detailed H₂/O₂ reaction mechanism. The results indicate that the blow-off limits for ζ = 0.3, 0.4 and 0.5 are 20, 31 and 36 m/s, respectively. Analyses reveal that for ζ = 0.3, flame blowout occurs due to insufficient recirculation zone size. However, flame blowout occurs due to the stretching effect in the shear layers when ζ = 0.4 and 0.5. Calculations indicate that the three cases have negligible differences in heat loss because the high temperature zones are located in the combustor centers; therefore, their effects on the combustor walls are mitigated.     

An experimental study of syngas combustion in a bidirectional swirling flow

The paper reports on the results of an experimental study of methane and syngas combustion as well as their co-firing in a bidirectional swirling flow. The results confirmed that the bidirectional flow structure provides a significant decrease in the lean blow-off equivalence ratio as well as that of emissions of main pollutants. The combustion intensification becomes more evident when using syngas is as fuel. The composition of the used syngas is as follows (by volume): H₂ - 29.42%; CO - 14.32%; CH₄ - 3.8%; N₂ - 49.11%; H₂O - 3.35%. In this case, the lean blow-off is achieved at ? < 0.1, NOx emission is halved, while CxHy and CO emissions become 20 times less compared to pure methane combustion. However, according to experimental results, the co-combustion of syngas (volume fraction V_syn = 15%) and methane is the most appropriate fuel utilization mode. It provides blow-off and emission properties similar to those for combustion of pure syngas, whereas energy consumption for its production is much lower. Moreover, unlike hydrocarbon fuel combustion, that of syngas in a bidirectional swirling flow is characterized by the presence of density stratification. This is accompanied by the flame formation at significantly different locations in the combustion chamber at lean and “ultra-lean” modes of operation. Hydrogen combustion most likely to occur in the core region at near-blow-off modes ? < 0.1, whereas normal ‘operating modes in the range 0.2 = ? ≤ 0.4 result in the formation of a conical flame surface where CH₄ and CO combustion occurs. These new results with respect to the flame structure as well as blow-off and emission properties make it possible to consider bidirectional vortex combustors for application in modern gas turbine power plants in order to meet the strict environmental and energy requirements.     

A computational study of combustion and extinction of opposed-jet syngas diffusion flames

This paper reports a numerical study on the combustion and extinction characteristics of opposed-jet syngas diffusion flames. A model of one-dimensional counterflow syngas diffusion flames was constructed with constant strain rate formulations, which used detailed chemical kinetics and thermal and transport properties with flame radiation calculated by statistic narrowband radiation model. Detailed flame structures, species production rates and net reaction rates of key chemical reaction steps were analyzed. The effects of syngas compositions, dilution gases and pressures on the flame structures and extinction limits of H₂/CO synthetic mixture flames were discussed. Results indicate the flame structures and flame extinction are impacted by the compositions of syngas mixture significantly. From H₂-enriched syngas to CO-enriched syngas fuels, the dominant chain reactions are shifting from OH + H₂→H + H₂O for H₂O production to OH + CO→H + CO₂ for CO₂ production through the key chain-branching reaction of H + O₂→O + OH. Flame temperature increases with increasing hydrogen content and pressure, but the flame thickness is decreased with pressure. Besides, the study of the dilution effects from CO₂, N₂, and H₂O, showed the maximum flame temperature is decreased the most with CO₂ as the dilution gas, while CO-enriched syngas flames with H₂O dilution has highest maximum flame temperature when extinction occurs due to the competitions of chemical effect and radiation effect. Finally, extinction limits were obtained with minimum hydrogen percentage as the index at different pressures, which provides a fundamental understanding of syngas combustion and applications.     

On a porous medium combustor for hydrogen flame stabilization and operation

In this study, the characteristics of hydrogen flame stabilization in porous medium combustor were investigated. The flame was observed in a quartz tube. The porous medium was oxide-bonded silicon carbide (OB-SiC) or aluminum oxide (Al₂O₃) with 60 PPI and 30 PPI pore size distributions. The results indicated that under a low equivalence operation, the flame would transform from surface combustion to interior combustion with an increased heating value. Under a high equivalence ratio, both interior combustion and flashback transition existed at the same time. The thermal conductivity of silicon carbide is higher than that of aluminum oxide. Thus, interior combustion region was more extensive under a low equivalence ratio operation with a high premixed gas velocity. Flashback was apparent for Al₂O₃ under high an equivalence ratio with low a premixed gas velocity. Consequently, hydrogen flame stability could be controlled by the pore size distribution and thermal conductivity of the porous media, input heating value and input equivalence ratio.     

Numerical investigation of diluent influence on flame extinction limits and emission characteristic of lean-premixed H2-CO (syngas) flames

In recent years, research efforts have been channeled to explore the use of environmentally-friendly clean fuel in lean-premixed combustion so that it is vital to understand fundamental knowledge of combustion and emissions characteristics for an advanced gas turbine combustor design. The current study investigates the extinction limits and emission formations of dry syngas (50% H₂-50% CO), moist syngas (40% H₂-40% CO-20% H₂O), and impure syngas containing 5% CH₄. A counterflow flame configuration was numerically investigated to understand extinction and emission characteristics at the lean-premixed combustion condition by varying dilution levels (N₂, CO₂ and H₂O) at different pressures and syngas compositions. By increasing dilution and varying syngas composition and maintaining a constant strain rate in the flame, numerical simulation showed among diluents considered: CO₂ diluted flame has the same extinction limit in moist syngas as in dry syngas but a higher extinction temperature; H₂O presence in the fuel mixture decreases the extinction limit of N₂ diluted flame but still increases the flame extinction temperature; impure syngas with CH₄ extends the flame extinction limit but has no effect on flame temperature in CO₂ diluted flame; for diluted moist syngas, extinction limit is increased at higher pressure with the larger extinction temperature; for different compositions of syngas, higher CO concentration leads to higher NO emission. This study enables to provide insight into reaction mechanisms involved in flame extinction and emission through the addition of diluents at ambient and high pressure.     

