Effect of mode switching on the temperature and heat flux in a unitized regenerative fuel cell

Unitized regenerative fuel cells operate in not only fuel cell but also water electrolyzer mode. Heat management is important for the stable operation of unitized regenerative fuel cells. In this work, temperature and heat flux on the surface of the gas diffusion layer at the hydrogen side of a unitized regenerative fuel cell are experimentally measured using thin film sensors. Four pairs of sensors with good linear relation coefficient are inserted in the unitized regenerative fuel cell. The variation of temperature and heat flux on the gas diffusion layer surface during mode switching is obtained. The effect of mode switching on temperature and heat flux in the unitized regenerative fuel cell is analyzed. Experimental results show that reactant switching significantly affects temperature and heat flux. Reactant switching also causes decreased temperature and variation in heat flux. Despite of the decrease of temperature caused by the low-temperature water, the temperature increases with the operation of the URFC. When the effect of reactant switching is ignored, temperature is further found to increase in fuel cell and water electrolyzer modes, and heat flux remains relatively stable.     

Experimental investigation on two‐phase flow in a unitized regenerative fuel cell during mode switching from water electrolyzer to fuel cell

Mode switching between fuel cell and water electrolyzer of a unitized regenerative fuel cell alters two‐phase flow dynamics in the channels. To fully understand the mode switching, the observation of two‐phase flow is necessary. In this work, experiments are conducted to investigate the two‐phase flow in the flow field of a unitized regenerative fuel cell during mode switching. A transparent window is assembled at the oxygen side to allow a direct view of the serpentine flow field. The two‐phase flow are captured by a high‐speed camera. Water has a significant effect on the mode switching. The switching from water electrolyzer to fuel cell is difficult because of the flooding problem. High temperature causes insufficient water in water electrolyzer mode without water supply and membrane dehydration in fuel cell mode. The voltage in fuel cell mode decreases more rapidly with fuel cell current density during mode switching.     

Effect of capillary pressure on liquid water removal in the cathode gas diffusion layer of a polymer electrolyte fuel cell

In order to investigate the effect of capillary pressure on the transport of liquid water in the cathode gas diffusion layer (GDL) of a polymer electrolyte fuel cell, a one-dimensional steady-state mathematical model was developed, including the effect of temperature on the capillary pressure. Numerical results indicate that the liquid water saturation significantly increases with increases in the operating temperature of the fuel cell. An elevated operating temperature has an undesirable influence on the removal of liquid water inside the GDL. A reported peculiar phenomenon in which the flooding of the fuel cell under a high operating temperature and an over-saturated environment is more serious in a GDL combined with a micro-porous layer (MPL) than in a GDL without an MPL [Lim and Wang, Electrochim. Acta 49 (2004), 4149–4156] is explained based on the present analysis.     

一体式再生燃料电池温度和热流密度非原位同步测量

一体式再生燃料电池的热流密度和温度分布的研究对电池热管理具有重要的意义。本文将自制的薄膜传感器植入一体式再生燃料电池中,进行非原位实验研究。在给定不同气体预热温度下,测量了一体式再生燃料电池内部热流密度和局部温度,并根据已得到的温度和热流密度计算出局部表面传热系数。结果表明,在不同的气体预热温度下,流道内气体的温度和气体扩散层表面的温差维持在3℃左右。气体扩散层表面的热流密度整体呈现出下降的趋势。靠近加热棒处的温度最高,但热流密度最低。相同的气体预热温度下,流道内气体和气体扩散层表面的温差对换热量的影响要大于温度梯度的影响;气体预热温度的上升对表面传热系数h的影响不大。30℃时,表面传热系数h值在450 ~ 750 W/(m²?K) 之间。40℃时,表面传热系数h在450 ~ 650 W/(m²?K)之间。     

Dynamic response of a unitized regenerative fuel cell under various ways of mode switching

Mode switching is an important process in unitized regenerative fuel cells. The complex interactions of heat and mass transfer during the operation of mode switching have a significant effect on cell performance. Twelve different ways of mode switching were proposed by controlling inlet boundary conditions of supplies and operating voltage. Numerical simulations were applied to analyze the dynamic response of heat and mass transfer as well as electrochemical signals under the different ways of mode switching. Current density increased with mass fraction of reactants. Cell heat source had an instant response to current density, but the temperature was slow to respond to the heat source. Hydrogen‐side inlet velocity had minimal impact on mode switching. The time for cell reaching stability increased with the increase of voltage change time, and the time for current density, mass transfer, and temperature reaching stable values increased in order. Unitized regenerative fuel cell had similar dynamic response in the 2 period: cell temperature increased in the fuel cell mode and decreased in the water electrolysis mode after mode switching.     

