Comparison of crumb microstructure from pound cakes baked in a microwave or conventional oven

Imaging, light microscopy and scanning electron microscopy were used to compare the microstructure of crumbs from pound cakes baked in a microwave or conventional oven. The microwave baking conditions for pound cake (240 W, 5 min) were established in previous research, conventional baked pound cakes were obtained using a swing oven at 180 °C for 40 min. Statistical differences in total cell, cell/cm² and mean cell area (P?0.05) were observed in the image analysis. Cells from microwaved pound cake crumbs were 20% larger. However, factor shape was 0.81 for both microwave and conventionally baked crumbs, and crumbs from both oven types were similar in appearance. Light microscopy revealed birefringence in crumbs from both types of pound cakes. Scanning electron microscopy revealed that the conventionally baked product had a greater amount of protein matrix however; the matrix structure of the crumb was comparable between microwave-baked and conventionally baked pound cakes. In conclusion, our results suggest that the unique aspects of pound cake dough, including its high content of fat, sugar and moisture, make it well suited to microwave baking.     

Relative importance of moisture migration and amylopectin retrogradation for pound cake crumb firming

Moisture migration largely impacts cake crumb firmness during storage at ambient temperature. To study the importance of phenomena other than crumb to crust moisture migration and to exclude moisture and temperature gradients during baking, crustless cakes were baked using an electrical resistance oven (ERO). Cake crumb firming was evaluated by texture analysis. First, ERO cakes with properties similar to those baked conventionally were produced. Cake batter moisture content (MC) was adjusted to ensure complete starch gelatinisation in the baking process. In cakes baked conventionally, most of the increase in crumb firmness during storage was caused by moisture migration. Proton nuclear magnetic resonance (¹H NMR) showed that the population containing protons of crystalline starch grew during cake storage. These and differential scanning calorimetry (DSC) data pointed to only limited amylopectin retrogradation. The limited increase in amylopectin retrogradation during cake storage cannot solely account for the significant firming of ERO cakes and, hence, other phenomena are involved in cake firming.     

Resistant Starch Content and Structural Changes in Maize (Zea mays) Tortillas During Storage

Storage of maize products such as tortillas may cause starch retrogradation and lead to resistant starch (RS) formation. This study was carried out to determine if storage of maize tortillas under refrigerated conditions enhanced RS content and/or modified RS structure. Improved Costeño variety maize grain was nixtamalized and processed into tortillas which were stored for five and ten days at 5°C. Total resistant starch (TRS) and retrograded resistant starch (RRS or RS3) contents were determined on raw and nixtamalized maize grain and tortillas stored for zero, five and ten days. Differential scanning calorimetry (DSC), X‐ray diffraction (XRD) and near‐infrared (NIR) spectroscopy were use to evaluate structural changes in retrograded resistant starch isolated from each sample type. Total starch content was 67 ± 1.5% for all samples, TRS ranged from 3.3% in the raw grain at 7.2% in tortillas stored for ten days, while RRS starch content ranged from 0% in the raw grain to 3.2% in tortillas stored for ten days. DSC showed endothermic transitions corresponding to amylopectin and amylose retrogradation, at 31.9 and 139.7°C in RRS from tortillas stored for five days, and at 47.9 and 146°C in RRS from tortillas stored for ten days. These values agreed with the higher total RS content recorded after prolonged storage. XRD revealed a starch crystallinity of 13.7% in tortillas stored for five days and 15.3% in those stored for ten days. NIR spectroscopy analysis showed evidence of structural changes in polymeric order that were more pronounced in RRS of tortillas stored for ten days, due to increase in crystalline region.     

