The flow field behaviours of under-expansion jet flame in premixed hydrogen/air explosion venting

The short chemical reaction time and high heat release of hydrogen fuel make a fine propulsion performance. Hydrogen is recognized as an excellent new resource. However, the inherent hazard of combustion and explosion should not be ignored. In this paper, the formation of the under-expansion jet flame (UEJF) of premixed hydrogen/air in explosion venting was simulated by ANSYS Fluent, and the wave system structures of the UEJF were systematically analyzed. The changes of pressure, Mach number, and main gas mass fraction distribution in the formation of the UEJF structures were described. The results indicated that the pressure difference at the outlet of explosion venting tube induced the intersection of expansion wave and reflected wave, and the formation of an obvious negative pressure area in the flow field. Meanwhile, alternating changes of the pressure in the jet center area propagated forward with the flame, resulting in the generation of UEJF. The fluxion of airflow at the outlet of explosion venting tube can be regarded as Prandtl-Meyer flow. The expansion angle was a positive correlation to the Mach number and the pressure ratio of the internal and external of the explosion venting tube. The distribution of H₂O, O₂, and –OH on the Mach disk revealed that the residual hydrogen reacted with O₂ to produce secondary or multiple explosions. Therefore, the attention and research on the hazard of the under-expansion jet field should be strengthened.     

Pressure release characteristics of premixed hydrogen-air mixtures in an explosion venting device with a duct

The technology of explosion venting with a duct can effectively reduce the destructive effect generated from gas accidental explosion in the place of intensive industrial production, while it is not applicable to the production site designed for the technology without ducts. Since it is not clear how to quantitatively evaluate the regularity of energy release in explosion venting especially under high cracking pressure, it is still challenging on the safe application of the technology. This paper aimed to explore the basic characteristics of explosion pressure in a 20 L sphere vessel and venting duct during hydrogen explosion venting for safety design. The effects of the cracking pressure and duct length on explosion pressure at different positions were systematically analyzed according to the test of the hydrogen with different concentrations in an explosion venting device with a duct. Comparing the results of explosion pressure characteristics with experiments conducted in a device without a duct, and quantitatively analyzing the pressure release rule, manifested that the presence of the duct reduced the explosion venting efficiency to a certain extent. In the meantime, by comparing the standard NFPA 68 (P_cra ≤ 0.075 MPa, 0.1 m³ ≤ V ≤ 10,000 m³) for safety design of explosion venting devices, the extended implementation scheme with a venting duct was assessed, implying that the calculation results from NFPA 68 were relatively stable in over-scope (P_cra > 0.075 MPa, V < 0.1 m³) measurement. In future industrial productions, the design of high-pressure hydrogen venting is suggested, leaving sufficient safety margin when referring to the result.     

Explosion venting of hydrogen-air mixtures from a duct to a vented vessel

Experiments were conducted on the vented explosion of hydrogen–air mixtures from a 150-cm-long duct to a cylindrical vessel with a vent at the center of its side wall to investigate the effects of vent burst pressure and an obstacle in duct on the process of explosion venting. Turbulent pressure oscillation owing to a pressure wave moving back and forth in a duct and vessel was observed for unvented explosions. For explosion venting from duct to vessel, flame acceleration in duct much increases the explosion overpressure in vessel. The maximum explosion in duct is always higher than that in vessel, and both of them increase with an increase in the vent cover thickness. An obstacle installed in duct significantly affected the explosion overpressure, which first increased and then decreased with an increase in the blockage ratio. Three pressure peaks were distinguished in the external pressure-time histories, which were resulted form different pressure waves formed outside the vessel.     

Under-expansion jet flame propagation characteristics of premixed H2/air in explosion venting

In premixed H₂/air explosion venting, an under-expansion jet may be caused by the pressure difference between the inside and outside of the explosion vent. Based upon the under-expansion jet, studying the structure of the under-expansion jet flame and the factors influencing its formation is essential to hydrogen safety in explosion venting. This study explored the basic characteristics of the under-expansion jet flame in premixed H₂/air explosion venting, and discussed the formation of two under-expansion structures (Mach disk and diamond shock wave) of such jet flames by conducting a premixed H₂/air explosion venting experiment. The influences of hydrogen fraction, explosion venting diameter, and duct length on the structure of under-expansion jet flames were evaluated. The results showed that after successful explosion venting, the under-expansion jet flame would be generated when the hydrogen fractions were 30–60 vol.%, and as the hydrogen fractions were 30–50 vol.%, the lengths of the venting duct were 30 and 50 cm. The duration of under-expansion jet flame was the longest when the hydrogen fraction was 40 vol.%. With the explosion venting diameter and hydrogen fraction increased, the spacing between under-expansion jet flame structures (S) increased. However, an increase in duct length led to the attenuation of the S. During the explosion venting, the under-expansion jet caused a pressure imbalance near the explosion vent and high-intensity convection forms on both sides of a jet, which can generate two or more explosions. Therefore, understanding the basic characteristics of under-expansion jet flame can aid the effective development of measures to prevent, mitigate, and protect against premixed H₂/air explosions.     

