Synthesis of N,N＇-dimethyl-N,N＇-didecyl-3-oxa-diglycolamide for extraction of lanthanides

A novel extractant,N,N'-dimethyl-N,N'-didecyl-3-oxa-diglycolamide(DMDDDGA),was designed and synthesized for extraction of lanthanides in the nuclear fuel reprocessing.The extraction behaviors of Gd,Dy,Er and Ho from nitric acid solution were investigated using DMDDDGA in chloroform.The effects of nitric acid concentration,extractant concentration,and temperature on the extraction were investigated.The distribution ratio of lanthanides increases with concentrations of the extractant and nitric acid,but decreases with increasing temperature,which indicates that the extraction process is exothermic.FT-IR spectra indicated that the C=0 in DMDDDGA is coordinated with metal ion in the extracted species and the stoichiometries of lanthanides(Ⅲ)complex are Gd(NO_3)_3·3DMDDDGA,Dy(NO_3)_3·4DMDDDGA,Er(NO_3)_3·4DMDDDGA,and Ho(NO_3)_3·4DMDDDGA.     

Helium Plasma Damage of Low-k Carbon Doped Silica Film: the Effect of Si Dangling Bonds on the Dielectric Constant

The low-k carbon doped silica film has been modified by radio frequency helium plasma at 5 Pa pressure and 80 W power with subsequent XPS, FTIR and optical emission spec- troscopy analysis. XPS data indicate that helium ions have broken Si-C bonds, leading to Si-C scission with C（1s） lost seriously. The Si（2p）, O（ls）, peak obviously shifted to higher binding en- ergies, indicating an increasingly oxidized Si（2p）. FTIR data also show that the silanol formation increased with longer exposure time up to a week. Contrarily, the CHa stretch, Si-C stretching bond and the ratio of the Si-O-Si cage and Si-O-Si network peak sharply decreased upon exposure to helium plasma. The OES result indicates that monovalent helium ions in plasma play a key role in damaging carbon doped silica film. So it can be concluded that the monovalent helium ions besides VUV photons can break the weak Si-C bonds to create Si dangling bonds and free methyl radicals, and the latter easily reacts with O_2 from the atmosphere to generate CO_2 and H_2O. The bonds change is due to the Si dangling bonds combining with H_2O, thereby, increasing the dielectric constant k value.     

Improved preparation and chemical kinetics on fully automated synthesis of [18F]-THK523,a PET imaging probe for Tau pathologies

Extensive accumulation of neurofibrillary tangles(NFTs)consistently correlate with the degree of cognitive impairment and neuronal circuitry deterioration associated with Alzheimer's disease.However,no PET probe is currently available for selective detection of NFTs in the living human brain.[~(18)F]-THK523 was developed as a potential in vivo imaging probe for tau pathology.In this paper,we report a new protected precursor,2-((2-(4-((tert-butoxycarbonyl)amino)phenyl)quinolin-6-yl)oxy)ethyl 4-methylbenzenesulfonate(THK-7),instead of2-((2-(4-aminophenyl)quinolin-6-yl)oxy)ethyl 4-methylbenzenesulfonate(BF241),and an improved automated radiosynfhesis of[~(18)F]-THK523 and the study on chemical kinetics of the labeling reaction of[~(18)F]-THK523,with high-yield(70±5%,n=6,decay-corrected to end of bombardment),and high radiochemical purity(90%)and specific activity(2.5±0.5Ci/umol)from protected precursor on fully automated module at the end of radiosynthesis(45-55 min).The chemical kinetics for[~(18)F]-THK523 demonstrates that nucleophilic substitution can be carried out easily with protected precursor.     

