影响换热面结垢诱导期的表面特性研究

换热面结垢是一个普遍存在的问题,而结垢诱导期的长短对污垢形成过程具有重要的影响,即使在相同实验条件下,不同材料换热面的结垢诱导期仍相差较大.因此本文通过对附着在换热面上的半球形污垢晶核进行受力分析,发现污垢晶核与换热面之间的附着力对其结垢诱导期长短起决定性作用,然后根据颗粒与平板间附着力模型,计算了污垢晶核与具有不同表面能的换热面间附着力,并与相应的结垢诱导期进行对比.结果表明:结垢诱导期的长短与换热面的表面能、污垢晶核与换热面间的附着力及表面粗糙度尺度有关.     

Influence of gas velocity on particulate fouling of exhaust gas recirculation coolers

The objective of this research is to study the influence of gas flow velocity on particulate fouling of exhaust gas recirculation (EGR) coolers. An experimental setup has been designed and constructed to simulate particulate fouling in EGR coolers in diesel engines. The setup consists of soot generator, gas/particle flow heater, testing section for EGR coolers and finally an exhaust system. Two sets of fouling experiments have been performed with and without water injection, and the gas velocity in each set has varied between 30, 70 and 120 m/s. The concentration of soot particles in the gas flow is 100 mg/m³, and the average diameter of the particles is 130 nm with a standard deviation of 55 nm. It has been found that the thermal resistance and thickness of the fouling layer and the fouling rate decrease as the gas velocity in the EGR cooler increases. If EGR coolers are operated with a gas velocity, which is just lower than the critical flow velocity for the largest particle in the flow, quick deterioration of the thermal performance of the heat exchanger will nevertheless occur. This strongly indicates that the gas velocity should exceed a certain critical flow velocity in order to prevent particulate fouling. In addition, the presence of water vapour in the gas flow improves the thermal performance of the cooler and decreases the fouling rate, and its influence decreases as the gas velocity increases.     

Development of a Computational Fluid Dynamics Model for Predicting Fouling Process Using Dynamic Mesh Model

Abstract

This article presents a comprehensive computational model capable of simulating fouling layer thickness evolution using dynamic mesh model. This computational methodology has been developed to reproduce the deposit generation during fouling process with an innovated work method. Dynamic mesh model, from Ansys Fluent software, and external routines have been used to implement this advanced numerical model which allows to move the boundaries of a region relative to other boundaries of the zone. The displacement of the nodes of the mesh is the mechanism that this model uses to adjust the geometry according to the fouling layer evolution. During the simulation process, the geometry under investigation is modified to reproduce the emergence and gradual change of the fouling layer. Different rules of deposition and removal of the fouling process can be implemented in the proposed algorithm. The direct interaction between fouling expressions and governing equations of the main flow is used to predict deposits formation and growth. In this article, numerical simulations of soot fouling layer formation have been presented. Deposit evolution has been calculated inside different heat exchanger technologies used in exhaust gas recirculation systems to analyze fouling process and to verify the advantages of this new computational strategy.     

Removal of gas-side particulate fouling layers by foreign particles as a function of flow direction

Removal of particulate fouling layers by externally injected particles as a function of flow direction with respect to gravity is investigated experimentally. Three orientations of flow have been investigated, horizontal flow, upward flow and a downward flow. It is found that fouling starts at the point of stagnation irrespective of the flow direction, and also starts at the top point of the heat exchanger tubes. Particulate fouling grows from these two points except for the downward flow, were the flow stagnation point coincides with the top point of the heat exchanger tubes and the growth of the fouling layer starts only from one point. It was not possible to remove the fouling layer in case of a horizontal and an upward flow by the externally injected particles, however in case of a downward flow most of the fouling layers were removed by the external particles. It can be concluded that the downward flow is the best flow orientation to linger particulate fouling and for removal of fouling layers by externally injected particles.     