Effects of hydrogen concentration and film thickness on the vented explosion in a small obstructed rectangular container

The explosion venting is an effective way to reduce hydrogen-air explosion hazards, but the explosion venting has been less touched in an obstructed container. The present study mainly focused on the effects of hydrogen concentration and film thickness on the explosion venting in a small obstructed rectangular container. High speed schlieren photography was employed to obtain the flame fine structure and velocity. Pressure transducers were used to measure the overpressure nearby the obstacle. The experimental results show that the obstacle has a significant effect on the flame shape, tip speed and overpressure. In the process of flame evolution, the flame surface becomes more wrinkled with time after the tulip flame. Compared with the cases without the obstacle, the flame surface becomes more distorted and wrinkled downstream of the obstacle under the influence of obstacle enhanced turbulence and flow instability. Upstream of the obstacle, the lower part of the flame surface becomes concave while the upper part shows convex. The pressure histories show that the maximum overpressure increases with the hydrogen concentration in the range of 11.8%–23.7%. Two main pressure peaks were observed for all hydrogen concentrations in the presence of the obstacle. The Helmholtz oscillations appear after the second pressure peak and its duration increases slightly when the hydrogen concentration increases. The combined effect of the obstacle and hydrogen concentration on the second peak overpressure is more significant than on the first peak overpressure. Moreover, the maximum overpressure shows a monotonic increase with the film thickness.     

Explosion venting of rich hydrogen-air mixtures in a small cylindrical vessel with two symmetrical vents

The safety issues related to explosion venting of hydrogen-air mixtures are significant and deserve more detailed investigations. Vented hydrogen-air explosion has been studied extensively in vessels with a single vent. However, little attention has been paid to the cases with more than one vent. In this paper, experiments about explosion venting of rich hydrogen-air mixtures were conducted in a small cylindrical vessel with two symmetrical vents to investigate the effect of vent area and distribution on the pressure buildup and flame behavior. Experimental results show that venting accelerates the flame front towards the vent but has nearly no effect on the opposite side. The maximum internal overpressure decreases while the maximum external flame length increases with the increase of the vent area. Two pressure peaks can be identified outside the vessel, which correspond to the external explosion and the following gas jet, respectively. Compared with the case of single vent, the use of two vents with same total vent area leads to nearly unchanged maximum internal and external overpressure but much smaller external flame length.     

Vented deflagration of a hydrogen-air mixture in a rectangular vessel with a hinged aluminum vent panel

Experiments on explosion venting of a stoichiometric hydrogen-air mixture ignited near the top vent of a 1-m³ rectangular vessel with a hinged aluminum vent panel were performed to investigate the effect of the panel area density on the pressure build-up and flame behavior. When using aluminum panels, three pressure peaks could be distinguished in the pressure-time histories. The first pressure peak, which increases with the panel area density, is the dominant one. However, the second and the third pressure peaks, with magnitudes ranging from 5 to 10 kPa, are independent of the panel area density. The use of aluminum panels weakens the external explosion because the gas mixtures were vented laterally shortly after the vent panel was opened. Panel inertia has a negligible effect on the final stage of the downward propagating flame. The maximum external flame length decreases with the increase in panel area density.     

Detailed investigation of flame transmission from a vessel to a discharge duct

The present paper deals with a problem of explosion initiated in a vessel and vented through a duct. On the basis of numerical simulation (CFD) and visualization by means of high speed camera it completes and discusses the existing results and hypotheses (especially those presented in the work of Ponizy and Leyer [1]) concerning the process of enhancement of vessel pressure rise during such an explosion. In particular, numerical simulation indicates that a secondary explosion in the duct, known as a “burn-up”, which is responsible for higher reduced explosion pressures during ducted venting, has its source in a highly turbulent zone generated at the duct entrance by the flame itself independently of the shape of the vessel/duct passage. Camera images confirm the hypothesis that the flame penetrating into the duct is strongly torn in this turbulent zone and mixed with fresh gases. On the other hand, these images show that the reverse flow created by the burn-up returns back to the vessel some amount of rapidly burning gases, which contributes to the vessel pressure increase in the same degree that the blockage of the outflow from the vessel and the intensification of combustion of the unburned mixture previously left in the vessel.     