Water removal characteristics of proton exchange membrane fuel cells using a dry gas purging method

Water removal from proton exchange membrane fuel cells (PEMFC) is of great importance to improve start-up ability and mitigate cell degradation when the fuel cell operates at subfreezing temperatures. In this study, we report water removal characteristics under various shut down conditions including a dry gas-purging step. In order to estimate the dehydration level of the electrolyte membrane, the high frequency resistance of the fuel cell stack was observed. Also, a novel method for measuring the amount of residual water in the fuel cell was developed to determine the amount of water removal. The method used the phase change of liquid water and was successfully applied to examine the water removal characteristics. Based on these works, the effects of several parameters such as purging time, flow rate of purging gas, operation current, and stack temperature on the amount of residual water were investigated.     

PEMFC purging at low operating temperatures: An experimental approach

In this paper, the effect of operating temperature on optimal purge interval for maximum energy efficiency in a proton exchange membrane fuel cell (PEMFC) with dead‐ended anode (DEA) was experimentally investigated. The study was conducted with a focus on challenges associated with operation at temperatures lower than the recommended designed temperature. With DEA, gradual voltage drop happens due to the accumulation of water and impurities such as nitrogen. Hence, periodic purging of the anode side is required to remove excess water and impurities that are accumulated at the anode side over time. Short purge intervals increase hydrogen loss that translates into low fuel utilisation, whereas long purge intervals result in voltage drop due to high water and impurity accumulations. Therefore, an optimal purge strategy should be implemented to maximise the stack energy efficiency. Depending on the operating conditions and loads, there are instances that a fuel cell stack operates at temperatures lower than its recommended designed temperature. Considering the temperature effect on the cell water management, operating temperature is an important factor to consider for optimising the purge strategy in PEMFCs. At lower operating temperatures (ie, below 50°C), more water is formed in liquid form, which makes the optimisation of purge strategy more challenging. For a stack temperature of 40°C, it was observed that with an increase in stack current from 0.25 to 0.45 A cm^?2, the optimal purge interval decreases from 90 seconds to around 45 seconds, respectively. Increasing the stack temperature from 40°C to 50°C resulted in an increase in the optimal purge interval to 120 seconds and 90 seconds for stack currents of 0.25 (ie, low current density) and 0.45 A cm^?2, respectively. At lower operating temperatures, more frequent purging schedules are needed accordingly to remove the liquid water from the cell. These results indicated that at lower operating temperatures, water accumulation at the anode side becomes more dominant compared with higher operating temperatures.     

Along‐channel flooding prediction of polymer electrolyte membrane fuel cells

Non‐uniform current distribution in polymer electrolyte membrane (PEM) fuel cells results in local over‐heating, accelerated ageing, and lower power output than expected. This issue is quite critical when a fuel cell experiences water flooding. In this study, the performance of a PEM fuel cell is investigated under cathode flooding conditions. A two‐dimensional approach is proposed for a single PEM fuel cell based on conservation laws and electrochemical equations to provide useful insight into water transport mechanisms and their effect on the cell performance. The model results show that inlet stoichiometry and humidification, and cell operating pressure are important factors affecting cell performance and two‐phase transport characteristics. Numerical simulations have revealed that the liquid saturation in the cathode gas distribution layer (GDL) could be as high as 20%. The presence of liquid water in the GDL decreases oxygen transport and surface coverage of active catalyst, which in turn degrades the cell performance. The thermodynamic quality in the cathode flow channel is found to be greater than 99.7%, indicating that liquid water in the cathode gas channel exists in very small amounts and does not interfere with the gas phase transport. A detailed analysis of the operating conditions shows that cell performance should be optimized based on the maximum average current density achieved and the magnitude of its dispersion from its mean value. Copyright © 2010 John Wiley & Sons, Ltd.     