Calcium Sulfate Fouling-Precipitation or Particulate: A Proposed Composite Model

Though it is of great importance, the majority of predictive models tend not to incorporate water chemistry in their formulations. The ionic diffusion model which was developed for CaCO₃, is based purely on crystallization, and is one of the few models that incorporates water chemistry. This model does not provide satisfactory predictions for CaSO₄ fouling. In this article, a new model is proposed for CaSO₄ fouling which takes into account the effect of both crystallization and particulate fouling and is capable of predicting the fouling resistance during the cleaning cycle as well as the fouling cycle. A removal term is incorporated into the model, as the occurrence of particulate fouling for CaSO₄ tends to weaken its crystalline structure and makes it more prone than CaCO₃ to removal. Properties of the electrolyte were evaluated using MINTEQA2 computer code, which is approved by the U.S. Environmental Protection Agency. In this model, particulate fouling is estimated using the physical mechanism for particle transport and adherence, crystallization is estimated by ionic diffusion, and the removal term is approximated using hydrodynamics of flow and deposit properties. The inclusion of both crystallization and removal terms incorporates the effects of both water chemistry and hydrodynamics of the flow and provides a relationship which not only can predict fouling but also can predict dissolution, by change of water quality and/or stopping the operation, or removal by shear stress. The proposed model was assessed using published experimental data. The results indicate that this model provides good predictions: the slope of predicted rates as a function of the experimental rates is 1.05. The experimental results, though limited in number, suggest that crystallization is not the main or only mechanism contributing to CaSO₄ fouling. Particulate fouling seems to be a major contributor. Further experimentation is in process to confirm the degree of particulate fouling and to substantiate or to modify the model accordingly.     

hiTRAN® Wire Matrix Inserts in Fouling Applications

Fouling characteristics are dictated largely by the properties of the thermal and hydrodynamic boundary layers. As a result, fouling mitigation strategies must take into account the conditions in this region. hiTRAN wire matrix tube inserts are a useful tool in altering the conditions near the tube wall, especially in the laminar and transition flow regions. This review article considers particle image velocimetry and laser doppler velocimetry measurements, which were employed in order to show the hydrodynamic differences between plain tubes and those containing inserts. Measurements indicate that the wall shear rate in tubes containing hiTRAN inserts operating in the laminar flow regime is similar to that for plain bore tubes operating in the turbulent flow regime. Moreover, the increased tube-side heat transfer coefficient that results from the reduction of the thermal boundary layer allows operation with smaller Effective Mean Temperature Differences (EMTDs). This enables the designer to reduce the tube wall temperature to a level below the fouling threshold temperature, e.g., to combat crude oil fouling. The results from the laser analyses into the hydrodynamic boundary layer are backed up by recent research data investigating the effect of hiTRAN inserts on sedimentation and particulate fouling. The thickness of the fouling layer was measured by applying a combination of photographic and laser measurement techniques. The results are compared to plain tube data and are reported as a function of both flow rate and hiTRAN insert packing density. The impact of altering the hydrodynamic and thermal conditions near to the wall is subsequently demonstrated for different fouling mechanisms. Studies of the impact of hiTRAN inserts on biological and chemical reaction fouling in crude oil processing are also reviewed. A better understanding of the threshold shear rates and wall temperatures for different fouling mechanisms is required for any study into the impact of fouling. Combining this knowledge with the principles outlined in this article clearly emphasizes the benefit of using hiTRAN wire matrix inserts as a powerful tool to mitigate fouling.     

Influence of sintering on the growth rate of particulate fouling layers

This article addresses the question; why the gas-side temperature affects the rate of particulate fouling of heat exchangers? An experiment was carried out in a gas-cooler of a full-scale biomass gasifier to investigate the influence of the gas-side temperature on the strength, structure and growth rate of particulate fouling layers. It is observed that the particulate fouling rate in the gas cooler decreases with sintering, which is a function of the gas-side temperature. Detailed impaction experiments are carried out to investigate the influence of sintering on the removal of particles from a particulate fouling layer due to an incident particle impact as well as the sticking of an incident particle to a particulate fouling layer. Sintering of a fouling layer lowers significantly the ability of an incident particle to stick to the fouling layer or to remove particles out of the layer. However, particles that are still able to deposit on the sintered fouling layer will not sinter immediately, and can be removed due to the incident particles impact. The removal of newly deposited particles on a fouling layer due to incident particles becomes easier as sintering of the fouling layer takes place. Accordingly, it may be stated that sintering reduces the fouling rate of heat exchangers by lowering the deposition of new particles and increasing the removal rate of newly deposited particles. This explains why the growth rate of particulate fouling layers decreases with the gas-side temperature.     

Effect of Condensable Species on Particulate Fouling

The flue gases emanating from the combustion of fuels or gasification process invariably comprise particulate matter and many chemical species in vapor form. The temperature of the flue gases gradually reduces when passing through different sections of heat exchanger, such as the superheater, evaporator, and so on. If the temperatures of the heat exchanger tube surface and the gas phase are favorable for condensation, the chemical species in the vapor form will condense on the particles and on the tube surface. The particle deposition behavior under these conditions is drastically different from the one observed in dry particulate fouling. In order to model the particle deposition under such circumstances, it is important to evaluate the criteria for particle adhesion to the surface. Impaction experiments of particles impacting a surface coated with a thin liquid film and particles that are coated with a liquid film impacting over a dry surface are performed to evaluate the limiting parameters under which a particle sticks to the surface without rebounding. The effects of liquid viscosity, liquid film thickness, and interacting material properties are evaluated. The experimental results are compared to the results of existing models and a suitable model for fouling is proposed. Controlled fouling experiments are performed for varying liquid films coated over a deposition tube under various process conditions to mimic the condensation effects on fouling. The results are compared with detailed impaction experiments.     