Experimental research on hydrogen/air explosion inhibition by the ultrafine water mist

This experimental study focused on the inhibition of ultrafine water mist on hydrogen explosion inside the closed vessel. The inhibition law and mechanism were studied through changes of explosion intensity, flame propagation velocity and temperature under different mist concentrations. Results indicate that flame propagation and pressure rise inside the closed vessel were corresponding. Explosion intensity was reduced after adding mist, which was mainly manifested in the reductions of explosion pressure and flame propagation velocity. Flame was accelerated to extinguish and the inhibition effect was enhanced with increasing mist concentration. However, the explosion prussure did not present obvious reduction as the mist concentration reached a certain value. Besides, it indicates that the absoption heat effect of ultrafine water mist was an important factor on hydrogen explosion inhibition by the reductions of flame temperature and propagation velocity. The inhibition effect was mainly attributed to the combination effect of physical and chemical inhibitions.     

Experimental and numerical study of the influence of initial temperature on explosion limits and explosion process of syngas-air mixtures

To study the effect of initial temperature of 30, 60, 90, and 120 °C on the explosion limits and the explosion process of the syngas-air mixtures, the explosion limits were tested by the explosive limit instrument, and the flame propagation process in the spherical pressure vessel was recorded by the high-speed camera. The ANSYS Fluent 3D software was used to simulate the explosion behavior of syngas-air mixtures. The results showed that with the increase of the initial temperature, the lower explosion limit of syngas decreased and the upper explosion limit increased, and the effect of initial temperature on the upper explosion limit of syngas was greater than that on the lower explosion limit. The flame development process in the simulation was consistent with that in the experiment, propagating outward spherically until it filled the entire container. Both experimental and numerical results presented the same trend of accelerating the flame propagation speed with the increase of initial temperature. In addition, the simulation also obtained multi-dimensional transient explosion parameters that were difficult to obtain in the experiment. The explosion process of syngas was analyzed by the explosion parameters such as temperature and pressure field in the explosion area. An increase in temperature decreased the maximum explosion pressure and shortened the time to reach the maximum explosion pressure.     

Effects of nitrogen addition on vented hydrogen–air deflagration in a vertical duct

In this paper, experiments were performed to investigate the coupling effects of venting and nitrogen addition ratio (χ) on flame behavior and pressure evolution during hydrogen–air deflagration within and outside a 1-m-high vertical duct with a vent on its top. Experimental results reveal that χ has significant effects on the pressure–time histories in the duct. Helmholtz oscillations of the internal overpressure were observed in all tests, and acoustic type oscillations appears in the tests only for χ = 25% and 30%. For a certain χ, the maximum overpressure (Pmax) increased with the distance to the vent, i.e., the highest overall explosion overpressure was attained near the duct bottom; however, the difference in Pmax between various measuring points decreases with an increase in χ. In all tests, a pressure peak in the duct was observed shortly after external explosion. The maximum internal and external overpressure decreased as χ was increased.     

Experimental study on the explosion behaviors of premixed syngas-air mixtures in ducts

Explosion characteristics of premixed syngas-air mixtures at room temperature and atmospheric pressure were experimentally reported when the explosion flame propagates in ducts with various heights (H) and lengths (L). The discussion was based on flame morphology and pressure dynamics. The ratio of L/H and the ratio of H₂/CO had a significant effect on the explosion flame behaviors as the explosion occurred in ducts. The structure of the explosion flame changes more drastically, as both the L/H ratio is large. The ratio of L/H affected the flame tip dynamics after the flame reached the duct wall, and the time of flame reaching the duct walls is divinable. For a given duct height, the shorter the duct length is, the faster flame propagates, and the maximum flame tip speed was higher as the duct length was small. For a given duct length, flame tip dynamics showed a nearly same development tendency, but the shorter the duct height, the faster the flame propagated. The venting pressure affected the overpressure dynamics, and the venting pressure increased with the increase of the L/H ratio and the H₂/CO. For a given duct height, the overpressure reached the maximum value almost at the same time, and the longer duct length resulted in the greater maximum overpressure. Finally, for a given duct length, the higher duct height caused the higher maximum overpressure.     

