Preliminary investigation of a transcritical CO2 heat pump driven by a solar‐powered CO2 Rankine cycle

In this paper, a transcritical carbon dioxide heat pump system driven by solar‐owered CO₂ Rankine cycle is proposed for simultaneous heating and cooling applications. Based on the first and second laws of thermodynamics, a theoretical analysis on the performance characteristic is carried out for this solar‐powered heat pump cycle using CO₂ as working fluid. Further, the effects of the governing parameters on the performance such as coefficient of performance (COP) and the system exergy destruction rate are investigated numerically. With the simulation results, it is found that, the cooling COP for the transcritical CO₂ heat pump syatem is somewhat above 0.3 and the heating COP is above 0.9. It is also concluded that, the performance of the combined transcritical CO₂ heat pump system can be significantly improved based on the optimized governing parameters, such as solar radiation, solar collector efficient area, the heat transfer area and the inlet water temperature of heat exchange components, and the CO₂ flow rate of two sub‐cycles. Where, the cooling capacity, heating capacity, and exergy destruction rate are found to increase with solar radiation, but the COPs of combined system are decreased with it. Furthermore, in terms of improvement in COPs and reduction in system exergy destruction at the same time, it is more effective to employ a large heat transfer area of heat exchange components in the combined heat pump system. Copyright © 2012 John Wiley & Sons, Ltd.     

Exergy analysis and optimization of a hydrogen production process by a solar-liquefied natural gas hybrid driven transcritical CO2 power cycle

A solar transcritical CO₂ power cycle for hydrogen production is studied in this paper. Liquefied Natural Gas (LNG) is utilized to condense the CO₂. An exergy analysis of the whole process is performed to evaluate the effects of the key parameters, including the boiler inlet temperature, the turbine inlet temperature, the turbine inlet pressure and the condensation temperature, on the system power outputs and to guide the exergy efficiency improvement. In addition, parameter optimization is conducted via Particle Swarm Optimization to maximize the exergy efficiency of hydrogen production. The exergy analysis indicates that both the solar and LNG equally provide exergy to the CO₂ power system. The largest amount of exergy losses occurs in the solar collector and the condenser due to the great temperature differences during the heat transfer process. The exergy loss in condenser could be greatly reduced by increasing the LNG temperature at the inlet of the condenser. There exists an optimum turbine inlet pressure for achieving the maximum exergy efficiency. With the optimized turbine inlet pressure and other parameters, the system is able to provide 11.52 kW of cold exergy and 2.1 L/s of hydrogen. And the exergy efficiency of hydrogen production could reach 12.38%.     

Energy and exergy performance assessment of a novel solar-based integrated system with hydrogen production

In this study, a new solar power assisted multigeneration system designed and thermodynamically analyzed. In this system, it is designed to perform heating, cooling, drying, hydrogen and power generation with a single energy input. The proposed study consists of seven sub-parts which are namely parabolic dish solar collector, Rankine cycle, organic Rankine cycle, PEM-electrolyzer, double effect absorption cooling, dryer and heat pump. The effects of varying reference temperature, solar irradiation, input and output pressure of high-pressure turbine and pinch point temperature heat recovery steam generator are investigated on the energetic and exergetic performance of integration system. Thermodynamic analysis result outputs show that the energy and exergy performance of overall study are computed as 48.19% and 43.57%, respectively. Moreover, the highest rate of irreversibility has the parabolic dish collector with 24,750 kW, while the lowest rate of irreversibility is calculated as 5745 kW in dryer. In addition, the main contribution of this study is that the solar-assisted multi-generation systems have good potential in terms of energy and exergy efficiency.     

