加氢站流程和配置技术现状与展望

加氢站（HRS）是氢能高效利用的重要环节,是促进燃料电池汽车行业发展的重要基础设施。本文介绍了外供氢加氢站一般系统流程及配置方法;整理了国内外关于系统流程的优化措施,其中包括常规系统的部件（如长管拖车、站侧储罐配置及预冷系统）的配置优化,以及非常规部件的新型系统（如喷射器、涡流管或膨胀机）的集成;最后对未来优化方向进行了展望。     

Techno-economic assessment of green hydrogen valley providing multiple end-users

A techno-economic analysis of a hydrogen valley is carried out in this paper. A hydrogen generator fed by a wind farm (WF) and/or a photovoltaic (PV) plant supplies four end-users: a stationary fuel cell, a hydrogen refuelling station, the injection in the natural gas pipeline and, in case of sufficient hydrogen surplus, a biological hydrogen methanation (BHM) process.The results demonstrated that an efficiency improvement and a reduction in hydrogen production costs arise from a balanced supply from wind and solar energy. Without the inclusion of a BHM process, hydrogen production costs lower than 7 €/kg were achieved by a hydrogen generator using 10–12% of the PV + WF annual energy with a PV share of 20%–50%. The hydrogen production costs were further reduced to 5 €/kg by introducing a BHM process and increasing the percentage of electrical energy supplied by the PV + WF system to 25% of its overall production.     

Safety investigation of hydrogen charging platform package with CFD simulation

Hydrogen has been expected as one of the most promising green energy sources, especially in transportation section. Despite its great potential as a new source of energy, it is reluctant to build hydrogen charging stations for the fear of accidents such as hydrogen leakage, fire, and following explosion. To reduce those problems and promote the acceptance of hydrogen charging station, this study focuses on the hydrogen charging platform package (HCPP) which is a new type of the mobile hydrogen station. Hydrogen leakage cases are investigated using CFD (computational fluid dynamics) simulation. The simulation is performed with the whole configuration of the HCPP including main components, storage, compressor, and dispenser. Based on the risk assessment, hydrogen leak scenarios with high possibilities of accidents are simulated. The simulation results show the leak length of hydrogen gas, its dispersion, and the various ranges of volume ratios of leaked hydrogen gas. Based on the simulation results, it is clearly confirmed that the leaked hydrogen gas with high concentration stays inside the HCPP. Therefore, the effects of ventilation to reduce the possibility of the explosion are continuously considered to investigate the safety of the HCPP in the case of the leakage accident.     

Assessment of offshore liquid hydrogen production from wind power for ship refueling

Green hydrogen from electrolysis has become the most attractive energy carrier for making the transition from fossil fuels to carbon-free energy sources possible. Especially in the naval sector, hydrogen has the potential to address environmental targets due to the lack of low-carbon fuel options. This study aims at investigating an offshore liquefied green hydrogen production plant for ship refueling. The plant comprises a wind farm for renewable electricity generation, an electrolyzer stack for hydrogen production, a water treatment unit for demineralized water production, and a hydrogen liquefaction plant for hydrogen storage and distribution to ships. A pre-feasibility study is addressed to find the optimal capacities of the plant that minimize the payback time. The model results show that the electrolyzer capacity shall be set equal to a value between 80% and 90% of the wind farm capacity to achieve the minimum payback times. Additionally, the wind farm capacity shall be higher than about 150 MW to limit the payback time to values lower than 11 years for a fixed hydrogen price of 6 €/kg. The Levelized Cost of Hydrogen results to be below 4 €/kg for a wide range of plant capacities for a lifetime of the plant of 25 years. Thus, the model shows that this plant is economically feasible and can be reproduced similarly for different locations by rescaling the different selected technologies. In this way, the naval sector can be decarbonized thanks to a new infrastructure for the production and refueling of liquified green hydrogen directly provided on the sea.     

