Study of molten carbonate fuel cell—microturbine hybrid power cycles

The interaction realized by fuel cell—microturbine hybrids derive primarily from using the rejected thermal energy and combustion of residual fuel from a fuel cell in driving the gas turbine. This leveraging of thermal energy makes the high temperature molten carbonate fuel cells (MCFCs) ideal candidates for hybrid systems. Use of a recuperator contributes to thermal efficiency by transferring heat from the gas turbine exhaust to the fuel and air used in the system.Traditional control design approaches, consider a fixed operating point in the hope that the resulting controller is robust enough to stabilize the system for different operating conditions. On the other hand, adaptive control incorporates the time-varying dynamical properties of the model (a new value of gas composition) and considers the disturbances acting at the plant (load power variation).     

A distributed energy system integrating SOFC-MGT with mid-and-low temperature solar thermochemical hydrogen fuel production

Solar thermochemical hydrogen production with energy level upgraded from solar thermal to chemical energy shows great potential. By integrating mid-and-low temperature solar thermochemistry and solid oxide fuel cells, in this paper, a new distributed energy system combining power, cooling, and heating is proposed and analyzed from thermodynamic, energy and exergy viewpoints. Different from the high temperature solar thermochemistry (above 1073.15 K), the mid-and-low temperature solar thermochemistry utilizes concentrated solar thermal (473.15–573.15 K) to drive methanol decomposition reaction, reducing irreversible heat collection loss. The produced hydrogen-rich fuel is converted into power through solid oxide fuel cells and micro gas turbines successively, realizing the cascaded utilization of fuel and solar energy. Numerical simulation is conducted to investigate the system thermodynamic performances under design and off-design conditions. Promising results reveal that solar-to-hydrogen and net solar-to-electricity efficiencies reach 66.26% and 40.93%, respectively. With the solar thermochemical conversion and hydrogen-rich fuel cascade utilization, the system exergy and overall energy efficiencies reach 59.76% and 80.74%, respectively. This research may provide a pathway for efficient hydrogen-rich fuel production and power generation.     

基于太阳能热驱动甲烷重整制氢的燃料电池发电系统性能研究

该文采用Aspen Plus软件建立膜反应器重整制氢及燃料电池模型,根据拉萨某日太阳能直接辐射强度（DNI）变化计算太阳能可供使用的能量,作为外热源输入重整系统,并分析反应温度、水碳比（S/C）及DNI对该系统各性能指标的影响,性能指标包括甲烷转化率、H₂收率、电池功率及电压、太阳能转换为氢能的效率。结果表明：反应温度为500 ℃,S/C为2.5时有利于太阳能甲烷湿重整反应;系统日性能结果显示在某日10:00—20:00时,电池输出功率120 kW,太阳能-化学能转化效率0.368,系统发电效率0.225。     

Efficient utilization of waste heat from molten carbonate fuel cell in parabolic trough power plant for electricity and hydrogen coproduction

Direct steam generating parabolic trough power plant is an important technology to match future electric energy demand. One of the problems related to its emergence is energy storage. Solar-to-hydrogen is a promising technology for solar energy storage. Electrolysis is among the most processes of hydrogen production recently investigated. High temperature steam electrolysis is a clean process to efficiently produce hydrogen. In this paper, steam electrolysis process using solar energy is used to produce hydrogen. A heat recovery steam generator generates high temperature steam thanks to the molten carbonate fuel cell's waste heat. The analytical study investigates the energy efficiency of solar power plant, molten carbonate fuel cell and electrolyser. The impact of waste heat utilization on electricity and hydrogen generation is analysed. The results of calculations done with MATLAB software show that fuel cell produces 7.73 MWth of thermal energy at design conditions. 73.37 tonnes of hydrogen and 14.26 GWh of electricity are yearly produced. The annual energy efficiency of electrolyser is 70% while the annual mean electric efficiency of solar power plant is 18.30%.The proposed configuration based on the yearly electricity production and hydrogen generation has presented a good performance.     