真空腔对爆炸火焰窒息作用研究

采用预装真空腔对管道内瓦斯爆炸后火焰传播进行遏制是一种新型泄爆抑爆技术,从科学实验、理论分析和数值模拟3个方面初步研究了真空腔对爆炸火焰的窒息作用,结果显示一定体积真空腔的介入使其后的实验管道中不再出现火焰传播,真空腔的存在使燃烧过程的氧化工况由剧烈向缓慢转变,阻止燃烧三角形形成闭环,自由基生长的速度小于自由基的消失速度,爆炸火焰在真空腔内被窒息,证明了真空腔泄爆抑爆技术对爆炸火焰具有明显窒息作用的结论。     

Ceiling-vented deflagrations of a hydrogen-air mixture in a 75 m3 container

A series of hydrogen explosions were conducted in a real scale container with and without vents. The effects of hydrogen concentration, ignition location, obstacles on the vented hydrogen-air explosions were investigated. Hydrogen explosions with concentration of 12% and 16% were conducted in constant volume container, and the maximum peak overpressure can reach 45 kPa and 175 kPa, respectively. During the vented hydrogen explosions, three overpressure peaks generated by the vent rupture, Helmholtz oscillation, and the thermo-acoustic-vibration coupling, respectively, were recorded. The maximum peak overpressure is about several kilopascal, the pressure reduction can reach 97.1% by comparison with peak overpressure developed in closed container. The obstacles change the way that the flame travel inside the container, and resultantly the flame propagates vertically and increases the flame area, which promotes the reaction and increases the peak overpressure, which also increases with the hydrogen concentration. Three engineering models used to depict the relationship between the vent area and the maximum reduced explosion pressure were assessed. Results show that the these models over-predict the maximum reduced explosion pressure for high-reactivity mixtures. However, for low reactivity, the Molkov’ models show a scatter while the NFPA68 gives a better prediction.     

Suppression effects of ultrafine water mist on hydrogen/methane mixture explosion in an obstructed chamber

The mitigation effects of ultrafine water mist on hydrogen/methane mixture explosions with hydrogen fraction (ϕ) of the range from 0% to 60% were experimentally studied in a vented chamber with obstacles. The spraying time, droplets size of water mist and the volume ratio of hydrogen were varied in the tests, and the key parameters that reflect the explosion characteristics such as the flame propagation imagines, flame propagation velocity, and explosion overpressure were obtained. The results show that the ultrafine water mist presents a significant mitigation effect on hydrogen/methane mixture explosions. The flame propagation structures are similar under the condition of without and with ultrafine water mist while the flame temperature is declined by the physical and chemical inhibition by ultrafine water mist. In addition, the mitigation effect increases with the increase of water mist flux. As a result, the maximum flame speed and overpressure of ϕ = 30% hydrogen/methane mixture explosion are declined by 33.3% and 58.4% under the condition of spraying for 2 min with 15 μm ultrafine water mist, respectively. Besides, the mitigation effects of ultrafine water mist on ϕ = 30% hydrogen/methane mixture explosion descends evidently with the increase of the droplets size of the range from 6 μm to 25 μm, which due to the easier evaporation and the greater total droplets surface area of the smaller water mist. However, the explosion mitigation effect of ultrafine water mist on the hydrogen/methane mixture actually descends with the increase hydrogen fraction.     

Numerical and experimental study of the influence of CO2 dilution on burning characteristics of syngas/air flame

In this study, effect of carbon dioxide dilution on explosive behavior of syngas/air mixture was investigated numerically and experimentally. Explosion in a 3-D cylindrical geometry model with dimensions identical to the chamber used in the experiment was simulated using ANSYS Fluent. The simulated results showed that after ignition, the flame front propagated outward spherically until it touched the wall, like the propagating flame observed in the experiment. Both experimental and simulated results presented a same trend of decreasing the maximum explosion pressure and prolonging the explosion time with CO₂ dilution. The results showed that for CO₂ additions, the maximum explosion pressure decreased linearly and the explosion time increased linearly, while the maximum rate of pressure rise decreased nonlinearly, which can be correlated to an exponential equation. In addition, both results showed a good agreement for syngas/air flame with CO₂ addition up to 20% in volume. However, larger discrepancies were observed for higher levels of CO₂ dilutions. Of the three diluents tested, carbon dioxide displayed the strongest effect in reducing explosion hazard of syngas/air flame compared to helium and nitrogen. Chemical kinetic analysis results showed that maximum concentration of major radicals and net reaction rates of important reactions drastically decreased with CO₂ addition, causing a reduction of laminar flame speed.     