A Study on Degree of Starch Gelatinization in Cakes Baked in Three Different Ovens

The main objective of the study was to determine the effects of different baking ovens and different cake formulations on the degree of starch gelatinization during cake baking. Baking was performed in microwave, infrared–microwave combination, and conventional ovens. Starch gelatinization levels of fat free, 25% fat, and 25% Simplesse™-containing cake samples were examined using differential scanning calorimeter (DSC) and rapid visco analyzer (RVA). Both DSC and RVA results showed that increasing baking time increased gelatinization level for all baking types significantly. It was also found that the effect of fat content on starch gelatinization was different depending on the type of baking. Addition of fat reduced the degree of starch gelatinization in conventional baking. However, fat enhanced the gelatinization in microwave and infrared–microwave combination ovens. Usage of Simplesse™ as a fat replacer decreased the starch gelatinization in all types of baking significantly. There was insufficient starch gelatinization in microwave-baked cakes in which the degree of gelatinization ranged from 55% to 78% depending on formulation. On the other hand, it ranged from 85% to 93% in conventionally baked cakes. Combining infrared with microwaves increased degree of starch gelatinization (70–90%).     

Effect of Retrograded Waxy Corn Starch on Bread Staling

Waxy corn starch pastes (10%) were stored at 5 °C for up to 35 days, and the powder specimens of retrograded starches thus obtained were added to wheat flour for bread baking at a level of 5%. The effect of retrograded starch on the staling of bread was determined. The loaf which contained retrograded waxy corn starch, which was prepared by storing the 10% paste at 5 °C for 7 days, showed an increase in specific volume and the results of the sensory evaluation showed that it was very acceptable. During the storage of bread, the increase in firmness and decrease in degree of gelatinization were suppressed by adding retrograded waxy corn starch. The moisture content of bread crumbs did not relate to firmness. Added retrograded waxy corn starch decreased the final viscosity of flour. The crystalline region of retrograded waxy corn starch used for bread baking included longer chains from amylopectin which in raw starch occurred in the amorphous region.     

Comparison of pound cake baked in a two cycle microwave-toaster oven and in conventional oven

The industrial and domestic use of microwaves has increased considerably over the past few decades. New researches about the interaction of different ingredients with microwave energy, has provided insight that is helping to improve the quality of microwave-baked products. The aim of this work was to determine the best potency and baking time conditions for pound cake and apply the image analysis methodology to analyze the structure of pound cake baked in a two cycle microwave-toaster oven compared with a conventionally baked. Weight loss, density, water activity, moisture, luminosity and seven parameters of Image Analysis were measured as baking quality parameters. Optimal baking conditions for the two-cycle microwave-toaster oven were obtained using surface response analysis. The best baking conditions resulted in a low power for the first cycle (204 W for 120 s), a high power for the second cycle (937 W for 70 s), and a toasting time of 5:30 min at 200 °C. Image analysis showed a 7% reduction in the crumb cell number of the cake baked with microwaves as compared to the conventional. The two cycle microwave-toaster oven generated a product with a higher volume (11%) and higher luminosity (2%) than the conventional process. Both of them were equally preferred by consumers, scoring 4.6 (I like very much) in a hedonic sensory test.     

Effects of gamma irradiation on starch digestibility of rice with different resistant starch content

Three rice cultivars (RS3M, RS4H and RS5L) differing in resistant starch contents but similar in genetic background were chosen to study the effects of gamma irradiation on starch physicochemical properties and digestibility. Irradiation increases the resistant starch content in all the three cultivars and in a dose‐dependent manner in rice with low‐resistant starch content (RS5L). Irradiation decreases apparent amylose content and gelatinisation temperature and changed the starch granule structure, while increasing V‐type crystallinity. Starch enzymatic hydrolysis rate was reduced following irradiation, and the effect of irradiation on reducing starch digestibility was negatively correlated with resistant starch content. Treatment with gamma irradiation has therefore a potential for increasing resistant starch content and producing low digestibility of starch in common rice.     

Production of Resistant Starch by Extrusion Cooking of Acid-Modified Normal-Maize Starch

ABSTRACT:  The objective of this study was to utilize extrusion cooking and hydrothermal treatment to produce resistant starch (RS) as an economical alternative to a batch-cooking process. A hydrothermal treatment (110 °C, 3 d) of batch-cooked and extruded starch samples facilitated propagation of heat-stable starch crystallites and increased the RS contents from 2.1% to 7.7% up to 17.4% determined using AOAC Method 991.43 for total dietary fiber. When starch samples were batch cooked and hydrothermally treated at a moisture content below 70%, acid-modified normal-maize starch (AMMS) produced a greater RS content than did native normal-maize starch (NMS). This was attributed to the partially hydrolyzed, smaller molecules in the AMMS, which had greater mobility and freedom than the larger molecules in the NMS. The RS contents of the batch-cooked and extruded AMMS products after the hydrothermal treatment were similar. A freezing treatment of the AMMS samples at −20 °C prior to the hydrothermal treatment did not increase the RS content. The DSC thermograms and the X-ray diffractograms showed that retrograded amylose and crystalline starch–lipid complex, which had melting temperatures above 100 °C, accounted for the RS contents.     