Fuel cell power conditioning unit for standalone application with real time validation

In recent era, fuel cells are emerging as better alternative to wind and solar based energy sources due to its reliability and high efficiency. Polymer Electrolyte Membrane Fuel Cell (PEMFC) is widely used in various applications due to low operating temperature and high energy density. On the other side low and unregulated stack voltage demands PEMFC integration with suitable power conditioning unit. However, the use of actual fuel cell power conditioning unit in design and testing for research is expensive. Any failure may lead to damage of source or power circuit. In this regard, the present work aims at developing a soft-computing model of PEMFC. Also, a DC-DC converter is designed to step-up the stack voltage. A classical PI controller is implemented to regulate the PEMFC fed power conditioning units for resistive loads. The proposed system is implemented is Hardware-In-the-Loop (HIL) using OPAL-RT's OP5600 Real Time Digital Simulator (RTDS).     

What is the design objective for portable power generation: Efficiency or energy density?

Recently, various alternatives to batteries, such as microfabricated fuel cell systems, have been proposed for portable power generation. In large-scale power production plants emphasis is placed on energy conversion efficiency. On the other hand, the intrinsic design objective for portable power generation devices is the energy density, i.e., the electrical energy generated from a given mass or volume of device and fuel cartridge. It is plausible to stipulate that an increase in the energy conversion efficiency of a system leads to an increase in energy density, but we demonstrate through theoretical analysis and case studies that the two metrics are not equivalent. In some cases, such as systems with a combination of fuels, maximizing efficiency leads to drastically different design, operation and performance than maximizing energy density. Another interesting observation is that, due to interaction between components, maximal component efficiency does not always imply maximal system efficiency.     

A theoretical study of molten carbonate fuel cell combined with a solar power plant and Cu–Cl thermochemical cycle based on techno-economic analysis

A novel power and hydrogen coproduction system is designed and analyzed from energetic and economic point of view. Power is simultaneously produced from parabolic trough collector power plant and molten carbonate fuel cell whereas hydrogen is generated in a three-steps Cu–Cl thermochemical cycle. The key component of the system is the molten carbonate fuel cell that provides heat to others (Cu–Cl thermochemical cycle and steam accumulator). A mathematic model is developed for energetic and economic analyses. A parametric study is performed to assess the impact of some parameters on the system performance. From calculations, it is deduced that electric energy from fuel cell, solar plant and output hydrogen mass are respectively 578 GWh, 25 GWh and 306 tons. The overall energy efficiency of the proposed plants is 46.80 % and its LCOE is 7.64 c€/kWh. The use of MCFC waste heat allows increasing the solar power plant efficiency by 2.15 % and reducing the annual hydrogen consumption by 3 %. Parametric analysis shows that the amount of heat recovery impacts the energy efficiency of fuel cell and Cu–Cl cycle. Also, current density is a key parameter that influences the system efficiency.     

Grid connected fuel cell and PV hybrid power generating system design with Matlab Simulink

Renewable energy sources have been taken the place of the traditional energy sources and especially rapidly developments of photovoltaic (PV) technology and fuel cell (FC) technology have been put forward these renewable energy sources (RES) in all other RES. PV systems have been started to be used widely in domestic applications connected to electrical grid and grid connected PV power generating systems have become widespread all around the world. On the other hand, fuel cell power generating systems have been used to support the PV generating so hybrid generation systems consist of PV and fuel cell technology are investigated for power generating. In this study, a grid connected fuel cell and PV hybrid power generating system was developed with Matlab Simulink. 160 Wp solar module was developed based on solar module temperature and solar irradiation by using real data sheet of a commercial PV module and then by using these modules 800 Wp PV generator was obtained. Output current and voltage of PV system was used for input of DC/DC boost converter and its output was used for the input of the inverter. PV system was connected to the grid and designed 5 kW solid oxide fuel cell (SOFC) system was used for supporting the DC bus of the hybrid power generating system. All results obtained from the simulated hybrid power system were explained in the paper. Proposed model was designed as modular so designing and simulating grid connected SOFC and PV systems can be developed easily thanks to flexible design.     

Dynamics and control of a thermally self-sustaining energy storage system using integrated solid oxide cells for an islanded building

A solid oxide cell-based energy system is proposed for a solar-powered stand-alone building. The system is comprised of a 5 kW_el solid oxide fuel cell (SOFC), a 9.5 kW_el solid oxide electrolysis cell (SOEC), and the required balance of plant. The SOFC supplies: 1- building demand in the absence of sufficient solar power, 2- heat for SOEC in endothermic and standby modes. Thermal integration of SOFC and SOEC is implemented through a network of heat exchangers, combined with set of control algorithms. Two control strategies were implemented to actuate the SOFC in response to endothermic heat demands of SOEC by manipulating: 1- electric power, 2- fuel utilization. The results of dynamic simulation of system for two scenarios (sunny day and cloudy day) showed successful compliance of temperature constraints with both methods. Manipulation of fuel utilization, however, resulted in better system performance in terms of efficiency and H₂ balance.     

