Technological Assessment of Chestnut Flour Doughs Regarding to Doughs from Other Commercial Flours and Formulations

The technological assessment of chestnut flour doughs was studied using Mixolab® apparatus, establishing a comparison with gluten (soft, hard and whole wheat) and gluten-free (rice and yellow corn) flour doughs as well as corn starch pastrymaking and breadmaking formulations. This equipment measures the torque in function of temperature and time, firstly at 30 °C (mixing curve) and secondly the mixing during heating (4 °C/min up to 90 °C) and cooling (4 °C/min up to 50 °C) steps (complete curve). Different hydrations of doughs ranging from 41.4% to 68.5% (flour basis) were necessary to reach the torque of 1.10?±?0.07 Nm. Parameters of mixing such as water absorption, development time, stability and mixing tolerance index were obtained. Parameters of heating and cooling cycle related to weakening of proteins, gelatinization starch, amylase activity and starch retrogradation as well as range of gelatinization temperatures were also determined. Chestnut flour showed suitable parameters in the mixing stage such as arrival time (1.93?±?0.1 min), stability (12.1?±?0.4 min) and departure time (14.0?±?0.3 min). In the heating cycle, chestnut flour exhibited close behaviour to soft wheat flour with cooking stability of 1.12?±?0.01 min and seems to be suitable for pastrymaking products. Finally, in the cooling cycle the behaviour revealed that products of this flour can present problems of staling and crumbs firmness due to high values (2.88 Nm) of C5 parameter.     

DIFFERENTIAL SCANNING CALORIMETRY OF STARCH12

At high water-to-starch (2:1) ratios a single endotherm was obtained for starch gelatinization. As the water-to-starch ratio was decreased the endotherm area decreased and the peak developed a trailing shoulder. At high water-to-starch ratios birefringence is lost over a temperature range of about 7°C. That narrow range increases to about 30°C at a low water-to-starch ratio. Starch and flour gave essentially the same endotherm initiation temperatures. In low-water systems the second DSC peak is much smaller with starch than with flour. It appears that in a starch system, water migrates during gelatinization. In dough, gluten limits that migration. As the level of sucrose was increased in a dough, the transition temperature increased and the gelatinization temperature range decreased. At the levels found in bread doughs both sugar and salt increase starch gelatinization temperatures.     

Mixing properties and rheological characteristics of dough used to make potato‐cereal soft wraps

We have studied mixing, rheology and stability of potato‐cereal flour doughs. These were prepared using samples of two varieties of cooked and cold‐stored potatoes. Dependent on variety a minimum duration of 24–48 h cold‐storage was required. Dough mixing torque plateau was inversely related to potato water content. This should be <79 g/100 g. It was also necessary to have a stable dough mixing torque plateau of >2 Nm at a specific total mechanical energy input of 18–22 kJ kg^?1. The resting temperature of the dough was also inversely related to its strength (plateau elastic modulus at time zero). Target dough strength should be about 25 kPa in a bob‐cup. Above 15 °C it decreased as a function of time and within 1 h it became too sticky for commercial processing. At 4 °C the dough remained stable. Sufficient potato starch retrogradation is a pre‐requisite to make optimal potato‐cereal flour dough for commercial processing.     

Effect of flour extraction rate and baking process on vitamin B1 and B2 contents and antioxidant activity of ginger-based products

The effect of flour extraction rate and baking on thiamine (vitamin B₁) and riboflavin (vitamin B₂) content and antioxidant capacity of traditional ginger cake was studied and then compared to white wheat bread. Ginger cake was formulated either with whole-grain (100% extraction rate) or with brown (92% extraction rate) rye flour and baked at 180 °C for 18 min. The antioxidant capacity was evaluated in terms of radical scavenging activity against peroxyl (ROO·) and superoxide anion radicals (O ₂ ^·? ). Thiamine content in rye doughs (F-100% and F-92%) was found to be 38% lower when compared to wheat dough. In contrast, whole-grain and brown rye doughs exhibited an almost fourfold higher riboflavin content than wheat dough. Rye dough baking led to reductions in thiamine (from 53 to 65%) and riboflavin (from 69 to 71%) contents. Likewise, thiamine and riboflavin contents in wheat dough were also reduced (56 and 10%, respectively) after baking; however, ginger cake with whole-grain rye flour exhibited significantly higher thiamine and riboflavin contents. Rye doughs and ginger cakes showed higher scavenging activities against ROO· radicals when compared to that of wheat dough and bread. Thus, baking significantly enhanced ROO· scavenging properties of ginger cakes while only a slight increase was observed in wheat bread. In contrary, baking gave rise to a decrease in SOD-like activity both in ginger cake or wheat bread. Our findings suggest that formulation with whole-grain rye flour can potentially increase B₁ and B₂ vitamin contents as well as the ROO· scavenging capacity of traditional ginger cake.     