Experimental investigation on voltage response to operation parameters of a unitized regenerative fuel cell during mode switching from fuel cell to electrolysis cell

In this work, a proton exchange membrane unitized regenerative fuel cell with a 25 cm² active area and a transparent window was designed to study the influence of mode switching from the fuel cell mode to the electrolysis cell mode on the cell voltage and the gas‐liquid two‐phase flow behaviors in the oxygen flow channels. Results indicate that: the growth rate of electrolysis cell voltage before the water pumped to the oxygen flow channels decreases with the increase of the fuel cell current density; while the growth rate of electrolysis cell voltage before the water pumped to the oxygen flow channels increases with the cell temperature; the voltage of electrolysis cell mode before the water pumped to the oxygen flow channels decreases with the increase of water flow rate; the different voltage reduction speeds are attributed to the different water flow rates. The water temperature has an obscure influence on the cell voltage of electrolysis cell mode before the water pumped to the oxygen flow channels.     

Steady state and dynamic performance of proton exchange membrane fuel cells (PEMFCs) under various operating conditions and load changes

The steady-state performance and transient response for H₂/air polymer electrolyte membrane (PEM) fuel cells are investigated in both single fuel cell and stack configurations under a variety of loading cycles and operating conditions. Detailed experimental parameters are controlled and measured under widely varying operating conditions. In addition to polarization curves, feed gas flow rates, temperatures, pressure drop, and relative humidity are measured. Performance of fuel cells was studied using steady-state polarization curves, transient I–V response and electrochemical impedance spectroscopy (EIS) techniques. Different feed gas humidity, operating temperature, feed gas stoichiometry, air pressure, fuel cell size and gas flow patterns were found to affect both the steady state and dynamic response of the fuel cells. It was found that the humidity of cathode inlet gas had a significant effect on fuel cell performance. The experimental results showed that a decrease in the cathode humidity has a detrimental effect on fuel cell steady state and dynamic performance. Temperature was also found to have a significant effect on the fuel cell performance through its effect on membrane conductivity and water transport in the gas diffusion layer (GDL) and catalyst layer. The polarization curves of the fuel cell at different operating temperatures showed that fuel cell performance was improved with increasing temperature from 65 to 75 °C. The air stoichiometric flow rate also influenced the performance of the fuel cell directly by supplying oxygen and indirectly by influencing the humidity of the membrane and water flooding in cathode side. The fuel cell steady state and dynamic performance also improved as the operating pressure was increased from 1 to 4 atm. Based on the experimental results, both the steady state and dynamic response of the fuel cells (stack) were analyzed. These experimental data will provide a baseline for validation of fuel cell models.     

Analysis and control of a fuel delivery system considering a two-phase anode model of the polymer electrolyte membrane fuel cell stack

The fuel delivery system using both an ejector and a blower for a PEM fuel cell stack is introduced as a fuel efficiency configuration because of the possibility of hydrogen recirculation dependent upon load states.A high pressure difference between the cathode and anode could potentially damage the thin polymer electrolyte membrane. Therefore, the hydrogen pressure imposed to the stack should follow any change of the cathode pressure. In addition, stoichiometric ratio of the hydrogen should be maintained at a constant to prevent a fuel starvation at abrupt load changes.Furthermore, liquid water in the anode gas flow channels should be purged out in time to prevent flooding in the channels and other layers. The purging control also reduces the impurities concentration in cells to improve the cell performance.We developed a set of control oriented dynamic models that include a anode model considering the two-phase phenomenon and system components The model is used to design and optimize a state feedback controller along with an observer that controls the fuel pressure and stoichiometric ratio, whereby purging processes are also considered. Finally, included is static and dynamic analysis with respect to tracking and rejection performance of the proposed control.     

Analytically investigating the characteristics of a high‐temperature unitized regenerative solid oxide fuel cell

A unitized regenerative solid oxide fuel cell (URSOFC) can be considered as a next‐generation power source and a storage device in the future since it can generate electricity in the SOFC mode and also produce H₂/O₂ in the solid oxide electrolyzer cell (SOEC) mode. In this paper, a two‐dimensional axisymmetric model is developed to simulate the characteristics of a URSOFC. The performance curves for an in‐house button URSOFC under different operating temperatures of 600, 700, and 800 °C are measured to validate the present model. Both the measured data and the prediction results reveal the beneficial effects of higher temperature on the cell performance. Based on the results of numerical simulations, the majority of the fuel gas is consumed at the interface of the electrolyte and the electrode, causing a great fuel concentration gradient near the interface. In addition, the predicted cell performance curves in both the SOFC and the SOEC modes correspond well with the measured data, demonstrating the applicability of this model in a button URSOFC. Copyright © 2013 John Wiley & Sons, Ltd.     

