A review of technical and regulatory limits for hydrogen blending in natural gas pipelines

There is rising interest globally in the use of hydrogen for the provision of electricity or heat to industry, transport, and other applications in low-carbon energy systems. While there is attention to build out dedicated hydrogen infrastructure in the long-term, blending hydrogen into the existing natural gas pipeline network is also thought to be a promising strategy for incorporating hydrogen in the near-term. However, hydrogen injection into the existing gas grid poses additional challenges and considerations related to the ability of current gas infrastructure to operate with blended hydrogen levels. This review paper focuses on analyzing the current understanding of how much hydrogen can be integrated into the gas grid from an operational perspective and identifies areas where more research is needed. The review discusses the technical limits in hydrogen blending for both transmission and distribution networks; facilities in both systems are analyzed with respect to critical operational parameters, such as decrease in energy density, increased flow speed and pressure losses. Safety related challenges such as, embrittlement, leakage and combustion are also discussed. The review also summarizes current regulatory limits to hydrogen blending in different countries, including ongoing or proposed pilot hydrogen blending projects.     

Hydrogen integration in power-to-gas networks

The share of renewable energy resources is consistently rising in the global energy supply, and power-to-gas technique is being seen as the feasible storage of surplus renewable electricity. In this regard the sensitivity of hydrogen towards various elements of the P2G network needs to be assessed. The study provides an overview of a number of P2G projects mainly concentrated in Europe, and summarizes the results of investigations carried out on the effects of hydrogen injection on the existing natural gas pipeline infrastructure. It has been found that each element of the natural gas infrastructure has a varying degree of acceptability to hydrogen concentration; however the determinant element affects the overall allowable hydrogen concentration. In the transmission network, compressors are the determinant element and have a limiting value of 10% hydrogen admixture. Distribution network and storage elements allow a 50% concentration of hydrogen. End use appliances have a tolerant range of 20–50%. The second portion of the study demonstrates the effect of hydrogen injection on gas quality, which reveals that an introduction of 2% hydrogen in the distribution network has negligible effect however a 10% hydrogen mixture affects the calorific value of the supplied fuel gas below the desired level.     

Preparation of hydrogen from metals and water without CO2 emissions

Considering the high calorific value and low-carbon characteristics of hydrogen energy, it will play an important role in replacing fossil energy sources. The production of hydrogen from renewable energy sources for electricity generation and electrolysis of water is an important process to obtain green hydrogen compared with classic low-carbon hydrogen production methods. However, the challenges in this process include the high cost of liquefied hydrogen and the difficulty of storing hydrogen on a large scale. In this paper, we propose a new route for hydrogen storage in metals, namely, electricity generation from renewable energy sources, electrolysis to obtain metals, and subsequent hydrogen production from metals and water. Metal monomers facilitate large-scale and long-term storage and transportation, and metals can be used as large-scale hydrogen storage carriers in the future. In this technical route, the reaction between metal and water for hydrogen production is an important link. In this paper, we systematically summarize the research progress, development trend, and challenges in the field of metal to hydrogen production. This study aim to aid in the development of this field.     

The emerging hydrogen economy and its impact on LNG

Hydrogen is gaining prominence as a critical tool for countries to meet decarbonisation targets. The main production pathways are based on natural gas or renewable electricity. LNG represents an increasingly important component of the global natural gas market. This paper examines synergies and linkages between the hydrogen and LNG values chains and quantifies the impact of increased low-carbon hydrogen production on global LNG flows. The analysis is conducted through interviews with LNG industry stakeholders, a review of secondary literature and a scenario-based assessment of the potential development of global low-carbon hydrogen production and LNG trade until 2050 using a novel, integrated natural gas and hydrogen market model. The model-based analysis shows that low-carbon hydrogen production could become a significant user of natural gas and thus stabilise global LNG demand. Furthermore, commercial and operational synergies could assist the LNG industry in developing a value chain around natural gas-based low-carbon hydrogen.     

