Surface wettability change during pool boiling of nanofluids and its effect on critical heat flux

The pool boiling characteristics of dilute dispersions of alumina, zirconia and silica nanoparticles in water were studied. Consistently with other nanofluid studies, it was found that a significant enhancement in critical heat flux (CHF) can be achieved at modest nanoparticle concentrations (<0.1% by volume). Buildup of a porous layer of nanoparticles on the heater surface occurred during nucleate boiling. This layer significantly improves the surface wettability, as shown by a reduction of the static contact angle on the nanofluid-boiled surfaces compared with the pure-water-boiled surfaces. A review of the prevalent CHF theories has established the nexus between CHF enhancement and surface wettability changes caused by nanoparticle deposition. This represents a first important step towards identification of a plausible mechanism for boiling CHF enhancement in nanofluids.     

Pool boiling characteristics of nanofluid on flat plate based on heater surface analysis

Nucleate pool boiling of Al₂O₃ based aqueous nanofluid on flat plate heater has been studied experimentally. For boiling of nanofluid (< 0.1 vol.%) on heating surface with ratio of average surface roughness to average diameter of particles much less than unity when boiling continue to CHF, the heat transfer coefficient of nanofluid boiling reduces while critical heat flux (CHF) increases. CHF enhancement increased with volume fraction of nanoparticles. Atomic force microscope (AFM) images from boiling surface showed that after boiling of nanofluid the surface roughness increases or decreases depending on initial condition of heater surface. Changes in boiling surface topology during different regions of boiling, wettability and thermal resistance of heater surface owing to nanoparticles deposition cause to variations in nanofluids boiling performance.     

Effect of nanoparticles on CHF enhancement in pool boiling of nano-fluids

To investigate the characteristics of CHF (Critical Heat Flux) enhancement using nano-fluids, pool boiling CHF experiments of two water-based nano-fluids with titania and alumina nanoparticles were performed using electrically heated metal wires under atmospheric pressure. The results showed that the water-based nano-fluids significantly enhanced CHF compared to that of pure water. SEM (Scanning Electron Microscopy) observation subsequent to the pool boiling experiments revealed that a lot of nanoparticles were deposited on heating surface during pool boiling of nano-fluids. In order to investigate the role of the nanoparticle surface coating on CHF enhancement of nano-fluids, pool boiling CHF of pure water was measured using a nanoparticle-coated heater prepared by pool boiling of nano-fluids on a bare heater. It was found that pool boiling of pure water on the naonoparticle-coated heater sufficiently achieved the CHF enhancement of nano-fluids. It is supposed that CHF enhancement in pool boiling of nano-fluids is mainly caused by the nanoparticle coating of the heating surface.     

Investigations on heat transfer enhancement in pool boiling with water-CuO nano-fluids

The main focus of the present work is to investigate Critical Heat Flux (CHF) enhancement using CuO nanofluid relative to CHF of pure water. To estimate the effect of nanoparticles on the CHF, pool boiling CHF values were measured for various volume concentrations of CuO nanofluid and compared with pure water. CHF enhancement of 130% was recorded at 0.2 % by volume of CuO nano-fluids. Surface roughness of the heater surface exposed to three measured heating cycles indicated surface modifications at different volume concentrations of nanofluid. SEM image of the heater surface revealed porous layer build up, which is thought to be the reason for CHF enhancement.     

Behavioral study of alumina nanoparticles in pool boiling heat transfer on a vertical surface

Experiments were carried out to investigate the pool boiling of alumina‐water nanofluid at 0.1 g/l to 0.5 g/l of distilled water, and the nucleate pool boiling heat transfer of pure water and nanofluid at different mass concentrations were compared at and above the atmospheric pressure. At atmospheric pressure, different concentrations of nanofluids display different degrees of deterioration in boiling heat transfer. The effect of pressure and concentration of nanoparticles revealed significant enhancement in heat flux and deterioration in pool boiling. The heat transfer coefficient of 0.5 g/l alumina‐water nanofluid was compared with pure water and clearly indicates deterioration. At all pressures the heat transfer coefficients of the nanofluid were lower than those of pure water. Experimental observation revealed particles coating over the heater surface and subsequent SEM inspection of the heater surface showed nanoparticles coating on the surface forming a porous layer. To substantiate the nanoparticle deposition and its effect on heat flux, investigation was done by measuring the surface roughness of the heater surface before and after the experiment. While SEM images of the heater surface revealed nanoparticle deposition, surface roughness of the heater surface confirmed it. Based on the experimental investigations it can be concluded that an optimum thickness of nanoparticles coating favors an increase in heat flux. Higher surface temperature due to the presence of nanoparticles coating results in the deterioration of boiling heat transfer. © 2011 Wiley Periodicals, Inc. Heat Trans Asian Res; Published online in Wiley Online Library ( wileyonlinelibrary.com/journal/htj ). DOI 10.1002/htj.20365     