Rheology of Gluten-Free Doughs from Blends of Chestnut and Rice Flours

Gluten-free flours blends using chestnut flour (CF) and rice flour (RF) were assayed in order to determine mixing and rheological properties of doughs at 30 °C as well as the thermal behaviour employing heating–cooling temperature steps. CF with different mean particle size (commercial, CCF: 169 μm and low particle size, CF1: 77 μm samples) was employed and blended with RF (46 μm) at several ratios (%) (CCF/RF: 90/10, 80/20, 70/30, 60/40, 50/50; CF1/RF: 25/75, 15/85, 5/95). Doughs from CCF, CF1 and RF flours were employed as reference systems. The rheological characterization of doughs conducted on the rheometer was performed by shear, oscillatory and creep-recovery assays. Rheological properties were significantly modified by flour ratio and by CF particle size. Creep-recovery curves showed that CCF/RF (70/30) and CF1/RF (25/75) improved the doughs elasticity by 41.1 % and 87.5 % compared with CCF and CF1, respectively. Cross, power and Burgers models were used to describe the flow curves, mechanical spectra and creep-recovery behaviour, respectively, of doughs. A mixing rule successfully reproduced the experimental data and fitting parameters of applied models as function of each flour fraction in the blends, except for oscillatory data.     

Separation of bread wheat flours into starch and gluten fractions: effect of water temperature alone or in combination with water to flour ratio

Two different commercial bread wheat flours (BF‐I, 65% extraction and BF‐V, 86% extraction) were separated into gluten and starch milk by making a dough, allowing some time for maturation, dispersing the dough in water and wet sieving/washing. The effect of using of warm water (20–45 °C) for dough making and washing on separation was studied for BF‐I flour at 640 g kg^?1 water to flour ratio of and 300 s maturation time, and the separation was found to improve with increase in temperature. The combined effects of water temperature (20–50 °C) and water to flour ratio (640–780 g kg^?1 for BF‐I and 620–870 g kg^?1 for BF‐V) were studied at 600 s maturation time. The quantities and dry matter contents of the gluten fraction and starch milk were measured; a sample of starch milk was centrifuged to obtain decantate, tailing and prime starch fractions, and the dry matter contents of each were determined. All the dried samples were also analysed for protein content, and the fractional recoveries of dry matter and protein in the gluten fraction, prime starch, tailings and decantate were calculated. The results indicated the optimum point for BF‐I flour to be the combination of optimum farinograph water absorption and 40 °C. BF‐V showed very poor separation behaviour within the ranges studied. At the optimum farinograph water absorption the use of warm water for dough making and 20 °C water for washing steps was also tried, but no significant improvement over the 20 °C results was obtained. © 2002 Society of Chemical Industry     

The effects of low mixing temperature on dough rheology and bread properties

In this research, the effects of a low mixing temperature on dough rheology and the quality of bread were investigated. In the experiments, strong flour samples (Type 550), 1.5% salt, 3% of yeast and 1% additive mixture were used and dough samples were mixed at 17 °C (low temperature), 23 °C (control) and 30 °C (high temperature). Five different periods (0, 30, 60, 90 and 120 min) were applied at the bulk fermentation stage. At the final proofing stage, the dough was fermented until it reached a constant height. It was determined that almost every bread from dough samples mixed at 17 °C resulted in not only the highest bread volume and bread weight, but also the best texture, elasticity and crumb structure. The results of dough samples mixed at 23 °C were worse than those of dough samples mixed at 17 °C. The worst results were obtained from dough samples mixed at 30 °C (high temperature). As a result, it may be concluded that the quality of bread from dough samples mixed at low temperature (17 °C) is superior to those from dough samples mixed at the higher temperatures. Besides these findings, it may also be stated that prolonging the period of bulk fermentation in dough samples mixed at 17 °C positively develops baking performances.     