Effects of nitrogen and argon on ammonia-oxygen explosion

The primary task of this work is to clarify ammonia-oxygen explosion characteristics under nitrogen and argon atmosphere. Firstly, the flame behavior and explosion pressure are experimentally obtained. Then their correlation is revealed quantitatively. The thermal, diffusive and chemical analysis is conducted at last. The results demonstrated that the variation tendency of flame propagation velocity (FPV), maximum explosion pressure (MEP) and maximum rate of pressure rise (MRPR) is completely consistent. All index of FPV, MEP and MRPR, becomes increased and decreased with increasing equivalence ratio, continues to decrease with increasing inert gas fraction. All index of FPV, MEP and MRPR under argon atmosphere is totally larger than that under nitrogen atmosphere. By considering the state equation of ideal gas, spherically smooth flame and adiabatic compression, the flame behavior and explosion pressure under nitrogen and argon atmosphere is significantly controlled by laminar burning speed (LBS). As the inert gas fraction and equivalence ratio change, the LBS under nitrogen and argon atmosphere is significantly controlled by adiabatic flame temperature. The joint action of adiabatic flame temperature and thermal diffusivity contributes to the LBS difference.     

Effect of initial pressure,temperature and equivalence ratios on laminar combustion characteristics of hydrogen enriched natural gas

In this study, the flame propagation characteristics of premixed natural gas–hydrogen–air mixtures were studied in constant volume combustion bomb by using the high-speed schlieren photography system. The flame radius, laminar flame propagation speed and the flame stretch rate were obtained under different initial pressure, temperature, equivalence ratios and hydrogen fractions. Meanwhile, the flame stability and their influencing factors were obtained by analyzing the Markstein length and the flame propagation schlieren photos under various combustion conditions. The results show that the stretched laminar propagation speed increases with the increase of the initial temperature and hydrogen fraction of the mixture, and will decreases with the increase of the initial pressure. Meanwhile, according to the Markstein length and the flame propagation pictures, the flame stability decreases with the increase of the temperature and hydrogen fraction, and the slight flaws occurred at the early stage; at larger flame radius, the flame stability is more sensitive to the variation of the initial temperature and hydrogen fraction than to that of initial pressure and equivalence ratio.     

The explosion thermal behavior of H2/CH4/air mixtures in a closed 20 L vessel

In this work, the explosion thermal behavior of H₂/CH₄/air mixtures, at different equivalence ratios (0.6–1.6) and hydrogen volume fractions (0%–100), was investigated in a confined 20-L chamber. The parameters of explosion time and pressure, as well as the explosion heat loss were quantitatively studied and analyzed. Moreover, the dominant chain reactions of the explosion process and heat release were identified via the detailed mechanism of the Foundational Fuel Chemistry Model (FFCM1). The results indicated that an increased H₂ volume fraction in the mixtures increased the peak explosion pressure, maximum pressure rise rate and deflagration index. In addition, the explosion duration and fast-burning period were greatly shortened. Both the adiabatic flame temperature and thermal diffusivity monotonically increased with increasing H₂ volume ratio. Moreover, the enhancement effect of the H₂ ratio on the thermal diffusivity of H₂/CH₄ mixtures was more prominent for fuel-rich mixtures than for fuel-lean mixtures. The obtained quantitative results are helpful for developing measures to prevent the potential explosion accidents.     

Large eddy simulation of premixed hydrogen/methane/air flame propagation in a closed duct

In this paper, large eddy simulation (LES) is performed to investigate the propagation characteristics of premixed hydrogen/methane/air flames in a closed duct. In LES, three stoichiometric hydrogen/methane/air mixtures with hydrogen fractions (volume fractions) of 0, 50% and 100% are used. The numerical results have been verified by comparison with experimental data. All stages of flame propagation that occurred in the experiment are reproduced qualitatively in LES. For fuel/air mixtures with hydrogen fractions of 0 and 50%, only four stages of “tulip” flame formation are observed, but when the hydrogen fraction is 100%, the distorted “tulip” flame appears after flame front inversion. In the acceleration stage, the LES and experimental flame speed and pressure dynamic coincide with each other, except for a hydrogen fraction of 0. After “tulip” flame formation, all LES and experimental flame propagation speeds and pressure dynamics exhibit the same trends for hydrogen fractions of 0 and 100%. However, when the hydrogen fraction is 50%, a slight periodic oscillation appears only in the experiment. In general, the different structures displayed in the flame front during flame propagation can be attributed to the interaction between the flame front, the vortex and the reverse flow formed in the unburned and burned zones.