An assessment of the use of fuel chemicals synthesized from captured carbon dioxide for renewable electricity storage

本文介绍了国际上利用可再生能源结合捕集CO₂制燃料的最新技术进展。以化学合成的反应热力学为基础,通过分析计算与流程模拟,得到捕集CO₂制燃料化学品储电的能耗与?流,初步评估了甲醇作为储存电能介质的能效,并与氢储能及甲烷储能进行了比较分析。比较结果表明,氢储能流程最短,效率最高,但是没有固碳的作用。对于实现储能与固碳,甲醇的氢原子经济性较好。甲烷产物热值与反应热都较高。甲醇储能效率损失主要由前端电解制氢环节造成。     

Techno-economic model and feasibility assessment of green hydrogen projects based on electrolysis supplied by photovoltaic PPAs

The use of hydrogen produced from renewable energy enables the reduction of greenhouse gas (GHG) emissions pursued in different international strategies. The use of power-purchase agreements (PPAs) to supply renewable electricity to hydrogen production plants is an approach that can improve the feasibility of projects. This paper presents a model applicable to hydrogen projects regarding the technical and economic perspective and applies it to the Spanish case, where pioneering projects are taking place via photovoltaic PPAs. The results show that PPAs are an enabling mechanism for sustaining green hydrogen projects.     

The production of hydrogen fuel from renewable sources and its role in grid operations

Understanding the scale and nature of hydrogen's potential role in the development of low carbon energy systems requires an examination of the operation of the whole energy system, including heat, power, industrial and transport sectors, on an hour-by-hour basis. The Future Energy Scenario Assessment (FESA) software model used for this study is unique in providing a holistic, high resolution, functional analysis, which incorporates variations in supply resulting from weather-dependent renewable energy generators. The outputs of this model, arising from any given user-definable scenario, are year round supply and demand profiles that can be used to assess the market size and operational regime of energy technologies. FESA was used in this case to assess what - if anything - might be the role for hydrogen in a low carbon economy future for the UK.In this study, three UK energy supply pathways were considered, all of which reduce greenhouse gas emissions by 80% by 2050, and substantially reduce reliance on oil and gas while maintaining a stable electricity grid and meeting the energy needs of a modern economy. All use more nuclear power and renewable energy of all kinds than today's system. The first of these scenarios relies on substantial amounts of ‘clean coal’ in combination with intermittent renewable energy sources by year the 2050. The second uses twice as much intermittent renewable energy as the first and virtually no coal. The third uses 2.5 times as much nuclear power as the first and virtually no coal.All scenarios clearly indicate that the use of hydrogen in the transport sector is important in reducing distributed carbon emissions that cannot easily be mitigated by Carbon Capture and Storage (CCS). In the first scenario, this hydrogen derives mainly from steam reformation of fossil fuels (principally coal), whereas in the second and third scenarios, hydrogen is made mainly by electrolysis using variable surpluses of low-carbon electricity. Hydrogen thereby fulfils a double facetted role of Demand Side Management (DSM) for the electricity grid and the provision of a ‘clean’ fuel, predominantly for the transport sector. When each of the scenarios was examined without the use of hydrogen as a transport fuel, substantially larger amounts of primary energy were required in the form of imported coal.The FESA model also indicates that the challenge of grid balancing is not a valid reason for limiting the amount of intermittent renewable energy generated. Engineering limitations, economic viability, local environmental considerations and conflicting uses of land and sea may limit the amount of renewable energy available, but there is no practical limit to the conversion of this energy into whatever is required, be it electricity, heat, motive power or chemical feedstocks.     

A multivariate coupled economic model study on hydrogen production by renewable energy combined with off-peak electricity

An economic prediction model of hydrogen production from renewable energy complemented with off-peak electricity is developed, and the cost of carbon emission for the off-peak electricity from grid is also considered. The variation of hydrogen cost with the utilization hours of off-peak electricity and the allowable range of off-peak electricity utilization hours under different carbon prices and grid average emission factors are investigated. The results show that it is influenced by the multiplication product of the carbon price and the average carbon emission factor of the grid electricity. The use of off-peak electricity reduces the cost of hydrogen when the multiplication product is less than a critical value, while it causes an increase in the cost of hydrogen when larger than the critical value. Off-peak electricity utilization hours are also constrained by the emission intensity requirement of low-carbon or clean hydrogen. In addition, a generalized multivariate coupled analysis method is developed by investigating single variable sensitivities and decision needs at different stages of the project. The results show that the key coupling variables in the site selection stage are hydrogen price, renewable energy utilization hours and integrated tariff, which is determined by both renewable energy and off-peak grid electricity. In the scheme design stage the key coupling variables are electrolysis energy consumption and unit installed cost. When project parameters are determined along with site specific hydrogen price and renewable energy tariffs, further scheme optimization can be undertaken.     