Harvesting of PEM fuel cell heat energy for a thermal engine in an underwater glider

The heat generated by a proton exchange membrane fuel cell (PEMFC) is generally removed from the cell by a cooling system. Combining heat energy and electricity in a PEMFC is highly desirable to achieve higher fuel efficiency. This paper describes the design of a new power system that combines the heat energy and electricity in a miniature PEMFC to improve the overall power efficiency in an underwater glider. The system makes use of the available heat energy for navigational power of the underwater glider while the electricity generated by the miniature PEMFC is used for the glider's sensors and control system. Experimental results show that the performance of the thermal engine can be obviously improved due to the high quality heat from the PEMFC compared with the ocean environmental thermal energy. Moreover, the overall fuel efficiency can be increased from 17 to 25% at different electric power levels by harvesting the PEMFC heat energy for an integrated fuel cell and thermal engine system in the underwater glider.     

PEM fuel cell performance with solar air preheating

Proton Exchange Membrane Fuel Cells (PEMFC) have proven to be a promising energy conversion technology in various power applications and since it was developed, it has been a potential alternative over fossil fuel-based engines and power plants, all of which produce harmful by-products. The inlet air coolant and reactants have an important effect on the performance degradation of the PEMFC and certain power outputs. In this work, a theoretical model of a PEM fuel cell with solar air heating system for the preheating hydrogen of PEM fuel cell to mitigate the performance degradation when the fuel cell operates in cold environment, is proposed and evaluated by using energy analysis. Considering these heating and energy losses of heat generation by hydrogen fuel cells, the idea of using transpired solar collectors (TSC) for air preheating to increase the inlet air temperature of the low-temperature fuel cell could be a potential development. The aim of the current article is applying solar air preheating for the hydrogen fuel cells system by applying TSC and analyzing system performance. Results aim to attention fellow scholars as well as industrial engineers in the deployment of solar air heating together with hydrogen fuel cell systems that could be useful for coping with fossil fuel-based power supply systems.     

Solar multi-mode heating system based on latent heat thermal energy storage and its application

为克服太阳能间断性和不稳定性的缺点进而实现太阳能集热与采暖的能量供需调节和全天候连续供热,提出了基于相变储热的太阳能多模式采暖方法（太阳能集热直接采暖、太阳能集热采暖+相变储热、太阳能相变储热采暖）,并在西藏林芝市某建筑搭建了太阳能与相变储热相结合的采暖系统,该系统可根据太阳能集热温度和外界供热需求实现太阳能多模式采暖的自动控制和自动运行。实验研究表明：在西藏地区采用真空管太阳能集热器可以和中低温相变储热器很好地结合,白天储热器在储热过程中平均储热功率为10.63 kW,储热量达到92.67 kW·h,相变平台明显;晚上储热器在放热过程中供热量达85.23 kW·h,放热功率和放热温度平稳,储放热效率达92%,其储热密度是传统水箱的3.6倍,可连续供热时间长达10 h,从而实现了基于相变储热的太阳能全天候连续供热,相关研究结果对我国西藏地区实施太阳能采暖具有一定的指导作用。     

Introducing an integrated SOFC,linear Fresnel solar field,Stirling engine and steam turbine combined cooling,heating and power process

A new integrated combined cooling, heating and power system which includes a solid oxide fuel cell, Stirling engine, steam turbine, linear Fresnel solar field and double effect absorption chiller is introduced and investigated from energy, exergy and thermodynamic viewpoints. In this process, produced electrical power by the fuel cell and steam turbines is 6971.8 kW. Stirling engine uses fuel cell waste heat and produces 656 kW power. In addition, absorption chiller is driven by waste heat of the Stirling engine and generates 2118.8 kW of cooling load. Linear Fresnel solar field produces 961.7 kW of thermal power as a heat exchanger. The results indicate that, electrical, energy and exergy efficiencies and total exergy destruction of the proposed system are 49.7%, 67.5%, 55.6% and 12560 kW, respectively. Finally, sensitivity analysis to investigate effect of the different parameters such as flow rate of inputs, outlet pressure of the components and temperature changes of the solar system on the hybrid system performance is also done.     