Particulate fouling in waste incinerators as influenced by the critical sticking velocity and layer porosity

Fouling of heat transfer surfaces introduces a major uncertainty into the design and operation of heat exchange equipment. Fouling layers as observed on the tube bundles of the economizer in a Dutch waste incinerator were thin and powdery. The fouling layer showed an asymptotic growth rate with a levelling off increase of the thickness. In this study, the influence of the critical sticking velocity on the growth rate of particulate fouling layers is described. The critical sticking velocity of an incident particle hitting a powdery layer is defined as the maximum impact speed at which the particle will stick to the layer. Since the critical sticking velocity is a key parameter in the deposition mechanism, a well-defined experimental set-up has been built to assign it. Experimental results showed that the critical sticking velocity increases with the porosity of the fouling layer. Literature shows that the porosity of a thin sintered powdery layer changes with the layer thickness. Based on the experimental results and the variation of porosity with thickness for a thin sintered powdery fouling layers, a correlation is developed which shows that the sticking velocity decreases exponentially as the fouling layer thickness increases. Therefore, fewer particles are likely to stick as the fouling layer builds up and consequently the deposition rate decreases. The change in the critical sticking velocity as the fouling layer builds up contributes to the explanation of the asymptotic growth of particulate fouling layers on the tube bundle of waste incinerators.     

The impact of heat exchanger fouling on the optimum operation and maintenance of the Stirling engine

This paper focuses on the effect of heat exchanger fouling on the performance of the Stirling engine in combined heat and power (CHP) application. Fouling results from using biomass fuels and affects the heat exchanger that transfers heat into the engine. This heat exchanger is referred to as the heater. The heat exchanger that recovers heat from the flue gases is also affected by fouling. To determine the performance of the Stirling engine, a commercial Stirling analysis tool is applied together with models that have been developed for the heat transfer in the heater, regenerator and cooler of the engine. The Stirling engine model uses constant temperatures for the heat addition and rejection, with the theory of displacement engine as a basis. The fouling in the heat exchanger is taken into account by using a fouling factor that corresponds with the degradation in the total heat transfer coefficient. The Stirling engine model together with the model for heat exchanger fouling makes it possible to estimate the effect of fouling on the performance of the Stirling engine. A cost model is developed for the engine to translate changes in performance into economy in CHP operation. In the studied application, the Stirling engine is operated by the heat demand. Together with the selected control method, performance and cost models compose a tool for the simulation and optimization of the system. The use of the models to determine the optimal cleaning interval of the heat exchanger surfaces is considered.     

Effect of Geometry and Flow Conditions on Particulate Fouling in Plate Heat Exchangers

This article describes particulate fouling experiments performed on small-scale and full-scale plate heat exchangers for three different corrugation angles (30 deg, 45 deg and 60 deg). The velocity effect has been studied as well as the particle type and concentration effects. The test duration ranges between 20 and 1,500 h in order to reach asymptotic behavior. The results clearly indicate that the corrugation angle has a major influence on the asymptotic fouling resistance. Increasing the corrugation angle leads to lower values for the fouling resistance. Furthermore, for a given corrugation angle, the asymptotic fouling resistance is inversely proportional to the velocity squared. Finally, the asymptotic fouling resistance is proportional to the particle concentration. Fouling mitigation can be obtained by taking into account at the design stage the heat exchanger geometry and fluid velocity.     

Simulation of particle deposition on the tube in ash-laden flow using the lattice Boltzmann method

The LBM-Lagrange tracking method with multiple relaxation time (MRT) model has been developed to predict the flow field and particle deposition a circular or elliptical tube in ash-laden gas turbulent flow with Re of 10,229. The model can be used for predict particle deposition effect on thermal resistance or fouling factor of heat exchangers mostly operating in turbulent flow.Particle deposition morphology on the circular and the elliptical tubes were obtained with the lattice Boltzmann method (LBM). The particle deposition mechanism has been investigated. The dominating mechanism of particle deposition on the circular tube is Brownian diffusion for the Stokes number of 0.002, whereas the dominating mechanism of particle deposition is drag inertia for the Stokes number larger than 0.031. When the long axis of the elliptical tube is parallel to the flow, both the collision efficiency and the deposition efficiency for the elliptical tube are fewer than those of the circular tube which means less particle deposition. It also can be concluded that both ratios of the collision efficiency and the deposition efficiency decrease with increasing axial length ratio of the elliptical tube. The elliptical tube is better than the circular tube as heat transfer surface in the aspect of preventing ash particle deposition.     