The production of electricity,heat and hydrogen with the thermal power plant in combination with alternative technologies

Alternative technologies in combination with thermal power plant allow the production of heat, electricity and hydrogen using renewable energy sources in combination with gas or coal, as a very important energy source in traditional energy engineering in Slovenia. The technologies aim, inter alia, to reduce greenhouse gas emissions, increase the use of renewable energy sources and take a step forward to the production of hydrogen as an alternative energy source in numerous applications. In view of the estimated demand for heat, electricity and hydrogen in the Savinja-?alek region, Slovenia, the technologies to meet such demand are proposed in this article from a technical perspective. An energy and economic analysis of the operation of the Thermal Power Plant (TPP) will be done. The TPP is operating in a variable operating regime. The possibility of stationary operation of the power plant will be analysed, the surplus of produced electricity will be used for the hydrogen production. The process is based on the Rankine-Clausius cycle (RC) with dual superheating using water or steam as the working media. The idea in this article, is to generate in the above mentioned facility as much hydrogen, heat, cold and electricity as needed by the Savinja-?alek region in industry, transport, etc. Thus, the power plant could operate optimally, constantly at 100% of power, which would allow simultaneous production of electricity, heat and hydrogen. Hydrogen could be used for sale on the market or for the electricity production or for heating. Hydrogen could be produced via electrolysis or thermochemical process. In the second part of article, the analysis of RC with concentrated solar energy and wood chips was analysed.     

Greenhouse gas emissions reduction by use of wind and solar energies for hydrogen and electricity production: Economic factors

This study addresses economic aspects of introducing renewable technologies in place of fossil fuel ones to mitigate greenhouse gas emissions. Unlike for traditional fossil fuel technologies, greenhouse gas emissions from renewable technologies are associated mainly with plant construction and the magnitudes are significantly lower. The prospects are shown to be good for producing the environmentally clean fuel hydrogen via water electrolysis driven by renewable energy sources. Nonetheless, the cost of wind- and solar-based electricity is still higher than that of electricity generated in a natural gas power plant. With present costs of wind and solar electricity, it is shown that, when electricity from renewable sources replaces electricity from natural gas, the cost of greenhouse gas emissions abatement is about four times less than if hydrogen from renewable sources replaces hydrogen produced from natural gas. When renewable-based hydrogen is used in a fuel cell vehicle instead of gasoline in a IC engine vehicle, the cost of greenhouse gas emissions reduction approaches the same value as for renewable-based electricity only if the fuel cell vehicle efficiency exceeds significantly (i.e., by about two times) that of an internal combustion vehicle. It is also shown that when 6000 wind turbines (Kenetech KVS-33) with a capacity of 350 kW and a capacity factor of 24% replace a 500-MW gas-fired power plant with an efficiency of 40%, annual greenhouse gas emissions are reduced by 2.3 megatons. The incremental additional annual cost is about $280 million (US). The results provide a useful approach to an optimal strategy for greenhouse gas emissions mitigation.     

Major auxiliary equipment needs for the world energy network project

Many national energy projects have been pursued in Japan. Some of them are very important to control the emission of CO₂ from fossil fuel. The world energy network (WE-NET) project based on a hydrogen combustion gas turbine is one of the national projects and has a high target of thermal efficiency up to 60% or more (HHV) [Proc. IJPGC, Vol. 2, Baltimore, 1998, p. 293; Proc. IJPGC, Vol. 2, Baltimore, 1998, p. 433; Annual Summary Report on WE-NET, 1997; J. JSME, 100 (947) (1997) 1034; J. GTSJ, 27 (4) (1999) 217]. However, this new technology has to be developed by an application of a combined cycle for gas and steam turbines and special auxiliary equipment such as an oxygen supply plant and heat exchangers. The hydrogen combustion gas turbine will be operated by pure hydrogen and oxygen supplied and kept to produce a pure water vapor only. If other gaseous components are included in the combustion gas, the thermal efficiency of the combined cycle is decreased by the breakdown effect of a condenser vacuum. In this project, hydrogen may be imported from some foreign countries where it has to be produced by using clean and renewable energies, for example, hydropower or solar energy. On the other hand, the oxygen to be distilled from the air has to be supplied by auxiliary equipment of a liquid oxygen plant. This auxiliary equipment, however, will consume much power.In an existing type of the liquid oxygen plant, about 10% of the total power plant output has been consumed for the additional power of oxygen supply. In addition, the WE-NET combined cycle of the hydrogen combustion gas turbine will be supported by many heat exchangers that have to be checked for their technical problems. This paper has been highlighted at high performance design and setup of the major auxiliary equipment of the oxygen supply plant and the heat exchangers. The R&D prospect of their auxiliary equipment to attain a high thermal efficiency of the combined cycle in the WE-NET project will be discussed.     