微波处理对板栗淀粉结晶度的影响

研究了微波辐射对板栗淀粉的结晶度及α度的影响。结果表明,微波辐射可有效影响板栗淀粉乳的结晶度和α度变化,在微波辐射功率一定的条件下,板栗淀粉乳的浓度不同,经微波辐射后的样品结晶度和α度变化也不同,板栗淀粉的浓度与经微波辐射后的样品α度呈反相关,与经微波辐射后样品的X-射线衍图谱的结晶峰面积及样品的结晶度呈正相关。     

Evaluation of four types of resistant starch in muffin baking performance and relationship with batter rheology

The influence of wheat flour partial replacement with different types of resistant starch (RS) in muffin batter rheological properties and in baked muffin height, volume and number of air bubbles was investigated. The type of RS affected the above-described properties differently. In comparison to the control batter (without RS), replacement with RS type 3 (Novelose 330 and C*Actistar) increased viscosity and viscoelasticity, at both 20 and 80 °C. On the contrary, RS type 2 (Hi-maize 260 and Novelose 240) decreased them. These differences in viscosity and viscoelasticity were related to different baking performance. The RS3 type muffins had higher height, volume and number of air bubbles than the RS2 type muffins. An increase in viscosity and elasticity of the raw batter and during the heating process favours bubble retention and stability, thus favours baking performance. However, despite the improvement provided by the RS type 3, the baking performance was still lower than in the control muffins. One feature that may contribute to the baking differences is the delay in all the RS batters in the starch gelatinization temperature.     

Effect of gelatinisation on slowly digestible starch and resistant starch of heat-moisture treated and chemically modified canna starches

The effects of gelatinisation on slowly digestible (SDS) and resistant starch (RS) of native and modified canna starches were investigated. Starch slurries (10% w/w) were gelatinised at 100 °C for 5, 10, 20 and 40 min using a rapid visco analyzer (RVA). Significant change in the degree of gelatinisation (DG) values of all starch samples was observed during the initial 10 min of gelatinisation; after that the DG values increased gradually with gelatinisation time. The RS contents in all gelatinised starches decreased with increasing gelatinisation time, while the SDS values fluctuated. Chemical modification affected DG values as well as RS/SDS contents. The RS contents in 10% (w/w) acetylated, hydroxypropylated, octenyl succinylated and cross-linked canna starches gelatinised at 100 °C for 40 min were 26.6%, 32.0%, 45.3% and 19.8%, respectively, which were higher than that of the native starch (12.4%). Canna starch modified by crosslinking had the highest SDS content when gelatinised for 20-40 min. Modification of canna starch by heat-moisture treatment resulted in a lower content of RS for all treated samples. However, the Vt-HMT25 (canna starch containing moisture content of 25% during heat treatment) when gelatinised for 5-20 min contained a higher amount of SDS, compared to unmodified starch. The most effective modification method for RS and SDS formation was octenyl succinylation, where the sum of RS and SDS approached that of Novelose260.     