Numerical investigation on mixing performance and diffusion combustion characteristics of H2 and air in planar micro-combustor

In the present work, the effects of inlet velocity and channel height (H₀ = 0.6 mm, 1.0 mm and 1.4 mm) on the mixing performance, flame stability limit and combustion efficiency of H₂ and air in a 2D planar micro-combustor with a separating plate were studied numerically. The results demonstrate that improved mixing can be achieved with a decrease in inlet velocity and channel height. Moreover, the flame blow-off limit is the largest for a micro-combustor with H₀ = 0.6 mm; the flame becomes inclined at a high velocity and the direction varies with the inlet velocity. Furthermore, a micro-combustor with a medium height (H₀ = 1.0 mm) can achieve the largest blowout limit among the three cases. Finally, for identical inlet velocities, the combustion efficiency increases with decreasing combustor height. In summary, these findings can provide a guideline for the optimal design of such micro-combustors.     

Non-equilibrium plasma assisted combustion of low heating value fuels

This paper describes the effects of non-equilibrium air plasma generated by a dielectric barrier discharge (DBD) on the combustion of low heating value fuels. The experimental results indicate that addition of a very small amount of energy to the air flow in the form of DBD significantly improves the flame stability. Moreover, main combustion characteristics such as flame propagation speed, combustion intensity and lean blow-off limits are also enhanced by the effect of plasma. Some active radicals such as excited O atom and excited N2 molecule are observed by spectrograph in the discharge area. Based on the results of numerical investigation we can conclude that these active radicals generated in discharge area can accelerate the production rate of active OH radical which plays a key role in the oxidation process of low heating value fuel, and thus the whole combustion process is accelerated.     

Experimental investigation of thermoacoustic coupling using blended hydrogen–methane fuels in a low swirl burner

In this study, experimental testing and analysis were performed to examine the combustion instability characteristics of hydrogen–methane blended fuels for a low-swirl lean premixed burner. The aim of this study is to determine the effect of hydrogen addition on combustion instability, and this is assessed by examining the flame response to a range of constant amplitude, single frequency chamber acoustic modes. Three different blends of hydrogen and methane (93% CH₄–7% H₂, 80% CH₄–20% H₂ and 70% CH₄–30% H₂ by volume) were employed as fuel at an equivalence ratio of 0.5, and with four different acoustic excitation frequencies (85, 125, 222 and 399 Hz). Planar laser induced fluorescence of the hydroxyl radical (OH-PLIF) was employed to measure the OH concentration at different phases of acoustic excitation and a Rayleigh Index was then calculated to determine the degree of thermoacoustic coupling. It was found, as has been previously reported, that the combustion characteristics are very sensitive to the fraction of hydrogen in the fuel mixture. The flame shows significant increases in flame base coupling and flame compaction with increasing hydrogen concentration for all conditions. While this effect enhances the flame response at non-resonant frequencies, it induces only minimal compaction and appears to decreases the coupling intensity at the resonant frequency.     

A novel Swiss-roll micro-combustor with double combustion chambers: A numerical investigation on effect of solid material on premixed CH4/air flame blow-off limit

A novel Swiss-roll micro-combustor with double combustion chambers is proposed to improve flame stability and extend blow-off limits. This study is aimed to numerically investigate the effect of solid material (i.e., SiC, stainless steel and copper) on premixed CH₄/air flame blow-off limit and reveal the flame stability mechanism. The simulated results show that this developed novel Swiss-roll micro-combustor not only can significantly anchor the flame owing to the flow recirculation behind the flame holders and the backward-facing steps, but also can further extend CH₄ blow-off limits owing to heat recirculation in the long Swiss-roll preheating channels. The three solid material micro-combustors present the relatively slight difference in the recirculation-zone size but the remarkably difference in heat recirculation and heat loss. Good heat recirculation and low heat loss rate are the dominant reason that is responsible for the differences of the blow-off limits in this micro-combustor. The stainless steel micro-combustor achieves the highest blow-off limits while the copper micro-combustor achieves the lowest blow-off limit. These deep insights can give some useful information to design a similar Swiss-roll micro-combustor.     

Effect of hydrogen addition on the combustion and emission of a diesel free-piston engine

The free-piston engine (FPE) is a new crankless engine, which operates with variable compression ratio, flexible fuel applicability and low pollution potential. A numerical model which couples with dynamic, combustion and gas exchange was established and verified by experiment to simulate the effects of different hydrogen addition on the combustion and emission of a diesel FPE. Results indicate that a small amount of hydrogen addition has a little effect on the combustion process of the FPE. However, when the ratio of hydrogen addition (R_H2) is more than 0.1, the R_H2 gives a positive effect on the peak in-cylinder gas pressure, temperature, and nitric oxide emission of the FPE, while soot emission decreases with the increase of hydrogen addition. Moreover, the larger R_H2 induces a longer ignition delay, shorter rapid combustion period, weaker post-combustion effect, greater heat release rate, and earlier peak heat release rate for the FPE. Nevertheless, the released heat in rapid combustion period is significantly enhanced by the increase of R_H2.