Experiments on dough rheology to improve screening of bread wheat cultivars

The bread‐making potential of flour may be roughly estimated by dough rheology, especially its tolerance to over‐mixing as determined with the farinograph. The objective of this study was to identify the relative effects of experimental conditions likely to affect dough mixing stability: mixer speed, temperature, salt, yeast and bread additives such as ascorbic acid and preservatives. The addition of 1–2% salt or ascorbic acid (50 mg kg^?1 flour) improved dough mixing stability and counteracted the negative effect of bread preservatives. Mixing salted dough at slow speed (63 rpm) and 25 °C might be a more realistic bread‐making procedure for performing dough rheology assays with equipment such as the farinograph, compared to official methods (only flour and water, no salt; 30 °C). Amongst five bread wheat cultivars, differences existed in dough strengthening response to both salt and ascorbic acid, a property that may find application in wheat breeding and screening.     

Rheological properties of commercial chestnut flour doughs with different gums

Rheology of chestnut flour (CF) doughs with arabic gum (AG), carboxymethyl cellulose (CMC), guar gum (GG) and tragacanth gum (TG) at different concentrations (up to 2.0%) were determined at 30 °C using a controlled stress rheometer. The mixing characteristics at 30 °C were achieved using Mixolab^® apparatus. Shear (0.01–10 s^?1), oscillatory (1–100 rad s^?1 at 0.1% strain), creep‐recovery (50 Pa for 60 s) and temperature sweep (30–100 °C) tests were performed. Rheological properties were significantly modified by gum added. Apparent viscosity of CF doughs, storage and loss moduli increased at content of AG (above 0.5%), CMC (at 1.0%), GG (above 1.5%) and TG (at 1.0%). Flow curves and mechanical spectra were fitted using Cross model and power models, respectively. The gelatinisation temperatures increased with gums. The same pasting trend was noticed using Mixolab^®. Creep‐recovery data, fitted by Burgers model, showed that elasticity of CF doughs improved with GG.     

Dynamic rheology of wheat flour dough. II. Assessment of dough strength and bread‐making quality

Controlled stress rheometry revealed that differences in wheat flour dough strengths could be observed by means of dynamic rheological measurements in the region of higher stress amplitude (ie >100 Pa). At lower stress amplitude (τ_o) the values of elastic modulus G′ for weak doughs were higher than those for strong doughs, but they decreased substantially beyond 100 Pa stress amplitude (τ_o), such that the G′ values for strong doughs crossed over the G′ values for weak doughs. Beyond a critical value of stress amplitude (ie 100 Pa), true differences in dough strengths could be seen on the basis of their elastic characteristics, because at large deformations protein–protein interactions played a more dominant role in the rheological behaviour of flour doughs. Dynamic rheological analysis demonstrated a very weak inverse relationship (R² = 0.16) between the G′ values of flour doughs and loaf volume data for 12 wheat cultivars of diverse bread‐making performance. However, the G′ values of glutens showed significant positive relationships with bread‐making performance, explaining 73% of the variation in loaf volume. © 2002 Society of Chemical Industry     

Effect of Fat Replacement by Inulin on Textural and Structural Properties of Short Dough Biscuits

The aim of this study was to evaluate the effects of inulin as fat replacer on short dough biscuits and their corresponding doughs. A control formulation, with no replacement, and four formulations in which 10, 20, 30, and 40 % of shortening was replaced by inulin were studied. In the dough, shortening was observed surrounding flour components. At higher fat replacement levels, flour was more available for hydration leading to significant (P?<?0.05) harder doughs: from 2.76 (0.12)?N in 10 % fat-replaced biscuits to 5.81 (1.56)?N in 30 % fat-replaced ones. Biscuit structure was more continuous than dough structure. A continuous fat layer coated the matrix surface, where starch granules were embedded. In general, weight loss during baking and water activity decreased significantly (P?<?0.05) as fat replacement increased. Biscuit dimensions and aeration decreased when fat replacement increased, e.g., width gain was +1.20 mm in 10 % fat-replaced biscuits and only +0.32 mm in 40 % fat-replaced ones. Panelist found biscuits with 20 % of fat replacement slightly harder than control biscuits. It can be concluded that shortening may be partially replaced, up to 20 %, with inulin. These low fat biscuits are similar than the control biscuits, and they can have additional health benefits derived from inulin presence.     