Simulation to analyze operation strategy of combined cooling and power system using a high-temperature polymer electrolyte fuel cell for data centers

With the development of the information and communication technology (ICT) industry, the energy consumption of data centers is continuously increasing. High-temperature polymer electrolyte fuel cells (HT-PEFC) have a high operating temperature of 120 °C or higher; thus, the heat generated from fuel cells stack is effectively used as a heat source for a absorption refrigerator (AR) to generate cooling. The combined cooling and power (CCP) system is proposed to satisfy the energy demand of data centers that require both power and cooling. The CCP system comprises an HT-PEFC and a double-effect AR that recovers the wasted heat of the fuel cell stack. As a result of analyzing the electrical and cooling efficiency of the CCP system according to the fuel cell operating conditions, the overall efficiency increased to 95%, which was significantly higher than the existing system. Based on the simulation of the developed model, coefficient of performance (COP) and cooling capacity depending on the temperature changes of chilled water and cooling water were calculated within the stack temperature range of 150–180 °C, and the COP changed from 1.1 to 1.58 depending on the conditions. The developed CCP system model can be used to plan strategies for flexible fuel cell operation according to the power and cooling demands required in the data center.     

Design and optimization of hybrid solar-hydrogen generation system using TRNSYS

Solar thermal systems are an efficient utilization of solar energy for hot water and space heating at domestic level. A Solar Water Heater (SWH) incorporating an Evacuated Glass Tube Collector (EGTC) is simulated using TRNSYS software. Efficiency parameters are pointed, and a parametric optimization method is adopted to design the system with maximum conceivable efficiency. In the first part, the selection of refrigerant for heat transportation in SWH loop is presented. A set of 15 working fluids are chosen, and their chemical properties are computed using NIST standard software (REFPROP). The selected working fluids are tested in the system under study and plots for energy gain and temperature are plotted using TRNSYS. Results showed that ammonia (NH₃) having specific heat 4.6kJ/kg-K and fluid thermal conductivity 2.12 kJ/hr-m supplies peak energy gain of 7500 kJ/h in winter and 8900 kJ/h in summer season along 120 °C temperature rise. On the other hand, R-123 having specific heat 0.65kJ/kg-K and fluid thermal conductivity 0.0293kJ/hr-m showed inferior performance during the simulation. A solar-hydrogen co-generation system is also designed and simulated under low solar insolation and warm climate regions to study annual hydrogen produced by the hybrid system. System comprises main components: a PV array, an electrolyzer, a fuel cell, a battery, a hydrogen storage unit and a controller in the complete loop. Results of Hydrogen cogeneration system provide 7.8% efficiency in the cold climate of Fargo North Dakota state due to lower solar insolation. While hot climate condition of Lahore weather provides efficiency of 11.8% which satisfy the statistics found in literature.     

Energy,exergy and exergo-environmental impact assessment of a solid oxide fuel cell coupled with absorption chiller & cascaded closed loop ORC for multi-generation

A novel solid oxide fuel cell (SOFC) multigeneration system fueled by biogas derived from agricultural waste (maize silage) is designed and analyzed from the view point of energy and exergy analysis. The system is proposed in order to limit the greenhouse gas emissions as it uses a renewable energy source as a fuel. Electricity, domestic hot water, hydrogen and cooling load are produced simultaneously by the system. The system includes a solid oxide fuel cell; which is the primary mover, a biogas digester subsystem, a cascaded closed loop organic Rankine cycle, a single effect LiBr-water absorption refrigeration cycle, and a proton exchange membrane electrolyzer subsystem. The proposed cascaded closed-loop ORC cycle is considered as one of the advanced heat recovery technologies that significantly improve thermal efficiency of integrated systems. The thermal performance of the proposed system is observed to be higher in comparison to the simple ORC and the recuperated ORC cycles. The integration of a splitter to govern the flue gas separation ratio is also introduced in this study to cater for particular needs/demands. The separation ratio can be used to vary the cooling load or the additional power supplied by the ORC to the system. It is deduced that net electrical power, cooling load, heating capacity of the domestic hot water and total energy and exergy efficiency are 789.7 kW, 317.3 kW, 65.75 kW, 69.86% and 47.4% respectively under integral design conditions. Using a parametric approach, the effects of main parameters on the output of the device are analyzed. Current density is an important parameter for system performance. Increasing the current density leads to increased power produced by the system, decreased exergy efficiency in the system and increased energy efficiency. After-burner, air and fuel heat exchangers are observed to have the highest exergy destruction rates. Lower current density values are desirable for better exergy-based sustainability from the exergetic environmental impact assessment. Higher current density values have negative effect on the environment.     

