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为研究碳化行为对碱性胶凝材料干燥收缩的影响,以水玻璃或NaOH为碱组分,制备Φ27.5×50mm碱矿渣水泥石试件,并测量Φ27.5×1mm水泥石薄片在干缩条件与碳化条件下的直径变化率,以表征碱矿渣水泥石的干燥收缩与碳化收缩.结果表明:在(20±1)℃,相对湿度(70±5)%的条件下,以NaOH为碱组分的碱矿渣水泥石干燥收缩大于以水玻璃为碱组分的碱矿渣水泥石干燥收缩;碳化使硅酸盐水泥石的收缩增加,但未增加碱矿渣水泥石的收缩;碱当量适当提高有利于减小碱矿渣水泥石的干燥收缩与碳化收缩;以模数为1.2~1.5的水玻璃配制的碱矿渣水泥石干燥收缩与碳化收缩较小. 相似文献
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碳化对碱矿渣水泥石孔结构的影响 总被引:1,自引:1,他引:0
以水玻璃(WG)和氢氧化钠(NH)为碱组分配制碱矿渣水泥石(AASS),采用氮吸附方法分析了这两种碱矿渣水泥石碳化前后的孔结构,并与硅酸盐水泥石(PC)作对比.结果表明:碳化前,以水玻璃为碱组分的矿渣水泥石比表面积最大,平均孔径最小,累积孔体积最大,最可几孔径最小;以氢氧化钠为碱组分的碱矿渣水泥石比表面积最小,平均孔径最大,累积孔体积最小,最可几孔径最大;而硅酸盐水泥石的比表面积、平均孔径、累积孔体积及最可几孔径均介于上述两者之间.碳化后,上述3种水泥石平均孔径、最可几孔径均减小;碱矿渣水泥石比表面积增大,硅酸盐水泥石比表面积减小. 相似文献
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本文采用基准水泥、粉煤灰、矿渣粉、石灰石粉制备胶砂,研究了在不同水胶比及不同复合胶凝材料组成在掺加减水剂条件下胶砂的抗压强度、抗裂性.结果表明:石灰石粉掺量为20%以下时胶砂抗压强度无明显下降;复合胶凝材料体系参照GB/T 17671—1999:胶凝材料总量与标准砂质量之比固定为1:3,胶砂强度并不是水胶比越小,抗压强度越高,而是在0.40水胶比时强度最高,水胶比0.38、0.36时强度有所降低.石粉和矿渣粉双掺或粉煤灰+石粉+矿渣粉三掺效果好.建议0.40作为含石粉的复合胶凝材料在掺加减水剂条件下评价其胶砂强度的水胶比. 相似文献
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使用简易电阻测试法测试并计算碱矿渣混凝土不同深度的电阻率比,然后使用千分表法测试不同水胶比碱矿渣混凝土的收缩性能,并使用质量法测试同条件下碱矿渣混凝土的质量损失.建立了碱矿渣混凝土质量损失与干燥收缩之间的线性关系,探寻了碱矿渣混凝土电阻率比与质量损失之间的关系.结果表明:碱矿渣混凝土质量损失与干燥收缩之间的相关系数R2大于0.890 9,且拟合曲线的斜率与碱矿渣混凝土水胶比相关性较大;碱矿渣混凝土的电阻率比对其质量损失十分敏感,且呈正相关,因此可通过监测碱矿渣混凝土的电阻率比来评价其干燥收缩性能. 相似文献
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研究了水泥用量、水胶比、砂率对超硫酸盐水泥混凝土力学性能和抗碳化性能的影响,采用X射线衍射(XRD)、扫描电镜(SEM)、傅里叶红外光谱(FT-IR)测试方法对比分析了超硫酸盐水泥混凝土与矿渣水泥混凝土的微观形貌和水化产物的差异.结果 表明:当水泥用量为8%时,超硫酸盐水泥混凝土的力学性能较佳,但抗碳化性能较差;当水胶... 相似文献
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系统测试了磨细矿渣微粉水泥砂浆、粉煤灰水泥砂浆及矿渣 -粉煤灰复合水泥砂浆的碳化深度 ,并从浆体孔隙率、Ca(OH) 2 含量和砂浆抗渗性分析了矿渣提高粉煤灰水泥基材料抗碳化能力的细观和微观机理 ,提出磨细矿渣微粉和粉煤灰复合是提高粉煤灰水泥基材料抗碳化能力最经济有效的措施 相似文献
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《Construction and Building Materials》2007,21(7):1576-1582
Basic properties of blast furnace slag cement mortar and concrete are investigated by adding inorganic activators. The result of this research concludes that slag cement mixed with suitable activator agents such as lime, gypsum and limestone powder could accelerate the compressive strength and tighten pore structure at early age. The addition of activator into mortar and concrete containing slag cement produces superior properties, reduced shrinkage and less carbonation compared to mortar and concrete containing slag cement without the addition of activator. Consequently, there are possibilities for manufacturing blast furnace slag cement, which could compensate the weak properties at early curing age. When compared with ordinary Portland cement, this cement has superior characteristics for long curing age. 相似文献