Energetic and exergetic analysis of CO2- and R32-based transcritical Rankine cycles for low-grade heat conversion

Transcritical Rankine cycles using refrigerant R32 (CH₂F₂) and carbon dioxide (CO₂) as the working fluids are studied for the conversion of low-grade heat into mechanical power. Compared to CO₂, R32 has higher thermal conductivity and condenses easily. The energy and exergy analyses of the cycle with these two fluids shows that the R32-based transcritical Rankine cycle can achieve 12.6–18.7% higher thermal efficiency and works at much lower pressures. An analysis of the exergy destruction and losses as well as the exergy efficiency optimization of the transcritical Rankine cycle is conducted. Based on the analysis, an “ideal” working fluid for the transcritical Rankine cycle is conceived, and ideas are proposed to design working fluids that can approach the properties of an “ideal” working fluid.     

Solar assisted multi-generation system using nanofluids: A comparative analysis

In this comparative study, a parabolic trough solar collector and a parabolic dish solar collector integrated separately with a Rankine cycle and an electrolyzer are analyzed for power as well as hydrogen production. The absorption fluids used in the solar collectors are Al₂O₃ and Fe₂O₃ based nanofluids and molten salts of LiCl–RbCl and NaNO₃–KNO₃. The ambient temperature, inlet temperature, solar irradiance and percentage of nanoparticles are varied to investigate their effects on heat rate and net power produced, the outlet temperature of the solar receiver, overall energy and exergy efficiencies and the rate of hydrogen produced. The results obtained show that the net power produced by the parabolic dish assisted thermal power plant is higher (2.48 kW–8.17 kW) in comparison to parabolic trough (1 kW–6.23 kW). It is observed that both aluminum oxide (Al₂O₃) and ferric oxide (Fe₂O₃) based nanofluids have better overall performance and generate higher net power as compared to the molten salts. An increase in inlet temperature is observed to decrease the hydrogen production rate. The rate of hydrogen production is found to be higher using nanofluids as solar absorbers. The hydrogen production rate for parabolic dish thermal power plant and parabolic trough thermal power plant varies from 0.0098 g/s to 0.0322 g/s and from 0.00395 g/s to 0.02454 g/s, respectively.     

Utilizing the multi-objective particle swarm optimization for designing a renewable multiple energy system on the basis of the parabolic trough solar collector

Today, to preserve fossil resources, mankind has to search for new ways to respond to its ever-increasing energy needs. In this study, a hybrid system of energy and the use of a parabolic trough solar collector to attract solar radiation was investigated to produce clean electricity, cooling, and hydrogen from thermodynamic and economic aspects. The designed system consisted of a parabolic trough solar collector, organic Rankine cycle, lithium-bromide absorption refrigeration cycle, and proton exchange membrane electrolysis system. The evaporator input temperature, turbine inlet temperature, solar radiation intensity, mass flow rate of collector and parabolic trough collector surface area were set as decision variables and the effect of these parameters on system performance and system exergy loss were investigated. The objective functions of this research were exergy efficiency and cost rate. In order to optimize this system, multi-objective particle swarm optimization algorithm was employed. Optimization results with particle swarm optimization indicated that the best rate of exergy efficiency is 3.12% and the system cost rate is 16.367 US$ per hour, at the same time. The system is capable of producing 15.385 kW power, 0.189 kg/day hydrogen and 56.145 kW cooling in its optimum condition. The results of sensitivity analysis showed that increasing mass flow rate at the collector, temperature at the evaporator inlet, and temperature at the turbine inlet have positive effect on the performance of the proposed system.     

Energy and exergy analyses on a novel hybrid solar heating,cooling and power generation system for remote areas

In this study, a small scale hybrid solar heating, chilling and power generation system, including parabolic trough solar collector with cavity receiver, a helical screw expander and silica gel–water adsorption chiller, etc., was proposed and extensively investigated. The system has the merits of effecting the power generation cycle at lower temperature level with solar energy more efficiently and can provide both thermal energy and power for remote off-grid regions. A case study was carried out to evaluate an annual energy and exergy efficiency of the system under the climate of northwestern region of China. It is found that both the main energy and exergy loss take place at the parabolic trough collector, amount to 36.2% and 70.4%, respectively. Also found is that the studied system can have a higher solar energy conversion efficiency than the conventional solar thermal power generation system alone. The energy efficiency can be increased to 58.0% from 10.2%, and the exergy efficiency can be increased to 15.2% from 12.5%. Moreover, the economical analysis in terms of cost and payback period (PP) has been carried out. The study reveals that the proposed system the PP of the proposed system is about 18 years under present energy price conditions. The sensitivity analysis shows that if the interest rate decreases to 3% or energy price increase by 50%, PP will be less than 10 years.     