Hydrogen pressure drop characteristics in a fuel cell stack

Research on hydrogen pressure characteristics was performed for a fuel cell stack to supply a rule of hydrogen pressure drop for flooding diagnostic systems. Some experiments on the hydrogen pressure drop in various operating pressure, temperature, flowrate and stack current conditions were carried out, and hydrodynamic calculation was managed to compare with the experiment results. Results show that the hydrogen pressure drop is strongly affected by liquid water content in the flow channel of fuel cells, and it is not in normal relation with flowrate when the stoichiometric ratio is inconstant. The total pressure drop can be calculated by a frictional pressure loss formula accurately, relating with mixture viscosity, stack temperature, operating pressure, stoichiometric ratio and stack current. The pressure drop characteristics will be useful for predicting liquid water flooding in fuel cell stacks before flow channels have been jammed as a diagnostic tool in electric control systems.     

不同操作和环境条件下的PEMFC低温冷启动数值模拟研究

基于COMSOL建立质子交换膜燃料电池低温冷启动一维瞬态多物理场耦合模型,该模型考虑气态水和膜态水在0 ℃以下结冰来研究恒电压输出、恒电流输出、膜态水初始含量以及环境温度等不同操作和环境条件对质子交换膜燃料电池低温冷启动性能的影响。结果表明,恒电压输出模式下,低电压操作相对于高电压能产生更多的热,温度上升更快,但结冰速率也会激增,从而导致性能衰减更快;恒电流输出模式相较于恒电压能达到更高的温度,但需更好的气体传质能力;如果低温冷启动之前吹扫不足导致膜水含量较高,膜的储水能力下降,这将造成输出性能下降更快,不利于冷启动的成功进行;启动时环境温度的不同会直接影响燃料电池低温冷启动成功与否,仅依赖被动加热成功启动的初始环境温度存在极限值。     

Performance assessment of a four-pass serpentine proton exchange membrane fuel cell with non-humidified cathode and cell state estimation without special measurement

Proton exchange membrane fuel cells are promising electrochemical energy conversion devices especially important for mobile technologies, including the automotive industry thanks to their quick start-up, low operation temperature, and relatively higher energy density characteristics. However, cell performance depends on many parameters like reactant temperature and humidification ratio, cell operating temperature, reactant feeding pressure, and flow field. In this study, the performance of a 50 cm² active area four-pass serpentine flow field hydrogen-air proton exchange membrane (PEM) fuel cell experimentally investigated for various cell operating temperatures and reactant back pressures without humidification on the cathode side. Dehydration or flooding condition of the cell is showed to be determined with tafel slope, limiting current density and types of voltage losses without using a special measurement. The results show that flooding, which is called mild flooding, is possible to be seen even at high cell temperature in a non-humidified cathode fuel cell, in case of exceeding operating pressures. Behavior of cell parameters under mild flooding and ongoing severe flooding are different from each other. Pressure increase at above 45 °C operating temperature is seen to served higher power output. However, at low back pressure with escalated operating temperature doesn't result with a substantial increase on performance since less amount of water is produced as a product of reaction causing membrane dehydration at relatively low current density levels thus increasing ohmic loss.     

Control-oriented modeling of gas purging process on the cathode of polymer electrolyte membrane fuel cell during shutting down

Gas purging process of cathode side during the shut-down procedure of a polymer electrolyte membrane fuel cell (PEMFC) system is of great importance for a successful cold start. This paper proposes a study on the modeling and control of the cathodic gas purging process, whose main purpose is to remove liquid water in the gas diffusion layer (GDL) and the membrane. The water removal process can be divided into three steps, which are called (a) the through-plane drying of the GDL, (b) the in-plane drying of the GDL, and (c) the vapor-transport from the membrane. A nonlinear model is firstly developed to describe the water removal process in the GDL and the membrane. It includes a one-dimensional three-step purging sub-model and an energy consumption sub-model considering the properties of the air compressor. Experiments are carried out to validate the water-remove model by using the membrane HFR. An optimal constant purging control strategy that minimizes energy consumption during the cathodic purging process is designed based on the model and verified in simulation.     