Techno-economic evaluation of hydrogen refueling stations with liquid or gaseous stored hydrogen

In this study, different hydrogen refueling station (HRS) architectures are analyzed energetically as well as economically for 2015 and 2050. For the energetic evaluation, the model published in Bauer et al. [1] is used and norm-fitting fuelings according to SAE J2601 [2] are applied. This model is extended to include an economic evaluation. The compressor (gaseous hydrogen) resp. pump (liquid hydrogen) throughput and maximum pressures and volumes of the cascaded high-pressure storage system vessels are dimensioned in a way to minimize lifecycle costs, including depreciation, capital commitment and electricity costs. Various station capacity sizes are derived and energy consumption is calculated for different ambient temperatures and different station utilizations. Investment costs and costs per fueling mass are calculated based on different station utilizations and an ambient temperature of +12 °C. In case of gaseous trucked-in hydrogen, a comparison between 5 MPa and 20 MPa low-pressure storage is conducted. For all station configurations and sizes, a medium-voltage grid connection is applied if the power load exceeds a certain limit. For stations with on-site production, the electric power load of the hydrogen production device (electrolyzer or gas reformer) is taken into account in terms of power load. Costs and energy consumption attributed to the production device are not considered in this study due to comparability to other station concepts. Therefore, grid connection costs are allocated to the fueling station part excluding the production device. The operational strategy of the production device is also considered as energy consumption of the subsequent compressor or pump and the required low-pressure storage are affected by it. All station concepts, liquid truck-supplied hydrogen as well as stations with gaseous truck-supplied or on-site produced hydrogen show a considerable cost reduction potential. Long-term specific hydrogen costs of large stations (6 dispensers) are 0.63 €/kg – 0.76 €/kg (dependent on configuration) for stations with gaseous stored hydrogen and 0.18 €/kg for stations with liquid stored hydrogen. The study focuses only on the refueling station and does not allow a statement about the overall cost-effectiveness of different pathways.     

Rapid sizing of a hydrogen-battery storage for an offshore wind farm using convex programming

This paper carries out a comprehensive analysis on an offshore wind farm equipped with a hybrid storage comprised of hydrogen and battery, from the perspective of economic effectiveness. To rapidly evaluate the system economy, a computationally efficient convex program that takes the nonlinear storage efficiencies into account is provided, which can simultaneously and synergistically optimize the storage sizing and energy management over a long offshore wind cycle. In the analysis, a case study on the optimal configuration and operation of the hybrid storage is thoroughly investigated, answering what the scalings are and how the storage functions in the offshore wind farm. Comparisons to other offshore wind farms with none or only one storage type further demonstrate the advantage of combining hydrogen plant and battery. Influences of the offshore wind electricity price of grid parity and hydrogen price on the system economies, in the terms of total annual cost, net annual profit and hydrogen production cost, are also discussed, revealing sensitivity and dependency of the scalings. Finally, this paper presents the future potential of applying hydrogen plant in the offshore wind farm, from the angles of hydrogen production cost and energy saving.     

Review on equipment configuration and operation process optimization of hydrogen refueling station

The construction of hydrogenation infrastructure is important to promote the large-scale development of hydrogen energy industry. The technical performance of hydrogen refueling station (HRS) largely determines the refueling efficiency and cost of hydrogen fuel cell vehicles. This paper systematically lists the hydrogen refueling process and the key equipment applicable in the HRS. It comprehensively reviews the key equipment configuration from the hydrogen supply, compression, storage and refueling of the HRS. On the basis of the parameter selection and quantity configuration method, the process optimization technology related to the equipment utilization efficiency and construction cost was quantitatively evaluated. Besides, the existing problems and prospects are put forward, which lays the foundation for further research on the technical economy of HRSs.     

Techno-economical evaluation of a hydrogen refuelling station powered by Wind-PV hybrid power system: A case study for İzmir-Çeşme

Hydrogen fuelling station is an infrastructure for the commercialisation of hydrogen energy utilising fuel cells, particularly, in the automotive sector. Hydrogen fuel produced by renewable sources such as the solar and wind energy can be an alternative fuel to depress the use of fuels based on fossil sources in the transport sector for sustainable clean energy strategy in future. By replacing the primary fuel with hydrogen fuel produced using renewable sources in road transport sector, environmental benefits can be achieved. In the present study, techno-economic analysis of hydrogen refuelling station powered by wind-photovoltaics (PV) hybrid power system to be installed in ?zmir-Çe?me, Turkey is performed. This analysis is carried out to a design of hydrogen refuelling station which is refuelling 25 fuel cell electric vehicles on a daily basis using hybrid optimisation model for electric renewable (HOMER) software. In this study, National Aeronautics and Space Administration (NASA) surface meteorology and solar energy database were used. Therefore, the average wind speed during the year was assessed to be 5.72 m/s and the annual average solar irradiation was used to be 5.08 kW h/m²/day for the considered site. According to optimisation results obtained for the proposed configuration, the levelised cost of hydrogen production was found to be US $7.526–7.866/kg in different system configurations. These results show that hydrogen refuelling station powered by renewable energy is economically appropriate for the considered site. It is expected that this study is the pre-feasibility study and obtained results encougare the hydrogen refuelling station to be established in Turkey by inventors or public institutions.     