The effect of par‐baking and frozen storage time on the quality of cup cake

The effects of frozen storage and initial baking time of par‐baked cake on baking loss, volume, moisture, colour and textural properties of cake obtained after thawing and rebaking were investigated. Cakes, par‐baked at 175 °C for 15, 20 and 25 min, were stored at ?18 °C for 3, 6 and 9 months. After storage, par‐baked cakes were thawed and rebaked at 175 °C for 10, 15 and 20 min. Baking loss, moisture content, L and +b colour values, firmness, gumminess and chewiness of the resulting full‐baked cakes were significantly affected by both par‐baking and frozen storage time, while specific volume, cohesiveness, springiness and resilience values were significantly affected by frozen storage time. The increase in the time of frozen storage of the par‐baked cake leads to a decrease in the quality of the rebaked cake, namely an increase of baking loss and cake crumb firmness, and a loss in the moisture content and specific volume. Moisture of cake crumb, L and +b colour values, firmness, gumminess and chewiness significantly increased as the par‐baking time increased. However, regarding baking loss, specific volume, moisture content and textural properties, 3‐month intermediate storage at ?18 °C and 20‐min initial baking time gave the best result among the cakes produced by using the two‐step baking procedure.     

Effect of debranching and heat‐moisture treatment on the properties of Thai rice flours

High and low amylose Thai rice flours (KC and ML, respectively) were used in this work, to increase the resistant starch (RS) content in the flour. Pullulanase debranching followed by heat‐moisture treatment (DHMT) altered the pasting properties, which increased the shear stability to the flours. The gelatinisation temperature determined by DSC was increased and the more retrogradation occurred in treated flour compared to the native flour. The SEM observation showed that the treatment did not change the morphology of the granules in both flours. The slowly digestible starch (SDS) content in DHMT KC was higher than in the native KC. The RS content in the treated ML flour was increased to 18.31% from 11.59% in native flour. These concluded that the treatment affected the digestibility, while maintaining the granular structure.     

Starch Structure and Digestibility of Rice High in Resistant Starch

Starch digestibility and starch structure of a high‐resistant starch (RS) rice (RS111) was compared to that of a wild rice type (R7954). RS111 exhibited high RS content and incomplete starch hydrolysis in both cooked rice and retrograded rice flour. High RS rice RS111 had a higher λ_max of absorbance and blue value of iodine‐binding starch complex and contained a higher percentage of intermediate chains of amylopectin than R/954. X‐ray diffraction pattern of RS isolated from cooked high RS rice displayed a mixture of B‐ and V‐type that was more resistant to starch hydrolysis by alpha‐amylase. Resistant starch in RS111 is composed mainly of linear amylose and some low‐molecular‐weight amylopectin.     

食物中抗性淀粉的研究进展

在查阅的近十几年对淀粉在人肠道内消化吸收的文献基础上,综述了食物中抗性淀粉的研究进展,抗性淀粉是指不能在健康正常人小肠中消化吸收的淀粉及其降解物食中物存在抗性淀粉可分为３类,物理包埋淀粉（ＲＳＩ）抗性淀粉颗粒（ＲＳ２）和老化淀粉（ＲＳ３）其检测一般采用体外肠道模拟酶解法,影响食物中抗性淀粉形成的因素主要有淀粉自身的理化性质,食物中的其它成分,处理方式和工艺以及食物形态等,抗性淀粉属于人体无法消化吸     

Influence of microwave heating and time on functional,pasting and thermal properties of cassava starch

The effect microwaving power and time on the functional, pasting and thermal properties of cassava starch was investigated. Cassava starch at a moisture content of 30% was microwaved at 600 and 700 W for 0, 5, 15, 30 and 60 s following a preliminary study. Microwaving power and time did not alter the crystalline pattern of the starch, but there were obvious changes in the starch morphology. Starch colour was significantly (P ≤ 0.05) altered by microwave heating, with the total colour difference increasing from 4.85 to 43.01. Microwave treatment increased starch gelatinisation temperatures but decreased the swelling power, water absorption capacity and the relative crystallinity. These changes were influenced by microwave heating power and time. The results further revealed that the peak viscosity (3714.00–1947.00 cP) and setback ratio (1.70–1.49) decreased with increasing microwave heating time. However, breakdown viscosity (322.67–897.63 cP) and pasting temperature (1947.00–3714.00 °C) increased.     