Water flooding and two-phase flow in cathode channels of proton exchange membrane fuel cells

The water flooding and two-phase flow of reactants and products in cathode flow channels (0.8 mm in width, 1.0 mm in depth) were studied by means of transparent proton exchange membrane fuel cells. Three transparent proton exchange membrane fuel cells with different flow fields including parallel flow field, interdigitated flow field and cascade flow field were used. The effects of flow field, cell temperature, cathode gas flow rate and operation time on water build-up and cell performance were studied, respectively. Experimental results indicate that the liquid water columns accumulating in the cathode flow channels can reduce the effective electrochemical reaction area; it makes mass transfer limitation resulting in the cell performance loss. The water in flow channels at high temperature is much less than that at low temperature. When the water flooding appears, increasing cathode flow rate can remove excess water and lead to good cell performance. The water and gas transfer can be enhanced and the water removal is easier in the interdigitated channels and cascade channels than in the parallel channels. The cell performances of the fuel cells that installed interdigitated flow field or cascade flow field are better than that installed with parallel flow field. The images of liquid water in the cathode channels at different operating time were recorded. The evolution of liquid water removing out of channels was also recorded by high-speed video.     

A two dimensional partial flooding model for PEMFC

Proton exchange membrane fuel cells (PEMFCs) have attracted much attention in these years. In PEMFCs, liquid/gas two-phase flow is a common phenomenon, which has great influence on fuel cell performance. However, the liquid water transport process has not been satisfactorily modeled yet. In this work, a two dimensional partial flooding model was developed, in which the pore size distribution of the gas diffusion layer (GDL) is taken into consideration in the explanation of fuel cell flooding for the first time. Liquid water produced is considered to flood a fraction of the GDL hydrophobic pores with diameter greater than the capillary condensation threshold diameter, and the unflooded pores will serve as passageway for gas transportation and the corresponding catalyst area is available for electrochemical reaction. Use this model, it is simple to explain membrane dehydration and electrode flooding. Different operation conditions have been studied with the model and the model polarization curves show reasonable accordance with the experimental results.     

Numerical and experimental studies on unitized regenerative proton exchange membrane fuel cell

Increasing energy need and running out of fossil-based fuels direct us to renewable energy resources. Although hydrogen is not an energy source by itself, it is an energy carrier with a high specific heat capacity. As it is used as fuel in unitized regenerative PEM fuel cells, water is separated in electrolyzer mode and stored by producing hydrogen when there is no need for energy. In this study, performance tests on the unitized regenerative PEM electrolyzer/fuel cell were carried out and numerical modelling has been performed. The validity of the developed model was confirmed by the results of the experimental study. Before starting the performance tests, the cell's leakproofness tests were carried out, and the appropriate torque force was optimized, reducing the contact resistance that causes performance loss. The material selection of the cell components and corrosion-resistant materials that can operate in both electrolyzer and fuel cell modes were preferred.In this study, 0.019 slpm of hydrogen and 0.0095 slpm of oxygen gas is produced in the electrolyzer mode, while a power density of 0.353 W/cm² is obtained in the fuel cell mode at 80 °C, from a unitized regenerative PEM fuel cell with a 5 cm² active area, whose cell elements are combined with a 3 Nm clamping torque by using 12 bolts.     

Liquid water flooding process in proton exchange membrane fuel cell cathode with straight parallel channels and porous layer

Liquid water management plays a significant role in proton exchange membrane fuel cell (PEMFC) performance, especially when the PEMFC is operating with high current density. Therefore, understanding of liquid water behavior and flooding process is a critical challenge that must be addressed. To overcome PEMFC durability problems, a liquid water flooding process is studied in the cathode side of a PEMFC with straight parallel channels and a porous layer using FLUENT^® v6.3.26 software with a volume-of-fluid (VOF) algorithm and user-defined-function (UDF). The general process of liquid water flooding within this type of PEMFC cathode is investigated by analyzing the behavior of liquid water in porous layer and gas flow channels. Two important phenomena, the “first channel phenomenon” and the “last channel phenomenon”, and their effects on the flow distribution along different parallel channels are discussed.