Effects of Al2O3/R-123 nanofluids containing C19H40 core–shell phase change materials on critical heat flux

In this paper, the curiosity is coming from how to bring out the fluidic capability of nanofluids (fluid itself) for critical heat flux (CHF) enhancement away from surface deposition effects such as improved wettability. The pool boiling characteristics of dilute dispersions of alumina and the microencapsulated C₁₉H₄₀ phase change material (MPCM) in R-123 were studied. Whereas other nanofluid studies only reported that a significant enhancement of CHF was achieved by buildup of a porous layer of nanoparticles on the heater surface during nucleate boiling, it was found that the additional CHF enhancement of 24% occurred with the MPCM compared to alumina nanomaterials. With solid–liquid phase changes, PCMs in suspension delay the occurrence of CHF by absorbing heat around from the heater, nucleate bubbles and merged bubbles while PCM shells prevent leakage of molten cores and allows the return to solid with exchanges of heat at some distances. The present study found that PCMs could make fluidic effects of nanofluid not relying on the surface depositions.     

Direct numerical simulations of pool boiling curves including heater's thermal responses and the effect of vapor phase's thermal conductivity

Effects of heater's thermal properties and vapor phase's thermal conductivity on saturated pool boiling above a large horizontal heater are simulated numerically based on an improved pseudo-potential liquid-vapor phase change lattice Boltzmann model. A transient conjugate heat transfer problem is under consideration, where the conjugate thermal boundary condition is imposed and heater's thermal responses during boiling processes are investigated. Saturated pool boiling curves from onset of nucleate boiling to critical heat flux (CHF), to transition boiling regime to stable film boiling regime are obtained numerically. It is found that the simulated critical heat flux (CHF) agrees reasonably well with existing analytical models. Also, the simulated boiling heat fluxes in stable film boiling regime are shown to be in good agreement with the existing analytical solution. Thus, this improved pseudo-potential liquid-vapor phase change lattice Boltzmann model is quantitatively validated. Simulation results demonstrate that there is significant maldistribution in temperature distribution near the top of heater surface in nucleate boiling regime, CHF point and transition boiling regime. As a result, two-dimensional heat conduction can not be ignored when evaluating heat flux closely beneath the heater's top surface. It is also shown that both heater's thermal conductivity and thermal mass (the product of density and specific heat at constant pressure) have no effect on CHF value as well as the boiling curve in nucleate boiling regime and film boiling regime for a thick heater. However, the transition boiling regime of the boiling curve moves to the left with the increasing heater thermal conductivity and heater thermal mass for a thick heater. Increasing the vapor theraml conductivity has no effect on CHF but would increase boiling heat flux in film boiling regime, and hence shortening the transition boiling regime.     

Surface effects of ribbon heaters on critical heat flux in nanofluid pool boiling

This paper deals with a study of enhanced critical heat flux (CHF) and burnout heat flux (BHF) in pool boiling of water with suspended silica nanoparticles using Nichrome wires and ribbons. Previously the current authors and other researchers have reported three-digit percentage increase in critical heat flux in silica nanofluids. This study investigates the effect of various heater surface dimensions, cross-sectional shapes as well as surface modifications on pool boiling heat transfer characteristics of water and water-based nanofluids. Our data suggest that the CHF and BHF decrease as heater surface area increases. For concentrations from 0.1 vol% to 2 vol%, the deposition of the particles on the wire allows high heat transfer through inter-agglomerate pores, resulting in a nearly 3-fold increase in burnout heat flux at very low concentrations. The nanoparticle deposition plays a major role through variation in porosity. The CHF enhancement is non-monotonic with respect to concentration. As the concentration is increased, the CHF and BHF decrease prior to increasing again at higher concentrations. Results show a maximum of 270% CHF enhancement for ribbon-type heaters. The surface morphology of the heater was investigated using SEM and EDS analyses, and it was inferred that the 2 vol% concentration deposition coating had higher porosity and rate of deposition compared with 0.2 vol% case.     