Design of Controller for New EAST Fast Control Power Supply

The effectiveness of the magnetic confinement of plasma can be improved by elongat- ing the plasma cross-section in tokamak devices. But elongated plasma has vertical displacement instability, so a feedback control system is needed to restrain the plasma＇s vertical displacement. A fast control power supply is needed to excite the active feedback coils, which produces a magnetic field to control the plasma＇s displacement. With the development of EAST, the fast control power supply needs to keep on enhancing the fast response and output current. The structure of a new power supply is introduced in this paper. The method of multiple inverters paralleled with the current sharing reactor is presented to meet the need for large current and fast control. According to the design demands of the EAST fast control power supply, the adjuster of the current close loop is applied to the inverter, which can advance its ability to restrain the loop current in low frequency and DC output. The result of the experiment confirms the validity of the proposed scheme and control strategy.     

Using Xe as a heavy atom for phase determination of protein trichosanthin structure

Under gas pressures of 1–3 MPa, xenon can be bound to discrete sites in hydrophobic cavities of protein,so as to use Xe as a heavy atom for determining phases in protein crystallography. Using single anomalous scattering diffraction method, we demonstrate that an interpretable electron density map can be obtained for protein trichosanthin from a single xenon derivative. We found, for the first time, a pre-existing hydrophobic cavity just under the protein surface of trichosanthin.     

Nitrogen Fixation into HNO3 and HNO2 by Pulsed High Voltage Discharge

Plasma processing induced by discharge offers a unique way to activate nitrogen molecules. Direct nitrogen fixation into water can be realized through this approach. In this study, air or pure nitrogen gas was used as the major nitrogen source bubbled into the discharge reactor. When a discharge occurred, nitrogen was dissociated to active species to take part in the aqueous chemical process. HNO3 and HNO2 were produced. The nitrogen fixation process was influenced distinctly by the presence of hydroxyl radicals. During a discharge of 21 min, HNO3 was the main product and occupied 95% of the total nitrogen content in water. Its concentration was 1.36 × 10^-3 mol/L^-1 with bubbling air and was 1.53 × 10^-3 mol L^-1 with bubbling nitrogen, while the yield was 2.32 × 10^-3 mol J^-1S^-1 and 2.06 × 10^-8 mol J^-1S^-1, respectively.     

Electron Acoustic Solitary Waves in Magnetized Quantum Plasma with Relativistic Degenerated Electrons

A model for the nonlinear properties of obliquely propagating electron acoustic solitary waves in a two-electron populated relativistically quantum magnetized plasma is presented. By using the standard reductive perturbation technique, the Zakharov-Kuznetsov （ZK） equation is derived and this equation gives the solitary wave solution. It is observed that the relativistic effects, the ratio of the cold to hot electron unperturbed number density and the magnetic field normalized by electron cyclotron frequency significantly influence the solitary structures.     

Damping of Geodesic Acoustic Mode by Trapped Electrons

We study the Landau resonance between geodesic acoustic mode（GAM） and trapped electrons as a GAM’s collisionless damping. The assumption of ˉωde 〈〈ωbeis adopted.The damping rate induced by trapped electrons is found to be an increasing function of q. In low q range, circulating-ion-induced damping rate is larger than that induced by trapped electrons.As q increases, the latter becomes larger than the former. The reason is that trapped electrons’ resonant velocity is close to vtefrom the lower side, whiles circulating ions’ resonant velocity gets bigger further from vti. So the number of resonant trapped electrons increases, whiles the number of resonant circulating ions decreases. The amplitude of damping rate induced by trapped electrons in the edge plasma can be comparable to that induced by circulating ions in the low q range.Another phenomenon we found is that in the chosen range of, the damping caused by trapped electrons has a maximum value at point εq for different q. The reason is that as is close to q,trapped electorns’ resonant velocity is close to vte.     

Double-mini-β_y optics design in the SSRF storage ring

Shanghai Synchrotron Radiation Facility(SSRF) will implement its Phase II beamline project in the near future. Two long straight sections of the SSRF storage ring will be installed with dual-canted insertion devices in this project. Double-mini-βy optics in the long straight sections is designed and optimized in order to obtain high brightness and good machine performance. In this paper, the results are summarized. The Phase II project proposes a lattice upgrade of super-bend, and the double-mini-βy optics with this upgraded lattice is presented,too.     