Multi-objective optimization of wind-hydrogen integrated energy system with aging factor

Large-scale hydrogen production with wind power generation has been gaining increasing attention and applications. Achieving a good balance between the capacity and cost of wind power generation however remains as a critical challenge restricting the development of wind-hydrogen integrated energy systems (WHIES). In addition, the aging factor may come in over time, making negative impacts on the efficiency and cost of WHIES. In this work, a method is proposed to seek a good balance between the capacity and cost of WHIES. Specifically, by comparing operational data and equipment condition, we evaluate the aging status of the wind power generation system and the hydrogen production system, then the aging economic model of WHIES is proposed. By taking into account the actual operating conditions in constructing the WHIES objective function with the aging factor, the proposed model allows striving to maximize the production capacity with the minimum cost. An improved multi-objective gray wolf optimizer algorithm is developed to solve the WHIES cost optimization problem. Finally, case studies are carried out via MATLAB based on the configuration and experimental data for a specific wind farm located in Ningxia, China. Our results help achieve a balance between maximizing capacity and minimizing cost under various conditions.     

Life cycle assessment of various hydrogen production methods

A comprehensive life cycle assessment (LCA) is reported for five methods of hydrogen production, namely steam reforming of natural gas, coal gasification, water electrolysis via wind and solar electrolysis, and thermochemical water splitting with a Cu–Cl cycle. Carbon dioxide equivalent emissions and energy equivalents of each method are quantified and compared. A case study is presented for a hydrogen fueling station in Toronto, Canada, and nearby hydrogen resources close to the fueling station. In terms of carbon dioxide equivalent emissions, thermochemical water splitting with the Cu–Cl cycle is found to be advantageous over the other methods, followed by wind and solar electrolysis. In terms of hydrogen production capacities, natural gas steam reforming, coal gasification and thermochemical water splitting with the Cu–Cl cycle methods are found to be advantageous over the renewable energy methods.     

Generation of typical operation curves for hydrogen storage applied to the wind power fluctuation smoothing mode

In this paper, a typical-operation-curve generation method of a hydrogen energy storage system operating under the mode of stabilizing wind power fluctuations is proposed. This method is used to optimize the power and capacity configuration of the energy storage system. The time series curves of the charging and discharging powers of the hydrogen energy storage are obtained by EMD decomposition, and the curves are classified according to the similarities and differences of the characteristic parameters in different time periods. After the classification, typical charging and discharging power values of each type of curve at each moment are obtained by a cloud model, and then, typical operation curves of each type are obtained by integration. On this basis, the power and capacity of the energy storage system are optimized with the objective of economic optimization through the MATLAB CPLEX toolbox. Combined with the measured data of a wind farm with an installed capacity of 400 MW in Northeast China, the validity and rationality of the typical operation curve generation method proposed in this paper are verified.     

A geospatial method for estimating the levelised cost of hydrogen production from offshore wind

This paper describes the development of a general-purpose geospatial model for assessing the economic viability of hydrogen production from offshore wind power. A key feature of the model is that it uses the offshore project's location characteristics (distance to port, water depth, distance to gas grid injection point). Learning rates are used to predict the cost of the wind farm's components and electrolyser stack replacement. The notional wind farm used in the paper has a capacity of 510 MW. The model is implemented in a geographic information system which is used to create maps of levelised cost of hydrogen from offshore wind in Irish waters. LCOH values in 2030 spatially vary by over 50% depending on location. The geographically distributed LCOH results are summarised in a multivariate production function which is a simple and rapid tool for generating preliminary LCOH estimates based on simple site input variables.     