Comparative assessment of greenhouse gas mitigation of hydrogen passenger trains

This paper examines a comparative assessment in terms of CO₂ emissions from a hydrogen passenger train in Ontario, Canada, particularly comparing four specific propulsion technologies: (1) conventional diesel internal combustion engine (ICE), (2) electrified train, (3) hydrogen ICE, and (4) hydrogen PEM fuel cell (PEMFC) train. For the electrified train, greenhouse gases from electricity generation by natural gas and coal-burning power plants are taken into consideration. Several hydrogen production methods are also considered in this analysis, i.e., (1) steam methane reforming (SMR), (2) thermochemical copper–chlorine (Cu–Cl) cycle supplied partly by waste heat from a nuclear plant, (3) renewable energies (solar and wind power) and (4) a combined renewable energy and copper–chlorine cycle. The results show that a PEMFC powertrain fueled by hydrogen produced from combined wind energy and a copper–chlorine plant is the most environmentally friendly method, with CO₂ emissions of about 9% of a conventional diesel train or electrified train that uses a coal-burning power plant to generate electricity. Hydrogen produced with a thermochemical cycle is a promising alternative to further reduce the greenhouse gas emissions. By replacing a conventional diesel train with hydrogen ICE or PEMFC trains fueled by Cu-Cl based-hydrogen, the annual CO₂ emissions are reduced by 2260 and 3318 tonnes, respectively. A comparison with different types of automobile commuting scenarios to carry an equivalent number of people as a train is also conducted. On an average basis, only an electric car using renewable energy-based electricity that carries more than three people may be competitive with hydrogen trains.     

Constructing users in the smart grid—insights from the Danish eFlex project

The smart grid is promoted as one of the key elements in a low-carbon transition in many countries. In Denmark, the dominant framing of the smart grid emphasises the challenge of integrating much more wind power into the electricity system and using electricity for heating (heat pumps) and transport (electric cars). In the process of radically transforming the electricity system, strategic system builders need to align many forces, including consumers, who play an important role in the functioning of such large networked systems. System builders need to explore, for instance, whether and how users can be motivated to be flexible in relation to moving electricity consumption over time. This paper reports on one of the first smart-grid-related projects in Denmark in which consumer aspects have been central and where potentials for flexible electricity consumption have been tested. The aim of the paper is to explore what can be learned from such experiments and which roles they play in the construction of the smart grid. In this context, the concept of the ‘aligned user’ is introduced.     

Integration and economic viability of fueling the future with green hydrogen: An integration of its determinants from renewable economics

The volatility of fossil fuel and their increased consumption have exacerbated the socio-economic dilemma along with electricity expenses in third world countries around the world, Pakistan in particular. In this research, we study the output of renewable hydrogen from natural sources like wind, solar, biomass, and geothermal power. It also provides rules and procedures in an attempt to determine the current situation of Pakistan regarding the workability of upcoming renewable energy plans. To achieve this, four main criteria were assessed and they are economic, commercial, environmental, and social adoption. The method used in this research is the Fuzzy Analytical Hierarchical Process (FAHP), where we used first-order engineering equations, and Levelized cost electricity to produce renewable hydrogen. The value of renewable hydrogen is also evaluated. The results of the study indicate that wind is the best option in Pakistan for manufacturing renewable based on four criteria. Biomass is found to be the most viable raw material for the establishment of the hydrogen supply network in Pakistan, which can generate 6.6 million tons of hydrogen per year, next is photovoltaic solar energy, which has the capability of generating 2.8 million tons. Another significant finding is that solar energy is the second-best candidate for hydrogen production taking into consideration its low-cost installation and production. The study shows that the cost of using hydrogen in Pakistan ranges from $5.30/kg to $5.80/kg, making it a competitive fuel for electric machines. Such projects for producing renewable power must be highlighted and carried out in Pakistan and this will lead to more energy security for Pakistan, less use of fossil fuels, and effective reduction of greenhouse gas emissions.     