Analysis of an innovative direct steam generation‐based parabolic trough collector plant hybridized with a biomass boiler

Direct steam generation (DSG) is the process by which steam is directly produced in parabolic trough fields and supplied to a power block. This process simplifies parabolic trough plants and improves cost effectiveness by increasing the permissible temperature of the working fluid. Similar to all solar‐based technologies, thermal energy storage is needed to overcome the intermittent nature of solar. In the present work, an innovative DSG‐based parabolic trough collector (PTC) plant hybridized with a biomass boiler is proposed and analyzed in detail. Two additional configurations comprising indirect steam generation PTC plants were also analyzed to compare their energy and exergy performance. To consider a wide range of operation, the share of biomass input to the hybridized system is varied. Energy and exergy analyses of DSG are conducted and compared with an existing indirect steam generation PTC power plants such as Andasol. The analyses are conducted on a 50 MW regenerative reheat Rankine cycle. The results obtained indicate that the proposed DSG‐based PTC plant is able to increase the overall system efficiency by 3% in comparison with indirect steam generation when linked to a biomass boiler that supplies 50% of the energy.     

Design and analysis of a new solar hydrogen plant for power,methane, ammonia and urea generation

In this paper, a solar power-based combined plant for power, hydrogen, methane, ammonia and urea production is proposed. A parabolic trough collector is utilized for the system prime mover. Moreover, steam Rankine cycle, organic Rankine cycle, hydrogen production and compression subsystem, ammonia, methane and urea production units, single-effect absorption cooling unit, and freshwater production plant are integrated together to develop the present system for better system performance and cost-effectiveness and reduced environmental impact. In order to analyze and evaluate the proposed multigeneration plant, thermodynamic, parametric and economic studies are performed. According to the assessment results, it is found that energetic and exergetic efficiencies of the present multigeneration plant are 66.12% and 61.56%, respectively. The comparisons of the subsystem and overall plant efficiencies show that the highest energetic and energetic efficiencies belong to freshwater production plant by 79.24% and 75.62%, respectively. In addition, the present parametric analysis indicates that an increase in the reference temperature, solar radiation intensity and working pressure of the solar process has a positive effect on the plant's performance. The cost analysis reveals that as the solar radiation intensity and the working pressure of the solar process increase, the hydrogen generation cost decreases. Furthermore, the hydrogen generation cost is achieved to be 1.94 $/kgH₂ at 650 W/m² of the solar radiation intensity, with other parameters remaining constant.     

Analysis of a novel solar energy-powered Rankine cycle for combined power and heat generation using supercritical carbon dioxide

Theoretical analysis of a solar energy-powered Rankine thermodynamic cycle utilizing an innovative new concept, which uses supercritical carbon dioxide as a working fluid, is presented. In this system, a truly ‘natural’ working fluid, carbon dioxide, is utilized to generate firstly electricity power and secondly high-grade heat power and low-grade heat power. The uniqueness of the system is in the way in which both solar energy and carbon dioxide, available in abundant quantities in all parts of the world, are simultaneously used to build up a thermodynamic cycle and has the potential to reduce energy shortage and greatly reduce carbon dioxide emissions and global warming, offering environmental and personal safety simultaneously. The system consists of an evacuated solar collector system, a power-generating turbine, a high-grade heat recovery system, a low-grade heat recovery system and a feed pump. The performances of this CO₂-based Rankine cycle were theoretically investigated and the effects of various design conditions, namely, solar radiation, solar collector area and CO₂ flow rate, were studied. Numerical simulations show that the proposed system may have electricity power efficiency and heat power efficiency as high as 11.4% and 36.2%, respectively. It is also found that the cycle performances strongly depend on climate conditions. Also the electricity power and heat power outputs increase with the collector area and CO₂ flow rate. The estimated COP_power and COP_heat increase with the CO₂ flow rate, but decrease with the collector area. The CO₂-based cycle can be optimized to provide maximum power, maximum heat recovery or a combination of both. The results suggest the potential of this new concept for applications to electricity power and heat power generation.     