Reliability evaluation and analysis for NEV charging station considering the impact of charging experience

Battery electric vehicles (BEVs) and hydrogen fuel cell vehicles (HFCVs) will predominate in near future, and the new energy vehicle (NEV) charging station which provides charging services for aforementioned NEVs could grow rapidly. The reliability of the NEV charging station would be the primary concern for early construction and NEV users. This study investigates the reliability evaluation of NEV charging station considering the impact of charging experience and analyzes the influence of various factors by comparing the evaluation results. The explicit modelling of the station considering power generation system, coupling devices and hydrogen storage is presented and an optimal revenue model is established to coordinate the operation of the station. A reliability index system is established to evaluate the charging reliability of the NEV charging station and reflect the charging experience. In addition, an amount model estimating the number of vehicles accessed in the coming days is proposed to address the impact of driver charging experience on the reliability evaluation. The results show that it is necessary to consider the charging experience in reliability evaluation. The comparison and analysis of reliability evaluation results reveal that the charging reliability and profit of the charging station are influenced by the initial hydrogen in tank, the price of hydrogen/electricity and the sizes of electrolyzer, hydrogen tank and fuel cell. The reliability evaluation provides guidance for determining the parameters of these factors.     

Development of a viability assessment model for hydrogen production from dedicated offshore wind farms

Dedicated offshore wind farms for hydrogen production are a promising option to unlock the full potential of offshore wind energy, attain decarbonisation and energy security targets in electricity and other sectors, and cope with grid expansion constraints. Current knowledge on these systems is limited, particularly the economic aspects. Therefore, a new, integrated and analytical model for viability assessment of hydrogen production from dedicated offshore wind farms is developed in this paper. This includes the formulae for calculating wind power output, electrolysis plant size, and hydrogen production from time-varying wind speed. All the costs are projected to a specified time using both Discounted Payback (DPB) and Net Present Value (NPV) to consider the value of capital over time. A case study considers a hypothetical wind farm of 101.3 MW situated in a potential offshore wind development pipeline off the East Coast of Ireland. All the costs of the wind farm and the electrolysis plant are for 2030, based on reference costs in the literature. Proton exchange membrane electrolysers and underground storage of hydrogen are used. The analysis shows that the DPB and NPV flows for several scenarios of storage are in good agreement and that the viability model performs well. The offshore wind farm – hydrogen production system is found to be profitable in 2030 at a hydrogen price of €5/kg and underground storage capacities ranging from 2 days to 45 days of hydrogen production. The model is helpful for rapid assessment or optimisation of both economics and feasibility of dedicated offshore wind farm – hydrogen production systems.     

Energy-storage configuration for EV fast charging stations considering characteristics of charging load and wind-power fluctuation

Fast charging stations play an important role in the use of electric vehicles (EV) and significantly affect the distribution network owing to the fluctuation of their power. For exploiting the rapid adjustment feature of the energy-storage system (ESS), a configuration method of the ESS for EV fast charging stations is proposed in this paper, which considers the fluctuation of the wind power as well as the characteristics of the charging load. The configuration of the ESS can not only mitigate the effects of fast charging stations on the connected distribution network but also improve its economic efficiency. First, the scenario method is adopted to model the wind power in the distribution network, and according to the characteristics of the EV and the driving probability, the charging demand of each station is calculated. Then, considering factors such as the investment cost, maintenance cost, discharging benefit, and wind curtailment cost, the ESS configuration model of the distribution network is set up, which takes the optimal total costs of the ESS for EV fast charging stations within its lifecycle as an objective. Finally, General Algebraic Modelling System (GAMS) is used to linearize and solve the proposed model. A simulation on an improved IEEE-69 bus system verifies the feasibility and economic efficiency of the proposed model.     

An analysis of hydrogen production from renewable electricity sources

Three aspects of producing hydrogen via renewable electricity sources are analyzed to determine the potential for solar and wind hydrogen production pathways: a renewable hydrogen resource assessment, a cost analysis of hydrogen production via electrolysis, and the annual energy requirements of producing hydrogen for refueling. The results indicate that ample resources exist to produce transportation fuel from wind and solar power. However, hydrogen prices are highly dependent on electricity prices. For renewables to produce hydrogen at $2 kg⁻¹, using electrolyzers available in 2004, electricity prices would have to be less than $0.01 kWh⁻¹. Additionally, energy requirements for hydrogen refueling stations are in excess of 20 GWh/year. It may be challenging for dedicated renewable systems at the filling station to meet such requirements. Therefore, while plentiful resources exist to provide clean electricity for the production of hydrogen for transportation fuel, challenges remain to identify optimum economic and technical configurations to provide renewable energy to distributed hydrogen refueling stations.     