Ecological and economic efficiency of the use of alternative energy technologies including hydrogen to reduce of the anthropogenic load in the central ecological area of the Baikal natural territory

The central ecological area of the Baikal natural territory covers some districts of the Irkutsk oblast and the Republic of Buryatia, located on the coast of the Lake Baikal. Due to the natural uniqueness and special status of doing economic activity, the assessment of the impact on the environment in this territory is very importance.An analysis of the functioning of energy objects showed that a significant part of the territory is provided with a centralized electricity supply with developed electric grid infrastructure. There are only a few remote settlements with autonomous electricity supply from diesel power plants.The main sources of pollution are numerous boiler houses that provide heat to the population, social and administrative institutions. In all, there are 98 heat energy sources in the territory, of which 66 (or 70%) use coal.The problems of environmental pollution are mainly caused by the use of coal in a small boiler house, worn-out equipment, and the lack of an appropriate level of flue gas treatment. The total estimated emission of pollutants into the atmosphere from heat energy sources is estimated at 20–25 thousand tons per year.In order to reduce the anthropogenic impact from energy objects, it is advisable to use renewable energy sources, hydrogen technologies, coal substitution with environmentally friendly fuels, use of electricity for heat energy supply, installation of environmental protection equipment and the implementation of energy-saving measures.The methodological approach and simulation models developed at MESI SB RAS were used to determine the competitiveness conditions of alternative technologies and energy carriers.The studies evaluated the environmental and economic efficiency of energy production technologies by using specific indicators: the capital intensity of reducing 1 ton of emissions and environmental capital return by 1 million rubles for the conditions of the central ecological area.The potential for reducing emissions into the atmosphere by use of renewable energy sources in autonomous energy supply areas is less than 1% of the current level of total emissions from energy objects. The potential for reducing emissions by replacing boiler houses with a capacity of less than 0,2 Gcal/h by a heat pump units is no more than 12%.The biggest environmental effect can be achieved by using alternative energy carriers including hydrogen instead of coal. Moreover, the potential for reducing emissions is 60% of the total emissions. In addition to these activities are the least capital intensive.The most effectively is the replacement of coal with natural gas. Rational gas consumption in the coastal areas of Lake Baikal is estimated at 175–190 thousand tons of equivalent fuel. The real possibility of transferring small boiler houses to gas arises during the construction of an export gas pipeline from Russia (through the territory of the Irkutsk oblast) to China via Mongolia, or by the small-scale production of liquefied natural gas.The most currently implemented direction is the use of electricity for heat energy supply. The potential volume of electricity to replace coal in boiler houses of the central ecological area is 1,3 TWh per year, however, the competitive electricity tariff is estimated less than 2 US c/kWh, which is several times lower than current tariffs.Hydrogen technology is currently very capital-intensive, but using it in a way similar to using electricity for heat eliminates pollutant and greenhouse gas emissions.Now days, there are no effective financial mechanisms aimed at stimulating the reduction of the anthropogenic pressure on the environment from existing energy sources, including for the use of alternative technologies. As the result, significant financial support is required in the form of special cost compensation mechanisms for energy producers and/or consumers.     

Evaluation of hydrogen storage technology in risk-constrained stochastic scheduling of multi-carrier energy systems considering power,gas and heating network constraints

The operation of energy systems considering a multi-carrier scheme takes several advantages of economical, environmental, and technical aspects by utilizing alternative options is supplying different kinds of loads such as heat, gas, and power. This study aims to evaluate the influence of power to hydrogen conversion capability and hydrogen storage technology in energy systems with gas, power, and heat carriers concerning risk analysis. Accordingly, conditional value at risk (CVaR)-based stochastic method is adopted for investigating the uncertainty associated with wind power production. Hydrogen storage system, which can convert power to hydrogen in off-peak hours and to feed generators to produce power at on-peak time intervals, is studied as an effective solution to mitigate the wind power curtailment because of high penetration of wind turbines in electricity networks. Besides, the effect constraints associated with gas and district heating network on the operation of the multi-carrier energy systems has been investigated. A gas-fired combined heat and power (CHP) plant and hydrogen storage are considered as the interconnections among power, gas and heat systems. The proposed framework is implemented on a system to verify the effectiveness of the model. The obtained results show the effectiveness of the model in terms of handling the risks associated with multi-carrier system parameters as well as dealing with the penetration of renewable resources.     