Experimental investigation of solar-assisted transcritical CO2 Rankine cycle for summer and winter conditions from exergetic point of view

This study deals with energy and exergy analysis of the experimental solar-assisted Rankine cycle working with an environmentally friendly working fluid transcritical CO₂. The experimental system consists of evacuated solar collectors, a heat recovery system, condenser, a pump, and an expansion valve to simulate the realistic turbine operation. The system was designed for electricity production and the heat supply for various applications. The experiments were made funder typical winter and summer days to evaluate seasonal system performance in Kyoto, Japan. According to the obtained results, the turbine capacity was calculated as 0.118 kW and 0.177 kW for winter and summer seasons. From the exergetic point of view, solar collectors were found to be the major contributor to the total exergy destruction with 96.32% for summer and 93.58% for the winter season. Therefore, the efforts should be focused on the collectors. Thus, any attempt for improving the system performance should be focused on solar collectors first. Furthermore, the exergetic efficiency of the overall system was calculated as 7.63% for the winter season and 4.08% for the summer season. As a result, the utilization of CO₂ in the energy conversion cycle can be sustainably developed and extended by providing a glimpse into the carbon-free clean energy future.     

Geothermal and solar energy–based multigeneration system for a district

In this study, parabolic trough collector with an integrated source of geothermal water is used with regenerative Rankine cycle with an open feedwater heater, an electrolyzer, and an absorption cooling system. The absorption fluids used in the solar collectors were Al₂O₃‐ and Fe₂O₃‐based nanofluids. Detailed energetic and exergetic analyses are done for the whole system including all the components. A comparative analysis of both the used working fluids is done and plotted against their different results. The parameters that are varied to change the output of the system are ambient temperature, solar irradiance, the percentage of nanofluids, the mass flow rate of the geothermal well, the temperature gradient of the geothermal well that had an effect on the net power produced, and the outlet temperature of the solar collector overall energetic and exergetic efficiencies. Other useful outputs by this domestic integrated multigeneration system are the heating of domestic water, space heating (maintaining the temperature at 40°C‐50°C), and desalination of seawater (flash distillation). The hydrogen production rate for both the fluids diverges with each other, both producing average from 0.00490 to 0.0567 g/s.     

Exergetic analysis of a solar thermal power system

This communication presents a second law analysis based on an exergy concept for a solar thermal power system. Basic energy and exergy analysis for the system components (viz. parabolic trough collector/receiver and Rankine heat engine, etc.) are carried out for evaluating the respective losses as well as exergetic efficiency for typical solar thermal power systems under given operating conditions. It is found that the main energy loss takes place at the condenser of the heat engine part, whereas the exergy analysis shows that the collector–receiver assembly is the part where the losses are maximum. The analysis and results can be used for evaluating the component irreversibilities which can also explain the deviation between the actual efficiency and ideal efficiency of a solar thermal power system.     

Performance assessment of parabolic dish and parabolic trough solar thermal power plant using nanofluids and molten salts