Performance of a hydrogen refueling station in the early years of commercial fuel cell vehicle deployment

Since 2003, the National Fuel Cell Research Center at the University of California, Irvine (UCI) has operated the first U.S. publicly accessible hydrogen refueling station (HRS). During this period, the UCI HRS supported all manufacturers in the early, pre-commercialization years of the fuel cell electric vehicle (FCEV). This paper describes and analyzes the performance of the UCI HRS during the first five years of FCEV commercialization, over which time the station has dispensed the most hydrogen daily in the California network. The station performance is compared to aggregate data published by NREL for all U.S. HRSs. Using the Hydrogen Delivery Scenario Analysis Model, typical daily refueling profiles are analyzed to determine the effect on HRS design. The results show different daily refueling profiles could substantially affect HRS design and ultimately the cost of hydrogen. While technical issues have been reduced, the compressor, dispenser, and fueling rate are areas for improvement.     

Decarbonising city bus networks in Ireland with renewable hydrogen

This paper presents techno-economic modelling results of a nationwide hydrogen fuel supply chain (HFSC) that includes renewable hydrogen production, transportation, and dispensing systems for fuel cell electric buses (FCEBs) in Ireland. Hydrogen is generated by electrolysers located at each existing Irish wind farm using curtailed or available wind electricity. Additional electricity is supplied by on-site photovoltaic (PV) arrays and stored using lithium-ion batteries. At each wind farm, sizing of the electrolyser, PV array and battery is optimised system design to obtain the minimum levelised cost of hydrogen (LCOH). Results show the average electrolyser capacity factor is 64% after the integration of wind farm-based electrolysers with PV arrays and batteries. A location-allocation algorithm in a geographic information system (GIS) environment optimises the distributed hydrogen supply chain from each wind farm to a hypothetical hydrogen refuelling station in the nearest city. Results show that hydrogen produced, transported, and dispensed using this system can meet the entire current bus fuel demand for all the studied cities, at a potential LCOH of 5–10 €/kg by using available wind electricity. At this LCOH, the future operational cost of FCEBs in Belfast, Cork and Dublin can be competitive with public buses fuelled by diesel, especially under carbon taxes more reflective of the environmental impact of fossil fuels.     

Optimization of wind farm turbines layout using an evolutive algorithm

The optimum wind farm configuration problem is discussed in this paper and an evolutive algorithm to optimize the wind farm layout is proposed. The algorithm's optimization process is based on a global wind farm cost model using the initial investment and the present value of the yearly net cash flow during the entire wind-farm life span. The proposed algorithm calculates the yearly income due to the sale of the net generated energy taking into account the individual wind turbine loss of production due to wake decay effects and it can deal with areas or terrains with non-uniform load-bearing capacity soil and different roughness length for every wind direction or restrictions such as forbidden areas or limitations in the number of wind turbines or the investment. The results are first favorably compared with those previously published and a second collection of test cases is used to proof the performance and suitability of the proposed evolutive algorithm to find the optimum wind farm configuration.     

Optimizing hydrogen production capacity and day ahead market bidding for a wind farm in Texas

Producing green hydrogen from wind energy is one potential method to mitigate curtailment. This study develops a general approach to examine the economic benefit of adding hydrogen production capacity through water electrolysis along with the fuel cell and storage facilities in a wind farm in north Texas. The study also investigates different day ahead market bidding strategies in the existence of these technologies. The results show that adding hydrogen capacity to the wind farm is profitable when hydrogen price is greater than $3.58/kg, and that the optimal day ahead market bidding strategy changes as hydrogen price changes. The results also suggest that both the addition of a fuel cell to reconvert stored hydrogen to electricity and the addition of a battery to smooth the electricity input to the electrolyzer are suboptimal for the system in the case of this study. The profit of a particular bidding scenario is most sensitive to the selling price of hydrogen, and then the input parameters of the electrolyzer. This study also provides policy implications by investigating the impact of different policy schemes on the optimal hydrogen production level.