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再生混凝土抗碳化性能的研究 总被引:4,自引:0,他引:4
系统研究了水胶比、水泥用量、再生粗集料性能、矿物掺和料、再生粗集料取代率、荷载水平等因素对再生混凝土碳化性能的影响.试验表明:再生混凝土的碳化性能不仅受新砂浆的影响,而且还受再生粗集料取代率及其自身强度的影响;矿物掺和料取代水泥使得再生混凝土的碳化深度增大;应力水平对再生混凝土碳化过程产生重大影响. 相似文献
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Cengiz Duran Atiş Cahit Bilim Özlem Çelik Okan Karahan 《Construction and Building Materials》2009,23(1):548-555
The development of new binders, as an alternative to traditional cement, by the alkaline activation of industrial by-products (i.e. ground granulated slag and fly ash) is an ongoing research topic in the scientific community [Puertas F, Amat T, Jimenez AF, Vazquez T. Mechanical and durable behaviour of alkaline cement mortars reinforced with polypropylene fibres. Cem Concr Res 2003;33(12): 2031–6]. The aim of this study was to investigate the feasibility of using and alkaline activated ground Turkish slag to produce a mortar without Portland cement (PC).Following the characterization of the slag, mortar specimens made with alkali-activated slag were prepared. Three different activators were used: liquid sodium silicate (LSS), sodium hydroxide (SH) and sodium carbonate (SC) at different sodium concentrations. Compressive and flexural tensile strength of alkali-activated slag mortar was measured at 7-days, 28-days and 3-months. Drying shrinkage of the mortar was measured up to 6-months. Setting times of the alkali-activated slag paste and PC paste were also measured.Setting times of LSS and SH activated slag pastes were found to be much slower than the setting time of PC paste. However, slag paste activated with SC showed similar setting properties to PC paste.LSS, SH and SC activated slag mortar developed 81, 29, and 36 MPa maximum compressive strengths, and 6.8, 3.8, and 5.3 MPa maximum flexural tensile strengths at 28-days. PC mortar developed 33 MPa compressive strength and 5.2 MPa flexural tensile strength. LSS and SH activated slag mortars were found to be more brittle than SC activated slag and PC mortars.Slag mortar made with LSS had a high drying shrinkage, up to six times that of PC mortar. Similarly, slag mortar made with SH had a shrinkage up to three times that of PC mortar. However, SC activated slag mortar had a lower or comparable shrinkage to PC mortar. Therefore, the use of SC as an activator for slag mortar is recommended, since it results in adequate strength, similar setting times to PC mortar and comparable or lower shrinkage. 相似文献
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研究了不同的外加剂对碱矿渣水泥砂浆干缩性能的影响。结果表明:掺减缩剂在一定程度上能够降低碱矿渣水泥砂浆干缩;而随掺引气剂、Na2SO4及Ca(OH)2均增大碱矿渣水泥砂浆的干缩。 相似文献
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