The present study has been conducted using nanofluids and molten salts for energy and exergy analyses of two types of solar collectors incorporated with the steam power plant. Parabolic dish (PD) and parabolic trough (PT) solar collectors are used to harness solar energy using four different solar absorption fluids. The absorption fluids used are aluminum oxide (Al₂O₃) and ferric oxide (Fe₂O₃)‐based nanofluids and LiCl‐RbCl and NaNO₃‐KNO₃ molten salts. Parametric study is carried out to observe the effects of solar irradiation and ambient temperature on the parameters such as outlet temperature of the solar collector, heat rate produced, net power produced, energy efficiency, and exergy efficiency of the solar thermal power plant. The results obtained show that the outlet temperature of PD solar collector is higher in comparison to PT solar collector under identical operating conditions. The outlet temperature of PD and PT solar collectors is noticed to increase from 480.9 to 689.7 K and 468.9 to 624.7 K, respectively, with an increase in solar irradiation from\ 400 to 1000 W/m². The overall exergy efficiency of PD‐driven and PT‐driven solar thermal power plant varies between 20.33 to 23.25% and 19.29 to 23.09%, respectively, with rise in ambient temperature from 275 to 320 K. It is observed that the nanofluids have higher energetic and exergetic efficiencies in comparison to molten salts for the both operating parameters. The overall performance of PD solar collector is observed to be higher upon using nanofluids as the solar absorbers. Copyright © 2015 John Wiley & Sons, Ltd.     

A comprehensive comparative energy and exergy analysis in solar based hydrogen production systems

In the presented paper, energy and exergy analysis is performed for thermochemical hydrogen (H₂) production facility based on solar power. Thermal power used in thermochemical cycles and electricity production is obtained from concentrated solar power systems. In order to investigate the effect of thermochemical cycles on hydrogen production, three different cycles which are low temperature Mg–Cl, H₂SO₄ and UT-3 cycles are compared. Reheat-regenerative Rankine and recompression S–CO₂ Brayton power cycles are considered to supply electricity needed in the Mg–Cl and H₂SO₄ thermochemical cycles. Furthermore, the effects of instant solar radiation and concentration ratio on the system performance are investigated. The integration of S–CO₂ Brayton power cycle instead of reheat-regenerative Rankine enhances the system performance. The maximum exergy efficiency which is obtained in the system with Mg–Cl thermochemical and recompression S–CO₂ Brayton power cycles is 27%. Although the energy and exergy efficiencies decrease with the increase of the solar radiation, they increase with the increase of the concentration ratio. The highest exergy destruction occurred in the solar energy unit.     

Exergoeconomic evaluation of novel solid oxide fuel cell-integrated solar combined cycle with different solar integration modes

The active use of fuel cells and solar energy in power generation systems can help reduce fossil energy consumption and improve the work capacity of the system, which is an important means to achieve the goal of “carbon neutrality”. In this study, novel solid oxide fuel cell-integrated solar combined cycle systems with different solar integration modes are proposed and investigated. The thermodynamic, environmental and economic performances of new systems with different solar collector integration modes are evaluated using the exergoeconomic theory and environmental performance analysis. The results show that when the new system uses trough solar collectors to replace part of the heating load of the second-stage high-pressure economizer and high-pressure boiler drum, the system has the highest exergy efficiency (52.91%), the lowest unit exergoeconomic cost (0.102109 $/kWh) and the lowest specific CO₂ emission rate (475.27 g/kWh). When the operating conditions of the system remain unchanged, this solar energy integration mode has the highest solar-to-electricity efficiency (26.69%) as well as thermal-to-electricity efficiency (44.22%), and can obtain the best profit in the same operating life. The new system can attain maximum energy efficiency and optimal economic benefits by using this solar energy integration mode.     

Exergetic analysis of transcritical CO2 residential air-conditioning system based on experimental data

The experimental system for the transcritical CO₂ residential air-conditioning with an internal heat exchanger was built. The effects of working conditions on system performance were experimentally studied. Based on the experimental dada, the second law analysis on the transcritical CO₂ system was performed. The effects of working conditions on the total exergetic efficiency of the system were investigated. The results show that in the studied parameter ranges, the exergetic efficiency of the system increases with the increases of gas cooler side air inlet temperature, gas cooler side air inlet velocity and evaporating temperature. And it will decrease with the increases of evaporator side air inlet temperature and velocity. Then, a complete exergetic analysis was performed for the entire CO₂ transcritical cycle including compressor, gas cooler, expansion valve, evaporator and internal heat exchanger under different working conditions. The average exergy loss in gas cooler is the highest one under all working conditions which is about 30.7% of the total exergy loss in the system. The second is the average exergy loss in expansion valve which is about 24.9% of the total exergy loss, followed by the exergy losses in evaporator and compressor, which account for 21.9% and 19.5%, respectively. The exergy loss in internal heat exchanger is the lowest one which is only about 3.0%. So in the optimization design of the transcritical CO₂ residential air-conditioning system more attentions should be paid to the gas cooler and expansion valve.     