Detection of Fouling in a Cross-Flow Heat Exchanger Using Wavelets

Detection of fouling in a heat exchanger experiencing perfect steady-state conditions is not very difficult. But the challenge is to detect fouling when all inputs (inlet temperature of the fluids and the mass flow rates) are simultaneously varying. In this paper it has been considered that the mass flow rates can vary in a ratio of 2, and that the inlet temperatures can vary by about ±20%. This first approach is dedicated to show the feasibility of using the wavelet transform. It has been considered that getting simulated data is the best way. In fact, it is then possible to introduce an arbitrary fouling factor. Thus, in the first part of the paper the model of the heat exchanger is presented. It is developed using Simulink. The validation is carried out on an electrical heater, for which it is possible to find an analytical solution for transient states. It is also shown that steady states are accurately computed over a large range of the number of transfer units and heat capacity rate ratios. Then a brief overview of the wavelet transform is given. Then basic examples show that the wavelet transform can help to find the trend of time series. It is then applied to the analysis of the “wavelet-transformed” effectiveness of the heat exchanger. This analysis is carried out on a sliding observation window (to be able to detect fouling on-line). It is shown that fouling is detected at a very early stage.     

Simultaneous Consideration of Flow and Thermal Effects of Fouling in Crude Oil Preheat Trains

Given models linking flow resistance and fouling resistance, it becomes possible to simulate the effects of fouling on the hydraulic performance of a refinery preheat train. Such a simulation has been used here to identify when plant throughput will be limited by pressure drop; how throughput can be improved through the cleaning of individual exchangers and groups of exchangers; and how much production can be maintained when individual exchangers are taken off-line. Determination of better operating strategy requires a simulation of both hydraulic and thermal performance. In this article we implement a pragmatic linked model and consider the results from a set of simulations.     

Optimization of Flow Direction to Minimize Particulate Fouling of Heat Exchangers

The influence of flow direction with respect to gravity on particulate fouling of heat exchangers is investigated experimentally to determine the optimal flow direction to minimize fouling. Four orientations of flow have been investigated: horizontal flow, upward flow, downward flow, and a flow under an angle of 45°. It is observed that fouling starts at the point of stagnation irrespective of the flow direction, and also at the top of the heat exchanger tubes. Particulate fouling grows from these two points till they meet and the fouling layer covers the whole surface of the heat exchanger tube. Fouling at the upper half of the tubes is much faster than the lower half of the tubes, and the fouling rate is faster at the bottom tubes of the heat exchanger section than at the upper tubes. The best orientation for lingering particulate fouling is the downward flow, where the flow stagnation point coincides with the top point of the heat exchanger tubes and the growth of the fouling layer only starts from one point.     

微粒污垢的特性分析

利用微粒污垢的一个预测模型，结合实验结果，研究了管壳式换热顺管内微粒污垢的积聚特性，考察了颗粒质量分数，颗粒直径和流体速度对渐近污垢热阻的影响，提出了大、中、小粒子及未知尺寸粒子的尺寸界限的参考值。     

三维变形管管内积灰特性数值模拟研究

烟气中的高灰分、高黏度、高腐蚀性成分不可避免地造成换热器烟气侧换热面积灰结垢的问题,如何有效解决这些问题一直是烟气换热器研究的焦点之一。三维变形管内的螺旋流增强了管内流体的湍动程度从而实现强化传热,基于其内部灰尘受气流携带而处于湍动便不易沉积的特点,本文通过数值模拟的方法探讨了三维变形管几何参数、粒径、气体流速对灰尘颗粒沉积率的影响。结果表明,在给定的粒径范围内,烟气流速和三维变形管的几何参数对灰分沉积率有重大影响。随着螺距和烟气流速的增大,灰尘颗粒沉积率降低,然而灰尘颗粒沉积率随着长短轴比和平均粒径的增大而增加。     

循环流化床脱硫塔内流场及气固分离特性数值模拟

1前言循环流化床烟气脱硫技术(CFB-FGD)已经成为我国燃用中、低硫煤(含硫量<2%)的中小电厂锅炉(<200 MW)优先推荐使用的技术。各代表技术都是参照经验参数和估算值进行设计,已有的理论研究成果也多是基于实验室或者小规模中试得出的,对于实际工程的适应性和放大性有待验证,因此