Structural development of sucrose‐sweetened and sucrose‐free sponge cakes during baking

The influence of sucrose, wheat starch and sorbitol upon the heat‐ and mass‐exchanging processes forming the structure of sponge cake was studied. Under the influence of wheat starch and sorbitol the structure of the sucrose‐free sponge cake was formed at more uniform total moisture release. This process was done at lower temperatures and smoother change of the sponge cake height with respect to the sucrose‐sweetened sponge cake. The porous and steady structure of both cakes was finally formed at identical time – between 18^th and 19^th minute, at the applied conditions for baking of each batter (metal pan with diameter 15.4 cm and depth 6.2 cm containing 300 g of batter and placed in an electric oven “Rahovetz – 02”, Bulgaria for 30 min at 180°C). The water‐losses at the end of baking (10.30% and 10.40% for the sucrose‐sweetened cake and sucrose‐free cake, respectively) and the final temperatures reached in the crumb central layers (96.6°C and 96.3°C for the sucrose‐sweetened cake and sucrose‐free cake, respectively) during baking of both samples were not statistically different. The addition of wheat starch and sorbitol in sucrose‐free sponge cake lead to the statistically different values for the porosity (76.15% and 72.98%) and the volume (1014.17 cm³ and 984.25 cm³) of the sucrose‐sweetened and sucrose‐free sponge cakes, respectively. As a result, the sucrose‐free sponge cake formed during baking had a more homogeneous and finer microstructure with respect to that of the sucrose‐sweetened one.     

Effect of Baking Conditions on Properties of Starch Isolated from Bread Crumbs: Pasting Properties,Iodine Complexing Ability,and X-ray Patterns

In order to understand starch changes induced by baking process at different locations of a slice of sandwich bread, namely the top, center, and bottom locations, starch was isolated from crumbs baked at two heating rates ( 6.31 and 4.67 °C/min) and evaluated for their pasting properties, gelatinization parameters, and iodine complexing ability. Results showed that starch isolated from the bottom and the center crumbs baked at higher heating rate presented the significant higher final viscosity and higher setback than that isolated from crumbs baked at lower heating rate. Thermal analysis showed that starch isolated from the center crumb of the bread slice presented the lower enthalpy value of gelatinization, confirming that these samples underwent higher heat-moisture treatment during the baking process. After equilibration at 0.97 a_w, the exposure to iodine vapor changed the X-ray diffraction intensity of starch samples. Polarized light microscopy showed that heating affects starch granule morphology due to the higher starch chain mobility and the higher granular swelling when breads were baked at lower heating rate.     

Optimization of microwave baking of model layer cakes

 Response surface methodology was used to optimize the formulation of microwave-baked cakes. The independent variables were water content, emulsifier content baking time, oven power, shortening content and starch type. The quality factors evaluated were specific gravity of batter and volume index, uniformity index and tenderness of the crumb. Constraints for quality factors were obtained by conventional baking of American Association of Cereal Chemists high-ratio cake formulation. Multiple contour plots showed the optimum region for various water and shortening combinations at different emulsifier, time and power levels. Cakes formulated with wheat starch, containing 0.3% polysorbate 60, 133.7% water and 45.2% shortening (flour substitute basis), baked for 6 min at 100% power yielded acceptable cakes that can compete with conventionally baked cakes. Rice and corn cakes had lower quality than conventionally baked high-ratio cakes. Power was found to be the most efficient independent variable affecting all the dependent variables. Received: 26 August 1999 / Revised version: 11 October 1999     

Resistant starch and thermal,morphological and textural properties of heat‐moisture treated rice starches with high‐, medium‐ and low‐amylose content

This study investigated the effects of heat‐moisture treatment (HMT) on the resistant starch content and thermal, morphological, and textural properties of rice starches with high‐, medium‐ and low‐amylose content. The starches were adjusted to 15, 20 and 25% moisture levels and heated at 110°C for 1 h. The HMT increased the resistant starch content in all of the rice starches. HMT increased the onset temperature and the gelatinisation temperature range (T_finish–T_onset) and decreased the enthalpy of gelatinisation of rice starches with different amylose contents. This reduction increased with the increase in the moisture content of HMT. The morphology of rice starch granules was altered with the HMT; the granules presented more agglomerated surface. The HMT affected the textural parameters of rice starches; the high‐ and low‐amylose rice starches subjected to 15 and 20% HMT possessed higher gel hardness.