Structure Design and Analysis of High-Voltage Power Supply for ECRH

In order to develop a high-voltage power supply （HVPS） with high quality parame- ters, not only its electrical circuit but also its structure should be studied in detail. In this paper, the structure design of the collector power supply for gyrotron is discussed first. Then the electri- cal field and potential simulations of its inain devices are analyzed. Finally, relevant calculations and conclusions are given.     

Degradation of Alizarin Red by Hybrid Gas-Liquid Dielectric Barrier Discharge

A system based on dielectric barrier discharge （DBD） with improved discharge sta- bility and homogeneity was used for the degradation of Alizarin Red （AR）. This special structure of the DBD system is characterized by the high voltage electrode, which is covered with a quartz tube and partially immersed in water, and by directly using the water as the ground electrode. A transition was realized from the filamentary mode for the conventional structure of the DBD to the semi-homogeneous mode for such a configuration of the plasma discharge. The spectra of plasma are dominated by N2 molecular lines in the ultraviolet-A radiation region. Plasma degra- dation of AR in this system exhibited pseudo-first-order reaction kinetics. The degradation rate of AR reached 95% or so after 14 min treatment under favorable conditions. Alkaline conditions are favorable for the degradation of AR. The increase of conductivity of the solution, input power and usage of oxygen bubbling could enhance AR degradation.     

New Current Control Method of DC Power Supply for Magnetic Perturbation Coils on J-TEXT

In order to advance the research on suppressing tearing modes and driving plasma rotation, a DC power supply （PS） system has been developed for dynamic resonant magnetic perturbation （DRMP） coils and applied in the J-TEXT experiment. To enrich experimental phe- nomena in the J-TEXT tokamak, applying the circulating current four-quadrant operation mode in the DRMP DC PS system is proposed. By using the circulating current four-quadrant oper- ation, DRMP coils can be smoothly controlled without the dead-time when the current polarity reverses. Essential circuit analysis, control optimization and simulation of desired scenarios have been performed for normal current. Relevant simulation and test results are also presented.     

Systematic study of dynamical dipole mode via the isospin-dependent Boltzmann-Uehling-Uhlenbeck model

Dynamical dipole mode in heavy-ion collisions has been studied by using an isospin-dependent BoltzmannUehling-Uhlenbeck(IBUU) model. We investigate the dependence of centroid energy and strength of the γspectrum on beam energy, N/Z ratio and mass asymmetry. The calculated yield and angular distribution of theγ-ray produced by dynamical dipole emission are consistent with the experimental data. The results show that the detailed study of dynamical dipole radiation can provide information on the isospin evolution of chargeasymmetric heavy-ion collisions around the normal nuclear density.     

Two-Dimensional Hybrid Model for High-Current Electron Beam Transport in a Dense Plasma

A two-dimensional hybrid code is developed to model the transport of a high-current electron beam in a dense plasma target. The beam electrons are treated as particles and described by particle-in-cell simulation including collisions with the target plasma particles. The background target plasma is assumed to be a stationary fluid with temperature variations. The return current and the self-generated electric and magnetic fields are obtained by combining Amp~re＇s law without the displacement current, the resistive Ohm＇s law and Faraday＇s law. The equations are solved in two-dimensional cylindrical geometry with rotational symmetry on a regular grid, with centered spatial differencing and first-order implicit time differencing. The algorithms implemented in the code are described, and a numerical experiment is performed for an electron beam with Maxwellian distribution ejected into a uniform deuterium-tritium plasma target.     