Thermal Physics and Critical Heat Flux Characteristics of Al2O3–H2O Nanofluids

This study investigates the influence of the thermal physics of nanofluids on the critical heat flux (CHF) of nanofluids. Thermal physics tests of nanoparticle concentrations ranged from 0 to 1 g/L. Pool boiling experiments were performed using electrically heated NiCr metal wire under atmospheric pressure. The results show that there was no obvious change for viscosity and a maximum enhancement of about 5 to 7% for thermal conductivity and surface tension with the addition of nanoparticles into pure water. Consistently with other nanofluid studies, this study found that a significant enhancement in CHF could be achieved at modest nanoparticle concentrations (<0.1 g/L by Al₂O₃ nanoparticle concentration). Compared to the CHF of pure water, an enhancement of 113% over that of nanofluids was found. Scanning electron microscope photos showed there was a nanoparticle layer formed on the heating surface for nanofluid boiling. The bubble growth was photographed by a camera. The coating layer makes the nucleation of vapor bubbles easily formed. Thus, the addition of nanoparticles has active effects on the CHF.     

Stabilizer effect on CHF and boiling heat transfer coefficient of alumina/water nanofluids

We measured the critical heat flux (CHF) and boiling heat transfer coefficient (BHTC) of water-based Al₂O₃ (alumina) nanofluids. To elucidate the stabilizer effect on CHF and BHTC of alumina/water nanofluids, a polyvinyl alcohol (PVA) was used as a stabilizer. The plate copper heater (10 × 10 mm²) is used as the boiling surface and the concentration of alumina nanoparticle varies 0–0.1 vol.%. The results show that the BHTC of the nanofluids becomes lower than that of the base fluid as the concentration of nanoparticles increases while CHF of it becomes higher. It is found that the increase of CHF is directly proportional to the effective boiling surface area and the reduction of BHTC is mainly attributed to the blocking of the active nucleation cavity and the increase of the conduction resistance by the nanoparticle deposition on the boiling surface.     

Sorption and agglutination phenomenon of nanofluids on a plain heating surface during pool boiling

The pool nucleate boiling heat transfer experiments of water (H₂O) based and alcohol (C₂H₅OH) based nanofluids and nanoparticles-suspensions on the plain heated copper surface were carried out. The study was focused on the sorption and agglutination phenomenon of nanofluids on a heated surface. The nanofluids consisted of the base liquid, the nanoparticles and the surfactant. The nanoparticles-suspensions consisted of the base liquid and nanoparticles. The both liquids of water and alcohol and both nanoparticles of CuO and SiO₂ were used. The surfactant was sodium dodecyl benzene sulphate (SDBS). The experimental results show that for nanofluids, the agglutination phenomenon occurred on the heated surface when the wall temperature was over 112 °C and steady nucleated boiling experiment could not be carried out. The reason was that an unsteady porous agglutination layer was formed on the heated surface. However, for nanoparticles-suspensions, no agglutination phenomenon occurred on the heating surface and the steady boiling could be carried out in the whole nucleate boiling region. For the both of alcohol based nanofluids and nano-suspensions, no agglutination phenomenon occurred on the heating surface and steady nucleate boiling experiment could be carried out in the whole nucleate boiling region whose wall temperature did not exceed 112 °C. The boiling heat transfer characteristics of the nanofluids and nanoparticles-suspensions are somewhat poor compared with that of the base fluids, since the decrease of the active nucleate cavities on the heating surface with a very thin nanoparticles sorption layer. The very thin nanoparticles sorption layer also caused a decrease in the solid–liquid contact angle on the heating surface which leaded to an increase of the critical heat flux (CHF).     