EFFECTS OF MOISTURE,SUCROSE, NaCl,AND ARABINOXYLAN ON RELAXATION IN WHEAT DOUGH AS MEASURED BY DMTA

The effects of sucrose, NaCl, and arabinoxylan on the α-relaxation of wheat doughs with different water contents were investigated using Dynamic Mechanical Thermal Analysis (DMTA). DMTA measurements were made at the heating rate of 2°C/min from at least 30°C below the observed onset of the α-relaxation (glass transition) to at least 30°C above the transition. The glass transition temperature, T_g , was taken from the onset temperature of the decrease in storage modulus (G′). The frequencies used were 0.1, 1, and 5 Hz and amplitude was 16 μm. The storage modulus, G′, showed α-relaxation in all doughs with added ingredients. Added ingredients decreased the glass transition temperature of dough. The T_g of doughs with different ingredients decreased with increasing water content of doughs over the whole a_w range used (0.113–0.753). Also, the T_g increased with increasing frequency.     

Effects of ingredients on the oxidation of linoleic acid by lipoxygenase in bread doughs

Flour and water doughs containing 1-¹⁴C-linoleic acid (18:2) and various ingredients were prepared to study the oxidation of linoleic acid by lipoxygenase in bread doughs. Lipids were extracted, treated with diazomethane, and ¹⁴C-labelled fatty acid methyl esters separated by thin-layer chromatography. Radioactivity was determined in silica gel bands containing unoxidised 18:2, hydroperoxy acids (L₁), hydroxy acids (L₂), hydroxyepoxy acids (L₃) and trihydroxy acids (L₄). Minor components detected by autoradiography were present mainly in L₃ and L₄. Recoveries of total radioactivity were always > 95%. Untreated flour-water dough was mixed aerobically for ?4 min, rested, and the lipids extracted after 10 min total dough time. Yields of ¹⁴C products were unoxidised 18:2 = 28.6 μmol, L₄ = 93.9 μmol/100 g dry flour. Similar yields were obtained from ClO₂-treated flour, both after 10 min and 60 min dough time. Salt, salt + yeast, or salt + yeast + ascorbic acid in the dough did not reduce 18:2 oxidation significantly, but increased L₃ at the expense of L₄. Soya flour preparations inhibited linoleic acid oxidation by 25–44%, but pure soya lipoxygenase had no effect at all. Heat treatment reduced the inhibitory effect of soya flour. Accessible thiol groups were not essential for lipoxygenase activity or for the reduction of L₁ to L₂ since adding cysteine or N-ethyl maleimide had negligible effects on the 18:2 oxidation products. Most of the flour carotenoids (xanthophylls) were bleached by wheat enzymes in non supplemented doughs, and all were bleached in doughs supplemented with soya flour. ¹⁴C-labelled triglyceride was not oxidised except in doughs containing soya flour mixed in air (1.5% oxidation) or oxygen (3 % oxidation). Soya flour contains lipoxygenase isoenzymes (principally lipoxygenase-2) which oxidise linoleate in triglycerides. This isoenzyme is evidently not present in wheat.     