Renewable hydrogen to recycle CO2 to methanol

The balance of the natural carbon cycle disrupted by the large consumption of fossil fuels, in particular coal producing electricity, may in principle be restored by using renewable hydrogen. This paper considers the opportunity to recycle the CO₂ produced burning fossil fuels with oxy-fuel combustion using renewable hydrogen as the second feed-stock. The product, methanol, is a transportation fuel having significant advantages over not only over hydrogen, but also gasoline, permitting much better fuel conversion efficiencies than gasoline thanks to the larger heat of vaporisation and the largest resistance to knock that make this fuel the best option for small, high power density, turbocharged, directly injected stoichiometric engines.     

钢铁企业日际煤气最优混合配比的算法研究

钢铁企业根据日际生产计划,可以确定日际生产的副产煤气总体积、各煤气消耗设备的热量需求。为进一步确定各设备消耗的混合煤气中的煤气配比,使煤气产耗平衡,提出混合煤气逆向分解方法,将各设备消耗的混合煤气中所包含的单一煤气成分体积,表示为各设备获得热量与混合煤气热值的函数,在此基础上建立日际煤气最优混合配比算法模型。该模型以各设备的混合煤气热值及热量作为决策变量,以各煤气消耗设备的热量偏差最小为目标,综合考虑各煤气设备的热值要求、自备电厂的热值、热量要求及煤气体积守恒等约束条件。采用遗传算法求解,并利用遗传算法基因初始化的范围区间控制混合煤气的热值范围。算例结果表明:建立的日际煤气最优混合配比算法模型,在优化煤气分配的同时,显著减少了约束方程及决策变量的数量,为钢铁企业日际煤气平衡调度提供了理论支撑。     

System-level energy efficiency is the greatest barrier to development of the hydrogen economy

Current energy research investment policy in New Zealand is based on assumed benefits of transitioning to hydrogen as a transport fuel and as storage for electricity from renewable resources. The hydrogen economy concept, as set out in recent commissioned research investment policy advice documents, includes a range of hydrogen energy supply and consumption chains for transport and residential energy services. The benefits of research and development investments in these advice documents were not fully analyzed by cost or improvements in energy efficiency or green house gas emissions reduction. This paper sets out a straightforward method to quantify the system-level efficiency of these energy chains. The method was applied to transportation and stationary heat and power, with hydrogen generated from wind energy, natural gas and coal. The system-level efficiencies for the hydrogen chains were compared to direct use of conventionally generated electricity, and with internal combustion engines operating on gas- or coal-derived fuel. The hydrogen energy chains were shown to provide little or no system-level efficiency improvement over conventional technology. The current research investment policy is aimed at enabling a hydrogen economy without considering the dramatic loss of efficiency that would result from using this energy carrier.     

The economic feasibility study of a 100-MW Power-to-Gas plant

Power-to-Gas (PtG) is a grid-scale energy storage technology by which electricity is converted into gas fuel as an energy carrier. PtG utilizes surplus renewable electricity to generate hydrogen from Solid-Oxide-Cell, and the hydrogen is then combined with CO₂ in the Sabatier process to produce the methane. The transportation of methane is mature and energy-efficient within the existing natural gas pipeline or town gas network. Additionally, it is ideal to make use of the reverse function of SOC, the Solid-Oxide-Fuel-Cell, to generate electricity when the grid is weak in power. This study estimated the cost of building a hypothetical 100-MW PtG power plant with energy storage and power generation capabilities. The emphasis is on the effects of SOC cost, fuel cost and capacity factor to the Levelized Cost of Energy of the PtG plant. The net present value of the plant is analyzed to estimate the lowest affordable contract price to secure a positive present value. Besides, the plant payback period and CO₂ emission are estimated.