The effect of capillary wicking action of micro/nano structures on pool boiling critical heat flux

It is well known that nanoparticles deposited on a heating surface during nanofluids boiling can change the characteristics of the heating surface and increase the critical heat flux (CHF) dramatically. We considered a new approach to investigate the nanoparticle surface effect on CHF enhancement using surfaces modified with artificial micro, nano, and micro/nano structures similar to deposited nanoparticle structures through the anodic oxidation on the zirconium alloy heater. We examined the effect of the capillary wicking action ability on the CHF enhancement due to the micro, nano, and micro/nano structured surfaces. The results demonstrated that the CHF enhancement on the modified surfaces was a consequence of the capillary wicking action ability of the artificial micro/nano structures through the high-speed visualization of the capillary wicking action.     

Measurement of a Heated Surface Temperature Using a High-Speed Infrared Camera During Critical Heat Flux Enhancement by a Honeycomb Porous Plate in a Saturated Pool Boiling of a Nanofluid

Abstract

This article presents an experimental study to investigate the critical heat flux (CHF) enhancement mechanism using honeycomb porous plate (HPP). The CHF enhanced significantly with combination of the HPP and nanofluid, up to 3.2?MW/m² at maximum compared to a plain surface, 1.0?MW/m². The mechanism by which the CHF is improved in this system was elucidated by measuring the temperature of the heated surface using an indium tin oxide (ITO) heater and a high-speed infrared camera. The pool boiling experiment of water and nanofluid is performed under saturated temperature and atmospheric pressure conditions. The CHF values obtained using ITO heater is in good agreement with a conventional CHF pool boiling experiment with HPP attachment. High-speed infrared camera is analyzed to understand the behavior of local temperature at various locations over time. It is observed at the burnout condition, the highest average temperature is occurred at the intersection of HPP wall. Moreover, the reversible dry spots were initiated in the cell part of the HPP, and small dry spots coalesced into a growth of large irreversible dryout that leads to burnout. Further CHF enhancement could be realized if the initiation of the dryout region could be suppressed.     

Flow boiling heat transfer in the evaporator of a loop thermosyphon operating with CuO based aqueous nanofluid

An experimental study was carried out to understand the flow boiling heat transfer of water based CuO nanofluids in the evaporator of a thermosyphon loop under steady sub-atmospheric pressures. Experimental results show that both the heat transfer coefficient (HTC) and the critical heat flux (CHF) of flow boiling in the evaporator of the thermosyphon loop could be enhanced by substituting nanofluids for water. The operating pressure has apparent impact on the HTC enhancement of nanofluids. However, the operating pressure has negligible effect on the CHF enhancement. There exists an optimal mass concentration of nanoparticles corresponding to the best enhancement effect. Experimental results show that the CHF enhancement results mainly from the existing of the coating layer on the heated surface formed by the sediment of nanoparticles. However, the HTC enhancement results from the effects of both the existing of the coating layer and the change of thermophysical properties of the working fluid.     

Simultaneous visualization of dry spots and bubbles for pool boiling of R-113 on a horizontal heater

A new experimental attempt was made to simultaneously observe the dynamic behaviors of bubbles and dry spots in the vicinity of boiling surface. Also, the two-dimensional bubble structures were obtained separately. From the visualization results, the formation of bubbles and dry spots occurs simultaneously. At critical heat flux (CHF), the surface rewetting is repeated by the local nucleate boiling around the large vapor film. At just after CHF, nucleate boiling at the locally wetted region is extinguished, resulting in the dryout of the whole heater surface. Therefore, we conclude that CHF is initiated from the locally limited nucleate boiling activity rather than any hydrodynamic instability.     

Non-linear dynamical analyses of transient surface temperature fluctuations during subcooled pool boiling on a horizontal disk

The class of dynamics in pool boiling on a large-size heater is assessed under subcooled pool boiling conditions. Transient surface temperature measurements are obtained using surface micro-machined K-type thin film thermocouples (TFT) in 10 °C subcooled pool boiling experiments on a 62.23 mm diameter silicon wafer using PF-5060 as the test liquid. Surface temperature data is obtained at each steady state condition to generate the boiling curve. The fraction of false-nearest neighbors, recurrence plots and space–time separation plots are obtained using the TISEAN package. The correlation dimension is then estimated from the re-constructed phase space data using a naïve algorithm. The correlation dimension varies from ～11.2 to 11.5 near onset of nucleate boiling (ONB), to ～7–10 in fully developed nucleate boiling (FDNB) ～7–9 near critical heat flux (CHF) condition, and from ～6.6 to 7.7 in film boiling. False-nearest neighbor estimates and recurrence plots show that nucleate boiling may be dominated by statistical processes near ONB and in partial nucleate boiling (PNB). In contrast, FDNB, CHF and film boiling seem chaotic and governed by deterministic processes.     