Design and evaluation of hybrid propulsion ship powered by fuel cell and bottoming cycle

Fuel cells are a promising power source in the electric propulsion systems for zero-emission vessels. The electric efficiency of fuel cells can be increased to 55% practically, but significant amounts of remaining energy from the electrochemical reaction are wasted as heat. This article proposes a hybrid propulsion system for ships that utilizes both the electric energy and thermal energy generated by fuel cells. The electric power capacity of fuel cells and the steam generation capacity of recovered heat from fuel cell systems are calculated, and then the propulsion power of the hybrid system is simulated by MATLAB Simulink. The overall energy efficiency of the proposed ship propulsion system is compared with that of conventional systems by comparing fuel consumption rate. Simulation results indicate that the proposed hybrid propulsion system can increase energy efficiency by 22.5% by additional utilization of the recovered heat from fuel cells.     

Organic Rankine Cycle coupling with a Parabolic Trough Solar Power Plant for cogeneration and industrial processes

Over the last 25 years solar power plants based on parabolic trough concentrators have been developed for the commercial power industry. On the other hand, in recent years, a way to harness the solar energy is to cogenerate through Concentrated Solar Power (CSP) technology coupled to an Organic Rankine Cycle (ORC) with potential applications to industrial processes. In this work we present a study of a small CSP plant coupled to an ORC with a novel configuration since useful energy is directly used to feed the power block and to charge the thermal storage. In order to analyze this novel configuration we consider a case study with cogeneration applied to textile industrial process at medium temperature. It turns out that this configuration reduces the size of the thermal storage disposal. The performance of the solar power plant was simulated with TRNSYS to emulate real operating conditions. We show the design, study and simulation results, including the production and efficiency curves for our load profile. Our results show that our system is a promising option for applications to medium temperature processes where electrical and heat generation is required.     

Study on design of molten salt solar receivers for beam-down solar concentrator

Systems using molten salt as thermal media have been proposed for solar thermal power generation and for synthetic fuel production. We have been developing molten salt solar receivers, in which molten salt is heated by concentrated solar radiation, in the Solar Hybrid Fuel Project of Japan. A cavity shaped receiver, which is suitable for a beam-down type solar concentration system, was considered. In order to design molten salt solar receivers, a numerical simulation program for the prediction of characteristics of receivers was developed. The simulation program presents temperature distributions of a receiver and molten salt with the use of heat flux distribution of solar radiation and properties of composing materials as input data. Radiation to heat conversion efficiency is calculated from input solar power and heat transferred to molten salt. The thermal resistance of molten salt and the maximum discharge pressure of molten salt pumps were taken into account as restrictions for the design of receivers. These restrictions require control of maximum receiver temperature and pressure drop in the molten salt channel. Based on the incident heat flux distribution formed with a 100 MWth class beam-down type solar concentration system, we proposed a shape of solar receiver that satisfies the requirements. The radiation to heat conversion efficiency of the designed receiver was calculated to be about 90%.     

Exergoeconomic evaluation of novel solid oxide fuel cell-integrated solar combined cycle with different solar integration modes

The active use of fuel cells and solar energy in power generation systems can help reduce fossil energy consumption and improve the work capacity of the system, which is an important means to achieve the goal of “carbon neutrality”. In this study, novel solid oxide fuel cell-integrated solar combined cycle systems with different solar integration modes are proposed and investigated. The thermodynamic, environmental and economic performances of new systems with different solar collector integration modes are evaluated using the exergoeconomic theory and environmental performance analysis. The results show that when the new system uses trough solar collectors to replace part of the heating load of the second-stage high-pressure economizer and high-pressure boiler drum, the system has the highest exergy efficiency (52.91%), the lowest unit exergoeconomic cost (0.102109 $/kWh) and the lowest specific CO₂ emission rate (475.27 g/kWh). When the operating conditions of the system remain unchanged, this solar energy integration mode has the highest solar-to-electricity efficiency (26.69%) as well as thermal-to-electricity efficiency (44.22%), and can obtain the best profit in the same operating life. The new system can attain maximum energy efficiency and optimal economic benefits by using this solar energy integration mode.