Numerical Simulation of Dual-Channel Communication of Column Plasma Antenna Excited by a Surface Wave

This paper focuses on the application of plasma as wireless antenna. In order to reveal the radiation characteristics of column plasma antenna, we chose the finite-difference time- domain （FDTD） numerical analysis method to simulate radiation impedance and efficiencies of each channel for a few sets of plasma densities and plasma collision frequencies. Simulation results demonstrate that a plasma antenna shares similar characteristics with a metallic antenna in radiation impedance and efficiency of each channel when an appropriate setting is adopted. Unlike a metallic antenna, a plasma antenna is capable of realizing such functions as dynamic reconfiguration, digital control and dual-channel communication. Thus it is possible to carry out dual-channel communication by plasma antenna, indicating a new path for modern intelligent communication.     

Experimental Investigation of the Properties of an Acoustic Wave Induced by Laser Ablation of a Solid Target in Water-Confined Plasma Propulsion

Acoustic waves generated in nanosecond pulsed-laser ablation of a solid target in both air and water-confined environments were measured experimentally. It was found that the amplitude of the acoustic wave tended to decrease with an increase in water thickness. The waves were analyzed by means of fast Fourier transform. It was shown that there are several frequency components in the acoustic waves with the dominant frequency shifting from high frequency to low frequency as the thickness of the water layer increases. Furthermore, strong acoustic pressure led to enhancement of the coupling of the laser energy to the target in laser plasma propulsion.     

PIXE analysis of proto-porcelain excavated from Tingziqiao kiln site of Deqing （China）

Particle induced X-ray Emission(PIXE) was used to analyze the proto-porcelain excavated from Tingziqiao kiln site of Warring States(475–221 BC) in Deqing County of Zhejiang Province, China. It was found that the porcelain body and glaze differ from each other in recipes. The porcelain clay of high silicon and low aluminum might be used to make the body of proto-porcelain. Lime and plant or wood ashes might be added into the glaze of the proto-porcelain. Cluster analysis was done to reveal the compositional relationship between the proto-porcelain samples.     

Calculation of Photo-Ionisation Cross Sections and Radiative Recombination Rate Coefficients for CO and CO+ Molecules

A method based upon the weighted total cross section （WTCS） theory is proposed to calculate the photo-ionisation cross sections and the radiative recombination rate coefficients between the fundamental level of CO and the main electronic states of its corresponding ion. Total photo-ionisation cross sections and radiative recombination rate coefficients are determined from the calculation of elementary vibrational photo-ionisation cross sections. Transitions be- tween CO＋（X, A and B） and CO（X） are considered. Total photo-ionisation cross sections and recombination coefficients are computed in the temperature interval 500-15000 K.     

Decontamination of 2-Chloroethyl Ethyl Sulfide by Pulsed Corona Plasma

Decontamination of 2-chloroethyl ethyl sulfide （2-CEES, CH_3CH_2SCH_2CH_2C1） by pulsed corona plasma was investigated. The results show that 212.6 mg/m^3 of 2-CEES, with the gas flow rate of 2 m^3/h, can be decontaminated to 0.09 mg/m^3. According to the variation of the inlet and outlet concentration of 2-CEES vapor with retention time, it is found that the reaction of 2-CEES in a pulsed corona plasma system follows the first order reaction, with the reaction rate constant of 0.463 s^-1. The decontamination mechanism is discussed based on an analysis of the dissociation energy of chemical bonds and decontamination products. The C-S bond adjacent to the C1 atom will be destroyed firstly to form CH3CH2S. and .CH2CH2C1 radicals. CH3CH2S. can be decomposed to .C_2H_5 and .S..S can be oxidized to SO_2, while .C_2H_5 can be finally oxidized to CO_2 and H_2O. The C-Cl bond in the .CH_2CH_2C1 radical can be destroyed to form .CH_2CH_2. and .C1, which can be mineralized to CO_2, H_2O and HCl. The H atom in the .CH_2CH_2C1 radical can also be substituted by -C1 to form CHCl_2-CHCl_2.