A novel renewable energy-based integrated system with thermoelectric generators for a net-zero energy house

A renewable energy based integrated system is developed to meet the total energy demands of a house located off-grid, and a thermodynamic analysis through energy and exergy methodologies is conducted for analysis, evaluation, and performance assessment. The present novel multigeneration system is mainly driven through the animal residues produced at the farm house. The proposed novel system is composed of nine main units namely, a biomass combustor, photovoltaic (PV) panels, parabolic solar trough collectors, thermoelectric generators, organic Rankine cycle, electrolyzer, homogeneous charged compression ignition (HCCI) engine, absorption chiller, and reverse osmosis (RO) unit. Biomass combustor runs an organic Rankine turbine for additional power during peak loads. The exhaust of gas turbine generates cooling to meet the cooling demand of the residential area of the farm house. PV panels are incorporated to generate hydrogen through electrolyzer. A HCCI engine generates power to compensate peak load as well as charging the farming vehicles of the farm house. The RO unit with energy recovery Pelton turbine produces fresh water for farming and residential use. The advanced integration of subsystems, thermoelectric generators and efficient utilization of waste, improves significant amount of energetic and exergetic efficiencies of overall multigenerational system. The energy and exergy efficiencies are enhanced in the order of 4.8% and 6.3%, respectively, after incorporating innovative cooling system to the PV modules. The overall energy and exergy efficiencies of the proposed multigeneration system with and without thermoelectric are found to be 67.6% and 57.1%, and 68.9% and 58.4%, respectively.     

Component exergy analysis of solar powered transcritical CO<Subscript>2</Subscript> rankine cycle system

In this paper,exergy analysis method is developed to assess a Rankine cycle system,by using supercritical CO2 as working fluid and powered by solar energy.The proposed system consists of evacuated solar collectors,throttling valve,high-temperature heat exchanger,low-temperature heat exchanger,and feed pump.The system is designed for utilize evacuated solar collectors to convert solar energy into mechanical energy and hence electricity.In order to investigate and estimate exergy performance of this system,the energy,entropy,exergy balances are developed for the components.The exergy destructions and exergy efficiency values of the system components are also determined.The results indicate that solar collector and high temperature heat exchanger which have low exergy efficiencies contribute the largest share to system irreversibility and should be the optimization design focus to improve system exergy effectiveness.Further,exergy analysis is a useful tool in this regard as it permits the performance of each process to be assessed and losses to be quantified.Exergy analysis results can be used in design,optimization,and improvement efforts.     

Analysis and evaluation of a new solar energy‐based multigeneration system

In this study, a novel, renewable energy based, multigeneration energy system is introduced, and solar energy is, in this regard, used to produce electricity for a multi‐unit building utilizing a Kalina cycle. For cooling a four‐stage absorption chiller running on excessive or recovered heat is used. An electrolyzer is employed to produce hydrogen from the unused portion of electricity. In addition, domestic hot water is obtained from the system. In the analysis, a comprehensive thermodynamic model of the system is developed; the exergy efficiencies of the overall system and its components are determined; and the effects of varying configurations and operating conditions on the system performance are investigated. The number of suites that the system can satisfactory meet the demands is determined. Finally, an environmental impact assessment is conducted to determine the reductions in the amount of greenhouse gases, which can easily be achieved here by this solar energy based multigeneration system. The highest energy efficiency of the system is 57%, while the maximum exergy efficiency is 36%. It produces a maximum power of 92 kW and has a maximum cooling effect of 128 kW. It saves 1398 t of CO₂ per year compared with a conventional system to produce the same amounts of outputs, which can sufficiently meet the demand of 94 suites, respectively. Copyright © 2016 John Wiley & Sons, Ltd.