Effect of sourdough processing and baking on the content of enniatins and beauvericin in wheat and rye bread

The occurrence of the emerging mycotoxins enniatins (ENNs) and beauvericin (BEA) has been reported in Fusarium-infected cereals. To study the effect of sourdough processing and baking on ENN B, ENN B1, and BEA concentrations, a recently developed stable isotope dilution assay for these mycotoxins was used. After milling of wheat and rye grains naturally contaminated with ENN B and ENN B1, approximately 70–82 % of the two ENNs were found in the bran fraction and the rest remained in flour. BEA was added to flour before sourdough fermentation. In an experiment on a microscale, dough was fermented for 24 h at 30 or 40 °C, which reduced part of the ENNs and BEA in particular at 40 °C. On a standard scale, mixing, resting, and proofing of the bread dough resulted in 13–19 % reduction of the ENNs compared with flour, but in no significant change of BEA. The final baking at 200 °C for 25 min led to a further decrease of the ENNs and BEA, ranging from 9 to 28 % compared with fermented dough. In case of rye sourdough bread, greater reductions of ENNs were found in crust than in crumb. For both wheat and rye flours, overall 25–41 % of ENN B, ENN B1, and BEA were reduced during the whole sourdough bread-making process.     

Effect of β-Glucan Concentrate on the Water Uptake,Rheological and Textural Properties of Wheat Flour Dough

The effects of the addition of β-glucan concentrate (2.5–10 g/100 g flour) and water (58–70 mL/100 g flour) on the rheological and textural properties of wheat flour doughs were studied. Various empirical (farinograph, extensograph, dough inflation, and dough stickiness) and fundamental rheological tests (oscillatory and creep-recovery) were employed to investigate composite dough structure and an attempt was made to correlate the data obtained from different instrumental measurements. The water absorption increased with the addition of β-glucan concentrate into wheat flour. An increase in mixing time and stability were recorded upon addition of β-glucan concentrate (≤ 5 g/100 g flour), and the extensibility decreased at similar condition. The composite dough exhibited predominating solid-like behavior. The mechanical strength, dough stickiness, the peak dough inflation pressure decreased with increasing water content but those parameters increased with β-glucan concentrate incorporation within the studied concentration range. Creep-recovery tests for 5 g β-glucan concentrate/100 g flour doughs recorded less resistance to deformation with an increase in water level and data were well described by the Burger model. Thermal scanning of doughs revealed that the protein denaturation peak was significantly influenced by water content, and the values were ranged between 110 and 124°C. Significant relationships between empirical and fundamental rheological testing methods were found.     

Effect of temperature and starch concentration on the creep/recovery behaviour of the grape molasses: modelling with ANN, ANFIS and response surface methodology

In this study, the effect of starch concentration (5, 7.5 and 10 %) and temperature (60, 70 and 80 °C) on the creep and recovery behaviour of grape molasses was investigated. Adaptive neuro-fuzzy inference system (ANFIS) and artificial neural network (ANN) models were established for the prediction of the compliance values (J(t)) based on temperature, starch concentration and time of the creep or recovery phases. The root mean square error, mean absolute error and R ² values were used for the comparison of the models which showed that the ANFIS model performed better than the ANN model for the desired purpose. The Burger model fitted the J(t) versus time data with R ² values ranging from 0.987 to 0.999. Response surface methodology (RSM) was performed to investigate the dependency of the creep (G ₀ , G ₁ , n ₀ and n ₁ ) and recovery (J _KV , B, C, J _max , J _∞ and  % recovery) parameters to temperature and starch concentration. As a result of this study, it was observed that deformation of the grape molasses samples increased with decrease in starch concentration and increase in temperature. The gel strength (S) values of the samples were also calculated and modelled by RSM. As increase in starch concentration caused an increase in S value, there was an inverse proportion between the temperature and S value.     

Effect of processing conditions on oligosaccharide profile of wheat sourdoughs

Oligosaccharide profiles in yeasted and unyeasted wheat sourdoughs inoculated withLactobacillus plantarum have been investigated. A surface response design (central composite design structure) has been used to study the effect of flour extraction rate (0.54, 1.11 and 1.68% ash content), dough yield (160, 200, and 240) and fermentation temperature (25, 30 and 35°C). Unfermented and 20 h fermented doughs were evaluated. Multivariate data analysis was used to analyse the data. Unfermented doughs contained variable amounts of glucose, fructose and maltose, but oligosaccharides with a degree of polymerization (DP) over 3 were not detected. The greatest levels of monosaccharides corresponded to yeasted sourdoughs from brown flours prepared at 30 and 35°C. Factor analysis of fermented sourdoughs showed three factors explaining 83% variability of the data. The first factor (43% variance explained) was directly related to oligosaccharides with a DP above 5, and inversely related to maltose content. Factor two (27%) was related to DP 3 and DP 4, and the third factor (16%) to glucose and fructose levels. The greatest quantities of maltose corresponded to white unyeasted sourdoughs, and the highest amounts of monosaccharides corresponded to brown unyeasted samples. On the other hand, yeasted sourdoughs contained higher amounts of oligosaccharides with DP 3 to DP 5. Samples of white flour, low consistency, yeasted and fermented at ≧30°C showed the biggest content of DP 6 and DP 7.     