Critical heat flux for CuO nanofluid fabricated by pulsed laser ablation differentiating deposition characteristics

In this study, CHF characteristics in pool boiling according to CuO nanoparticles deposition characteristics are investigated compared with that of pure water. The deposition characteristics are controlled by using in-house prepared CuO nanofluids in two ways such as one-step method of pulsed laser ablation in liquid (PLAL) and two-step method of particles dispersion. Morphology of CuO nanoparticles in shape and size is analyzed by TEM while SEM images are obtained to observe the deposition structures on heated surfaces. Also, contact angle and capillary height for deposition layer on the surfaces after pool boiling experiments are measured to investigate the surface wettability. Rayleigh–Taylor instability wavelength on the surface with respect to a unified CHF enhancement mechanism is measured indirectly by a condensation method.     

Experimental Investigations of Pool Boiling Heat Transfer Characteristics on a Vertical Surface Using CuO Nanoparticles in Distilled Water

Experiments were conducted on pool boiling heat transfer using dilute dispersions of CuO nanoparticles in distilled water at and above atmospheric pressure. Pool boiling characteristics of CuO nanofluid were studied at different pressures and concentrations. Characterization of the heating surface was done both qualitatively and quantitatively by taking the scanning electron microscopy (SEM) images and by subsequent measurement of surface roughness of the heater. SEM images of the heater surface showed nanoparticle deposition on the heater surface, suggesting surface modification. Thorough visualization showed microcavities on the heater surface, which provide an excellent location for nucleation sites enhancing heat transfer. However, these microcavities, once filled up with the suspended nanoparticles, reduced active nucleation sites, deteriorating the boiling heat transfer coefficient. Based on the experimental investigations it was concluded that there is an optimum thickness of nanoparticles coating at which heat flux is maximum and beyond this coating boiling heat transfer coefficient decreases. At higher pressures, boiling heat transfer coefficient and specific excess temperature remained nearly the same. This showed that pressure has negligible or no role to play in boiling heat transfer using nanofluids.     

Effusivity-based correlation of surface property effects in pool boiling CHF of dielectric liquids

Although the effects of fluid properties, pressure, and subcooling, as well as heater geometry, on the pool boiling critical heat flux, or CHF, are relatively well established, explanations for the surface property effects remain controversial. Proposed formulations, embodying the dependence of CHF on the product of the heater thermal effusivity and thickness are described and compared with available data. A composite correlation for pool boiling CHF, accounting for the conduction and hydrodynamic limits, as well as the effects of pressure, subcooling, and length, is proposed. This effusivity-based correlation is found to predict a broad range of pool boiling CHF data for dielectric liquids, for thermal effusivity values between 0.2 and 120, pressure from 100 to 450 kPa, and subcoolings from 0 to 75 K, with a standard deviation of 12.5%.     

On the Relation between Nucleation Site Density and Critical Heat Flux of Pool Boiling

ABSTRACT

It is traditionally accepted that the critical heat flux (CHF) decreases with increasing nucleation site density (NSD). However, such a CHF-NSD relation was no longer observed in the BETA-B experiment performed on nano-film heaters; instead the increase of NSD resulted in a gain in CHF. To address this seeming contradiction in the relation between critical heat flux and nucleation site density, the present work employed probabilistic analysis to reveal the different tendencies. A concept of effective NSD was proposed, which concerns the active nucleation sites appear within a bubble lifetime, and the resulting bubbles have the chance of direct interaction. We assumed that the boiling crisis on a heater surface is mainly induced by two mechanisms: dry spot expanding in isolated bubble regime for low-NSD surface, coalescence of dry spots under multiple bubbles in fully developed nucleate boiling regime for high-NSD surface, or a combination of the two in the transition regime for medium-NSD surface. Accordingly, we estimated the critical heat flux of each boiling regime at which the boiling crisis occurs. The result indicated that there is a threshold of nucleation site density below which the increase of NSD is contributing to CHF enhancement, while the trend is inverted beyond the threshold.