Wet separation of wheat flours into starch and gluten fractions: the combined effects of water to flour ratio–dough maturation time and the effects of flour aging and ascorbic acid addition

The process of making a dough, allowing time for maturation, dispersing the dough in water and wet sieving/washing to obtain a protein fraction and starch milk was studied using response surface methodology by changing the water to flour ratio in dough making (400–710 g kg^?1), maturation time (45–660 s) and the type of flour. Two grades of bread wheat flour and durum clear flour were studied. The effects of aging at ambient temperature for up to 29 days and the addition of ascorbic acid at 100 or 500 mg kg^?1 flour on separation behaviour were also studied for freshly milled high‐grade (65% extraction) bread wheat flours at constant maturation time, 600 s, and at optimum farinograph water absorption value. The quantities and dry matter contents of the protein fraction and starch milk were measured; a sample of starch milk was centrifuged to obtain decantate, tailings and prime starch fractions, and the dry matter contents of each were determined. All the dried samples were also analysed for protein content. The fractional recoveries of dry matter and protein in the protein fraction, prime starch, tailings and decantate were calculated for each experiment. The acid values of flour oils were also determined on some aged flour samples. The results indicated superior separation characteristics in high‐grade wheat flour compared with lower‐grade flours. The water to flour ratio was more influential than maturation time within the range studied. Contrary to the initial expectation, no statistically significant effect of flour aging was observed in the studies with no additive, and ascorbic acid addition was not found to improve the wet separation behaviour, the separation behaviour becoming even worse at the 100 mg kg^?1 level. Acid value showed a slight increase with time. © 2002 Society of Chemical Industry     

THE EFFECT OF HEAT AND SHEAR ON THE VISCOELASTIC PROPERTIES OF SOY FLOUR DOUGH

This paper is concerned with the effect of heat and shear on the rheological properties of defatted soy dispersions and doughs of 30 to 60% flour by weight. Capillary and rotary rheometers (Rheometrics Mechanical Spectrometer) were used to heat doughs up to 75° C and shear them simultaneously. In one series of experiments using a modified Instron capillary rheometer the doughs were heated to several different temperatures and then sheared. The linear viscoelastic properties of the dough which were determined by means of a plate-plate rheometer were then compared to the fresh dough and those of a heated but nonsheared dough. In another experiment a cone-and-plate rheometer was used to heat and shear the dough. The linear viscoelastic response of the dough was used to monitor any changes as it was heated and sheared. It was observed that only in the higher moisture dispersions (i.e., moisture contents greater than 50%) were there any signs of an increase in rheological properties which might be associated with “cooking”. It was concluded that cooking of soy flour doughs most likely does not involve the formation of a permanent network formed by covalent chemical bonds. Hence, in extrusion cooking processes involving soy flour doughs, it may not be necessary to treat the rheological properties of the dough as a thermosetting system.     

Effect of Maize Resistant Starch and Transglutaminase: A Study of Fundamental and Empirical Rheology Properties of Pan Bread Dough

The effect of maize resistant starch (MRS) and transglutaminase (TG) on rheological and thermal properties of pan bread dough was studied. The MRS was added as an alternative to increase the fiber ingestion while TG supplies the gluten dilution, catalyzing protein bonds. A second order central composite design (2²) with three central and four star points was applied, and the results were compared to those of pan bread dough prepared without MRS and TG, as control. The presence of MRS and TG significantly (P?n index (degree of strain hardening). Only starch gelatinization enthalpy significantly changed (P?相似文献